This thesis is a detailed observational study of the accretion processes in T Tauri stars (TTS). The interaction between the central star, the circumstellar disk and the magnetic field gives rise to a wide range of features in the spectra of TTS. The current picture of TTS is based on rather simple models assuming that accretion is a homogeneous and axisymmetric process. Although these models have been successful in explaining some observational signatures of TTS such as the shape of emission lines, the static nature of these models makes them unsuitable for describing the strong variability of the veiling spectrum and emission lines of TTS. An improved understanding of this variability is of key importance to study the dynamic processes related to the accretion flow and the winds. This study is based on a set of high-quality spectroscopic observations with the UVES spectrograph at the 8-m VLT in 2000 and 2002. These spectra, with exposure times as short as 10-15 minutes, have high spectral resolution and high signal-to-noise ratios and cover a large part of the optical wavelength range. From this dataset we determine the basic physical parameters of several TTS and model their photospheres. These models then serve as a basis for a detailed investigation of variations of the veiling continuum and line emission. We confirm that the level of veiling correlates with some of the strongest emission lines and that coherent changes in accretion occur on a timescale of a few hours, comparable to the free-fall time from the disk to the star. From the properties of the emission lines formed close to the central star and in the stellar wind we derive restrictions on the geometry of the observed systems. Because the intrinsic axial symmetry of a single star makes it almost impossible to disentangle rotational modulation from inhomogeneity and axial asymmetry of the accretion flow, we study a series of spectra of a close spectroscopic binary at different orbital phases and derive the 3D structure of flows between the disk and the star. Finally, we calculate the profiles of hydrogen emission lines by iteratively solving 3D NLTE radiative transfer in a state-of-the-art magnetospheric model.

Diss. Stockholm : Handelshögsk.

Typische assoziative Verdicker für wässrige Systeme basieren auf linearen, doppelt hydrophob endmodifizierten Poly(ethylenglykolen) (PEGs). Diese Polymere aggregieren aufgrund ihrer Struktur in wässriger Lösung und bilden ein Netzwerk aus verbrückten Polymer-Mizellen. Dabei kann ein Polymer-Molekül maximal zwei Mizellen miteinander verbinden. Bisher ist unklar, wie die Anzahl der Endgruppen eines verzweigten, mehrfach hydrophob endmodifizierten hydrophilen Polymers die Struktur und Dynamik solcher Netzwerke beeinflusst. Die Synthese verzweigter Polymere auf PEG-Basis erfolgt mittels lebender ionischer Polymerisation und ist experimentell aufwändig. Das Einführen hydrophober Endgruppen erfordert zusätzliche Synthese-Schritte. In dieser Arbeit wurden hydrophile Sternpolymere mit hydrophoben Endgruppen in einem Schritt hergestellt. Dazu wurde die Technik der radikalischen Polymerisation unter Kettenübertragung durch reversible Addition und anschließende Fragmentierung (reversible addition-fragmentation chain transfer, RAFT) genutzt. Die Synthese der Sternpolymere erfolgte von einem multifunktionalen Kern, der die R-Gruppe der RAFT-Kettenüberträger (chain transfer agents, CTAs) bildete. Die dazu benötigten CTAs wurden so konzipiert, dass mit ihrer Hilfe sowohl die Anzahl der Arme des Sternpolymers (von 2 bis 4), als auch die Länge der hydrophoben Endgruppe (C4, C12, C18) variiert werden konnte. Der große Vorteil der RAFT-Polymerisation ist, dass sie viele polare Monomere für die Synthese der hydrophilen Arme des Sternpolymers toleriert. In dieser Arbeit wurden als Modell-Monomere Oligo(ethylenglykol)methylether-acrylat (OEGA) und N,N-Dimethylacrylamid (DMA) eingesetzt. Beide Monomere bilden nicht-ionische hydrophile Polymere. Poly(OEGA) ist ein Kammpolymer, das auf PEG basiert. Poly(DMA) besitzt dagegen eine deutlich kompaktere Struktur. Die erhaltenen amphiphilen Sternpolymere wurden umfassend molekular charakterisiert. Die Molmassen wurden mit verschiedenen GPC-Systemen bestimmt und der Grad der Endgruppenfunktionalisierung wurde mittels UV/Vis- und 1H-NMR-Spektroskopie überprüft. Die Polymerisation von OEGA zeigt mit den CTAs einige Charakteristika der Polymerisation mit reversibler Deaktivierung (RDRP, auch „kontrollierte radikalische Polymerisation“), wird aber durch Kettenübertragung zum Monomer bzw. Polymer gestört. Diese Nebenreaktion ist auf die Struktur des Monomers als Oligoether zurückzuführen. Bei allen untersuchten Polymerisationen von DMA mit den multifunktionalen CTAs steigt die Molmasse linear mit dem Umsatz. Die erhaltenen Polymere zeigen durchweg monomodale und enge Molmassenverteilungen (PDI ≤ 1,2). Die Molmassen lassen sich in einem weiten Bereich von 25 kg/mol bis 150 kg/mol einstellen und die Endgruppen der Polymere bleiben zu 90 % erhalten. Während die Polymerisation von DMA sowohl mit den di- als auch den trifunktionalen CTAs innerhalb von 3 h zu quantitativen Umsätzen verläuft, wird der quantitative Umsatz des Monomers bei der Polymerisation mit tetrafunktionalen CTAs erst nach 4 h erreicht. Diese Verzögerung ist auf eine Retardierung in der Anfangsphase der Polymerisation zurückzuführen, die sich aus der besonderen Struktur der tetrafunktionalen CTAs erklärt. Auf dem System zur Polymerisation von DMA aufbauend ließen sich Gradienten-Block-Copolymere in Eintopfreaktionen herstellen. Dazu wurde nach Erreichen des quantitativen Umsatzes von DMA ein zweites Monomer zur Reaktionsmischung gegeben. Mit Ethylacrylat (EtA) wurden so lineare amphiphile symmetrische Triblock-Copolymere erhalten. Dabei wurde die Länge des hydrophoben Blocks durch unterschiedliche Mengen an EtA variiert. Mit N,N-Diethylacrylamid (DEA) wurden lineare symmetrische Triblock-Copolymere sowie 3-Arm Stern-Diblock-Copolymere hergestellt, die über einen thermisch schaltbaren zweiten Block verfügen. Bei diesen Polymeren lässt sich die Länge des hydrophoben Teils in situ durch Veränderung der Temperatur variieren. Das Verhalten der amphiphilen Sternpolymere in wässriger Lösung und in Mikroemulsion wurde im Rahmen einer Kooperation an der TU Berlin mit Hilfe von Kleinwinkel-Neutronenstreuung (SANS), dynamischer Lichtstreuung (DLS) und Rheologie untersucht. Die Polymere wirken durch Assoziation der hydrophoben Endgruppen als effektive Verdicker sowohl allein in wässriger Lösung als auch in Mikroemulsion. Die Struktur des gebildeten Netzwerks hängt dabei von der Konzentration des Polymers in der Lösung und der Länge der Endgruppe (Hydrophobie) ab. Die dynamischen Eigenschaften der Lösungen werden außerdem durch die Anzahl der Arme der Polymere bestimmt. / Typically, associative thickeners for aqueous system consist of linear, hydrophobically α,ω-end-capped poly(ethylene glycols) (PEGs). Owing to their structure, these polymers aggregate in aqueous solution, forming a network of bridged micelles. Thus, one polymer molecule can link not more than two micelles. Until now it is unclear whether the structure and dynamics of such networks are influenced by the number of end groups of a branched multiply hydrophobically end-capped hydrophilic polymers. Branched PEG-based polymers are synthesized using the laborious and limited techniques of living ionic polymerization. Introducing hydrophobic end groups demands a multiple-step process. This work presents the one-step synthesis of hydrophilic star polymers with hydrophobic end groups, using reversible addition fragmentation chain transfer (RAFT) polymerization. This radical polymerization method is easy to use and tolerates a large number of polar monomers for the synthesis of the hydrophilic arms of the star polymers. The arms of the polymer were grown from a multifunctional core that formed the R-group of the chain transfer agents (CTAs). The CTAs where tailored to be able to vary the number of arms of the star polymers from 2 to 4 and to vary the length (and therefore the hydrophobicity) of the end groups (C4, C12, C18). Two different polar monomers where used as model monomers: Oligo(ethylene glycol)methyl ether acrylate (OEGA) and N,N-Dimethylacrylamide (DMA). Both monomers yield non-ionic hydrophilic polymers. While poly(OEGA) is a comb polymer based on PEG, poly(DMA) exhibits a more compact structure. The amphiphilic star polymers were characterized extensively. The molar masses were determined using GPC in various solvents and the degree of end functionalisation was monitored using 1H NMR and UV/Vis spectroscopy. The polymerization of OEGA shows some of the expected characteristics of reversible deactivation radical polymerization (RDRP). However, chain transfer to monomer and polymer is a prominent side reaction, limiting the use of this monomer for the fabrication of well-defined material. This reaction can be attributed to the structure of the monomer being an oligoether. For all examined polymerizations of DMA with the multifunctional CTAs the molar mass increased linearly with conversion. The molar mass distributions were monomodal and narrow (PDI ≤ 1.2). Expected values were reached for molar masses from 25 to 150 kg/mol and the end group functionality was about 90 % in all cases. While the polymerization of DMA using di- and trifunctional CTAs proceeded to quantitative conversion within 3 h, an initial retardation period of about 60 min was observed for the polymerization using tetrafunctional CTAs. This retardation was attributed to the peculiar molecular structure of these CTAs. Owing to the well-controlled features of the polymerization of DMA using the multifunctional CTAs, this system was used to obtain tapered block copolymers in a one-pot process. These structures were achieved by adding a second monomer to the reaction mixture after the quantitative conversion of DMA. Using ethyl acrylate (EtA), linear amphiphilic symmetrical triblock copolymers were synthesized. The length of the hydrophobic block was tailored by the addition of varying amounts of EtA. With N,N-Diethylacrylamide as a second monomer, linear symmetric triblock copolymers as well as 3-arm star diblock copolymers were obtained that contain a thermosensitve block. Altering the temperature of aqueous solutions of these polymers varies the length of the hydrophobic block in situ. At the TU Berlin, the behavior of the polymers was studied in aqueous solution as well as in microemulsion. The solutions were characterized by small angle neutron scattering (SANS), dynamic light scattering (DLS) and rheology. The end groups of the polymers aggregate, making the polymers efficient thickeners both in aqueous solution and in microemulsion. The structure of the formed network depends on the concentration of the polymer in solution and on the length of the end group. The dynamic properties of the solutions are governed additionally by the number of arms.

No description available.

This thesis describes some aspects of noncommutative geometry and conformal field theory. The motivation for the investigations made comes to a large extent from string theory. This theory is today considered to be the most promising way to find a solution to the problem of unifying the four fundamental interactions in one single theory. The thesis gives a short background presentation of string theory and points out how noncommutative geometry and conformal field theory are of relevance within the string theoretical framework. There is also given some further information on noncommutative geometry and conformal field theory. The results from the three papers on which the thesis is based are presented in the text. It is shown in Paper 1 that, for a gauge theory in a flat noncommutative background only the gauge groups U(N) can be used in a straightforward way. These theories can arise as low energy limits of string theory. Paper 2 concerns boundary conformal field theory, which can be used to describe open strings in various backgrounds. Here different orbifold theories which are described using simple currents of the chiral algebra are investigated. The formalism is applied to ``branes´´ in Z2 orbifolds of the SU(2) WZW-model and to the D-series of unitary minimal models. In Paper 3 two different descriptions of an invariant star-product on S² are compared and the characteristic class that classifies the star-product is calculated. The Fedosov-Nest-Tsygan index theorem is used to compute the characteristic class.

Parkinson's disease (PD) is a degenerative illness whose cardinal symptoms include rigidity, tremor, and slowness of movement. In addition to its widely recognized effects PD can have a profound effect on speech and voice.The speech symptoms most commonly demonstrated by patients with PD are reduced vocal loudness, monopitch, disruptions of voice quality, and abnormally fast rate of speech. This cluster of speech symptoms is often termed Hypokinetic Dysarthria.The disease can be difficult to diagnose accurately, especially in its early stages, due to this reason, automatic techniques based on Artificial Intelligence should increase the diagnosing accuracy and to help the doctors make better decisions. The aim of the thesis work is to predict the PD based on the audio files collected from various patients.Audio files are preprocessed in order to attain the features.The preprocessed data contains 23 attributes and 195 instances. On an average there are six voice recordings per person, By using data compression technique such as Discrete Cosine Transform (DCT) number of instances can be minimized, after data compression, attribute selection is done using several WEKA build in methods such as ChiSquared, GainRatio, Infogain after identifying the important attributes, we evaluate attributes one by one by using stepwise regression.Based on the selected attributes we process in WEKA by using cost sensitive classifier with various algorithms like MultiPass LVQ, Logistic Model Tree(LMT), K-Star.The classified results shows on an average 80%.By using this features 95% approximate classification of PD is acheived.This shows that using the audio dataset, PD could be predicted with a higher level of accuracy.

Purpose: The purpose of this study is to investigate how and to what degree Swedish multinational companies (MNCs) adapt to local conditions when they establish subsidiaries in China, and if cultural differences play an important role in their operations. Background: The major challenge for MNCs establishing abroad is the configuration and integration of their country subsidiaries (Galbraith, 2000). Therefore, it is vital to understand how activities within an organization, such as structures, processes, reward systems, and people practices, should be designed in order for the company to be as efficient as possible (Weiss, 2007; Kesler & Kates, 2011). Swedish direct investments in China have increased significantly in the late 2000s, especially in the eastern regions, where a majority of about 650 Swedish companies in China are located (Swedish Trade Council, 2012a). Establishing across borders is a step towards future growth, but it is important to note that a cross-border expansion comes with many challenges (Galbraith, 2000). Method: This study uses a qualitative research method by investigating the experiences and practices of two Swedish multinational companies with operations in Shanghai, China. Information has been collected from eight respondents in the form of interviews and open-ended questionnaires. Conclusion: Swedish MNCs standardize their organization to a large extent when they establish subsidiaries in China, and culture has a slight influence on the practices of Swedish MNCs but does not play a major role for the business as a whole.

This paper deals with decision problems related to the star problem in trace monoids, which means to determine whether the iteration of a recognizable trace language is recognizable. Due to a theorem by G. Richomme from 1994 [32, 33], we know that the star problem is decidable in trace monoids which do not contain a submonoid of the form {a,c}* x {b,d}*. Here, we consider a more general problem: Is it decidable whether for some recognizable trace language and some recognizable or finite trace language P the intersection R ∩ P* is recognizable? If P is recognizable, then we show that this problem is decidale iff the underlying trace monoid does not contain a submonoid of the form {a,c}* x b*. In the case of finite languages P, we show several decidability and undecidability results.

This thesis presents our recent study of few interesting problems involving activated processes. This chapter gives an overview of the thesis. It is now possible to do single molecule experiments involving enzyme molecules. The kinetics of such reactions exhibits dynamic disorder associated with conformational changes of the enzyme-substrate complex. The static disorder and dynamic disorder of reaction rates, which are essentially indistinguishable in ensemble-averaged experiments, can be determined separately by the real-time single-molecule approach. In our present work we have given a theoretical description of how rate of reactions involving dynamic disorder is studied using path integral approach. It is possible to write the survival probability and the rate of the process as path integrals and then use variational approaches to get bounds for both. Though the method is of general validity, we illustrate it in the case of electronic relaxation in stochastic environment modeled by a particle experiencing diffusive motion in harmonic potential in presence of delta function sink. The exact solution of corresponding Smoluchowski equation was found earlier[1] analytically in Laplace domain with sink having arbitrary strength and position. Exact evaluation of path integral calculation to survival probability is not possible analytically. Wolynes et al.[2] have done an approximate calculation to get bounds to the survival probability in the Laplace domain. A bound in the Laplace domain is not as useful as a bound in the time domain and hence we use the direct approximate variational path integral technique to calculate both lower and upper bound of survival probability in time domain. We mimic the delta function sink by quadratic sink for which the path integral can be solved exactly. The strength of the quadratic sink is treated as variational parameter and using the optimized value for it, one can estimate the optimized lower as well as upper bound of survival probability. We have also calculated a lower bound to the rate. The variational results are compared with the exact ones, and it is found that the results for the two parameter case are better than those of one parameter case. To understand how good our approximation is, we calculate the bounds in survival time and found them to be in good agreement with exact results. Our approach is valid for any arbitrary initial distribution that one may start with. We consider the Kramers problem for a long chain polymer trapped in a biased double well potential. Initially the polymer is in the less stable well and it can escape from this well to the other well by the motion of its N beads across the barrier to attain the configuration having lower free energy. In one dimension we simulate the crossing and show that the results are in agreement with the kink mechanism suggested earlier. In three dimensions, it has not been possible to get analytical “kink solution”for an arbitrary po-tential; however, one can assume the form of the solution of the non-linear equation as a kink solution and then find a double well potential in three dimensions. To verify the kink mechanism, simulations of the dynamics of a discrete Rouse polymer model in a double well in three dimensions were done. We find that the time of crossing is proportional to the chain length which is in agreement with the results of kink mechanism. The shape of the kink solution is also in agreement with the analytical solution in both one and three dimensions. We then consider the dynamics of a short chain polymer crossing over a free energy barrier in space. Adopting the continuum version of the Rouse model, we find exact expressions for the activation energy and the rate of crossing. For this model, the analysis of barrier crossing is analogous to semiclassical treatment of quantum tunneling. Finding the saddle point for the process requires solving a Newton-like equation of motion for a fictitious particle. The analysis shows that short chains would cross the barrier as a globule. The activation free energy for this would increase linearly with the number of units N in the polymer. The saddle point for longer chains is an extended conformation, in which the chain is stretched out. The stretching out lowers the energy and hence the activation free energy is no longer linear in N . The rates in both the cases are calculated using a multidimensional approach and analytical expressions are derived using a new formula for evaluating the infinite products. However, due to the harmonic approximation made in the derivation, the rates are found to diverge at the point where the saddle point changes over from the globule to the stretched out conformation. The reason for this is identified to be the bifurcation of the saddle to give two new saddles. A correction formula is derived for the rate in the vicinity of this point. Numerical results using the formulae are presented. It is possible for the rate to have a minimum as a function of N . This is due to the confinement effects in the initial state. We analyze the dynamics of a star polymer of F arms confined to a double well potential. Initially the molecule is confined to one of the minima and can cross over the barrier to the other side. We use the continuum version of Rouse-Ham model. The rate of crossing is calculated using the multidimensional approach due to Langer[3].Finding the transition state for the process is shown to be equivalent to the solution of Newton’s equations for F independent particles, moving in an inverted potential. For each star polymer, there is a critical total length N Tc below which the polymer crosses over as a globule. The value of NTc depends on the curvature at the top of the barrier as well as the individual arm lengths. So we keep the lengths of (F -1) arms fixed and increase the length of the F th arm to get the minimum total length NTc. Below NTc the activation energy is proportional to the total arm length of the star. Above N Tc the star crosses the barrier in a stretched state. Thus, there is a multifurcation of the transition state at NTc. Above NTc, the activation energy at first increases and then decreases with increasing arm length. This particular variation of activation energy results from the fact that in the stretched state, only one arm of the polymer is stretched across the top of the barrier, while others need not to be. We calculate the rate by expanding the energy around the saddle upto second order in the fluctuations. As we use the continuum model, there are infinite modes for the polymer and consequently, the prefactor has infinite products. We show that these infinite products can be reduced to a simple expression, and evaluated easily. However, the rate diverges near N Tc due to the multifurcation, which results in more than one unstable mode. The cure for this divergence is to keep terms upto fourth order in the expansion of energy for these modes. Performing this, we have calculated the rate as a function of the length of the star. It is found that the rate has a nonmonotonic dependence on the length, suggesting that longer stars may actually cross over faster.

Thesis (M. Arch.)--University of Hong Kong, 2002. / Includes special report study entitled: The Star ferry Pier & the bus terminus. Includes bibliographical references.