Existing models of the hydrogeology in the Blue Ridge Province in the eastern United States generally assume a simplified two-layered system consisting of shallow unconsolidated and relatively homogeneous and porous regolith with a water-table aquifer that slowly supplies water downward to the underlying variably fractured crystalline bedrock. In these models, interconnected fractures in the crystalline bedrock act as conduits for predominantly downward vertical and limited horizontal flow. Fracture density is depthà limited and correlated with proximity to topographic lineaments. Current models consider the porous regolith as the primary water storage reservoir for the entire aquifer system. In this research, detailed hydrogeologic studies in the Blue Ridge Province in Floyd County, Virginia reveal a substantially different framework for groundwater flow. Recent acquisition of two-dimensional surface resistivity profiles collected using a variety of array techniques combined with borehole geophysical logs revealed new insights into this geologically complex province. Dipole-dipole arrays were particularly important in gathering high resolution resistivity profiles that document horizontal and vertical resistivity variation reflecting changes in subsurface geology and anomalous low resistivity areas in crystalline bedrock associated with fault zones. The shallow regolith contains unsaturated areas and also localized sand and clay prone facies with water table and confined aquifer conditions residing locally. Hydraulic heads between the shallow aquifer and the deeper fractured bedrock aquifer can vary by 20 m vertically. Within the crystalline bedrock are anomalous lower resistivity intervals associated with ancient fault shear zones. Brecciated rock adjacent to the shear zones, and the shear zones themselves, can be hydraulically conductive and serve as pathways for groundwater movement. Aquifer testing of the regolith-bedrock fracture system occurred over a 6-day period and produced rapid and relatively uniform drawdowns in surrounding wells completed in the fractured bedrock aquifers. The shallow aquifers experienced minimal drawdowns from the aquifer test indicating low vertical hydraulic conductivity and limited communication between the shallow and deeper bedrock aquifers. Water chemistry and chlorofluorocarbon (CFC) age dating analyses indicated significant differences between water samples from the shallow and deep aquifers. A new conceptual model for Blue Ridge aquifers is proposed based on these research findings. / Ph. D.

Physical and geophysical data collected at the Fractured Rock Research Site in Floyd County, Virginia indicate that recharge rates to the subsurface are controlled by a small scale thrust fault associated with regional thrust faulting within the Blue Ridge Province. Recharge rates appear to be correlated to spatial variation in the hydraulic conductivity of the regolith, which has been influenced by weathering rates and the metamorphic and structural history of the underlying parent material. Previous studies conducted at the Fractured Rock Research Site suggest that recharge potential can be separated into two regions: one over a vertically oriented shear zone associated with the small scale thrust fault, and the other overlying a thrust fault hanging wall. The angle of dip of the thrust fault shear zone and the fracturing within the crystalline rock adjacent to the fault plane appear to serve as geologic controls that preferentially direct infiltrated meteoric water to a deeper confined aquifer. The structural competence of the granulite gneiss thrust fault hanging wall appears to act as a barrier to deeper groundwater recharge, causing the formation of a shallow semi-confined aquifer within the overlying regolith. In-situ analysis of matric potential and moisture content shows two distinctly different recharge processes that are spatially correlated with the structure of the shallow subsurface (regolith overlying the vertically oriented shear zone and regolith overlying the thrust fault hanging wall), and have been shown to have strong temporal correlations with the dynamics of the underlying saturated conditions. Recharge flux estimates within the regolith overlying the thrust fault hanging wall are uncharacteristically high, and appear to be offset within the monitored region by the upward hydraulic gradient associated with the potentiometric surface of the underlying semi-confined aquifer. Because of the influence exerted by the upward hydraulic gradient on matric potential within the unsaturated regolith overlying the semi-confined aquifer, accurate recharge estimates could not be obtained from the matric potential data recorded by the tensiometers along this portion of the transect. Recharge flux within the regolith overlying the vertically oriented shear zone is strongly controlled by the orientation and aerial extent of the thrust fault shear zone, and highlights the importance of accurate delineation of recharge areas in crystalline rock aquifer systems. / Master of Science

The Grenville orogeny was a protracted (~200 m.y.) series of “hot” magmatic- metamorphic events that contributed to the growth of the Laurentian margin in the late Mesoproterozoic. The granites contain remarkably high Zr content, lack xenocrysts, and become zircon saturated at high temperatures, which are all unusual for felsic magmas. The “hot Grenville granite” hypothesis is tested and use of high-Zr granitoids as potential zones of crustal magma generation through: U-Pb geochronology and cathodoluminescence imaging to assess inherited zircon components; quantitative modeling of zircon crystallization history using rhyolite-MELTS; and Ti-in-zircon thermometry. U-Pb zircon ages for two samples from the Virginia Blue Ridge are 1168 ± 25 Ma (2209 ppm Zr; Tzr = 1032°C) and 1050 ± 13 Ma (918 ppm Zr; Tzr = 898°C). A sample from the NJ – Hudson Highlands has been dated at 1018 ± 11 Ma (1238 ppm Zr; Tzr = 960°C). These samples produce crystallization histories that range over higher temperatures (983–1060°C) than colder, low-Zr counterparts and contain Ti concentrations of 2 to 86 ppm. This analytical approach will further the understanding of zircon’s utility and limitations as a proxy in granite petrogenesis, and constrain thermal models that produced uncommon lithospheric conditions that led to widespread hot granite production at a unique period in Earth history.

The Cartoogechaye terrane (CT) is an enigmatic migmatite terrane within the Central Blue Ridge province of the southern Appalachians. Previous work identified exotic Pb isotope compositions within the CT (Quinn, 2012). More recent studies that mapped the extent of potentially exotic metaigneous lithologies yield U-Pb zircon ages consistent with a native Laurentian margin metasedimentary origin (Larkin, 2016). This study focused on the possible extent of similar lithologies in the Clyde quadrangle and provides further constraints on the crustal affinity of the CT. The Clyde quadrangle consists of four distinct lithologic packages: the CT, Ashe metamorphic suite, Great Smoky Group, and Grenville basement. Five samples within the Clyde quadrangle and one sample from Wayah Bald quadrangle were collected for detrital zircon (DZ) U-Pb geochronology and whole rock geochemistry for comparison similar anlayses from other bedrock units in the region. Dominant DZ age modes consist of the Grenville doublet (1050 Ma and 1150 Ma) or a modified version of it. Minor age modes exist at ~450 Ma, 600-750 Ma, and 1300-1550 Ma. Zircons for all but one sample display heterogeneous external and internal cathodoluminescence morphologies, consistent with a sedimentary protolith for the paragneisses. Whole rock compositions are consistent with weathering of and derivation from a local basement source. U-Pb age data are most consistent with an eastern Laurentian sedimentary provenance for five samples. The presence of 450-460 Ma grains is most consistent with high-grade Taconian regional metamorphism. The lack of a major Shawinigan age mode and zircon morphology for ca. 980-1050 Ma metamorphic zircons indicate that sample CLY16-1 is a syn-orogenic metasediment within the Grenville basement underlying the CT.