No description available.

Thesis (M.S. in geology)--Washington State University, May 2010. / Title from PDF title page (viewed on June 23, 2010). "School of Earth and Environmental Science." Includes bibliographical references (p. 87-96).

Thesis (M.Sc.)--Acadia University, 2001. / Includes bibliographical references (leaves 151-156). Also available on the Internet via the World Wide Web.

Thesis (M.S.)--University of Nevada, Reno, 2006. / "December, 2006." Includes bibliographical references (leaves 55-60). Online version available on the World Wide Web.

No description available.

Alteration of ultramafic rocks is ubiquitous to their occurrence near the surface. Primary mantle minerals like olivine and pyroxenes are unstable at low pressure and temperatures and undergo hydration (serpentinization), carbonation and weathering reactions forming hydrated and carbonated minerals. Employing a variety of analytical techniques including: electron microprobe, X-Ray diffraction, major and trace element geochemistry, Mg isotopes geochemistry and geochemical modelling this work seeks to contrain conditions ofa lteration and trace changes in composition of peridotite during alteration. In Wadi Fins in the southeast of Oman peridotites outcrop at the bottom of a canyon overlaid by a thick sequence 1.5 km of Cretaceous to Eocene shallow oceanic limestones and dolostones. The peridotites exhibit different types of alteration. While the common view is that serpentinization and carbonation of peridotites is isochemical this is not the case for alteration in Wadi Fins. Peridotites tens of meters below the unconformity are characterized by a striking grid of carbonate and serpentine veins. The calcite veins and relatively low MgO/SiO2 suggest that the peridotites reacted with a hydrous fluid derived from interaction of seawater with the overlying sediments composed of limestones with minor amounts of chert. This is further affirmed by average δ13C, δ18O and 87Sr/86Sr from carbonate veins in the peridotites that are similar to values of the sediments. Clumped isotope thermometry on calcite veins in peridotite establish that they formed at 25–60 ℃. Reaction path modeling of carbonate- quartz derived fluids with peridotite reproduces the observed mineral assemblage composed of carbonate and serpentine with similar Mg and MgO/SiO2 at high water to rock ratios, with carbon, H2O and silica added to the rock by the reacting fluid. Close to the unconformity the altered peridotites are characterized by concentric alteration halos recording variable fO2 and fS2. The partially serpentinized cores preserved primary minerals and record extremely low oxygen fugacities (fO2~10^(-75) bars). Two alteration zones are present evident from the alteration color. These zones exhibit nonisochemical alteration characterized by intergrowths of stevensite/lizardite. The alteration zones record progressively higher (fO2) recorded by Ni-rich sulfides and iron oxides/hydroxides. The alteration zones lost 20-30% of their initial magnesium content, together with mobilization of iron over short distances from inner green zones into outer red zones, where iron was reprecipitated in goethite intermixed with silicates due to higher fO2. The loss of magnesium in this peridotites motivated the final section of work. Mg isotopic compositions of partially serpentinized harzburgites and dunites in Oman are identical to average mantle and bulk silicate Earth (δ26Mg=-0.25‰) while altered periodites from Wadi Fins get heavier with increasing alteration. Analyses of peridotite alteration products including samples from Wadi Fins and carbonates from Wadi Tayin were used to show that isochemical serpentinization at low W/R does not fractionate Mg isotopes. I propose a mechanism that with increasing W/R and co-precipitation of Mg-carbonates and serpentine leads to carbonates with light isotopic compositions (Magnesite δ26Mg =-3.3 and dolomite δ26Mg=-1.91) and serpentine with heavy compositions (up to δ26Mg =-0.96 in serpentine veins). This complementary enrichment-depletion and the finite 14C ages of the carbonates suggest that serpentinization is ongoing along carbonation in Oman at ambient temperatures. Rates of calcite precipitation in travertines inferred from Δ26Mgcal-fl suggest that travertine formation in Oman sequesters a total of 10^6-10^7 kg CO2/yr.

Thesis (Ph. D.)--University of Oregon, 2003. / Typescript. Includes vita and abstract. Includes bibliographical references (leaves 211-235). Also available for download via the World Wide Web; free to University of Oregon users.

Thesis (M.S. in Geology)--Vanderbilt University, Aug. 2006. / Title from title screen. Includes bibliographical references.

Multiple generations of normal faults dismembered, tilted, and exposed thicknesses of up to 15 km of the upper crust in portions of central and southern Arizona. This extension, variable in distribution and magnitude, was superimposed on the axis of the Laramide magmatic arc and dismembers many porphyry copper systems, allowing for detailed study of vertical and lateral zonation of alteration around these centers. This study examines tilted fault blocks containing portions of porphyry systems across Arizona, focusing on hydrothermal alteration deep and distal in these systems (3+ km paleodepth) to develop a more complete understanding of porphyry occurrences as larger geochemical systems. This study focuses on Na-Ca and coarse muscovite alteration in the roots of Laramide porphyry copper systems across Arizona (Ajo, Sierrita, Kelvin-Riverside, Mt. Grayback, Granite Mountain, Charleston, Globe-Miami, Sycamore Canyon, Copper Basin, Texas Canyon, and Copper Creek), provides a detailed study of Middle Jurassic coarse muscovite alteration at Luhr Hill in the Yerington district, Nevada, and documents the structural and hydrothermal evolution of the Ajo mining district in southwestern Arizona. Most areas in this study are interpreted to be highly extended, highly eroded, or both, allowing for study of deep hydrothermal alteration. Na-Ca alteration has been previously documented extensively along the Jurassic arc of the southwestern United States but less widely known in younger plutons, notably of Laramide age in Arizona. Coarse muscovite alteration previously has rarely been documented in porphyry copper systems, and this study shows that coarse muscovite alteration is likely present in systems where root zones are exposed at surface. Na-Ca alteration also is present in many in Laramide porphyry systems, though volumetrically minor, as no Laramide system contains more than a few volume perfect Na-Ca alteration in a given hydrothermal system. Na-Ca alteration in Laramide systems can include Ca, Na-Ca and Na alteration but is dominated by Na alteration (epidote-albite-chlorite ± actinolite). At Ajo, both Na-Ca and coarse muscovite alteration are present within the district due to superposition of temporally unrelated hydrothermal alteration, coupled with complex extensional deformation. This study shows that both Na-Ca and coarse muscovite alteration are more common in Laramide porphyry copper systems than previously recognized, that Na-Ca alteration is most commonly developed as shallower Na alteration (albite-epidote-chlorite ± actinolite), common deeper Na-Ca alteration (oligoclase-actinolite-epidote), and rare, deep Ca alteration (oligoclase-diopside-actinolite ± garnet ± epidote). Na-Ca alteration is commonly less voluminous in Laramide systems than documented in systems along the Jurassic arc. Coarse muscovite alteration, commonly termed greisen, occurs structurally below and commonly postdates potassic alteration and likely formed from late-stage, low-temperature, magmatic-hydrothermal fluids. Coarse muscovite alteration associated with more silicic magmatic compositions is developed at shallower depths and contains muscovite with higher trace element contents, coarse muscovite alteration with more variable mineral assemblages, and coarse muscovite veins that are better mineralized. Coarse muscovite alteration (greisen) occurs as the main mineralized veins at the tops of evolved metaluminous to peraluminous granites in W-Sn systems, as well mineralized veins in the cores and tops of Mo-Cu porphyry systems, and as poorly mineralized veins in the roots of porphyry copper systems. Detailed understanding of coarse muscovite alteration in a given district can, therefore, can be an indicator of depth or petrologic affiliation of a system. These results provide a better understanding of late-stage magmatic-hydrothermal alteration and hydrothermal alteration associated with the incursion of external fluids into the root zones of porphyry copper systems.

abstract: Mantle derived basalts along the entirety of the Earth’s Mid-Ocean Ridge (MOR) spreading centers are continuously altered by seawater, allowing the hydrosphere to subsume energy and exchange mass with the deep, slowly cooling Earth. Compositional heterogeneities inherent to these basalts—the result of innumerable geophysical and geochemical processes in the mantel and crust—generate spatial variation in the equilibrium states toward which these water-rock environments cascade. This alteration results in a unique distribution of precipitate assemblages, hydrothermal fluid chemistries, and energetic landscapes among ecosystems rooted within and above the seafloor. The equilibrium states for the full range of basalt compositional heterogeneity present today are calculated over all appropriate temperatures and extents of reaction with seawater, along with the non-equilibrium mixtures generated when hydrothermal fluids mix back into seawater. These mixes support ancient and diverse ecosystems fed not by the energy of the sun, but by the geochemical energy of the Earth. Facilitated by novel, high throughout code, this effort has yielded a high-resolution compositional database that is mapped back onto all ridge systems. By resolving the chemical and energetic consequences of basalt-seawater interaction to sub-ridge scales, alteration features that are globally homogeneous can be distinguished from those that are locally unique, guiding future field observations with testable geochemical and biochemical predictions. / Dissertation/Thesis / Doctoral Dissertation Geological Sciences 2020