Concrete is the most widely used construction material worldwide, yet, it presents major sustainability drawbacks due to the CO2 released during the manufacturing of its main constituent, cement. Several approaches are used to improve concrete’s eco-efficiency and reduce the binder intensity index, a metric used to measure the eco-efficiency of concrete, to a value below that of conventional concrete mixtures (i.e., 10 kg/m3.MPa-1 for 25-40 MPa mixtures). Particle Packing Models (PPM) is consequently an approach that can be used to enhance system packing density, reducing cement content while increasing hardened state properties and durability (i.e., reducing porosity). However, packed mixtures normally present issues in the fresh state while their hardened state performance is not fully comprehended. Therefore, this Ph.D. project proposes a new mix-design method called PPM-MP approach to develop eco-efficient mixtures. First, a detailed laboratory investigation was conducted on mixtures developed using the proposed approach in order to understand their fresh and hardened state performance. Concrete samples containing distinct ranges of cement content (320, 250, 200, 150 kg/m3) and slump (180, 90, and 20 +/- 20 mm) were fabricated and a wide range of fresh state tests (pH, temperature, fresh density, air content, slump and rheology over time) and hardened state tests (apparent porosity, surface electrical resistivity, compressive strength, and modulus of elasticity) were performed over time. Then, its performance against the alkali-silica reaction (ASR) induced expansion and deterioration, which is one of the leading and most damaging distress mechanisms issues in durability, was evaluated. In this section of the project, four sustainable concrete mixtures developed with varying cement content (e.g., 325, 250, 200, and 150 kg/m3) were developed and compared to a control mixture containing 420 kg/m3 of cement content. The mixtures were tested over a year under Concrete prism test (CPT) setup, which is the current method used to evaluate concrete ASR and using three different non-boosted test setups (i.e., Wrapped - W, Soaked - S, and Encapsulated - E). Moreover, two distinct types of highly reactive aggregates (e.g., Springhill Greywacke coarse aggregate and Texas Polymictic sand) were selected. Microscopic analysis was used to better understand the impact of ASR on sustainable mixtures, as well as the differences in ASR-damage and crack propagation under different test protocols. The results show the feasibility of producing an eco-efficient mixture in a more efficient manner which may contribute to the Net Zero Concrete targets. The proposed PPM-MP approach improves the sustainability of concrete mixtures and can be used for specific projects requiring 28-day compressive strength ranging from 18 to 45 MPa and slumps (180, 90, and 20 +/- 20 mm).

Im Rahmen des Forschungsprojekts ”TMF-Rissverlaufsberechnung für ATL-Heißteile“ des FVV e.V. wurden Untersuchungen zur Entwicklung eines Rissfortschrittsgesetzes unter thermomechanischer Wechselbeanspruchung (thermo-mechanical fatigue, TMF) für das austenitische Gusseisen Ni-Resist D-5S durchgeführt. Ziel der experimentellen Arbeiten war es, mit einseitig gekerbten Proben (SENT) eine Datenbasis für Risswachstum unter TMF-Belastung zu schaffen. Das Werkstoffverhalten des betrachteten austenitischen Gusseisens Ni-Resist D-5S wurde mithilfe eines validierten viskoplastischen, temperaturabhängigen Materialmodells modelliert, das zur Berücksichtigung großer Verzerrungen und Rotationen am Riss auf große Deformationen erweitert wurde. Zur Beurteilung des Rissfortschritts unter TMF wurde die zyklische Rissspitzenöffnungsverschiebung (ΔCTOD) als geeigneter Beanspruchungsparameter verwendet. Für die Simulation der Rissausbreitung wurde ein automatischer FEM-Algorithmus mit inkrementeller, adaptiver Neuvernetzung entwickelt. Dabei wurden Verformungen und inelastische Zustandsvariablen auf das neue Netz übertragen. Der Einfluss verschiedener Parameter innerhalb der Simulationsstruktur wurde analysiert. Ein verbesserter Mapping-Algorithmus zur Übertragung der Zustandsvariablen wurde entwickelt. Mithilfe begleitender 2D FEM-Simulationen wurden die Rissfortschrittskurven des Werkstoffs basierend auf den experimentellen Daten ermittelt und unter Anwendung des ΔCTOD Konzepts in parametrisierter Form dargestellt. Zusätzlich wurden Rissfortschrittsgesetze durch den Einsatz von Machine-Learning-Konzepten bestimmt. Dies ermöglicht erstmals eine quantitative Vorhersage der Rissentwicklung unter Beanspruchungsbedingungen mit Großbereichsfließen unter Berücksichtigung von TMF. / As part of the research project ”TMF crack propagation calculation for ATL hot parts“ of the FVV e.V., an investigation was carried out to develop a crack propagation law under thermomechanical fatigue (TMF) for the austenitic cast iron Ni-Resist D-5S. The aim of the experimental work was to create a database for crack growth under TMF loading with single edge notch tension specimens (SENT). The material behavior of the austenitic cast iron under consideration, Ni-Resist D-5S, was modeled using a validated viscoplastic temperature dependent material model, which was extended to large deformations to account for large distortions and rotations in the crack. The cyclic crack opening displacement (ΔCTOD) was used as a suitable loading parameter to assess crack propagation under TMF. An automatic FEM algorithm with incremental adaptive remeshing was developed for the simulation of crack propagation. In the process, the deformations and inelastic state variables were transferred to the new mesh. The influence of different parameters within the simulation structure was analyzed. An ideal mapping algorithm for the transfer of state variables was developed. With the help of accompanying 2D FEM simulations, the crack propagation curves of the material were determined on the basis of the experimental data and presented in parameterized form using the concept ΔCTOD. Furthermore, crack propagation laws were determined using machine learning concepts. This allows for the first time a quantitative prediction of crack development under loading conditions with large scale yielding taking TMF into account.

This master thesis project was performed in collaboration with Scania CV AB, Engine Materials group. The purpose with the project was to investigate different ceramic TBC (Thermal Barrier Coating) thermal insulation properties inside the combustion chamber. Experimental testing was performed with a Single-Cylinder engine with TBC deposited on selected components. A dummy-valve was developed and manufactured specifically for this test in order to enable a water cooling system and to ease the testing procedure. The dummy-valve consists of a headlock, socket, valve poppet and valve shaft. Additionally, a copper ring is mounted between the cylinder head and the valve poppet to seal the system from combustion gases. Thermocouples attached to the modified valve poppet and valve shaft measured the temperature during engine test to calculate the heat flux. The TBCs consisted of three different materials: 7-8% yttrium-stabilized zirconia (8YSZ), gadolinium zirconia and lanthanum zirconia. The 8YSZ TBC was tested as standard, but also with microstructural modifications. Modifications such as pre-induced segmented cracks, nanostructured zones and sealed porosity were used. The results indicated that the heat flux of 8YSZ-standard, 8YSZ-nano and 8YSZ-segmented cracks was in level with the steel reference. In the case of 8YSZ-sealed porosity the heat flux was measured higher than the steel reference. Since 8YSZ-standard and 8YSZ-sealed porosity are deposited with the same powder it is believed that the high heat flux is caused by radiative heat transfer. The remaining samples have had some microstructural changes during engine testing. 8YSZ-nano had undergone sintering and its nanostructured zones became fewer and almost gone after engine testing leading to less heat barrier in the top coat of the TBC. However, for 8YSZ-segmented cracks and gadolinium zirconia lower heat flux was measured due to the appearance of horizontal cracks. These cracks are believed to act as internal barriers as they are orientated perpendicular to the heat flow. During long-time (5 hour) engine tests the 8YSZ-standard exhibited the same phenomena: a decrease in heat flux due to propagation of horizontal cracks. One-dimensional heat flux was not achieved and the main reason for that was caused by heating and cooling of the shafts outer surface. However, the dummy-valve system has proven to be a quick, easy and stable to perform tests with a Single-Cylinder engine. Both water-cooling and long-time engine tests were conducted with minor issues. The dummy-valve has been further developed for future tests. Changes to the valve shaft are the most remarkable: smaller diameter to reduce heat transfer and smaller pockets to ensure better thermocouple positioning. Another issue was gas leakage from the combustion chamber through the copper ring and valve poppet joint. The copper ring will be designed with a 1 mm thick track to improve sealing, hence better attachment to the valve poppet.

Les outillages de mise en forme à chaud sont soumis à des sollicitations thermomécaniques transitoires. Ils sont donc confrontés à la fissuration par fatigue. Le but de ce travail est d'étudier le comportement et la durée de vie en fatigue des aciers d'outillage, notamment leurs résistances à la propagation de fissure. Dans un premier temps, les chargements thermiques imposés aux outillages de fonderie sous pression de magnésium et d'emboutissage à chaud ont été évalués. Ensuite, le comportement et la durée de vie de l'acier à haute conductivité thermique HDC1 ont été étudiés et comparés à l'acier AISI H11 (acier de référence) en fonction de la température. L'acier HDC1 présente un adoucissement cyclique stable à 20°C et 300°C. Par contre, l'intensité d'adoucissement est plus importante à hautes températures. La durée de vie a été étudiée en utilisant les lois de Manson-Coffin et de Basquin. A hautes températures, l'oxydation devient un mécanisme d'endommagement primordial pour l'acier HDC1 et provoque des durées de vie plus courtes que celles observées sur l'acier AISI H11. La résistance à la propagation de fissure de fatigue a été déterminée dans des aciers à la température ambiante par le biais de critères : l'amplitude de facteur d'intensité de contrainte (∆K) et l'amplitude d'ouverture en pointe de fissure (∆CTOD). La méthode de corrélation d'images a permis de mesurer (∆COD) et d'évaluer (∆CTOD). L'ensemble de ces résultats a permis de mettre en évidence l'effet de fermeture de fissure et le comportement plastique en pointe de fissure. ∆CTOD présente un bon critère pour rationaliser la propagation de fissure dans les aciers étudiés.Enfin, la simulation numérique de la propagation de fissure en fatigue a été menée dans l'acier AISI H11 à 600°C par la méthode de relâchement des nœuds en éléments finis. L'effet des modèles de comportement monotone (élastoplastique) et cyclique (élastoviscoplastique) a été étudié sur le calcul de l'ouverture de fissure et la plasticité en pointe de fissure. L'influence du modèle de comportement est faible sur le calcul de l'amplitude d'ouverture de fissure ∆COD, du fait d'une plasticité confinée en pointe de fissure. Alors que, le modèle de comportement cyclique est mieux adapté pour décrire la plasticité en pointe de fissure. / Hot metal forming tools are subjected to cyclic thermomechanical loading and damage by complex fatigue/wear/oxidation interactions. Thermal solicitations were measured on high pressure die casting and hot stamping processes. Based on thermal measurements, the isothermal fatigue behaviour and lifetime of a new high conductivity steel HDC1 were investigated at different temperatures and strain amplitude then compared to AISI H11 steel. As AISI H11, continue cyclic softening was observed in HDC1 at all temperatures. The Manson-Coffin and Basquin laws were used for life prediction models under different temperatures. It was observed that the fatigue/oxidation interaction was a principal damage mechanism of the HDC1 steel at high temperature. Fatigue crack propagation in steels was investigated at room temperature in SENT specimens. A digital image correlation technique was used to evaluate crack opening (∆COD) and crack tip opening displacement (∆CTOD) ranges. Crack growth rate were investigated using ∆K (Paris law) and ∆CTOD criteria. It was observed that the cyclic crack tip plasticity control the crack propagation resistance. Crack closure could be evaluated by ∆CTOD.Finite element method by debond technique was used to model the crack propagation of AISI H11 at 600°C using both monotonic elasto-plastic (EP) and cyclic elasto-viscoplastic (EVP) constitutive laws materials. The comparison of ∆COD calculated and measured had shown that monotonic EP and cyclic EVP had no significant effect on the ∆COD, mainly due to the small-scale yielding conditions. It is however observed that the cyclic constitutive law was the best suitable model for the crack tip plasticity effect.

Ziel der vorliegenden Arbeit war es, die Zusammenhänge zwischen der molekularen Architektur, Morphologie und den mechanischen bzw. bruchmechanischen Eigenschaften in S-SB-S-Triblockcopolymeren und deren Blends und in PI-PS-Multipfropfcopolymeren herauszuarbeiten und damit einerseits einen Beitrag für das Verständnis der Struktur-Eigenschaftsbeziehungen in Block- und Pfropfcopolymeren zu leisten und andererseits Möglichkeiten zur Entwicklung neuer Materialien aufzuzeigen, welche besondere Eigenschaftskombinationen aufweisen und damit ein bedeutendes Interesse für industrielle Anwendungen hervorrufen. Für die Untersuchungen wurde dabei der PS-Außenblockanteil und das S/B-Verhältnis im SB-Mittelblock in S-SB-S-Triblockcopolymeren, die Thermoplast/Thermoplastisches Elastomer (TP/TPE) -Zusammensetzung in S-SB-S-Triblockcopolymer-Blends sowie die Funktionalität und die Anzahl der Verknüpfungspunkte in PI-PS-Multipfropfcopolymeren variiert. Zur Charakterisierung der Phasenmischbarkeit und der Morphologie wurden die dynamisch mechanische Analyse (DMA), die Transmissionselektronenmikroskopie (TEM) und die Röntgenkleinwinkelstreuung (SAXS) angewandt. Die mechanischen Eigenschaften wurden mit dem einachsigen Zugversuch untersucht. Bruchmechanische Untersuchungen erfolgten unter Anwendung der „Essential Work of Fracture“- (EWF-) Methode, welche als Konzept der „Post-Yield“-Bruchmechanik innerhalb der Fließbruchmechanik für duktile nanostrukturierte polymere Materialien sehr gut anwendbar ist und Aussagen zur Bruchzähigkeit der Materialien liefert. Zur näheren Charakterisierung des zeitaufgelösten Deformationsverhaltens sowie der Rissausbreitungskinetik wurden die Dehnungsfeldanalyse, eine Bruchflächenanalyse mittels Rasterelektronenmikroskopie (REM) sowie das Risswiderstandskurven-Konzept angewandt. Die Untersuchungen der S-SB-S-Triblockcopolymersysteme und der PI-PS-Multipfropfcopolymere konnten den signifikanten Einfluss der molekularen Architektur, der Blockzusammensetzung und des PS-Gehaltes auf das Phasenverhalten, die Morphologie und die Eigenschaften klar herausstellen. Durch die Variation dieser Parameter kann das Eigenschaftsspektrum von thermoplastisch zu elastomer eingestellt und somit sowohl TPs oder TPEs mit hoher Steifigkeit und Zähigkeit als auch TPEs mit superelastischem Charakter erzeugt werden. Daraus eröffnet sich ein breiter Anwendungsbereich dieser Materialien, welche aufgrund ihrer Transparenz und physiologischen Verträglichkeit auch interessante optische und gesundheitliche Vorteile mitbringen. Es konnte gezeigt werden, dass durch die systematische Variation der Architektur die gezielte Einstellung gewünschter Eigenschaftsprofile möglich ist. Die Arbeit leistet somit einen Beitrag zur Entwicklung anwendungsorientierter Materialkonzepte, welche ingenieurwissenschaftlich interessant sind. / The aim of this thesis was to study the relation between molecular architecture, morphology and (fracture) mechanical properties of S-SB-S triblock copolymers and PI-PS multigraft copolymers. Hence, this work should contribute to the understanding of structure-property-relationship in block and multigraft copolymers and thus offer possibilities for the development of novel materials with special properties interesting for industrial application. Within this study in the case of S-SB-S triblock copolymers the PS outer block content and the S/B ratio of the middle block, in the case of S-SB-S triblock copolymer blends the thermoplast/thermoplastic elastomer (TP/TPE) composition and in case of PI-PS multigraft copolymers the functionality and number of branch points were varied. For the characterisation of morphology and phase miscibility dynamic mechanical analysis (DMA), transmission electron microscopy (TEM) and small angle X-ray scattering (SAXS) were applied. Uniaxial tensile tests were carried out to investigate the mechanical properties. The fracture mechanical behaviour was studied using essential work of fracture (EWF) concept based on the post yield fracture mechanic principles, which is suitable to characterise fracture toughness of ductile nanostructured materials. The time resolved analysis of deformation and fracture behaviour was characterised qualitatively by strain field analysis, scanning electron microscopy (SEM) of the fractured surfaces and quantitatively by evaluation of the crack propagation kinetics and construction of R-curves. This study clearly highlights the significant influence of molecular architecture block composition and PS content on the phase behaviour, morphology and properties of S-SB-S triblock copolymers and PI-PS multigraft copolymers. By varying these parameters the property profile can be adjusted diversifying from thermoplastic to elastomeric and both TP or TPE materials with high stiffness and toughness and TPEs with super-elastic characteristics can be designed. Hence, fundamentally it offers a broad scope of application of these materials, in which physiological compatibility and transparency are added advantages. Thus, conceptually it could be shown, that by systematic variation of the architecture desired property profiles can be adjusted. Therefore the present work contributes to the development of application-oriented material concepts, which are interesting in engineering terms.

科学研究費補助金 研究種目:基盤研究(B)(2) 課題番号:09450047 研究代表者:田中 啓介 研究期間:1997-1999年度

Soy flour (SF), a by-product of the soybean oil extraction processing, was investigated for its application in soy-polypropylene composites for interior automotive applications. The emphasis of this work was the understanding of this new type of filler material and the contribution of its major constituents to its thermal stability and impact properties. For this reason, reference materials were selected to represent the protein (soy protein isolate (SPI)) and carbohydrate (soy hulls (SH)) constituents of the soy flour. Additional materials were also investigated: the residue obtained after the protein removal from the soy flour which was called insoluble soy (IS), and the remaining liquid solution after acid precipitation of the proteins, containing mostly sugars and minerals, which was called soluble sugar extract (SSE). Two treatments, potassium permanganate and autoclave, were analyzed for their potential to modify the properties of the soy composite materials. An acid treatment with sulfuric acid conducted on soy flour was also considered. The soy materials were studied by thermogravimetric analysis (TGA) under isothermal (in air) and dynamic (in nitrogen) conditions. SPI had the highest thermal stability and SSE the lowest thermal stability for the early stage of the heating process. Those two materials had the highest amount of residual mass at the end of the dynamic TGA in nitrogen. The two treatments showed minimal effect on the isothermal thermal stability of the soy materials at 200 ??C. A minor improvement was observed for the autoclave treated soy materials. Fourier transformed infrared (FTIR) spectroscopy indicated that the chemical surface composition differed according to type of the soy materials but no difference could be observed for the treatments within one type of soy material. Contact angle analysis and surface energy estimation indicated differences of the surface hydrophobicity of the soy materials according to type of material and treatment. The initial water contact angle ranged from 57 ?? for SF to 85 ?? for SH. The rate of water absorption increased dramatically after the autoclave treatment for IS and SPI. Both materials showed the highest increase in the polar surface energy fraction. In general, the major change of the surface energy was associated with change of the polar fraction. After KMnO4 treatment, the polar surface energy of SF, IS and SPI decreased while SH showed a slight increase after KMnO4 treatment. A relationship between protein content and polar surface energy was observed and seen to be more pronounced when high protein containing soy materials were treated with KMnO4 and autoclave. Based on the polar surface energy results, the most suitable soy materials for polypropylene compounding are SPI (KMnO4), SH, and IS (KMnO4) because their polar surface energy are the lowest which should make them more compatible with non-polar polymers such as polypropylene. The soy materials were compounded as 30 wt-% material loading with an injection moulding grade polypropylene blend for different combinations of soy material treatment and coupling agents. Notched Izod impact and flexural strength as well as flexural modulus estimates indicated that the mechanical properties of the autoclaved SF decreased when compared to untreated soy flour while the potassium permanganate treated SF improved in impact and flexural properties. Combinations of the two treatments and two selected (maleic anhydride grafted polypropylene) coupling agents showed improved impact and flexural properties for the autoclaved soy flour but decreased properties for the potassium permanganate treated soy flour. Scanning electron microscopy of the fractured section, obtained after impact testing of the composite material, revealed different crack propagation mechanisms for the treated SF. Autoclaved SF had a poor interface with large gaps between the material and the polypropylene matrix. After the addition of a maleic anhydride coupling agent to the autoclaved SF and polypropylene formulation, the SF was fully embedded in the polymer matrix. Potassium permanganate treated SF showed partial bonding between the material and the polymer matrix but some of the material showed poor bonding to the matrix. The acid treated SF showed cracks through the dispersed phase and completely broken components that did not bind to the polypropylene matrix. In conclusion, the two most promising soy materials in terms of impact and flexural properties improvement of soy polypropylene composites were potassium permanganate treated SF and the autoclaved SF combined with maleic anhydride coupling agent formulation.

Diploma thesis deals with topic of using aramid (Kevlar) fibres in road engineering in asphalt mixtures. Theoretical part of thesis is describing characteristics of aramid fibres and their technical usage. Thesis deals with research and application of aramid fibres abroad and also in Czech Republic. Practical part deals with influence of aramid fibres, namely FORTA FI fibres in mixture with modified binder for wearing course. An integral part of this thesis is a description of all methods that were used during the processing of the practical part. In the end of the thesis there are outcomes of tests and theoretical research.

Cette étude a pour objectif principal d’établir une stratégie de modélisation robuste, fiable et performante pour décrire des propagations de fissures d’échelle centimétrique en régime ductile dans des composants industriels. Le modèle d’endommagement de GTN écrit en grandes déformations est utilisé pour modéliser l’endommagement ductile. Ce modèle conduit généralement à une localisation de la déformation, conformément à l’expérience. L’échelle caractéristique de ce phénomène est introduite dans les équations de comportement via l’adoption d’une formulation non locale.Sur le plan numérique, ce modèle non local rend bien compte de la localisation dans une bande d’épaisseur donnée lorsqu’on raffine suffisamment le maillage. Par ailleurs, le problème de verrouillage numérique associé au caractère initialement isochore de la déformation plastique est limité en utilisant une formulation à base d’éléments finis mixtes. Enfin, la distorsion des éléments totalement cassés (i.e. sans rigidité apparente), qui pourrait nuire à la bonne convergence des simulations numériques, est traitée par une régularisation viscoélastique.L’ensemble de ces ingrédients sont appliqués pour simuler la propagation de fissure dans un milieu infini plasticité confinée), de sorte à établir un lien avec les approches globales en J-Δa. L’émoussement, l’amorçage et la (grande) propagation de fissure sont bien prédits. Le modèle est également appliqué à une tuyauterie métallique testée en grandeur réelle dans le cadre du projet européen Atlas+. Après une phase d’identification des paramètres sur éprouvette, les réponses globales et locales d’autres éprouvettes et du tube sont confrontés aux résultats expérimentaux. Ces résultats illustrent le degré de robustesse, de fiabilité et de performance qu’on peut attendre du modèle. / The major goal of this work is to establish a robust, reliable and efficient modeling technique so as to describe ductile tearing over a distance of several centimeters in industrial cases. The GTN damage model expressed in the context of finite strains is chosen to model ductile damage. Generally, the model leads to strain localization in agreement with experimental observations. The characteristic length scale of this phenomenon is introduced into the constitutive equations through the use of a nonlocal formulation.On a numerical ground, the nonlocal model controls the width of the localization band as soon as the mesh is sufficiently refined. Besides, the issue of volumetric-locking associated with plastic incompressibility is handled using a mixed finite element formulation. Finally, the distortion of broken elements (i.e. without any stiffness), which may affect the computational convergence of numerical simulations, is treated using a viscoelastic regularization.The improved GTN model is applied to simulate crack propagation under small-scale yielding conditions, so as to establish a relation with the global (J-Δa) approach. Crack tip blunting, crack initiation and (large) crack propagation are well captured. The model is also applied to a full-scale metallic pipe in the framework of the UE project Atlas+. After a phase of parameter calibration based on the experimental results on some small specimens, the global and local responses of other small specimens and of the full-scale pre-cracked pipe are compared with the experimental results. The results illustrates the robustness, the reliability and the efficiency of the current model.

Ziel der vorliegenden Arbeit war es, die Zusammenhänge zwischen der molekularen Architektur, Morphologie und den mechanischen bzw. bruchmechanischen Eigenschaften in S-SB-S-Triblockcopolymeren und deren Blends und in PI-PS-Multipfropfcopolymeren herauszuarbeiten und damit einerseits einen Beitrag für das Verständnis der Struktur-Eigenschaftsbeziehungen in Block- und Pfropfcopolymeren zu leisten und andererseits Möglichkeiten zur Entwicklung neuer Materialien aufzuzeigen, welche besondere Eigenschaftskombinationen aufweisen und damit ein bedeutendes Interesse für industrielle Anwendungen hervorrufen. Für die Untersuchungen wurde dabei der PS-Außenblockanteil und das S/B-Verhältnis im SB-Mittelblock in S-SB-S-Triblockcopolymeren, die Thermoplast/Thermoplastisches Elastomer (TP/TPE) -Zusammensetzung in S-SB-S-Triblockcopolymer-Blends sowie die Funktionalität und die Anzahl der Verknüpfungspunkte in PI-PS-Multipfropfcopolymeren variiert. Zur Charakterisierung der Phasenmischbarkeit und der Morphologie wurden die dynamisch mechanische Analyse (DMA), die Transmissionselektronenmikroskopie (TEM) und die Röntgenkleinwinkelstreuung (SAXS) angewandt. Die mechanischen Eigenschaften wurden mit dem einachsigen Zugversuch untersucht. Bruchmechanische Untersuchungen erfolgten unter Anwendung der „Essential Work of Fracture“- (EWF-) Methode, welche als Konzept der „Post-Yield“-Bruchmechanik innerhalb der Fließbruchmechanik für duktile nanostrukturierte polymere Materialien sehr gut anwendbar ist und Aussagen zur Bruchzähigkeit der Materialien liefert. Zur näheren Charakterisierung des zeitaufgelösten Deformationsverhaltens sowie der Rissausbreitungskinetik wurden die Dehnungsfeldanalyse, eine Bruchflächenanalyse mittels Rasterelektronenmikroskopie (REM) sowie das Risswiderstandskurven-Konzept angewandt. Die Untersuchungen der S-SB-S-Triblockcopolymersysteme und der PI-PS-Multipfropfcopolymere konnten den signifikanten Einfluss der molekularen Architektur, der Blockzusammensetzung und des PS-Gehaltes auf das Phasenverhalten, die Morphologie und die Eigenschaften klar herausstellen. Durch die Variation dieser Parameter kann das Eigenschaftsspektrum von thermoplastisch zu elastomer eingestellt und somit sowohl TPs oder TPEs mit hoher Steifigkeit und Zähigkeit als auch TPEs mit superelastischem Charakter erzeugt werden. Daraus eröffnet sich ein breiter Anwendungsbereich dieser Materialien, welche aufgrund ihrer Transparenz und physiologischen Verträglichkeit auch interessante optische und gesundheitliche Vorteile mitbringen. Es konnte gezeigt werden, dass durch die systematische Variation der Architektur die gezielte Einstellung gewünschter Eigenschaftsprofile möglich ist. Die Arbeit leistet somit einen Beitrag zur Entwicklung anwendungsorientierter Materialkonzepte, welche ingenieurwissenschaftlich interessant sind. / The aim of this thesis was to study the relation between molecular architecture, morphology and (fracture) mechanical properties of S-SB-S triblock copolymers and PI-PS multigraft copolymers. Hence, this work should contribute to the understanding of structure-property-relationship in block and multigraft copolymers and thus offer possibilities for the development of novel materials with special properties interesting for industrial application. Within this study in the case of S-SB-S triblock copolymers the PS outer block content and the S/B ratio of the middle block, in the case of S-SB-S triblock copolymer blends the thermoplast/thermoplastic elastomer (TP/TPE) composition and in case of PI-PS multigraft copolymers the functionality and number of branch points were varied. For the characterisation of morphology and phase miscibility dynamic mechanical analysis (DMA), transmission electron microscopy (TEM) and small angle X-ray scattering (SAXS) were applied. Uniaxial tensile tests were carried out to investigate the mechanical properties. The fracture mechanical behaviour was studied using essential work of fracture (EWF) concept based on the post yield fracture mechanic principles, which is suitable to characterise fracture toughness of ductile nanostructured materials. The time resolved analysis of deformation and fracture behaviour was characterised qualitatively by strain field analysis, scanning electron microscopy (SEM) of the fractured surfaces and quantitatively by evaluation of the crack propagation kinetics and construction of R-curves. This study clearly highlights the significant influence of molecular architecture block composition and PS content on the phase behaviour, morphology and properties of S-SB-S triblock copolymers and PI-PS multigraft copolymers. By varying these parameters the property profile can be adjusted diversifying from thermoplastic to elastomeric and both TP or TPE materials with high stiffness and toughness and TPEs with super-elastic characteristics can be designed. Hence, fundamentally it offers a broad scope of application of these materials, in which physiological compatibility and transparency are added advantages. Thus, conceptually it could be shown, that by systematic variation of the architecture desired property profiles can be adjusted. Therefore the present work contributes to the development of application-oriented material concepts, which are interesting in engineering terms.