A high temperature magnetic bearing system using high temperature permanent magnets from Electron Energy Corporation (EEC) is under development. The system consists of two radial bearings, one thrust bearing, two radial catcher bearings and one motor. The purpose of this research is to develop one of the critical components of the system, namely, the High Temperature Permanent Magnet motor. A novel High Temperature Permanent Magnet (HTPM) Brushless DC(BLDC) motor capable of operating at 1000 degrees F (538 degrees C) is designed. HTPMs developed at Electron Energy Corporation are buried into the rotor. The high temperature motor is designed to produce 5.1kw of power at a top running speed of 20000 rpm. The numerical values of the motor voltage, power and torque output are predicted from calculations of the nonlinear finite element model of the motor. The motor stator is wound, potted, cured and high potential tested at 1000 degrees F. A servo amplifier from Advanced Motion Control is used to drive the high temperature motor. High temperature displacement sensors are set up for sensing the rotor position to form a closed loop motion control. However, the noise problem of the high temperature sensors causes a failure of this approach. An open loop approach is then developed and this approach succeeds in spinning the rotor with the capability of self-starting. The status of the full system assembling is introduced. Some other components of the system are briefly presented.

Research in the fields of molecular conductors and magnets over the past four decades has involved collaborative efforts of chemists and physicists whose common goal is to design useful materials composed of molecular building blocks. Of particular interest are materials whose properties can be tuned by electronic or steric changes in the molecular sub-units. The research on TCNQ derivatives described in this thesis was inspired by the observation that, although a vast amount of research has been directed at understanding binary M(TCNQ•-) materials, analogous compounds based on substituted TCNQ acceptors are surprisingly scarce. Single crystals of a new structure type for the M+(TCNQ)•- binary family were isolated from reactions of two dihalogenated TCNQ derivatives with Cu(I) ions, namely Cu(TCNQX2) (X = Cl, Br). The new 3-D compound Cu(TCNQCl2) exhibits the highest conductivity of the M+(TCNQ)•- series to date, despite the greater separation of TCNQCl2 units as compared to other derivatives. Compounds of lower dimensionality were also obtained, namely the 2-D Cu(TCNQBr2)(CH3CN) and 1-D Cu(TCNQI2)(CH3CN)2 phases. Several 2p-3d heterospin molecular magnets were also synthesized. For example a “magnetic sponge” material based on a 2-D hexagonal framework of composition {[Mn2(TCNQF4)(CH3OH)7.5(H2O)0.5]-(TCNQF4)2•7.5CH3OH}∞, as well as molecular magnets based on first row metal ions and TCNQF4 ligands of composition MII(TCNQF4)-•(TCNQF42-)0.5(CH3CN) (M = Mn, Co) were prepared. In addition, unprecedented isostructural 2-D frameworks based on combinations of first row metal ions with TCNQBr2 radicals of composition [M(TCNQBr2)2(H2O)2]∞ (M = Mn, Zn) were synthesized. Lanthanide chemistry is also described in this dissertation. A series of mononuclear Ln-TCNQF4 heterospin complexes of composition {MIII[TCNQF4]2[H2O]x}(TCNQF4)(3H2O) (M = La, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er and Yb) was also obtained which exhibit remarkable properties. In this family of compounds there exists an unprecedented subtle interplay between single molecule magnetic behavior and phonon bottleneck effect behavior for the Tb analogue. Magnetic ordering was observed for the Sm analogue. A homologous series of 1-D materials based on alternating lanthanide ions and hexacyanometallates of formula {[Ln(tptz)(H2O)4Fe(CN)6]•8H2O}∞ (Ln = Pr, Nd, Sm, Eu, Gd, Tb) was obtained and a detailed magnetic study provided incontrovertible evidence that the SmIII-[FeIII(CN)6]3- compound exhibits ferromagnetic and not antiferromagnetic coupling as had been reported for related 1-D chains.

The Large Hadron Collider (LHC) is presently under construction at CERN. The LHC is a circular accelerator that stores proton beams and accelerates them to a 7 TeV beam energy for high energy physics research. The required bending and focusing/defocusing fields are achieved with superconducting magnets. Such a superconducting magnet-based accelerator can be controlled only when the field errors of production and installation of all magnetic elements are known to the required accuracy. The ideal way to compensate the field errors is to have direct diagnostics on the beam. For the LHC, however, a system solely based on beam feedback may be too demanding. The present baseline for the LHC control system hence requires an accurate forecast of the magnetic field and the multipole field errors to reduce the burden on the beam-based feedback. The field model is the core of this magnetic prediction system, also known as \emph{the Field Description for the LHC} (FIDEL). The model will provide the forecast of the magnetic field at a given time, magnet operating current, magnet ramp rate, magnet temperature, and magnet powering history. The model is based on the identification and physical decomposition of the effects that contribute to the total field in the magnet aperture of the LHC dipoles. This thesis presents the tool that was constructed to ease the detection, identification and finally correction of errors in the raw data from the series measurements of the main dipoles of the LHC. The results after cleaning all measurement data for the over 240 dipoles measured at cold, using this tool, is also presented. Another aspect of the Thesis is the presentation of a procedure devised to extract the model parameters for the main dipole magnets of the LHC by using the cleaned data. The procedure and the model are verified and validated by application to the magnets of the 7-8 sector of the LHC.

Considerable efforts are being devoted to designing enhanced molecular magnetic materials, in particular single molecule magnets (SMMs) that can meet the requirements for future technologies such as quantum computing and spintronics. A current trend in the field is enhancing the global anisotropy in metal complexes using single-ion anisotropy. The work in this dissertation is devoted to the synthesis and characterization of new building blocks of the highly anisotropic early transition metal ion V(III) with the aim of incorporating them into heterometallic molecular materials. The results underscore the importance of tuning the local coordination environments of metal ions in order to ensure enhanced single ion anisotropy. A family of mononuclear axially distorted vanadium (III) compounds, A[L_(3)VX_(3)] (3-9) (X = F, Cl or Br, A^(+) = Et_(4)N^(+), nBu_(4)N^(+) or PPN^(+) , L_(3) = Tp or Tp* (Tp = tris(-1-pyrazolyl)borohydride), Tp* = tris(3,5-dimethyl-1-pyrazolyl)borohydride)), and [Tp*V(DMF)_(3)](PF_(6))_(2) were studied. Replacement of the Tp ligand in 3 with the stronger π-donor Tp* results in a near doubling of the magnitude of the axial zero-field splitting parameter D_(z) (D_(z) = -16.0 cm^(-1) in 3, and -30.0 cm^(-1) in 4) as determined by magnetic measurements. Such findings support the idea that controlling the axial crystal field distortion is an excellent way to enhance single-ion anisotropy. High Field-High Frequency EPR measurements on 4 revealed an even higher D value, -40.0 cm^(-1). Interestingly, compound 4 exhibits evidence for an out-of-phase ac signal under dc field. In another effort, a new series of vanadium cyanide building blocks, PPN[V(acac)_(2)(CN)_(2)]∙PPNCl (13) (acac = acetylacetonate), A[V(L)(CN)_(2)] (A^(+) = Et_(4)N^(+), L = N,N'-Ethylenebis(salicylimine) (14), A = PPN^(+), L = N,N'-Ethylenebis(salicylimine) (15), L = N,N'-Phenylenebis(salicylimine) (16), and L = N,N'-Ethylenebis(2-methoxysalicylimine) (17)) were synthesized. Magnetic studies revealed moderate Dz values (-10.0, 5.89, 3.7, 4.05 and 4.36 cm^(-1) for 13-17 respectively). The first family of cyanide-bridged lanthanide containing molecules with a trigonal bipyramidal (TBP) geometry, (Et_(4)N)_(2)[(Re(triphos)(CN)_(3))_(2)(Ln(NO_(3))_(3))_(3)]-∙4CH_(3)CN (19-27 with Ln = La, Ce, Pr, Nd, Sm, Gd, Tb, Dy and Ho) were prepared using the [(triphos)Re(CN)_(3)]^(-) building block, results that add valuable information to our database of compounds with a TBP geometry. Magnetic studies revealed diverse magnetic responses including slow relaxation of the magnetization at zero field for 25 and 26 , an indication of SMM behavior.

We perform micromagnetic simulations in MuMax3 on various magneticnanostructures to study their magnetic state and response to external fields. Theinteraction and ordering of nanomagnetic arrays is investigated by calculating themagnetostatic energies for various configurations. These energies are then used inMonte Carlo simulation to study the thermal behaviour of systems of nanomagneticarrays. We find that the magnetic state of the nanostructures are related to theirshape and size and furthermore affect the emergent properties of the system, givingrise to temperature dependent ordering among the individual structures. Results fromboth micromagnetic and statistical mechanic simulations agree well with availableexperimental data, although the Monte Carlo algorithm encounter problems at lowsimulation temperatures.

Fault tolerant motor drives are becoming more important in safety critical applications. Although a single motor module fault tolerant drive may be sufficient in some applications, this motor drive only offers limited redundancy. This thesis investigated the dual motor module fault tolerant drive system in which two motor modules were connected electrically in phase and on a common shaft provide redundancy and to increase the reliability of the entire drive system. A general phase current mathematical model to produce the desired output torque was developed to minimize copper loss and torque ripple in the motor drive, which is applicable to both sinusoidal and trapezoidal brushless permanent magnet motor types. A detailed fault effect investigation was performed in this thesis and it is concluded that switch short-circuit fault is the most serious fault since it reduces the electromagnetic torque output significantly and generates larger torque ripple in the motor drive due to the presence of large drag torque. Three fault remedial strategies were proposed to compensate the torque loss and to reduce the torque ripple under different faulty conditions. It is concluded from the analytical results that fault remedial strategy 3 is the tradeoff algorithm in which the zero torque ripple factor can be achieved with only a modest increase in copper loss comparing with the minimum possible value. Two practical dual motor module fault tolerant brushless permanent magnet drive test arrangements with different motor structures were developed in this thesis. The computer simulation studies using the MATLAB Simulink were performed to verify the effectiveness of the proposed fault remedial strategies. The efficiency of the motor drive was predicted based on torque loss measurements and the results were verified in the simulation study. The effect of faults on the drive efficiency was investigated as well. The entire fault tolerant motor drive control system was also developed to verify the analytical and simulation results. A fault detection and identification method to detect switch open-circuit faults, switch short-circuit faults, and the winding short-circuit faults was also proposed. Its advantages are the simplicity of the implementation and reduction of the cost of the drive system. The experimental results demonstrated that the proposed fault remedial strategies can be implemented in real time motor control and are effective to compensate the torque loss and reduce the torque ripple. / Thesis (Ph.D.) -- University of Adelaide, School of Electrical and Electronic Engineering, 2008

Thesis (Ph.D.)--University of Wollongong, 2005. / Typescript. Includes bibliographical references: leaf 188-200.

Molecule-based magnets (molecular magnets) have attracted much interest in recent decades both from an experimental and from a theoretical point of view, not only because of their interesting physical effects, but also because of their potential applications: e.g., molecular spintronics, quantum computing, high density information storage, and nanomedicine. Molecular magnets are at the very bottom of the possible size of nanomagnets. On reducing the size of objects down to the nanoscale, the coexistence of classical properties and quantum properties in these systems may be observed. In additional, molecular magnets exist with structural variability and permit selective substitution of the ligands in order to alter their magnetic properties. Therefore, these characteristics make such molecules suitable candidates for studying molecular magnetism. They can be used as model systems for a detailed understanding of interplay between structural and magnetic properties of them in order to optimize desired magnetic properties. This thesis considers the investigation of magnetic properties of several new transition metal molecular compounds via different experimental techniques (continuous wave electron spin resonance (CW ESR), pulse ESR, high-field/high-frequency ESR (HF-ESR) and static magnetization techniques). The first studied compounds were mono- and trinuclear Cu(II)-(oxamato, oxamidato)/bis(oxamidato) type compounds. First, all components of the g-tensor and the tensors of onsite ACu and transferred AN HF interactions of mononuclear Cu(II)- bis(oxamidato) compounds have been determined from CW ESR measurements at 10 GHz and at room temperature and pulse ELDOR detected NMR measurements at 35 GHz and at 20 K. The spin density distributions of the mononuclear compounds have been calculated from the experimentally obtained HF tensors. The magnetic exchange constants J of their corresponding trinuclear compounds were determined from susceptibility measurements versus temperature. Our discussion of the spin density distribution of the mononuclear compounds together with the results of the magnetic characterization of their corresponding trinuclear compounds show that the spin population of the mononuclear compounds is in interplay with the J values of their corresponding trinuclear compounds. The second studied compounds were polynuclear Cu(II)-(bis)oxamato compounds with ferrocene and ferrocenium ligands. The magnetic properties of these compounds were studied by susceptibility measurements versus temperature to determine J values. In addition, the ESR technique is used to investigate the magnetic properties of the studied compounds because they contain two different magnetic ions and because only the ESR technique can selectively excite different electron spin species. These studies together with geometries of the ferrocenium ligands determined by crystallographic studies indicate that the magnetic interaction between a central Cu(II) and a Fe(III) ions changed from the antiferromagnetic coupling to the ferromagnetic coupling when a stronger distortion of the axial symmetry in the feroccenium cation exists. Therefore, the degree of the distortion of the feroccenium cation is a control parameter for the sign of the interaction between the central Cu(II) ion and the Fe(III) spins of the studied compounds. The last two studied molecular magnets were a binuclear Ni(II) compound (Ni(II)-dimer) and a cube-like tetranuclear compound with a [Fe4O4]-cube core (Fe4-cube). HF-ESR measurements enabled us to determine the g-factor, the sign, and the absolute value of the magnetic anisotropy parameters. Using this information together with static magnetization measurements, the J value and the magnetic ground state of the studied compounds have been determined. In Ni(II)-dimer, two Ni(II) ions, each having a spin S = 1, are coupled antiferromagnetically that leads to a ground state with total spin Stot = 0. An easy plane magnetic anisotropy with a preferable direction for each Ni(II) ion is found. For Fe4-cube, a ground state with total spin Stot = 8 has been determined. The analysis of the frequency dependence and temperature dependence of HF-ESR lines reveals an easy axis magnetic anisotropy (Dcube = -22 GHz (-1 K)) corresponding to an energy barrier of U = 64 K for the thermal relaxation of the magnetization. These results indicate that Fe4-cube is favorable to show single molecular magnet (SMM) behavior.

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