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Syntheses and functionalization of block copolymers based on polystyrene-block-poly(4-vinylpyridine) and polystyrene-block-polyisoprene /Hou, Sijian. January 1999 (has links)
Thesis (Ph. D.)--University of Hong Kong, 2000. / Includes bibliographical references.
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Structure-property relationships of multiphase copolymers /York, Gregory A., January 1990 (has links)
Thesis (Ph. D.)--Virginia Polytechnic Institute and State University, 1990. / Vita. Abstract. Includes bibliographical references (leaves 354-365). Also available via the Internet
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Synthesis and characterisation of amphiphilic block copolymers /Morkel, C. E. January 2005 (has links)
Thesis (Ph. D.)--University of Stellenbosch, 2005. / Includes bibliographical references. Also available via the Internet.
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Syntheses and functionalization of block copolymers based on polystyrene-block-poly(4-vinylpyridine) and polystyrene-block-polyisoprene侯斯健, Hou, Sijian. January 1999 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
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Block copolymers / by J.R. UrwinUrwin, John Robson January 1972 (has links)
1 v. (various pagings) : / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Thesis (D.Sc. 1972) from the Dept. of Physical and Inorganic Chemistry, University of Adelaide
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Physical properties of poly (n-alkyl acrylate) copolymersO'Leary, Kelly Ann 28 August 2008 (has links)
Not available / text
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Radical-mediated modification of polyolefins: investigation of the synthesis of graft copolymersKaufman, Michael Steven 08 May 2008 (has links)
A range of strategies exist for the production of polyolefin block copolymers with well-defined morphologies for the compatibilization of immiscible blends; however, high sensitivity to impurities and use of expensive transition-metal catalysts limit their economic viability. An alternative method is the solvent-free coupling of dislike polymers using peroxides and multifunctional coagents. This technique, however, does not distinguish between a blend of gelled homopolymers and the intended copolymer. The use of a solution-based approach, like the one described in this report, for the radical-mediated coupling of polyolefins with dislike polymers allows for the full
characterization of the copolymer without the formation of gel.
A one- and two-step synthesis for the coupling of two homopolymers in solution is
demonstrated using triallyl trimesate. The one-step approach produced a copolymer in low yields due to the differences in reactivity between the homopolymers. The
two-step synthesis consisted of the solvent-free grafting of the coagent to the less
reactive polymer, followed by coupling in solution with the other polymer. Though
this technique demonstrated improved yields over that of the one-step approach, the overall yields were limited due to the dilution effects of the high solvent levels
needed for comiscibility. The coupling of polyethylene with poly(ethylene oxide) had
a maximum graft yield of 9.5%, whereas the coupling between polypropylene and a
thermoplastic polyolefin elastomer was negligible.
It was found that the grafting of allylic ester coagents to polyethylene results in an
uneven graft distribution. Given enough peroxide and coagent, the material will
reach its gel point where there is a small, high molecular weight population with a
disproportionately high graft content, while the remaining chains contained a modest concentration of bound coagent. Furthermore, a survey of the effectiveness of several common coagents in the radical-mediated crosslinking of polyethylene was investigated where it was found that allylic coagents had a greater contribution to the
crosslink density of the resin than vinyl coagents. / Thesis (Master, Chemical Engineering) -- Queen's University, 2008-05-06 19:37:13.916
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A generalized model for crystallization in random copolymersSusarla, Prameela January 2001 (has links)
No description available.
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Novel synthesis of branched vinyl polymersIsaure, Francoise January 2003 (has links)
No description available.
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Physicochemical study of poly (isoprene:styrene) block copolymersGirolamo, Mario January 1971 (has links)
235 leaves : ill. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Thesis (Ph.D.)--Dept. of Physical and Inorganic Chemistry, University of Adelaide, 1972
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