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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
301

Non-Equilibrium Dynamics of Active Nematic Elastomers

Unknown Date (has links)
Active nematic elastomers are a class of active materials that possess the elasticity of a rubber, and the orientational symmetry of a liquid crystal. Their constituent elements are typically elongated, cross-linked and active. The cross-linking of the elements leads to an elasticity that prevents the material to ow like a liquid. These elements are active in a sense that they continuously consume and dissipate energy, creating a state that is far-from-equilibrium. Active nematic elastomers may be a good physical model for biological systems such as the metaphase spindle, a complex biological machine that is made of an integrated assembly of microtubules and molecular motors. These motors not only cross-link the microtubules, but also actively slide them against each other, creating a highly dynamic, non-equilibrium state. The metaphase spindle, like other non-equilibrium structures in biology, has important functions to perform. During mitosis, the spindle is responsible for (1) capturing the sister chromatids, (2) bringing all the sister chromatids to the equator of the mother cell, and (3) segregating the daughter chromosome to the opposite poles of the cell. Thus, a fundamental challenge to biological physics is to understand the complex dynamics of the spindle, and similar systems, using the tools of non-equilibrium statistical mechanics. In this Thesis, we develop and explore a phenomenological model for an active nematic elastomer. We formulate the dynamics of this phenomenological model by incorporating the contribution of the active elements to the standard formulation of the hydrodynamic equations of a passive system. In a coarse-grained picture, the activity is taken into account as an extra active stress, proportional to the alignment tensor, added to the momentum equation of an otherwise passive nematic elastomer. Having obtained the equations of motion of an active nematic elastomer, we then investigate the response of the system to an external field by means of examining the structure and the stability of the modes. An active nematic elastomer has eight modes, in which six modes are propagating and two modes are massive. Out of the six propagating modes, two modes are in the longitudinal direction, linked to the density waves, and the other four modes are in the transverse direction, linked to the shear waves. The nature of these propagating modes transitions from dissipative and oscillatory, and vice versa, depending on the length scales. In particular, their stability is largely determined in the hydrodynamic limit, by a competition between the stabilizing effect of the elasticity and the destabilizing effect of the activity. In fact, the activity renormalizes the elastic coefficients down to even a negative value in some cases and thus, rendering the system linearly unstable. This is in contrast to the well-known instability of an active nematic liquid crystal, which is always linearly unstable. We then map out and discuss the stability phase diagram of the active nematic elastomer. Next, we compute and study various equal-time correlation functions of an active nematic elastomer, assuming that the noise spectra are thermal in origin. We find that they can be conveniently arranged into two terms. The first term has the exact mathematical structure of the equal-time correlation functions of a passive nematic elastomer, albeit with certain coefficients renormalized by activity. The second term, which is proportional to the activity, represents the non-equilibrium nature of an active nematic elastomer, and manifestly breaks the Fluctuation-Dissipation Theorem. We also find that (1) the displacement-displacement correlation function decays inversely with the square of the wave number for both the compressible and incompressible nematic elastomer, similar to that of a passive nematic elastomer, with elastic coefficients renormalized by the activity. (2) The density-density correlation function approaches a constant at the long wave-length limit, since the conservation of mass links the density to the rate of changes of the displacement in the longitudinal direction. (3) The director-displacement correlation function is purely imaginary, and thus the director is locked to the displacement with a (π/2) phase-shift. (3) The director-director correlation function approaches a constant value in the long-wavelength limit, instead of decaying inversely with the square of the wave number, like it would for a liquid crystal. This is because of the massive mode stems from the coupling energy, and it indicates that director in the large length scale is locked to a specific angle. These theoretical results are in qualitative agreement with the experimental measurements of the spindle. / Includes bibliography. / Dissertation (Ph.D.)--Florida Atlantic University, 2019. / FAU Electronic Theses and Dissertations Collection
302

Antiretroviral treatment programme outcomes scenarios in South Africa in the next two decades

Maseko, Batlile Paulos. January 2012 (has links)
Thesis (MPH) -- University of Limpopo, 2012. / No Summary
303

Kinetics of the reactions of active nitrogen with methyl chloride and ethylene.

Brown, George Ronald. January 1970 (has links)
No description available.
304

Surface properties of polymeric surfactants

Court, Colin Edwin, University of Western Sydney, College of Science, Technology and Environment January 2001 (has links)
Polystyrenes with carboxyl end-groups (PS-COOH)and poly (tert-butyl acrylates) (PtBA) of different molar mass were synthesised by anionic polymerisation using n-butyllithium as the initiator. Gel permeation chromatography (GPC) was used to calculate the molecular weight and polydispersity of these polymers. The tacticity of these polymers was determined using Carbon 13 Nuclear Magnetic Resonance Spectroscopy (13C NMR). FT-IR was used to confirm the tacticity of the samples. Matrix-assisted laser desorption ionisation time-of-flight mass spectrometry (MALDI-TOF) was used to confirm the presence of the carboxyl end-groups. All of the films studied in this project were transferred to mica substrates using the Langmuir-Blodgett deposition method. Both single layer and multiple layer films were constructed using this technique. Atomic force microscopy (AFM) was used to observe the surface topology of these films. / Doctor of Philosophy (PhD) (Science)
305

Novel methods of transduction for active control of harmonic sound radiated by vibrating surfaces

Burgemeister, Kym A. January 1996 (has links)
Large electric transformers such as those used in high voltage substations radiate an annoying low frequency hum into nearby communities. Attempts have been made to actively control the noise by placing a large number of loudspeakers as control sources around noisy transformers to cancel the hum. These cancellation systems require a large number of loudspeakers to be successful due to the imposing size of the transformer structures. Thus such systems are very expensive if global noise reduction is to be achieved. The aim of this thesis is to investigate theoretically and experimentally the use of thin perforated panels closely placed to a heavy structure to reduce the radiation of unwanted harmonic noise. These panels can themselves be vibrated to form a control source radiating over a large surface surrounding the primary source. The problem of the equipment overheating inside the enclosure is alleviated because the holes in the panels still allow natural cooling. An initial study is carried out to determine the resonance frequencies of perforated panels. The use of previously determined effective elastic properties of the panels and Finite Element Analysis to theoretically calculate their resonance frequencies is examined. Secondly the attenuation provided by active noise control using perforated panels as control sources is explored by use of a coupled analysis, where the primary source is assumed to influence the radiation of the perforated control panel. This analysis was found to predict poorly the amount of attenuation that could be achieved, so an uncoupled analysis is undertaken, where both the primary and control sources are assumed to radiate independently of each other. Not only does this greatly simplify the theoretical analysis but it also enables prediction of attenuation levels which are comparable to those determined experimentally. The theoretical model is reformulated to enable comparison of the sound power attenuation provided by perforated panel control sources with that of traditional acoustic and structural control sources. Finally, the use of modal filtering of traditional acoustic error sensor signals to give transformed mode (or power mode) sensors is examined. The independently radiating acoustic transformed modes of the panel are determined by an eigenanalysis and a theoretical analysis is presented for a farfield acoustic power sensor system to provide a direct measurement of the total radiated acoustic power. The frequency dependence of the sensor system, and the amount of global sound power attenuation that can be achieved is examined. Experimental measurements are made to verify the theoretical model and show that a sound power sensor implemented with acoustic sensors can be used in a practical active noise control system to increase the amount of attenuation that can be achieved. Alternatively the sound power sensor can be used to reduce the number of error channels required by a control system to obtain a given level of attenuation when compared to traditional error criteria. The power mode sensor analysis is then applied to the perforated panel control system, with similar results. / Thesis (Ph.D.)--Engineering (Department of Mechanical Engineering), 1996.
306

Virtual sensors for active noise control.

Munn, Jacqueline M January 2003 (has links)
The need to attenuate noise transmitted into enclosed spaces such as aircraft cabins, automobiles and mining cabins has provided the impetus for many active noise control studies. Studies into active interior noise control began with a pressure squared cost function utilising multiple error sensors and control sources in an attempt to produce global control of the interior sound field. This work found problems with observability of the primary disturbances and a large number of error sensors and control sources were required to produce global control. Since this early work in the 1980's, many new acoustic based cost functions have been developed to improve on the performance of the pressure squared cost function. This thesis will focus on one novel acoustic cost function, virtual error sensing. Virtual error sensing is a relatively new technique which produces localised zones of attenuation at a location remote to the physical sensors. The practical advantage of this method is the people within these enclosed spaces are able to observe a reduction in sound pressure level without their movement being restricted by error sensors located close to their ears. The aim of this thesis is to further investigate the performance of forward-difference virtual error sensors in order to understand the factors that affect the accuracy of the pressure prediction at the virtual location and use this information to develop more accurate and efficient forward- difference virtual sensors. These virtual sensors use linear arrays of microphones containing two or more microphone elements and a linear or quadratic approximation is used to predict the sound at the virtual location. The prediction method determines the weights applied to each microphone signal to predict the sound pressure level at the virtual location. This study investigates susceptibility of the sensors to corruption as a result of phase and sensitivity mismatch between the microphones, as well as in the location of the elements in the error sensing array. A thorough error analysis of the forward-difference virtual microphones was performed in a one-dimensional sound field and in a plane wave sound field. The accuracy of the quadratic virtual microphone was found to be strongly affected by the presence of short wavelength extraneous noise. From this study, two novel virtual error sensing techniques were developed, namely; higher-order virtual sensors and adaptive virtual sensors. The higher-order virtual error sensors still employ the linear and quadratic prediction method but extra microphone elements are added to the array. The aim of these higher-order virtual microphones is to produce a more accurate prediction of the pressure at the virtual location by spatially filtering out any short wavelength extraneous noise that may corrupt the prediction. These virtual sensors were tested in a realtime control scenario in both a one-dimensional reactive sound field and in a free field. This work found that the higher-order virtual microphones can improve the prediction accuracy of the original virtual sensors but are still prone to problems of phase, sensitivity and position errors. Finally, the adaptive LMS virtual sensors were investigated in a SIMULINK simulation and tested experimentally using real-time control in a one-dimensional sound field. It was hoped that an adaptive LMS algorithm could overcome previous difficulties arising from inherent and transducer errors by adapting the weights of the signals from the sensing elements which form the array. The algorithm adapts the sensing microphone signals to produce the same signal as the microphone at the virtual location. Once this has been achieved, the sensing microphone weights are fixed and the microphone at the virtual location is removed, thus creating a virtual microphone. The SIMULINK simulation allowed the performance of the fixed weight and virtual microphones to be investigated in the presence of only phase errors, sensitivity errors and position errors and in the presence of all three combined. This work showed that the adaptive virtual sensors had the ability to compensate for the errors. The number of modes used in the simulations was varied to observe the performance of all virtual sensors in the presence of higher-order modes. The prediction accuracy of the fixed weight virtual sensors was found to be greatly affected by the presence of higher-order modes. The use of the adaptive virtual microphones to produce localised zones of quiet was examined experimentally using real-time control. The study found the real-time control performance is superior to that of the fixed weight higher-order virtual microphones and the original forward-difference virtual microphones. / Thesis (Ph.D.)--School of Mechanical Engineering, 2003.
307

Signatures of the propagation of primary and secondary cosmic ray electrons and positrons in the galaxy

Porter, Troy Anthony. January 1999 (has links) (PDF)
Includes bibliographical references (8 p.) Examines some of the consequences of the acceleration and production, and propagation, of high energy electrons and positrons in the Galaxy. In particular, predictions are made of the diffuse photon signals arising from the interactions of electrons and positrons with gas, low energy photons, and the galactic magnetic field during their transport in the Galaxy.
308

Enseigner et apprendre la grammaire : le cas de la phrase et de la ponctuation au cycle II

Jarno-El Hilali, Guénola 04 July 2011 (has links) (PDF)
La grammaire - longtemps considérée comme routinière, ennuyeuse et formaliste - est un objet de réflexions au centre de nouvelles préoccupations en matière d'enseignement. En témoignent les programmes mettant en avant l'importa,ce de notions relatives à l'énonciation, à la cohésion textuelle, à côté des études relatives à la grammaire de phrase. Ce travail vise à contribuer aux réflexions sur l'acquisition de cette discipline. Il se matérialise autour de la phrase et de la ponctuation. Qu'est-ce que la phrase ? La ponctuation ? Une connaissance spontanée ? Un savoir appris à l'école ? Comment donner du sens à cet enseignement ? Comment le penser ? L'organiser ? C'est autour de ces questions que s'organise ce travail : une première partie regroupe les principaux courants grammaticaux "classiques" et "contemporains" qui ont eu un impact durable sur l'enseignement de la phrase et de la ponctuation ; une deuxième porte sur une synthèse des fondements de l'enseignement et de l'apprentissage de la grammaire, mis en lumière par les recherches récentes dans les domaines de la psychologie cognitive et de la didactique ; une troisième s'attache à analyser les manuels d'enseignement et autres documents didactiques utilisés dans les salles de classe ; une quatrième enfin livre les conclusions auxquelles nous sommes parvenus au terme de plusieurs expériences menées dans des classes de CP et de CE1 : l'une sur l'approche de la phrase en contexte, l'autre sur l'approche du système de ponctuation. De ce travail, nous retenons que nos propositions didactiques peuvent réconcilier les élèves avec la grammaire, et plus particulièrement avec la ponctuation, bête noire de la production écrite.
309

Implementation and Testing of a Semi-Active Damping System

Nordin, Peter January 2007 (has links)
<p>The purpose of this thesis is to implement and test a semi-active damping system based on a concept from an earlier thesis. The project includes implementation of mechanical, hydraulic and electronic hardware, aswell as controller software. The idea is to measure the movements of the vehicle chassis and based on these measurements set the damping torque using hydraulics. To be able to develop, test and evaluate the system, realistic input data must be available. To acquire such data, driving trials have been conducted on a variety of tracks.</p><p>The first part of the system is the sensors that measure chassis movements. Both accelerometers and a gyro has been used. To remove drift and high frequency vibrations, the signals are filtered. The suggested controller from the earlier thesis requests damping torque based on the dampers vertical velocity. When accelerometer signals are integrated, measurement and rounding errors causes drift in the velocity. To compensate for this, a floating average is calculated and used.</p><p>The main hydraulic component is a pressure reduction valve that controls the pressure inside the damper. Higher pressure will give higher damping torque. The reaction speed of the system is mostly depending on the hydraulic components. It is important to know the time delay from a change in the valve control signal, to when the actual pressure in the damper has been reached. Tests have shown that a large step, going from 10 Bar to 60 Bar takes approximately 46ms, and that a small step from 1 Bar to 20 Bar takes 63ms. The valve is faster when higher pressure levels are requested. In addition to the hydraulic response time the delay through the signal filters, measured to about 14ms, must be added.</p><p>The sensors are affected by vibrations. If these can be reduced, the digital filters can be made less sharp with a lower filter delay as result. It is also important to have a good control computer so that large rounding errors in the filter calculations can be avoided. This would greatly decrease drift in the integrated velocity.</p>
310

Protect team handler (PTH)

Alhabashneh, Mohammad Abad Alhameed January 2006 (has links)
<p>There is always a need for easy-to-follow processes that enable accurate and non-time consuming solutions. Nowadays we see a lot of different approaches to development processes in software engineering. This project is concerned with how to manage a software development process in a reliable, secure and efficient way. Software is available which provides some help for project managers / administrators to work more productively, with effective communication. Using such systems, it is possible to keep track of all the phases of development, including task distribution, making maximum use of previous hands-on experience and increasing productivity, to deliver a finished product in minimum time. No existing solution, however, fulfills all the desirable criteria. This paper describes the motivation, design and implementation of an improved development management system using Active Server Pages and Microsoft Internet Information Services with a backend Microsoft Access Database developed using a waterfall software development process. The resulting system is described and evaluated. This system will be beneficial for software houses, because they can communicate on the web, allowing efficiency gains by avoiding the need to call meetings for distribution of tasks among employees, with the additional advantage of location-transparent team management through the Internet.</p>

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