A Nappe Lima Duarte está situada no sudeste do Orógeno Brasília. É constituída por paragnaisses migmatíticos com granada, sillimanita, biotita e muscovita, e ortoquartzitos grossos, com intercalações esparsas de gnaisses calciossilicáticos e de anfibolitos. O Complexo Mantiqueira, infraestrutura alóctone da nappe, ocorre na forma de lascas tectonicamente imbricadas na mesma. É constituído por ortognaisses migmatíticos e polimetamórficos, tipo TTG, com intercalações de rochas metabásicas granulíticas, na forma de enclaves máficos alongados e boudins, geralmente concordantes com a foliação principal. Também ocorrem rochas charnockíticas aparentemente intrusivas nos ortognaisses Mantiqueira, com rochas metabásicas associadas. A associação mineral observada nos paragnaisses (Grt + Bt + Sil + Pl + Rt +Ilm + Qtz ± Ms ± Kfs ± Ky) é relacionada a um metamorfismo progressivo de fácies anfibolito superior, caracterizado por reações de quebra de muscovita e geração de feldspato potássico. As condições de pico bárico obtidas no THERMOCALC para a associação com cianita são de 10 ± 0.6 kbar, a 807 ± 25ºC. O pico térmico de 827 ± 44ºC a 8.2 ± 1.8 kbar, no limite da curva de quebra da dumortierita, foi obtido no THERMOCALC com a associação mineral envolvendo sillimanita. As rochas metabásicas inseridas nos ortognaisses do Complexo Mantiqueira e rochas charnockíticas associadas apresentam a associação Grt-Cpx-Pl-Qtz±Opx+Hbl, que é diagnóstica do fácies granulito de alta pressão. São caracterizadas pela presença de texturas coroníticas progressivas de Grt-Cpx-Pl-Qtz nos contatos entre Opx, Pl e/ou opacos, aparentemente de origem ígnea, que marca a passagem do campo dos granulitos de pressão intermediária para o campo dos granulitos de alta pressão. As condições de pico registradas nos veios constituídos por Grt-Cpx-Pl nos metagabronoritos é de 831.8ºC, a 10 kbar. O granada granulito registra o pico metamórfico a 890 ± 41ºC, a 9.26 ± 1.93 kbar. Cálculos realizados no TWEEQU forneceram condições de equilíbrio de 801ºC, a 9.6 kbar para a associação de fácies granulito. As condições de pico bárico nas rochas charnockíticas são de 14.36 ± 1.9 kbar, a 680ºC, enquanto que as temperaturas máximas registradas são de 885.17ºC, a 10 kbar. Cálculos realizados no THERMOCALC forneceram temperatura de 771 ± 166ºC, a 11.8 ± 2.4 kbar. As rochas metabásicas relacionadas ao Complexo Mantiqueira apresentam baixas concentrações de elementos LILE, possivelmente devido ao empobrecimento destes elementos durante o metamorfismo através de perdas por reações de desidratação. Os dados geoquímicos apontam fontes do tipo E-MORB para grande parte das rochas metabásicas, embora sempre com enriquecimento em ETR maior, o que é sugestivo de fontes enriquecidas. O Grt-cpx anfibolito simplectítico apresenta assinaturas geoquímicas distintas, com enriquecimento maior em elementos LILE e ETRL, o que sugere uma origem a partir de fontes OIB. Os padrões de ETR e diagramas de variação multi-elementares de elementos traço sugerem que as rochas charnockíticas têm fontes relacionadas à ambientes de arco vulcânico. Os paragnaisses, em fácies anfibolito superior a granulito, registram uma trajetória inicial horária, descompressiva ao campo da sillimanita. É distinta da trajetória inicial anti-horária exibida pelas rochas metabásicas e charnockíticas, que registram nas coronas de Grt-Cpx-Pl o metamorfismo progressivo de fácies granulito de alta pressão. Sugere-se que esse relativo aumento de pressão tenha sido condicionado pela colocação dos metassedimentos da Nappe Lima Duarte sobre as rochas do Complexo Mantiqueira, porém no mesmo campo de temperatura. Assim, o avanço da nappe metassedimentar pode ter sido responsável pelo soterramento das rochas metabásicas e charnockíticas relacionadas com o Complexo Mantiqueira, o que justifica a pressão mais elevada nestes litotipos. A etapa de exumação foi compartilhada por ambas, o que é evidenciado nas semelhanças de condições metamórficas durante a trajetória de resfriamento quase isobárico, porém com os litotipos do Complexo Mantiqueira em nível crustal mais profundo. / The Lima Duarte Nappe is located in southeastern Brasília Orogen and is composed by migmatitic paragneisses presenting garnet, sillimanite, biotite and muscovite, and coarse-grained orthoquartzites, with few amphibolite and calc-silicate interlayers. The Mantiqueira Complex occurs as tectonic imbricated lenses in the Lima Duarte Nappe, resembling an allochthon structure. It comprises TTG-type migmatitic and polymetamorphic orthogneisses, presenting granulitic metabasic interlayers, as mafic bands and lenses, as well as boudins, which are often concordant with the main foliation. Charnockitic rocks are apparently intrusive in the Mantiqueira orthogneisses, with associated metabasic rocks. The mineral assemblage observed in paragneisses (Grt + Bt + Sil + Pl + Rt + Ilm + Qtz ± Ms ± Kfs ± Ky) is related to an upper amphibolite facies progressive metamorphism characterized by muscovite breakdown reactions producing potassic feldspar. The peak baric conditions obtained in the THERMOCALC processing software for the assemblage involving kyanite are 10 ± 0.6 kbar and 807 ± 25ºC. The thermal peak of 827 ± 44ºC and 8.2 ± 1.8 kbar obtained in THERMOCALC for the assemblage envolving sillimanite, is placed in the boundary of breakdown curve for dumortierite. The metabasic rocks interlayered in Mantiqueira Complex orthogneisses show the Grt-Cpx-Pl-Qtz±Opx+Hbl assemblage, indicating high pressure granulite facies. They are characterized by the presence of Grt-Cpx-Pl progressive coronitic textures between Opx, Pl and/or opaques boundaries, apparently with an igneous origin, which marks the transitions from intermediate pressure granulites field to high pressure granulite field. The peak conditions recorded in Grt-Cpx-Pl veins in metagabbronorites is 831.8ºC, and 10 kbar. The garnet granulite records the metamorphic peak at 890 ± 41ºC, and 9.26 ± 1.93 kbar. Thermobarometric calculations performed at TWEEQU revealed equilibrium conditions at 801ºC, and 9.6 kbar based on granulite facies mineral assemblage. The peak baric conditions achieved by the charnockitic rocks are 14.36 ± 1.9 kbar, and 680ºC, while maximum temperatures recorded are 885.17ºC, and 10 kbar. Thermobarometric calculations performed at THERMOCALC revealed temperatures of 771 ± 166ºC, and 11.8 ± 2.4 kbar. The metabasic rocks related to Mantiqueira Complex show low concentrations of LILE elements, possibly due to the depletion of these elements during metamorphism in dehydrating reactions. Geochemical data point out to E-MORB type sources for the great majority of metabasic rocks, even though with an REE enrichment, suggesting more enriched sources. The symplectitic Grt-Cpx amphibolite show distinct geochemical signatures, characterized by a greater enrichment in LILE and light-REE elements, suggesting an OIB source for their origin. REE patterns and trace element spidergrams suggest that charnockitic rocks sources are related to a volcanic arc tectonic setting. Paragneisses, in upper amphibolite to granulite facies, recorded an initial clockwise path, decompressing to the sillimanite field. It differs from initial counterclockwise path exhibited by the metabasic and charnockitic rocks, which preserves the progressive high pressure granulite facies metamorphism in Grt-Cpx-Pl coronae. This pressure increase is probally related to the metassediments of the Lima Duarte Nappe, that thrusted over the Mantiqueira Complex rocks, although in the same temperature field. The buried character of metabasic and charnockitic rocks may be caused by the thrust of the metassedimentary nappe, justifying the higher pressure found in these lithotypes. The exhumation phase was shared by both of them, which is confirmed in the metamorphic similarities conditions, as they cooled out together in a near isobaric path, although the Mantiqueira Complex lithotypes were in a deeper crustal level.

Meta-mafic intrusions with an intrusion age of 1.6-0.9 Ga are found along a north-south trend in theTransitional section of the Eastern Segment in Sweden. These intrusions are garnet-bearing and thus anexception to other meta-mafic intrusions found in Sweden. Meta-mafic intrusions that are garnet-bearingare usually found in the Caledonides to the northeast and in the south west of Sweden where the pressureshave been naturally high due to orogenic events or subduction.The study was conducted on these intrusions around the community of Ölme, to understand themetamorphic and metasomatic history of the area. The focus lies on the transition from magmaticgabbroic intrusions to metamorphosed metagabbros and highly foliated garnet-amphibolites. AveragePT estimates was calculated using THERMOCALC and classical geothermobarometry, so that acomparison between the qualitative and quantitative data could be made.The study indicates metamorphism at amphibolite to upper amphibolite facies conditionsfor the metagabbros and the garnet-amphibolites.Average PT-estimates for the garnet-amphibolites gives metamorphic peak temperatures of 680°-730° Cwith pressures of 9.0-11.0 kbar at the Träfors locality, and metamorphic peak temperatures of 660°-770° Cwith pressures of 9.5-11.0 kbar at the Skråkvik locality. These results are comparable to research donefurther to the south on similar intrusions, with temperatures of 700° C and pressures of 10 kbar.It is concluded that the meta-mafic intrusions at the Skråkvik locality have been metamorphosed in adry system, in contrast to the Träfors locality which seems to have been affected by more pervasiveretrograde metamorphism and fluid-rock interaction. It is also concluded that mafic intrusionscan preserve their magmatic textures even under high pressure conditions.

The continental crust is the record of the history of the Earth, of the processes and events that have contributed to the planet's evolution. It is now understood that the continental crust is growing continuously since the early ages of the Earth. Archean-Proterozoic boundary marks one of the major transition periods in the crustal evolution processes. However, there are only few crustal remnants available to investigate this milestone of Earth history, reported with significant chemical discontinuity. The Neoarchean crustal fragments of southern India provide a window to probe the processes that happened during such transitions. The geology of southern India can be broadly divided in to the Archean Dharwar Craton (DC) of granites and greenstones belts to the north and an assembly of crustal blocks experienced granulite grade metamorphism to the south from Archean to Neoproterozoic, namely the Southern Granulite Terrain (SGT). The relationship between DC and SGT terranes are not well established, primarily due to lack of studies on the growth and evolution on each of the crustal blocks. This study focuses on the crustal tract between Salem Attur Shear Zone and the Cauvery Shear Zone of the SGT. This region lies to the east of Palghat Cauvery Shear System, which is considered as dextral shear zone, suture zone, Neoproterozoic terrain boundary and reworked Archean crust in the previous studies. However, so far no comprehensive studies had been reported from the region that consists of a spectrum of rocks charnockite, granitic gneiss, hornblende gneiss, granite and mafic-ultramafics litho-units inclusive of a layered complex. The objectives of this study are 1) to understand the crustal formation processes in Kolli-massif 2) to delineate the chronology of events or processes through radiometric dating. 3) to understand the crustal reworking and evolutionary processes in Kolli-massif . Major tools used in this study include petrology (field studies and petrography), geochemistry, U-Pb Zircon geochronology, Sr-Nd and Hf Isotopes. The content of this thesis is divided in to six chapters. Chapter 1 is an introduction to the topic – crustal growth. It discusses the importance of continental crustal process in understanding the evolutionary history of the 2500 Ma Earth. It also emphasizes on the reason to investigate Kolli-massif which is a part of the Southern Granulite Terrain. Chapter 2 deals with the literature review which is relevant in the context of the study. The chapter discusses topics like structure of the Earth crust, various models proposed on the generation of continental crust (continuous as well as episodic) and also the models discussed in the literature on the generation of TTG (subduction of oceanic crust and ocean plateau and non-subduction). An overall view on crustal reworking and recycling is also included. The chapter ends with a short review on southern Indian crustal tectonics and a detailed discussion on the evolution Palghat Cauvery Shear Zone. Chapter 3 describes the geology of the study area Kolli-massif in details. This includes the structural, lithological units, field relation and geochronolgical aspects combined and their implications on the crustal assembly of southern India. Chapter 4 is a discussion on the results, interpretation and implications of crustal generation and evolution of the Archean Kolli-massif. This chapter is subdivided to four. Chapter 4.1 deals with possible source and tectonic settings for the magma generation which lead to the formation of Archean Sittampundi Complex. The whole rock and spinel chemistry two different suggests both MORB and arc signature for these rocks. Although this is such a quite contrasting scenario, such scenarios are known to occur in an intra-oceanic subduction in the Archean as well as modern analogue. The search for MOR setting lead to Kanjamalai, where major rocks like metagabbro show geochemical affinity, as described in Chapter 4.2. The presence of rocks like plagiogranite also supports MORB affinity. Based on field observations and above evidences Kanjamalai complex is interpreted as subducted remnant of an Archean Mid Oceanic Ridge. Chapter 4.3 deals with the major rock type of the region charnockite and granitic gneiss. The whole geochemical chemistry suggests arc signatures (depleted HFS elements, enriched LREE) and negative Nd and Hf isotope suggests reworked magma. However, the high HREE content and absence of Eu anomaly in the charnockite but reverse case of granitic gneiss indicates they might have of a different source and may not solely by the subduction of oceanic crust described in chapter 4.1. Combining the results from Hf and Nd isotopes that shows the presence of an older crust of age 2700-2900 Ma, it can be concluded that the an older oceanic crust, probably with an ocean plateau was part of subduction and magma genesis. The presence of garnet websterite describes accretion in operation in the generation of Kolli-massif. Chapter 4.4 deals with crustal recycling. The results on the investigation on meta-BIFs yielded results that can be interpreted that the iron formations were deeply subducted. The proposal of accretionary tectonics is also supported by the presence of meta-BIFs in the shear zone with in the Kolli-massif. Chapter 5 deals with the Neoproterozic reworking of the Archean Kolli-massif. The investigations on the sapphirine bearing granulite suggest that the rocks have undergone UHT metamorphism (6Kbar and 925˚C). The geochronogical evidences shows that the zircon rim growth ca. 550 Ma over a 2480 Ma crust. This suggests crustal reworking that would have happened during the Gondwana amalgamation happened during the Neoproterozoic time.It is therefore concluded in Chapter 6 that the Kolli-massif is having an Archean nucleus that was grown by the arc accretion. This reworked during the regional metamorphism along with the Gondwana metamorphism in the Neoproterozoic. Further scope of this study is also discussed.

A Nappe Lima Duarte está situada no sudeste do Orógeno Brasília. É constituída por paragnaisses migmatíticos com granada, sillimanita, biotita e muscovita, e ortoquartzitos grossos, com intercalações esparsas de gnaisses calciossilicáticos e de anfibolitos. O Complexo Mantiqueira, infraestrutura alóctone da nappe, ocorre na forma de lascas tectonicamente imbricadas na mesma. É constituído por ortognaisses migmatíticos e polimetamórficos, tipo TTG, com intercalações de rochas metabásicas granulíticas, na forma de enclaves máficos alongados e boudins, geralmente concordantes com a foliação principal. Também ocorrem rochas charnockíticas aparentemente intrusivas nos ortognaisses Mantiqueira, com rochas metabásicas associadas. A associação mineral observada nos paragnaisses (Grt + Bt + Sil + Pl + Rt +Ilm + Qtz ± Ms ± Kfs ± Ky) é relacionada a um metamorfismo progressivo de fácies anfibolito superior, caracterizado por reações de quebra de muscovita e geração de feldspato potássico. As condições de pico bárico obtidas no THERMOCALC para a associação com cianita são de 10 ± 0.6 kbar, a 807 ± 25ºC. O pico térmico de 827 ± 44ºC a 8.2 ± 1.8 kbar, no limite da curva de quebra da dumortierita, foi obtido no THERMOCALC com a associação mineral envolvendo sillimanita. As rochas metabásicas inseridas nos ortognaisses do Complexo Mantiqueira e rochas charnockíticas associadas apresentam a associação Grt-Cpx-Pl-Qtz±Opx+Hbl, que é diagnóstica do fácies granulito de alta pressão. São caracterizadas pela presença de texturas coroníticas progressivas de Grt-Cpx-Pl-Qtz nos contatos entre Opx, Pl e/ou opacos, aparentemente de origem ígnea, que marca a passagem do campo dos granulitos de pressão intermediária para o campo dos granulitos de alta pressão. As condições de pico registradas nos veios constituídos por Grt-Cpx-Pl nos metagabronoritos é de 831.8ºC, a 10 kbar. O granada granulito registra o pico metamórfico a 890 ± 41ºC, a 9.26 ± 1.93 kbar. Cálculos realizados no TWEEQU forneceram condições de equilíbrio de 801ºC, a 9.6 kbar para a associação de fácies granulito. As condições de pico bárico nas rochas charnockíticas são de 14.36 ± 1.9 kbar, a 680ºC, enquanto que as temperaturas máximas registradas são de 885.17ºC, a 10 kbar. Cálculos realizados no THERMOCALC forneceram temperatura de 771 ± 166ºC, a 11.8 ± 2.4 kbar. As rochas metabásicas relacionadas ao Complexo Mantiqueira apresentam baixas concentrações de elementos LILE, possivelmente devido ao empobrecimento destes elementos durante o metamorfismo através de perdas por reações de desidratação. Os dados geoquímicos apontam fontes do tipo E-MORB para grande parte das rochas metabásicas, embora sempre com enriquecimento em ETR maior, o que é sugestivo de fontes enriquecidas. O Grt-cpx anfibolito simplectítico apresenta assinaturas geoquímicas distintas, com enriquecimento maior em elementos LILE e ETRL, o que sugere uma origem a partir de fontes OIB. Os padrões de ETR e diagramas de variação multi-elementares de elementos traço sugerem que as rochas charnockíticas têm fontes relacionadas à ambientes de arco vulcânico. Os paragnaisses, em fácies anfibolito superior a granulito, registram uma trajetória inicial horária, descompressiva ao campo da sillimanita. É distinta da trajetória inicial anti-horária exibida pelas rochas metabásicas e charnockíticas, que registram nas coronas de Grt-Cpx-Pl o metamorfismo progressivo de fácies granulito de alta pressão. Sugere-se que esse relativo aumento de pressão tenha sido condicionado pela colocação dos metassedimentos da Nappe Lima Duarte sobre as rochas do Complexo Mantiqueira, porém no mesmo campo de temperatura. Assim, o avanço da nappe metassedimentar pode ter sido responsável pelo soterramento das rochas metabásicas e charnockíticas relacionadas com o Complexo Mantiqueira, o que justifica a pressão mais elevada nestes litotipos. A etapa de exumação foi compartilhada por ambas, o que é evidenciado nas semelhanças de condições metamórficas durante a trajetória de resfriamento quase isobárico, porém com os litotipos do Complexo Mantiqueira em nível crustal mais profundo. / The Lima Duarte Nappe is located in southeastern Brasília Orogen and is composed by migmatitic paragneisses presenting garnet, sillimanite, biotite and muscovite, and coarse-grained orthoquartzites, with few amphibolite and calc-silicate interlayers. The Mantiqueira Complex occurs as tectonic imbricated lenses in the Lima Duarte Nappe, resembling an allochthon structure. It comprises TTG-type migmatitic and polymetamorphic orthogneisses, presenting granulitic metabasic interlayers, as mafic bands and lenses, as well as boudins, which are often concordant with the main foliation. Charnockitic rocks are apparently intrusive in the Mantiqueira orthogneisses, with associated metabasic rocks. The mineral assemblage observed in paragneisses (Grt + Bt + Sil + Pl + Rt + Ilm + Qtz ± Ms ± Kfs ± Ky) is related to an upper amphibolite facies progressive metamorphism characterized by muscovite breakdown reactions producing potassic feldspar. The peak baric conditions obtained in the THERMOCALC processing software for the assemblage involving kyanite are 10 ± 0.6 kbar and 807 ± 25ºC. The thermal peak of 827 ± 44ºC and 8.2 ± 1.8 kbar obtained in THERMOCALC for the assemblage envolving sillimanite, is placed in the boundary of breakdown curve for dumortierite. The metabasic rocks interlayered in Mantiqueira Complex orthogneisses show the Grt-Cpx-Pl-Qtz±Opx+Hbl assemblage, indicating high pressure granulite facies. They are characterized by the presence of Grt-Cpx-Pl progressive coronitic textures between Opx, Pl and/or opaques boundaries, apparently with an igneous origin, which marks the transitions from intermediate pressure granulites field to high pressure granulite field. The peak conditions recorded in Grt-Cpx-Pl veins in metagabbronorites is 831.8ºC, and 10 kbar. The garnet granulite records the metamorphic peak at 890 ± 41ºC, and 9.26 ± 1.93 kbar. Thermobarometric calculations performed at TWEEQU revealed equilibrium conditions at 801ºC, and 9.6 kbar based on granulite facies mineral assemblage. The peak baric conditions achieved by the charnockitic rocks are 14.36 ± 1.9 kbar, and 680ºC, while maximum temperatures recorded are 885.17ºC, and 10 kbar. Thermobarometric calculations performed at THERMOCALC revealed temperatures of 771 ± 166ºC, and 11.8 ± 2.4 kbar. The metabasic rocks related to Mantiqueira Complex show low concentrations of LILE elements, possibly due to the depletion of these elements during metamorphism in dehydrating reactions. Geochemical data point out to E-MORB type sources for the great majority of metabasic rocks, even though with an REE enrichment, suggesting more enriched sources. The symplectitic Grt-Cpx amphibolite show distinct geochemical signatures, characterized by a greater enrichment in LILE and light-REE elements, suggesting an OIB source for their origin. REE patterns and trace element spidergrams suggest that charnockitic rocks sources are related to a volcanic arc tectonic setting. Paragneisses, in upper amphibolite to granulite facies, recorded an initial clockwise path, decompressing to the sillimanite field. It differs from initial counterclockwise path exhibited by the metabasic and charnockitic rocks, which preserves the progressive high pressure granulite facies metamorphism in Grt-Cpx-Pl coronae. This pressure increase is probally related to the metassediments of the Lima Duarte Nappe, that thrusted over the Mantiqueira Complex rocks, although in the same temperature field. The buried character of metabasic and charnockitic rocks may be caused by the thrust of the metassedimentary nappe, justifying the higher pressure found in these lithotypes. The exhumation phase was shared by both of them, which is confirmed in the metamorphic similarities conditions, as they cooled out together in a near isobaric path, although the Mantiqueira Complex lithotypes were in a deeper crustal level.

<p> The Whitestone Anorthosite is a relatively small anorthosite body (160 km2 ) located within the Parry Sound structural domain, Western Grenville Province, Ontario. Both the anorthosite and the surrounding gneisses have been affected by a granulite grade metamorphic event which predates the Grenville Orogeny. The outer margin of the anorthosite body has been strongly deformed and recrystallized and is characterized by a pervasive metasomatic alteration consisting of garnet, scapolite, hornblende, apatite, biotite, sphene, carbonate and opaques. The country rock gneisses exhibit a corresponding discontinuous, and highly variable, reaction aureole. Pre-existing mafic gneisses are particularily affected, being characterized by the breakdown of orthopyroxene and hornblende, an increase in garnet, clinopyroxene, apatite and opaques, and enrichment in Fe, Ti and P. </p> <p> The metasomatic alteration exhibited by the Whitestone Anorthosite is thought to be due to a combination of two processes: 1. Mechanical mixing at the anorthosite/country rock contact during intense deformation (tectonic assimilation), and 2. Widespread absorption of mobile components (predominantly volatiles) from both included material and the surrounding gneisses. </p> <p>The formation of the country rock reaction aureole is a continuous solid state metamorphic process, whereby mobile components are preferentially leached from the rock leaving a mafic restite. Post-deformation cooling of the anorthosite, combined with an increased volatile flux, has imparted a polygonal mosaic texture suggestive of contact metamorphism. The typical garnet-clinopyroxene assemblage exhibited by mafic gneisses within the reaction aureole, is a consequence of the increased Fe/Mg ratio which stabilizes this assemblage at lower P, T conditions. The temperature of final equilibration and recrystallization is estimated to be 750 ± 70 °C, based on clinopyroxene-garnet geotherrnometry. </p> <p> A similar metasomatic interaction, to the one outlined in this thesis, is to be expected at all anorthosite/country rock contacts which have been overprinted by granulite metamorphism. </p> / Thesis / Master of Science (MSc)

The Madurai Block is the largest granulite block in Southern Granulite Terrain which lies between Palghat-Cauvary shear zone in the North and Achankovil shear zone in the South. This terrain underwent extreme crustal metamorphism under ultrahigh-temperature metamorphic conditions which provides vital information about the tectonic process of the lower crust. Ultrahigh temperature metamorphism was defined by Harley (1998b) as a subclass of granulite facies metamorphism of crustal rocks in which peak temperature exceeds 900°C at moderate pressures (7-13 kbar) in the deep crust. However, considering the lacunae about the present understanding of ultrahigh temperature metamorphism, the study attempts to identify the heat source and role of lower crustal fluids in high temperature metamorphism. To understand the role of lower crustal fluids, a case study on migmatised metapelites from the Kodaikanal region was done where the metapelites have undergone UHT metamorphism. In-situ electron microprobe Th-U-Pb isochron (CHIME) dating of monazites in a leucosome and surrounding silica saturated and silica under saturated restite from the same outcrop indicate three principal ages which can be linked in with the evolutionary history of these rocks. The monazite grains in leucosome sample show alteration along the rims. These altered rims are experimentally replicated in a monazite-leucosome experiment at 800°C and 200MPa. This experiment, coupled with earlier published monazite-fluid experiments involving high pH alkali-bearing fluids at high P-T, helps to confirm the idea that alkali-bearing fluids, in the melt and along grain boundaries during crystallization, were responsible for the formation of the altered monazite grain rims via the process of coupled dissolution-reprecipitation. Lower crustal fluids during migmatization and high temperature metamorphism from leucosome monazites signify the need for a more precise texturally-controlled geochronological determination. Considering the possible heat source of high temperature metamorphism, the role of associated rocks of charnockites/granites and ultramafics was studied from Kodaikanal and Ganguvarrpatti. The results indicate that both charnockites and granites are not the heat source of high temperature metamorphism. However, to recognize the ultramafic as the potential heat source the sapphirine-bearing high Mg-Opx bearing rock was studied from Kambam town. The sapphirine–cordierite intergrowth pods are characterized by unique texture and peraluminous sapphirine composition suggesting that these domains could represent cryptic pathways through which aluminous melts migrated. The mineral phase equilibria considerations suggest that such peraluminous melts interacted with Mg-rich orthopyroxene in the host granulite at 1025°C and 8 kbar, with subsequent isobaric cooling. The underplated mafic magma (T>1000°C) is suggested as a possible mechanism that provided the heat source for partial melting of lower crust and the UHT metamorphism. Moreover, field evidence of metapelite in direct contact with an ultramafic body was observed resulting into granulite grade metamorphism. The other evidence of ultramafic magma as heat source is though the mineral chemistry and geochemical modeling of the studied ultramafic rocks.

Thesis (DSc)--Stellenbosch University, 2015. / ENGLISH ABSTRACT: Anatexis is the first step in granite genesis. Partial melting in the lower crust may produce leucoratic features of unusual chemical compositions, very different from the final products of crustal differentiation. Therefore, the links that exists between some migmatites and crustal-derived granites can be ambiguous. This study is an investigation of the anatectic history of a high-grade terrain: the Southern Marginal Zone of the Limpopo Belt (SMZ), north to the Kaapvaal Craton in South Africa. The work involved an integrated field, metamorphic, geochemical and geochronogical study of the metasedimentary granulites from two separate quarries in the northern zone of the Southern Marginal Zone, the Bandelierkop quarry and the Brakspruit quarry, where Neoarchean high-grade partial melting features can be observed. The project has aimed to address two main issues: (1) to accurately constrain the pressuretemperature conditions and the age of the metamorphic episode in the SMZ, with implication for the geodynamic processes near the end of the Archean, (2) to investigate the fluid-absent partial melting reactions that control formation of K2O-poor leucosomes and to understand the chemical relationships in the system source-leucosome-melt–S-type granite. The P-T-t record retained in the Bandelierkop Formation metapelites, constrained by phase equilibria modelling as well as zircon LA-ICP-MS geochronology, gives an insight into crustal differentiation processes in the lower crust. Rocks in both quarries indicate high-temperature metamorphism episodes with peak conditions of 840-860 oC and 9-11 kbar at c. 2.71 Ga with formation of leucosomes (L1) during the prograde path. Minor leucocratic features (L2) were produced during decompression to 6-7 kbar. The end of the metamorphic event is marked by the granulites/amphibolites facies transition (< 640 oC) at c. 2.68 Ga. The maximum deposit age for the detrital zircons in the metapelites (c. 2.73 Ga) indicates a rapid burial process ( 0.17 cm.y1). Those evidences strongly support that the Southern Marginal Zone contains sediments deposited in an active margin during convergence, and that the metapelites were metamorphosed and partially melted as a consequence of continental collision along the northern margin of the Kaapvaal Craton at c. 2.7 Ga. The leucocratic features generated along this P-T-t path display an unusual chemistry with low K2O and FeO+MgO content and high CaO content. The combination of field observations, chemical mapping and geochemical analyses leads to the conclusion the major part of the leucosomes (L1) crystallized prior to syn-peak of metamorphism concurrent with melt extraction from the source. This study documents the details of leucosomes formation using field observations in the Southern Marginal Zone and numerical modelling. This work demonstrates that the formation of K2O-poor leucosome in the metasedimentary lower crust is controlled by the difference in volume of equilibration and heterogeneities within the migmatites. The partial melting of the source coupled with melt loss and water diffusivity within the melt transfer site is a potential mechanism to explain the chemical link in the sytem residuum– melt–S-type granite. / AFRIKAANSE OPSOMMING: Anateksis is die eerste stap in granietgenese. Meganismes wat in die onderste kors aan die werk is, is verantwoordelik vir korsdifferensiasie en bepaal die chemiese samestelling van die graniet. Hierdie studie het’n ondersoek behels van die anatektiese geskiedenis van ’n ho egraadse terrein: die suidelike randstreek van die Limpopo-gordel, noord van die Kaapvaal-kraton in Suid-Afrika. Die werk het ’n ge integreerde veld- , metamorfiese, geochemiese en geochronologiese studie van die metasedimentêre granuliete van twee afsonderlike groewe in die noordelike sone van die suidelike randstreek (SRS), die Bandelierkop-groef en die Brakspruit-groef, waar Neoarge iese ho egraadse gedeeltelike smeltkenmerke waargeneem kan word, ingesluit. Die projek was gerig op die ondersoek van twee belangrike kwessies: (1) om die drukâtemperatuurtoestande en die ouderdom van die metamorfiese episode in die SRS akkuraat te beheer, met implikasie vir die geodinamiese prosesse naby die einde van die Arge ikum, en (2) om die reaksies onder gedeeltelik gesmelte toestande wat die vorming van migmatiete beheer, te ondersoek en die chemiese verwantskappe in die stelsel bron - leukosoom - smelt - S-tipe graniet te begryp. Die P-T-t-rekord wat in die Bandelierkop-formasie metapeliete behoue is, ingeperk deur modellering van fase-ekwilibria asook sirkoon LA-ICP-MS-geochronologie, gee insig in korsdifferensiasieprosesse in die onderste kors. Rotse in albei groewe dui op metamorfismeepisodes teen hoë temperature met piektoestande van 840â860 oC en 9â11 kbar teen ongeveer 2.71 Ga met vorming van leukosome (L1) gedurende die progradeerpad. Geringe leukokratiese eienskappe (L2) het tydens dekompressie tot 6â7 kbar ontstaan. Die einde van die metamorfiese voorval word gekenmerk deur die fasiesoorgang van granuliete / amfiboliete (<640 oC) by ongeveer 2.68 Ga. Die maksimum afsettingsouderdom vir die detitrale sirkone in die metapeliete (ongeveer 2.73 Ga) dui op Å snelle begrawingsproses ( 0.17 cm.y1). Daardie bewyse bied sterk ondersteuning daarvoor dat die SRS sedimente bevat wat gedurende konvergensie in Å aktiewe rand afgeset is, en dat die metapeliete gemetamorfoseer en gedeeltelik gesmelt het as gevolg van kontinentbotsing langs die noordelike rand van die Kaapvaal-kraton teen ongeveer 2.7 Ga. Die leukokratiese eienskappe wat langs hierdie P-T-t-pad opgewek word, toon Å ongewone chemiese samestelling met lae K2O en FeO+MgO-inhoud en ho e CaO-inhoud. Die kombinasie van veldwaarnemings, chemiese kartering en geochemiese ontledings lei tot die gevolgtrekking dat die grootste deel van die leukosome (L1) gekristalliseer het voor die syn-piek van metamorfisme tesame met smeltekstraksie van die bron. Hierdie studie het die besonderhede van leukosoomformasie met behulp van veldwaarnemings in die SRS en numeriese modellering opgeteken. Hierdie werk toon aan dat korsdifferensiasie in die metasedimentêre onderste kors deur Å ander volume van ekwilibrasie en heterogeniteite in die migmatiete beheer word. Die gedeeltelike smelting van die bron gepaard met smeltverlies en waterdiffusiwiteit tot in die smeltoordragterrein is ’n potensiele meganisme om die chemiese skakel in die stelsel residuum-smelt-S-tipe graniet te verklaar.

Les riches gisements filoniens aurifères de Tirek-Amesmessa, situés dans le Sud algérien, sont liés au fonctionnement d'un cisaillement décrochant majeur, (Zone de Cisaillement Est Ouzzalienne, ZCEO) tardi-panafricain ( 540Ma), dont le compartiment ouest est constitué par l'unité granulitique d'In Ouzzal, d'âge archéen, métamorphisée au cours du cycle éburnéen (2Ga) L'étude pétro-structurale régionale, celle des inclusions fluides (microthermomètrie, analyse par sonde Raman), des isotopes stables (C,O,H) et du plomb des galènes, permettent de découper l'histoire des gisements en trois cycles: Cycle 1 : Une longue période de fonctionnement ductile de la ZCEO, accompagnée de l'intrusion de roches basiques syncinématiques, se termine par une altération hydrothermale complexe (bérisites) localisée dans des couloirs de déformation et suivie de la mise en place de filons de quartz. La déformation ductile, évoluant vers le fragile en fin de cycle se focalise de façon croissante dans les quartz. La future zone minéralisée agit comme une structure drainant un type assez constant de fluides à température décroissante (500 à 300°C) et à profondeur assez stable (18 à 15km): fluides aqueux "métamorphiques" contenant une composante carbonique mantélique en relation avec les intrusions basiques syncinématiques. Le cycle Il : correspond à la maturation tectonique du quartz: microfracturation en plusieurs stades au cours de la remontée vers la surface jusque vers 4-5km. Des fluides de type saumures relaient les précédents. Le cycle III : voit la minéralisation aurosulfurée (sphalérite puis galène-or) se déposer en utilisant la microperméabilité créée précédemment. Le dépôt de l'or résulte d'un mélange de fluides (dont des saumures) qui traversent l'unité granulitique selon des circuits de profondeur différente, dans le contexte d'un hydrothermalisme activé par de grandes intrusions acides tardi-tectoniques. La nature des fluides impliqués, les isotopes du plomb des galènes, les teneurs en or des protolithes granulitiques d'In Ouzzal impliquent que ces derniers constituent les roches mères de l'or.

Ce travail regroupe un ensemble de chapitres traitant de différents aspects des granulites, en mettant l'accent sur les compositions basiques. Ces chapitres sont indépendants, mais sont reliés entre eux par des renvois de l'un à l'autre. La première approche pour l'étude des granulites est géochimique: il est montré, dans un article en collaboration avec Andriambololona D., que les éléments de transition, peu affectés par le métamorphisme, peuvent être utilisés pour caractériser les métabasites. La suite du travail est consacrée à une étude pétrologique des formations granulitiques de Madagascar et du Massif Central français. Au chapitre II, l'étude détaillée d'un assemblage coronitique à HB-Ky-Ga est l'occasion de proposer une grille pétrogénétique dans le système CMASFH. Cette étude explique clairement les associations observées, soulève le problème de la rareté du disthène dans ces roches et apporte une explication graphique à la diversité des associations minéralogiques observées dans les métabasites qui sont décrites dans les chapitres suivants. Dans les chapitres III et IV, sur l'exemple d'un massif troctolitique, on montre la diversité de faciès pétrographiques qui peut être obtenue au cours d'un métamorphisme isochimique ou métasomatique, avec variation de la pression des fluides. Des associations faisant intervenir des minéraux rares sont décrites: sérendibite, clintonite, staurotide magnésienne, saphirine. On s'interroge sur les relations chronologiques entre le métamorphisme et la métasomatose ; contemporains ou non ? Un parallélisme est fait avec les grospydites dont le problème de l'origine se pose dans les mêmes termes. Dans le chapitre V, est présentée une étude pétrogénétique d'un complexe gabbro-anorthositique du Sud malgache, formation semblable aux classiques suites anorthositiques (Adirondacks, par ex.). Le chapitre est divisé en trois parties : (1) description pétrographique détaillée des différents faciès ; (2) évaluation quantitative des paramètres extensifs du métamorphisme, grâce à une utilisation systématique des principaux géothermobarométriques conventionnels ; (3) discussion sur la mise en place du complexe plutonique et les relations avec le métamorphisme. L'étude des métasédiments associés à ce complexe (chapitre VI) confirme les évaluations thermodynamiques du chapitre V. C'est aussi l'occasion de décrire quelques associations rares à kornérupine, grandidiérite, Sp-Qz, etc. Le chapitre VII décrit la seule éclogite de basse température actuellement connue dans le précambrien: les implications géotectoniques sont discutées. Le chapitre VIII porte sur l'étude d'un métamorphisme de très hautes températures. Des conditions supérieures à 1000°C auraient affectées des métavolcanites métasomatisées. Il est intéressant de remarquer que ces conditions extrêmes passent totalement inaperçues en utilisant les géothermomètres usuels, puisque ceux-ci indiquent des températures de 600 à 700°C ! En guise de conclusion, s'appuyant sur les données pétrologiques recueillies, un modèle géodynamique faisant appel à une extension lithosphérique, suivi d'un épisode compressif, est proposé. Celui-ci s'intègre dans le modèle collisionnel envisagé pour la ceinture mobile mozambicaine, dont Madagascar représente la bordure orientale.

Deformation and partial melting have long been recognized to occur together, but differentiating which actually occurred first has remained enigmatic. Prevailing theories suggest that partial melting typically occurs first, and deformation is localized into melt-rich areas because they are rheologically weak. However, evidence from three different areas, suggests the role of strain has been underestimated in localizing partial melting. The Wet Mountains of central Colorado provide evidence for synchronous partial melting and deformation, with each process enhancing the other. Throughout the Wet Mountains, deformation is concentrated in areas where melt producing reactions occurred, and melt appears to be localized along deformation-related features. Melt microstructures present within the Wet Mountains correlate well with crustal-scale plutons and magmatic bodies and provide a proxy for crustal-scale melt flow. Granitic gneisses from the Llano Uplift, central Texas, provide evidence for partial melting occurring within small-scale shear zones and surrounding country rocks, synchronously. In the field, shear zones appear to contain former melt, whereas the country rock does not provide macroscopic evidence for partial melting. However, detailed microstructural investigation of shear zones and country rocks indicates the same density of melt microstructures, in both rock types. Melt microstructures are important for understanding the full melting history of a rock and without detailed structural and petrographic analysis, erroneous conclusions may be reached. Granulite-facies migmatites of the Albany-Fraser Orogen, southwestern Australia, have undergone partial melting, synchronous with three phases of bidirectional extension. Four major groups of leucosomes, including: foliation-parallel, cross-cutting, boudin neck and jumbled channelway leucosomes and late pegmatites were analyzed via whole-rock geochemistry, and there is evidence for fluid-saturated and -undersaturated biotite- and amphibole-dehydration melting. Migmatites from these three locations contain pseudomorphs of melt along subgrain and grain boundaries, areas of high dislocation density, in quartz and plagioclase. For these rocks that involve multicomponent systems, the primary cause for preferential melting in high strain locations is enhanced diffusion rates along the subgrain boundary because of pipe diffusion or water associated with dislocations. / text