This work is devoted to describe the possibilities of mechanical activations of admixtures used in concrete. Then, the verification options of grind fly ash, both from brown and black coal, from the classical as well as fluidized combustion and examination their impact on physical and mechanical properties of concrete, especially on long-term development to old age 180 days. Further attention is paid to assessing the impact of the use of mechanically activated fly ash on hydration heat evolution and the associated volume changes in the age of 1 to 90 days. In this work are presented the results of basic technological tests on concretes using admixtures, especially fly ash.

Indiana University-Purdue University Indianapolis (IUPUI) / INTRODUCTION: New sealers have been placed on the market to improve the property of a hermetic seal within the root canal and decrease the gap between the gutta-percha and dentin wall. Differences in the adhesive properties of endodontic sealers may be expected because their interaction with either dentin or gutta-percha may vary with their chemical composition. No specific interaction either with dentin or gutta-percha is expected from the setting reaction of calcium hydroxide based sealers and the epoxy-based sealers. The setting reaction of the zinc oxide-eugenol mixtures is a chelation reaction occurring with the zinc ion of the zinc oxide. Development and maintenance of the seal are essential to optimize the long-term success rate of root canal treatment. An ideal endodontic sealer should, in part, adhere firmly both to dentin and gutta-percha. PURPOSE: The purpose of this study is to evaluate the sealing properties of EndoSequence BC sealer TM ,a bioceramic sealer, and Roth’s sealer using gutta-percha with warm vertical condensation and using the single cone technique with the EndoSequence BC sealer only. The goal is to see if there is a significant difference in microleakage between teeth sealed with the bioceramic sealer and teeth sealed with Roth’s sealer. MATERIALS & METHODS: Eighty-five single-rooted maxillary anterior teeth were used for this study. Endodontic cleaning and shaping of each root canal system was accomplished using K-type hand files and NiTi Rotary files. Group A consisted of twenty-seven anterior teeth, which were obturated using EndoSequence BC sealer and gutta-percha with System B and Obtura. Another twenty-seven anterior teeth, Group B, was obturated using Roth’s sealer and gutta-percha with System B and Obtura. A final group, Group C with 27 teeth was obturated using the single cone technique by means of a single gutta-percha point with Endosequence BC sealer. Two teeth were used as a positive control group, and two other teeth as a negative control group. A microbial leakage apparatus was constructed using a similar two-chamber method described by Torabinejad et al. E. faecalis ATCC 29212 was the test bacteria which was used in this study to determine microleakage The outcome of interest (bacterial turbidity) and time-to-leakage (in days), will be determined for each of the samples. Survival analysis will be used to compare the two groups, with a Kaplan-Meier plot to visualize the results and a nonparametric log-rank test for the group comparison RESULTS: No microleakage was observed in the negative control or group B. Microleakage was observed in all the positive control. Group A and C had a significantly higher proportion of samples with microleakage than group B (p<0.0001), but group A and C were not significantly different from each other (p=0.50). Time to microleakage was also significantly lower in group A and C than group B (p<0.0001), but group A and C were not significantly different from each other (p=0.37). CONCLUSION: In conclusion, using E. faecalis as our test bacteria, the microleakage of canals obturated with gutta percha and Roth's sealer was significantly less than canals obturated with gutta percha and EndoSequence BC sealer.

Indiana University-Purdue University Indianapolis (IUPUI) / Objective: Zinc-reinforced glass ionomer restorative material (ZRGIC) has been proposed as an improved restorative material. The study compared the mechanical properties of a ZRGIC restorative material (ChemFil Rock, (Dentsply)), with three commercially available glass ionomers (GICs); Fuji IX GP Extra (GC America), Ketac Molar (3M ESPE) and EQUIA Fil (GC America). A resin composite, Premise (Kerr), was included as a control group except for fracture toughness. Methods: Fracture toughness (KIC) testing was done according to ISO 13586, using single edge notched-beam specimens (n=10), loaded until failure in a three-point bending test device. Specimens (n=9) for the hardness, roughness and abrasive wear testing were made by mixing and inserting the restorative materials into individual stainless steel molds followed by flattening and polishing. Knoop microhardness (KHN) was performed (25 g, 30 s),on pre-determined areas of the polished surfaces. For toothbrushing wear resistance and roughness, specimens were brushed in an automated brushing machine (200 g) with a suspension of dentifrice and water (1:1, w/v) for 20,000 strokes. Specimen surfaces were scanned in an optical profilometer before and after brushing to obtain surface roughness (Ra) and mean height (surface) loss using image subtraction and dedicated software. Data were analyzed using Wilcoxon Rank Sum tests (α=0.05). Results: ChemFil Rock had the highest change in surface roughness (Ra)(0.79±0.14; p<0.001) and the lowest microhardness (KHN) values (52.39±2.67; p<0.05) among all GICs. Its wear resistance was comparable to other GICs (p>0.05). ChemFil Rock had lower fracture toughness (0.99±0.07, KIC) compared to Equia Fil (p<0.01) and higher compared to the other GICs (p<0.01). Conclusion: The new ZRGIC restorative material showed intermediate fracture toughness, high change in surface roughness, and low microhardness compared to three other commercial GICs. All materials were supplied by respective manufacturers.

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The purpose of this research was to investigate the effects of reclaimed asphalt pavement (RAP) content and cement content on the strength and durability of recycled aggregate base materials. Specifically, the unconfined compressive strength (UCS) and final dielectric value in the Tube Suction Test (TST) were measured in a full-factorial experimental design including five RAP contents, five cement contents, and three replicate specimens of each possible treatment. Specimen mixtures consisted of 0, 25, 50, 75, or 100 percent RAP and 0.0, 0.5, 1.0, 1.5, or 2.0 percent Type I/II Portland cement. Both the RAP and base materials were sampled from the I-84 pavement reconstruction project performed in Weber Canyon near Morgan, Utah, during the summers of 2004 and 2005. The laboratory testing procedures consisted of material characterizations, specimen preparation, and subjection of the specimens to strength and durability testing, and the data were evaluated using analysis of variance (ANOVA) testing. Both the RAP and base materials included in this research were determined to be non-plastic, and the AASHTO and Unified soil classifications for the RAP material were determined to be A-1-a and SM (well-graded sand with gravel), respectively, and for the base material they were A-1-a and SW-SM (well-graded sand with silt and gravel), respectively. The optimum moisture contents (OMCs) for the blended materials were between 5.6 and 6.6 percent, and maximum dry density (MDD) values were between 129.7 and 135.5 lb/ft3. In both cases, decreasing values were associated with increasing RAP contents. The results of the ANOVA performed on the UCS data indicate that UCS decreases from 425 to 208 psi as RAP content increases from 0 to 100 percent and increases from 63 to 564 psi as cement content increases from 0.0 to 2.0 percent. Similarly, the final dielectric value decreases from 14.9 to 6.1 as RAP content increases from 0 to 100 percent and decreases from 14.0 to 5.8 as cement content increases from 0.0 to 2.0 percent. With design criteria requiring 7-day UCS values between 300 and 400 psi and final dielectric values less than 10 in the TST, the results of this research suggest that milling plans should be utilized to achieve RAP contents in the range of 50 to 75 percent, and a cement content of 1.0 percent should be specified for this material. Cement contents less than 1.0 percent are not sufficient to stabilize the material, and greater cement contents may cause cracking. Because control of the actual cement content in the field depends on the contractor's equipment and skill, inspection protocols should be implemented during construction to ensure high-quality work. Additional recommendations are associated with the construction process. The specimens prepared in this research were compacted to relative densities of 100 percent using modified Proctor energy. Therefore, field compaction levels must approach these density values if the same material properties are to be achieved. In addition, all specimens tested in this study were cured at 100 percent relative humidity. Following compaction in the field, cement-treated layers should be moistened frequently during the first few days after construction or promptly sealed with a prime coat or wearing surface to ensure that the cement continues to hydrate. Variability in RAP and cement contents should also be minimized to achieve consistent material properties.

Frost heave is a primary mechanism of pavement distress in cold regions. The distress exhibited is dependent on the frost susceptibility of the soil within the depth of frost penetration, the availability of subsurface water, and the duration of freezing surface temperatures. Cement stabilization is one technique used to mitigate the effects of frost heave. The tube suction test (TST) is one possible method for determining the frost susceptibility of soils in the laboratory. The purpose of this research was to assess the utility of the TST for identifying non-frost-susceptible (NFS) materials stabilized with cement. This research investigated two aggregate base materials from Alaska that have exhibited negligible frost susceptibility in the field. The unconfined compressive strength (UCS), final dielectric value in the TST, and frost heave at three levels of cement treatment and in the untreated condition were evaluated for both materials. The data collected in this research indicate that, for the two known NFS materials included in this study, the TST is a good indicator of frost heave behavior. The total heave of the untreated materials was approximately 0.15 in. at the conclusion of the 10-day freezing period, which classifies these materials as NFS according to the U.S Army Corp of Engineers. Both materials had final dielectric values of less than 10 in the TST, indicating a superior moisture susceptibility rating. The results of this research suggest that the TST should be considered for identifying NFS materials, including those stabilized with cement. Additional testing should be performed on known NFS materials stabilized with cement and other additives to further assess the validity of using the TST to differentiate between frost-susceptible and NFS materials. Consistent with previous studies, this research indicates that, once a sufficient amount of cement has been added to significantly reduce frost heave, additional cement has only a marginal effect on further reduction. Therefore, to avoid unnecessary expense in construction, the minimum cement content required for preventing frost heave should be identified through laboratory testing and specified by the engineer. In this work, UCS values ranging between 200 psi and 400 psi after a 7-day cure were typically associated with this minimum cement content. Because the scope of this research is limited to two aggregate base materials, further testing is also necessary to validate this finding.

Full-depth reclamation (FDR) is an increasingly common technique that is used to rehabilitate flexible pavements. Implementation of FDR on rehabilitation projects produces several desirable benefits. However, these benefits are not fully realized due to the fact that state department of transportation specifications typically limit the reclaimed asphalt pavement (RAP) content of pavement base material to 50 percent. The objective of this research was to evaluate the effects of RAP content, cement content, temperature, curing time, curing condition, and moisture state on the strength, stiffness, and deformation characteristics of cement-treated base (CTB) mixtures containing high percentages of RAP.For this research, one aggregate base material and one RAP material were used for all samples. RAP content ranged from 0 to 100 percent in increments of 25 percent, and low, medium, and high cement levels corresponding to 7-day unconfined compressive strength (UCS) values of 200, 400, and 600 psi, respectively, were selected for testing. Moisture-density, UCS, resilient modulus, and permanent deformation tests were performed for various combinations of factors, and several statistical analyses were utilized to evaluate the results of the UCS, resilient modulus, and permanent deformation testing.The results of this work show that CTB containing RAP can be made to achieve 7-day UCS values approaching 600 psi regardless of RAP content. With regards to stiffness, the data collected in this study indicate that the resilient modulus of CTB containing RAP is affected by temperature in the range from 72 to 140°F for the low cement level. Permanent deformation of CTB containing RAP is significantly affected by RAP content and cement level at the test temperature of 140°F. At the low cement level, temperature is also a significant variable. As the 7-day UCS reaches approximately 400 psi, permanent deformation is reduced to negligible quantities. The results of this research indicate that the inverse relationship observed between permanent deformation and 7-day UCS is statistically significant.Given that the principle conclusion from this work is that CTB with high RAP contents can perform satisfactorily as a base material when a sufficient amount of cement is applied, agencies currently specifying limits on the percentage of RAP that can be used as a part of reclaimed base material in the FDR process should reevaluate their policies and specifications with the goal of allowing the use of high RAP contents where appropriate.

Hydrated cement paste (HCP), which is present in various cement-based materials, includes a number of constituents with distinct nano-structures. The elastic properties of the HCP crystals are calculated using molecular dynamics (MD) methods. The accuracy of estimated values is verified by comparing them with the results from experimental tests and other atomistic simulation methods. The outcome of MD simulations is then extended to predict the elastic properties of the C-S-H gel by rescaling the values calculated for the individual crystals. To take into account the contribution of porosity, a detailed microporomechanics study is conducted on low- and high-density types of C-S-H. The obtained results are verified by comparing the rescaled values with the predictions from nanoindentation tests. Moreover, the mechanical behavior of the HCP crystals is examined under uniaxial tensile strains. From the stress-strain curves obtained in the three orthogonal directions, elastic and plastic responses of the HCP crystals are investigated. A comprehensive chemical bond and structural damage analysis is also performed to characterize the failure mechanisms of the HCP crystals under high tensile strains. The outcome of this study provides detailed information about the nonlinear behavior, plastic deformation, and structural failure of the HCP phases and similar atomic structures.

Limestone is one of the main components of cement production. Limestone has been quarried in Skövde, Sweden, since the end of 19th century and Cementa AB has been operating the quarry since 1973. Aside from limestone, there are also Alum shale of Cambrian age, mudstones as well as bentonite layers of Ordovician age present in the quarry.  The production of cement evidently is important for Sweden’s infrastructure, and the quarry in Skövde is one of few known locations in the country with limestone with the right composition. Therefore, it is important to increase the knowledge regarding the character of the limestone to make accurate predictions for the future regarding the cement production. The geological knowledge of the area is already extensive; however, the aim of this thesis is to expand this knowledge further by constructing a 3D geological model. The data which has been used to construct the model are field observations, drill core data, chemical data, high-resolution pictures (photogrammetry) and resistivity measurements (field and samples). The resistivity measurements were done using the multiple gradient array, and apparent resistivity was inverted using Res2Dinv. The geological modelling was done using Leapfrog geo (© Seequent Systems, Incorporated). Two models have been proposed as a result of this project; one where high-grade limestone of lesser quality and whitestone has been regrouped with two other units (A) and one including all units (B). In the most recent drilling campaign, the nomenclature used to distinguish the units has been modified and does not differentiate high-grade limestone of lesser quality and whitestone from the rest. This affects coherence of the model and for this reason two models have been built. Both models show roughly flat lying units in the area of interest. Both low-grade limestone and lower waste stone units have consistent thickness in both models. The major difference between the models is how the high-grade limestone unit is modelled as a consequence of the additional units in model B. The result from the resistivity measurements shows unexpectedly low values, when compared to values from the literature as well as the measurements on hand samples from the quarry. The reason for these low values is still unclear, and therefore resistivity data has been used with caution. Considering this, it appears that resistivity measurements is not a suitable technique to characterize the subsurface in this particular area.  The models produced in this project provides information regarding thickness and extent of the units and overlying soil. As such, the new knowledge can be used to plan future prospecting campaigns, make projections, and estimates within current mining permits and evaluate how future mining can be conducted. / Kalksten är huvudkomponenten när det kommer till cementproduktion, vilken också behöver ha en specifik kemi för att vara lämplig att tillverka cement av. Kalksten av denna specifika kvalité har brutits i Skövde, Sverige, sedan slutet av 1800-talet. Cementproduktionen startade dock 1924 och Cementa köpte upp gruvan och fabriken 1973. I brottet finns förutom kalksten även alunskiffer, slamsten och bentonitlager. Vidare finns det två olika kvalitéer på kalkstenen, en med högt kalciumoxidvärde och en med lägre kalciumoxidvärde. Totalt representerar de formationer som finns i gruvan en 50 miljoner år lång historia av sedimentation. Cement utgör en grundläggande del för Sveriges infrastruktur, och brottet i Skövde är en av få platser i landet med en kalksten som har rätt kemi. Därmed är det viktigt att utöka kunskapen gällande karaktären på kalkstenslagren i och vid brottet för att kunna göra mer korrekta uppskattningar om Sveriges framtida cementproduktion. I dagsläget är kunskapen om geologin i och kring gruvan omfattande tack vare bland annat tidigare prospekteringskampanjer. Syftet med detta arbete är utöka den geologiska kunskapen ytterligare genom att konstruera en geologisk 3D modell. Denna geologiska 3D modell har skapats av data såsom borrhålsdata, resistivitetsmätningar samt drönarbilder för att bättre karakterisera de olika geologiska formationerna. På grund av att indelningen av de geologiska enheterna har varit olika mellan de tidigare prospekteringskampanjerna har två 3D modeller med olika upplösning skapats i stället för en. Modelleringen har fokuserats på ett område nordväst om nuvarande brytområde. Båda modellerna har sub-horisontella geologiska enheter inom intresseområdet. Vidare har modellerna liknande tjocklek och utbredning på enheterna i sin övre del, men skiljer sig åt längre ner. Detta på grund av att den ena modeller har flera enheter, vilket således även påverkar närliggande enheter. Dessa två modeller har utökat den geologiska kunskapen om området, till exempel de geologiska enheternas mäktighet och utbredning, samt hur mäktigt jordtäcket i området är. Denna nya kunskap kan användas för att planera och estimera hur brytning kan ske i framtiden. Det är dock viktigt att poängtera att det är modeller som skapats, vilka är antaganden av verkligheten.

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