<p> The objectives of the present study were to investigate the reaction mechanisms and the effects of certain physical variables on the overall reaction rate of the conversion of aqueous Na2S to gaseous H2S by bubbling with CO2 gas, which is a simultaneous absorption-desorption reaction.</p> <p> The dependence of reaction rate on the physical variables investigated were the volumetric flow rate and the CO2 partial pressure of inlet gas and reaction temperature. Potential advantages of a pressurized reaction system were also studied. It was found that the effect of reaction temperature on the overall reaction rate was relatively small as compared to that of inlet gas flow rate and CO2 partial pressure.</p> <p> Gas-liquid interfacial area was estimated and the overall reaction rate constant determined. It was found that the carbonation conversion of Na2S is first order with respect to both the HS- ion concentration of the liquid phase and the CO2 partial pressure of the inlet gas.</p> <p> The rate limiting step of the overall conversion reaction, under the present laboratory conditions, appeared to be the desorption of hydrogen sulfide.</p> / Thesis / Master of Science (MSc)

<p> An Experimental investigation has been conducted to determine the effects on degree of reduction and efficiency of utilization of gases of changes in the levels of several variables when reducing fixed beds of commercial hematite pellets. The effects on reduction behaviour of changes in the levels of reducing gas composition and flow rate, and reaction temperature, were determined by graphical and numerical techniques.</p> / Thesis / Master of Engineering (MEngr)

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Orientador: João Batista Aparecido / Banca: Jose Luiz Gasche / Banca: Paulo Gilberto de Paula Toro / Resumo: Cavitação em bombas centrífugas é a formação de bolhas de vapor do fluido bombeado na região de sucção do equipamento. As bolhas de vapor formadas em algum local do escoamento, em geral na região de sucção da bomba, entrarão posteriormente em colapso. Este fenômeno é importante cientificamente, tecnicamente e economicamente. Cientificamente é interessante, pois envolve o escoamento de um fluido em estado líquido, simultaneamente ocorre a formação de bolhas de vapor, que também escoam juntamente ao fluido líquido. O processo de vaporização e condensação de um fluido é complexo, pois envolve mudança de fase, um fenômeno térmico não linear. Tecnicamente, é importante porque quando o escoamento se dá com cavitação os parâmetros hidrodinâmicos do escoamento bem como da bomba, em geral, são fortemente alterados na direção termodinâmica de maior produção de irreversibilidades. Economicamente, é custoso porque a cavitação, em geral, leva a perda de eficiência termodinâmica dos processos e em conseqüência haverá maior custo na produção de um dado bem, diminuindo a eficiência econômica e a competitividade da empresa. O escoamento com cavitação na sucção de bombas apresenta três aspectos danosos principais: cavitação pulsante com baixa vazão; cavitação não pulsante com baixa altura útil; e erosão cavitacional. A cavitação pulsante é caracterizada por grande formação de bolhas de forma transitória com baixa freqüência e grande amplitude, gerando forças vibratórias importantes no sistema de bombeamento. A cavitação pulsante também causa colapso do fluxo de massa do fluido bombeado com valores que vão do fluxo normal da instalação até valores quase nulos, transitoriamente. Na cavitação pulsante a erosão cavitacional e a queda na altura útil são pequenas... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: Cavitation in centrifugal pumps is the development of vapor bubbles from the pumped liquid into equipment suction region. Vapor bubbles developed somewhere in the flow, generally in the pump suction, will afterwards along the flow to collapse. This phenomenon is scientifically, technically and economically important. Scientifically, it is interesting because involves the flow of a fluid on liquid state, and simultaneously happens vapor bubbles development that also flow together the liquid fluid. Fluid vaporization and condensation processes are complex because involves phase change, a non-linear thermal phenomenon. Technically, it is important because when the flow happens with cavitation the flow and pump hydrodynamic parameters, generally, are strongly modified toward bigger thermodynamic irreversibility production. Economically, it is expensive because cavitation, generally, leads to thermodynamic process efficiency loss, and consequently it will have bigger costs for production of a given good, then decreasing economic efficiency and company competitiveness. Flow with cavitation in the pump suction presents three main devastating aspects: surging cavitation with low flow rate; steady cavitation with low total head; and cavitational erosion. Surging cavitation is characterized by unsteady, low frequency and high amplitude, intense bubbles development, producing strong vibration forces into the pumping system. Surging cavitation also causes the collapse of pumped fluid mass flow rate with values that goes from the normal flow to values that almost reach the zero flow, unsteadily. In surging cavitation, the cavitational erosion and the breakdown in total head are small. In steady cavitation the mass flow rate, and even the flow rate... (Complete abstract click electronic access below) / Mestre

[pt] A fim de garantir a segurança das instalações marítimas de produção de óleo e gás natural, parte do gás produzido é continuamente queimada, em função de condições específicas. Tais condições incluem paradas de emergência ou o alívio de inventário de gás devido a flutuações operacionais. A queima nestes ambientes acontece a uma grande faixa de vazões de gás, o que resulta em reduzido número de alternativas tecnológicas para sua medição. A medição de vazão a partir da tecnologia ultrasônica por tempo de trânsito vem sendo largamente utilizada, porém com incertezas relativamente elevadas, dadas as limitações da solução tecnológica. Devido a tais limitações, diversos órgãos reguladores da área de óleo e gás ao redor do mundo admitem diferentes percentuais para estimativa de incerteza da queima. No Brasil, a regulamentação estabelece um percentual máximo de 5 porcento para a queima de gás, não sendo porém específica quanto a que grandeza refere-se (vazão volumétrica ou volume). Esta dissertação traz um estudo sobre a incerteza de volumes horários, diários e mensais de gás produzidos por uma unidade de produção marítima por dezesseis meses, avaliando o impacto da incerteza na medição de vazão de queima sobre a incerteza dos volumes apurados. Foi avaliado o impacto de aspectos da medição ultrasônica de vazão de gás e da computação de volumes de produção a partir desta nos volumes apurados. Conclui-se que a medição de vazão e sua respectiva incerteza afetam de modo pouco significativo a incerteza dos volumes computados de queima. / [en] In order to assure safety at maritime oil & gas production facilities, part of the produced gas is continually burned (flared), depending upon specific operating conditions. These conditions include emergency shutdown and gas inventory relief due to process fluctuations. In such environments, gas flaring occurs at very large flow rate range, reducing the number of available technological choices for flow rate measurement. Transit-time ultrasonic flow measurement has been commonly used for this task, although with relatively high uncertainties due to technology limitations. Because of that, various oil & gas regulator authorities around the world impose different rules for flare measurement uncertainty. In Brazil, the regulation establishes a maximum percentage of 5 percent for flare measurement uncertainty, but it is not specific about the target (flow rate or volume). This dissertation presents a study on the effects of flow rate uncertainty on hourly, daily and monthly produced volume uncertainty in the maritime environment for a 16-month period, evaluating the impact of flare flow rate measurement on volume uncertainty. Aspects of gas transit-time ultrasonic flow rate measurement and volume computation over resulting volumes are evaluated. The conclusion is that flow rate measurement and its associated uncertainty have little effect on computed volume uncertainties.

The main objective of this study is to explore the complex fluid flow phenomena that result in the generation of a high frequency noise in counterbalance valves through an experimental and numerical investigation of the flow. Once the influence of the different components involved in noise generation is established, a secondary objective is the introduction of design modifications that eliminate the undesired effect without altering the operation envelope or the performance of the valve. A hydraulic test bench was used to carry out an experimental investigation of the noise generation process. A computer based data acquisition system was used to record pressure fluctuations, flowrates and hydraulic oil temperatures in a production valve under a variety of operational conditions. Extensive experimental measurements and numerical modeling lead to the hypothesis that noise generation is the result of an acoustic resonance triggered by shear layer instability at the valve inlet. The pressure gradients developed when the shear layer entrains the stagnant fluid in the valve main cavity cause the layer to become unstable and oscillate. The oscillation frequency will depend on a great number of factors such as valve geometry, pressure and velocity gradients and the density and viscosity of the fluid. It is postulated that the observed noise is generated when this frequency matches one of the resonant frequencies of the valve cavity. The proposed mechanism is theoretically poorly understood and well beyond simplified analysis, its accurate numerical simulation is computational very intensive requiring sophisticated CFD codes. The numerical investigation was carried out using STAR–CCM+, a commercially available CFD code featuring 3-D capabilities and sophisticated turbulence modeling. Streamline, pressure, velocity-vector and velocity-scalar plots were obtained for several valve configurations using steady and unsteady state flow simulations. An experimental and numerical analysis of an alternative valve geometry was carried out. Experimental results demonstrated a greatly reduced instability range. The numerical analysis of the unsteady behavior of the shear-layer streamlines for both valves yielded results that were compatible with the experimental work. The results of this investigation promise a great positive impact on the design of this type of hydraulic valves.