Thesis (MSc)--Stellenbosch University, 1934. / No Abstract Available

Thesis (PhD)--Stellenbosch University, 2001. / ENGLISH ABSTRACT: Please refer to fulltext for abstract / AFRIKAANSE OPSOMMING: Sien asb volteks vir opsomming.

published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy

The main objective of this study was to improve our understanding of biological filtration (biofilm type) treatment for manganese (Mn) removal in drinking water. Biological filtration treatment involves biofilms of Mn(II)-oxidizing microorganisms attached to solid filter material that remove and immobilize dissolved Mn(II) in raw water by conversion to black MnO2(s) precipitates. Mn-biological filtration is an emerging green technology that can serve as an alternative to conventional physicochemical treatments but its full potential is hindered by various factors. These include lack of understanding the: (1) optimal removal conditions for Mn, (2) mechanisms for Mn releases of the accumulated Mn in the biofilter, and (3) effects of recalcitrant natural organic matter (NOM) on biofiltration. Confounding these issues is the unknown identity of the diverse microbial communities which occupy the biofilms attached to the filter media. To investigate these issues, biological Mn removal was studied in laboratory bench scale reactors using a new Mn(II)-oxidizing bacterium isolate, Pseudomonas Putida EC112. The main research hypothesis formulated that the transition metal catalyst, MnO2(s), can increase the bioavailable carbon and energy from recalcitrant NOM (e.g., humic acids (HA)) to biological filters. Mn and HA can be found in most natural waters, including groundwaters, lakes and streams. To test the hypothesis, the potential for strain EC112 growth and Mn(II) oxidation utilizing the organic substrate products from the oxidation reaction between HA and MnO2(s) was assessed. Biological Mn(II)-oxidation kinetics were investigated in batch (suspended cell) and continuous flow (biofilm) bioreactors at optimal pH and temperature conditions for strain EC112. Batch kinetics was successfully characterized with the Monod model. Continuous flow steady-state kinetics was modeled with a single, zero-order kinetic parameter. Enhanced Mn(II) removal capacity was observed for strain EC112 in batch and continuous flow reactors in the presence of HA and MnO2. The effect of MnO2(s) on HA biodegradability was studied and optimal conditions for biodegradation were identified. Biofilter Mn(II) releases were observed during the continuous flow bioreactor experiments. Release conditions were identified and releases modeled using pseudo first-order kinetics. Changes in HA structure induced by MnO2(s) oxidation were studied with Fourier transform infrared (FT-IR) and proton nuclear magnetic spectroscopy (1H-NMR).

Notre travail est consacré à l'étude des matériaux carbonés utilisés comme réducteurs pour la production des alliages de manganèse dans le four électrique à arc immergé. Le choix du réducteur est important pour l'optimisation du procédé métallurgique et sa réactivité au CO2 est le paramètre le plus important utilisé par les producteurs de ferroalliages pour évaluer sa qualité. Les objectifs de notre travail sont : ? d'établir les critères de sélection du coke métallurgique ou réducteur de remplacement, utilisés pour la production des alliages de manganèse dans le four électrique, en utilisant la réactivité au CO2 comme le principal paramètre pour évaluer sa qualité ; ? d'un point de vue plus fondamental, apporter une meilleure compréhension des réactions du carbone dans le réacteur industriel. Dans l'optique d'une modélisation globale du four électrique, notre travail fournit des paramètres cinétiques d'une des réactions les plus importantes du procédé : la réaction de Boudouard. L'étude de la réductibilité des oxydes de manganèse pourrait donc être une nouvelle étape vers la construction d'un modèle global du réacteur industriel. Un troisième volet d'expériences utile à la modélisation serait l'étude de l'influence de la nature et du calibre du réducteur sur la résistivité électrique de la charge.

<p>The general trend in gear industry, today, is an increased focus on gear transmission efficiency. Gear transmission efficiency losses arise from loaded and unloaded gear contacts, seals, lubricant and bearings. One way of minimising the losses is to lower the lubricant viscosity. This will reduce the speed dependent losses. However, the load dependent losses might increase. To avoid this, the ratio between lubricant film thickness and surface roughness must be maintained, which can be fulfilled by producing smoother gear surfaces. As a starting point for this realisation process, the present manufacturing processes, the design tools and the characteristics of the gear flank interface must be further investigated and developed. This must be achieved with an emphasis on economic production.</p><p>This thesis focuses on our understanding of how different gear manufacturing methods —particularly the contribution of the running-in process—affect the surface characteristics, with the view of increasing gearbox efficiency. The thesis consists of a summary and three appended papers.</p><p>Paper A and paper B discuss the relationship between design parameters and real gear wheel surfaces manufactured with different manufacturing methods. The research hypothesis was that the contact area ratio is a descriptive parameter for the contact condition. Paper A deals with the influence of manufacturing method on the initial contact conditions and also serves as a validation of the simulation program used. The emphasis in Paper B is the changes that occur during running-in, and to correlate these changes to design requirements. Paper C approaches the influences of manganese phosphate-coating and lubricants with respect to friction and the risk of scuffing at the initial contact.</p><p>The main conclusions of this thesis are that the contact area ratio presents a descriptive measure of how surface topography influences the contact, seen at both a global (form deviation) and local (roughness) level. The surface topography caused by the manufacturing method has a significant influence on the contact area ratio. This is an important result, since neither national standards nor commercially available gear evaluation programs handle surface topography on the local scale. Shaving was found to have the highest contact area ratio, and should therefore be the best choice if deviations from case hardening could be minimised. It is also confirmed that gear-like surfaces coated with manganese phosphate have a low coefficient of friction, and raise the limiting load for scuffing failure enormously compared to the ground equivalent.</p> / QC 20100518 / KUGG / Sustainable gear transmission realization

Northwestern Mexico is characterized by different metallogenic provinces that are included along the Basin and Range, the Sierra Madre Occidental, and the Baja California geological provinces. With the purpose of contribute to the current understanding of the mineralizing processes, the present study focused on two important copper metallogenic provinces: the Cananea Porphyry District in Sonora, and the Sediment-hosted Stratiform Copper- and Mn-deposits in Baja California Sur. The U-Pb zircon ages from the mineralizing porphyries from Cananea district suggest a continued magmatic activity period of ~6 Ma. Also suggests a period of ~20 Ma for the entire magmatic activity in the district. The Re-Os molybdenite ages demonstrate five well-constrained mineralization events in the district; the main mineralization is constrained over a short period of time (~4 Ma). The new molybdenite age from the Pilar deposit documents the oldest mineralizing pulse, suggesting possibly the initiation of the Laramide mineralization in northern Sonora. A detailed study of Mariquita porphyry Cu and Lucy Cu-Mo deposits in the Cananea district was performed. Four hydrothermal stages were defined in Mariquita, whereas a single hydrothermal pulse characterizes Lucy. Emplacement depths between 1-1.2 km, and temperatures between 430-380ºC characterized the mineralization from Mariquita, whereas deeper emplacement depths and higher mineralization temperatures characterized Lucy. The stable isotope systematic and fluid inclusion data determined that the mineralizing fluids in Mariquita deposit are essentially magmatic during the earlier hydrothermal stages, whereas the last stage is the mixing between magmatic and winter meteoric-waters. The mineralizing fluids from Lucy deposit are magmatic in origin. A comprehensive study was performed in the Cu-Co-Zn-Mn ineralization of the Boléo District, and Mn-oxide mineralization along the eastern coast Baja California Sur. The REE and trace element in the Mn-oxides demonstrated the exhalative nature of the mineralizing hydrothermal fluids, and exclude the hydrogenous nature. The stable isotope systematic in ore and gangue minerals, along with the Cu-isotope data helped to decipher the nature of mineralizing and non-mineralizing fluids. The application of Pb, Sr and Re-Os isotope systems was applied to constrain the nature of the fluids involved during the mineralization processes and that the metal sources.

No description available.

No description available.

No description available.