The application of visible/near-infrared hyper-spectral analysis to monitor the quality of frying oil and fried breaded chicken nuggets was investigated. / Partial least squares (PLS) calibration models were developed to predict the acid value, total polar components and viscosity of heated oils with different ratios of hydrogenation. Coefficient of determination (R2) and root mean square error (RMSE) were calculated to assess the performance of each model. Results of the study demonstrated good prediction ability of the calibration models for the quality parameters with R2 values of over 0.92. / The second study was based on developing calibration models for prediction of moisture and fat contents of fried breaded chicken nuggets with different levels of moisture and fat contents. Performing the same procedure for evaluation of the PLS calibration models, results of the study demonstrated that moisture and fat contents of fried breaded chicken nuggets could be predicted with R2 values of 0.92.

This study presents techniques that can be applied to optimize the quality of coated fried chicken nuggets. / Heat and mass transfer during deep fat frying of breaded chicken nugget was simultaneously modeled using the moving boundary concept. Numerical software FEMLABRTM 3.0 was used to solve the proposed model. To validate the model, experiments were conducted. Chicken nuggets were made with wheat flour based batter and breading. The samples were fried in a fryer using oil temperatures at 160, 170 and 180°C. Total frying times ranged from 90 to 300 s. A good agreement was obtained between predicted and observed results. / During the deep-frying process, the chicken nuggets samples shrank because of moisture loss and protein denaturation. Particle density and bulk volume shrinkage were analyzed at 3 different frying temperatures (160, 170 and 180°C). Particle density and shrinkage of the samples was measured using the liquid displacement technique with water. A linear relation was found for particle densities with moisture loss. The relationship between volumetric shrinkage and moisture loss was also found to be linear and the linear equation may be useful in predicting the volumetric shrinkage during frying. / In order to reduce the oil absorption of chicken nuggets during the frying process, the influence of pretreatment in microwave on the moisture and oil transfer in the coating and core layers of coated chicken nuggets were studied. Chicken nuggets pretreated in a microwave oven for 1 or 2 min were fried at 160°C for times ranging from 90 to 300 s to evaluate oil transfer. Microwave pretreatment had an important effect on moisture loss and oil uptake of chicken nuggets during deep-fat frying.

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No description available.

The present study sought for practical ways to improve the frying performance of oils without compromising the availability of the essential fatty acids and nutraceuticals. To this end, the influence of temperature, oxygen concentrations, and compositions of minor components on frying performance was investigated. A novel frying protocol, utilizing carbon dioxide blanketing, was developed and found to significantly improve the performance of the frying oil. Optimizing both the amounts and the compositions of endogenous minor components also improved the performance of the frying oil. Twenty one novel antioxidants were synthesized and evaluated under frying and storage conditions. Antioxidant formulations consisting of a combination of endogenous and synthesized antioxidants were developed and tested in an institutional frying operation. A rapid and effective frying test was developed to assess the frying performance of oils and applied antioxidants. Furthermore, a novel procedure for direct hydroxynonenal analysis in frying oil was developed. / xx, 249 leaves; 29 cm

La friture profonde de type batch a été étudiée dans le projet FUI Fry’In (Réf. AAP17, 2014-2018) dans le but de proposer des innovations de rupture pour des friteuses batch domestiques et professionnelles. La thèse a appuyé le projet sur la maîtrise de deux effets négatifs de la friture : i) la thermo-oxydation de l’huile responsable des mauvaises odeurs et produits de dégradation ainsi que ii) la prise d’huile généralement favorisée au détriment de son égouttage. L’étude a été réalisée en combinant des mesures directes (spectroscopie et imagerie infrarouges en mode ATR, photo-ionisation, mesures DSC, imagerie rapide…) et modélisation multi-échelle (écoulement de l’huile et égouttage lors du retrait, description lagrangienne des réactions en présence d’un écoulement, couplage avec les ciné-tiques de dissolution de l’oxygène). La complexité du processus de thermo-oxydation a été réduite en considérant les hydroperoxydes comme une forme de stockage organique de l’oxygène, qui propage l’oxydation dans des régions en anoxie. Leur décomposition produit de nombreux composés de scission, dont la nature est influencée par les conditions locales de température et de concentration en oxygène. La prise d’huile a été décrite comme le bilan net entre l’huile charriée au moment du retrait et l’huile égouttée. L’égouttage a été étudié sur des barreaux métalliques et des produits réels. Il se conduit à la formation de quatre à huit gouttes en quelques secondes. Les cinétiques de drainage anisothermes ont été prédites par un modèle mécanistique. Le mécanisme spécifique de prise d’huile en cours de friture a été aussi analysé ; il se produit uniquement dans le cas des produits préfrits congelés. / Batch deep-frying has been investigated within the collaborative project FUI Fry’In (ref. AAP17, 2014-2018) with the aim of proposing breakthrough innovations for small and medium size appliances. The PhD thesis was part of the project and focused on two specific adverse effects of deep-frying on food products: oil thermo-oxidation responsible for break-down products and off-flavors, and oil pickup process usually favored relatively to oil dripping. The work was carried out by combing direct measurements (FTIR-ATR spectroscopy and imaging, photoionization, DSC measurements, fast imaging…) and multiscale modeling (oil flow and oil dripping during product re-moval, Lagrangian description of reactions in aniso-thermal flows, coupling with oxygen dissolution kinetics). The complex problem of thermo-oxidation was split into simpler mechanisms by noticing that hydroperoxides are a kind of long-lived form of or-ganic oxygen, which trigger propagation in deep re-gions under anoxia. Their decomposition lead to various scission products, which were shown to be in-fluenced by both local temperature and oxygen con-centration. Oil uptake was described as the net balance between the amount of dragged oil during product removal and oil dripping at the tips of the product. The dripping process studied on both metal-lic sticks and real products occurs in less than few seconds and leads to a formation of four to eight drop-lets. The detailed drainage kinetics in anisothermal conditions were captured and predicted with the pro-posed mechanistic models. The specific mechanism of oil uptake during the immersion stage was eluci-dated and was shown to occur only in parfried frozen products.