No description available.

No description available.

Corrosion of reinforced concrete is the most challenging durability problem that threatens reinforced concrete structures, especially structures that are subject to severe environmental conditions (i.e., Highway Bridges, Marine structures, etc.). Corrosion of reinforcing steel leads to cracking and spalling of the concrete cover and billions of dollars are spent every year on repairing such damaged structures. New types of reinforcements have been developed in order to avoid these high cost repairs. Thus it is important to study the corrosion behavior of these new types of reinforcements and compare them to the traditional carbon steel reinforcements.<p> This study aimed at characterizing the corrosion behavior of three competing reinforcing steels; conventional carbon steel, micro-composite steel (MMFX-2) and 316LN stainless steel, through experiments in carbonated and non-carbonated concrete exposed to chloride-laden environments. Synthetic pore water solutions have been used to simulate both cases of sound and carbonated concrete under chloride ions attack. A three electrode corrosion cell is used for determining the corrosion characteristics and rates. Multiple electrochemical techniques were applied using a Gamry PC4 potentiostat manufactured by GAMRY INSTRUMENTS. DC corrosion measurements were applied on samples subjected to fixed chloride concentration in the solution. EIS measurements were applied on samples subjected to incremental chloride additions. Furthermore, carbon steel rebars embedded in concrete samples pre-contaminated with chloride ions added to the mix will be used to relate corrosion rates inside concrete to those obtained from synthetic solutions and to measure moisture content inside concrete using a nondestructive TDR-based technique.

Corrosion of reinforced concrete is the most challenging durability problem that threatens reinforced concrete structures, especially structures that are subject to severe environmental conditions (i.e., Highway Bridges, Marine structures, etc.). Corrosion of reinforcing steel leads to cracking and spalling of the concrete cover and billions of dollars are spent every year on repairing such damaged structures. New types of reinforcements have been developed in order to avoid these high cost repairs. Thus it is important to study the corrosion behavior of these new types of reinforcements and compare them to the traditional carbon steel reinforcements.<p> This study aimed at characterizing the corrosion behavior of three competing reinforcing steels; conventional carbon steel, micro-composite steel (MMFX-2) and 316LN stainless steel, through experiments in carbonated and non-carbonated concrete exposed to chloride-laden environments. Synthetic pore water solutions have been used to simulate both cases of sound and carbonated concrete under chloride ions attack. A three electrode corrosion cell is used for determining the corrosion characteristics and rates. Multiple electrochemical techniques were applied using a Gamry PC4 potentiostat manufactured by GAMRY INSTRUMENTS. DC corrosion measurements were applied on samples subjected to fixed chloride concentration in the solution. EIS measurements were applied on samples subjected to incremental chloride additions. Furthermore, carbon steel rebars embedded in concrete samples pre-contaminated with chloride ions added to the mix will be used to relate corrosion rates inside concrete to those obtained from synthetic solutions and to measure moisture content inside concrete using a nondestructive TDR-based technique.

D. Tech. Chemical, Metallurgical and Materials Engineering / Corrosion is the chemical or electrochemical interaction between a material, especially metals, and their environment resulting in mild to severe deterioration of the material and its properties. The economic impact and problems resulting from corrosion has drawn strong attention from scientists and engineers worldwide. Stainless steel is the most important engineering metal worldwide, and industrially stainless steel is used extensively due to its resistance to corrosion e.g. in acid pickling, industrial acid cleaning, acid descaling, oil well acidizing and the petroleum industry. The corrosion resistance of stainless steels is due to the formation of a protective film which covers the steel surface instantaneously when exposed to mild operational conditions in the presence of oxygen; however, the oxide is most often porous and insufficient to protect the steel from further oxidation and corrosion attack in harsh environments. It is hypothesized that: In-depth understanding of the electrochemical behaviour of ferrous alloys in interaction with selected organic compounds in acidic environments will enhance inhibitor application for corrosion control; Failure and poor performance of most inhibitor admixtures can be eliminated with comprehensive knowledge of electrochemical interaction at the metal-inhibitor interface, passive film formation, duration and breakdown, adsorption characteristics, bond formation and molecular structure effect; Optimization of the current electroanalytical method will enhance effective pitting corrosion detection, analysis and control with the use of organic inhibiting compounds. The primary aim of this research is to develop the science required for the effective assessment, development and confident use of organic compounds (heterocyclic compound, organosulphur compound, simple alcohol, aromatic amine compound, aromatic amine derivative and aminoalcohol) and tested alloys (austenitic stainless steel type 304 and mild steel) for applications in astringent environments through conventional and optimized corrosion monitoring techniques.

No description available.

Thesis (Ph. D.)--University of New South Wales, 2002. / Also available online.

Thesis (Ph. D.)--University of Missouri-Columbia, 2007. / The entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file. Title from title screen of research.pdf file (viewed on December 28, 2007) Includes bibliographical references.

In applications where resistance to localised corrosion is required, stainless steel alloys containing molybdenum are generally used thanks to their superior resistance to localised attack in aggressive environments. For ferritic stainless steels, vanadium additions have been found to also have a beneficial effect on the resistance to localised corrosion. In this study vanadium and molybdenum were compared directly as alloying elements in 18% chromium ferritic stainless steel as far as their effect on increasing the resistance to localised corrosion is concerned. Pitting potentials in a neutral chloride solution were used as the criterion for qualifying resistance to localised corrosion and it was shown that vanadium gave similar or slightly higher pitting potentials at addition levels of up to 4% (weight percent). It was subsequently found that the mechanism by which the molybdenum and the vanadium increase the resistance to localised corrosion, are not the same. The experimental data for the molybdenum containing alloys corresponded well with other work done in this field. The positive effect of molybdenum additions on the pitting resistance of these alloys could be explained through its effect in lowering the dissolution rate in the active dissolution region by enriching on the dissolving surface. The vanadium additions to these alloys were shown not to have an effect on the active dissolution kinetics. The effect of these two alloying elements on the initiation of metastable pits were examined, but no meaningful advantage for the vanadium containing alloys over the rest could be found. It is suggested that vanadium play a role in changing the dissolution kinetics of the salt film, which forms during the growth of a metastable pit. A delayed dissolution of salt film remnants would lead to a loss of the enriched pit solution, which would cause the metastable pit to repassivate. / Dissertation (M Eng (Metallurgical Engineering))--University of Pretoria, 2007. / Materials Science and Metallurgical Engineering / unrestricted

The effect of nonstirred aqueous Portland cement solution on the corrosion rates of zinc and cadmium metal using Tafel extrapolation and linear polarization measurements has been investigated. Results indicate that for the corrosion systems under investigation, zinc metal has a higher corrosion potential and lower corrosion rate than cadmium metal.