This thesis examines the feasibility of assimilating space borne remotely-sensed microwave data into WATClass using the ensemble Kalman filter. WATClass is a meso-scale gridded hydrological model used to track water and energy budgets of watersheds by way of real-time remotely sensed data. By incorporating remotely-sensed soil moisture estimates into the model, the model’s soil moisture estimates can be improved, thus increasing the accuracy of the entire model. Due to the differences in scale between the remotely sensed data and WATClass, and the need of ground calibration for accurate soil moisture estimation from current satellite-borne active microwave remote sensing platforms, the spatial variability of soil moisture must be determined in order to characterise the dependency between the remotely-sensed estimates and the model data and subsequently to assimilate the remotely-sensed data into the model. Two sets of data – 1996-1997 Grand River watershed data and 2002-2003 Roseau River watershed data – are used to determine the spatial variability. The results of this spatial analysis however are found to contain too much error due to the small sample size. It is therefore recommended that a larger set of data with more samples both spatially and temporally be taken. The proposed algorithm is tested with simulated data in a simulation of WATClass. Using nominal values for the estimated errors and other model parameters, the assimilation of remotely sensed data is found to reduce the absolute RMS error in soil moisture from 0.095 to approximately 0.071. The sensitivities of the improvement in soil moisture estimates by using the proposed algorithm to several different parameters are examined.

Field pea is the most produced and exported pulse crop in Canada, and makes a major contribution to Western Canadian agricultural diversification programs. Canada is now the world largest exporter of pea, lentil and chickpea and is fourth in dry bean. The demand for Canadian pulse products is steadily rising and the export market would continue to rise with the expected increased in production. Field pea exported to countries with tropical climates is at particular risk due to rapid loss of quality. It is therefore important to develop practical strategies for safe storage of feed pea. Knowledge on the moisture adsorption and spoilage characteristics of pea stored in adverse storage conditions is important in the transportation and storage of this export commodity. <p> This study was initiated to examine the conditions that lead to quality losses in storage and transport of pea. Tropical and subtropical conditions were simulated in airtight chambers. Relative humidities (RH) of 60, 70, 80 and 90% were created by saturated salt solutions in airtight chambers at temperatures of 10, 20 and 30°C, while the same range of humidity was provided by dilute sulphuric acid in airtight chambers at 40°C in environmental cabinets. The four RH levels at each temperature for both whole and feed-grade pea were tested in duplicate. The samples were observed for changes in moisture content (MC), mold appearance and RH in specific time intervals. The amount of produced carbon dioxide (CO2) was measured in airtight chambers during storage to control the condition existing in sealed airtight chambers. Also, all components of feed-grade pea were exposed to RH of 90% and temperature of 40°C in separate airtight chambers to find the effect of each component on mold appearance. Molds were identified after appearance on the samples in order to pinpoint potential toxicity. <p> Both feed and whole sound peas became molded after a short time of storage at high temperatures and high RH, but those stored at 70% and below did not develop mold after 175 days at 30 and 40°C (experiment duration) and 216 days at 10 and 20°C (experiment duration). Molds were identified mostly as species of Aspergillus and Penicillium. The amount of CO2 in the airtight chambers showed almost no difference from the ambient CO2 except at high temperature and high RH when samples had gone molded. <p> Moisture adsorption equations were developed based on the moisture adsorption data in dynamic environment. Although the Page model showed to fit the data better, the exponential model was chosen to fit the data because its parameters can be better expressed as a function of temperature and RH of the storage environment. <p> The mold-free days for both feed pea and clean pea were modeled at temperatures of 10, 20, 30 and 40°C and RH of 80 and 90%.

In this thesis, heat and moisture transfer between supply and exhaust air streams are investigated for a run-around system in which the coupling material is a desiccant coated solid that is transported between two exchangers. The finite difference method is used to solve the governing partial differential equations of the cross-flow heat exchangers in the supply and exhaust ducts. The outlet air properties are calculated for several inlet air operating conditions and desiccant properties. The accuracy of the heat transfer model is verified by comparing the simulations with well-known theoretical solutions for a single cross flow heat exchanger and a liquid coupled run-around system. The difference between the analytical predictions and the numerical model for sensible effectiveness for each exchanger and the run-around system were found to be less than 1% over a range of operating conditions. The model is also verified by modifying the boundary conditions to represent a counter flow energy wheel and comparing the calculated sensible, latent, and total effectiveness values with correlations in the literature. <p>Using the verified model for energy exchangers and the run-around energy recovery system, the sensible, latent and overall effectiveness are investigated in each exchanger and the run-around system during simultaneous heat and moisture transfer. The overall effectiveness of the run-around energy recovery system is dependent on the air flow rate, the solid desiccant flow rate, the desiccant properties, specific surface area, the size of each exchanger, and the inlet air operating conditions. The run-around system can achieve a high overall effectiveness when the flow rates and exchangers properties are properly chosen. Comparisons between the solid desiccant and salt solution run-around system effectiveness (Fan, 2005 and Fan et al, 2006) shows they are in good agreement. In a sensitivity study, the thickness of desiccant on the fibre is investigated in the solid run-around system. It was found that good performance is obtained with very thin desiccant coatings (1 or 2 micron). During the practical use of this system, a desiccant coated fibre could be inserted into very porous balls or cages that protect the desiccant coated fiber from mechanical wear. The performance sensitivity for this kind of run-around system is demonstrated.

Understanding the hydrological controls on subsurface flow and transport is of considerable importance in the study of reclaimed landscapes in the oil sands region of Canada. A significant portion of the reclaimed landscape will be comprised of a thin veneer (~ 1 m) of clay-rich reclamation soil overlying saline-sodic shale overburden, which is a waste by-product from the mining process. The global objective of this study was to investigate the first-order controls on soil moisture and salt transport dynamics within clay-rich reclamation covers overlying low permeability waste substrates. The study site is located in a cold, semi-arid climate in the oil sands region of northern Alberta. Preferential flow was the dominant mechanism responsible for the development of perched water table conditions on the cover-waste interface during the spring snow melt. Hydrological and geochemical data indicated that snowmelt infiltration occurs via the macroporosity while the ground is still frozen. An isotope hydrograph separation conducted on water collected in a weeping tile confirmed the presence of fresh snowmelt water at the onset of subsurface flow. This water transitions to a chemical signature that is comprised of approximately 80% connate pore water as a result of chemical equilibration between pore water in the soil matrix and fresh water in the macropores.<p>Detailed mapping of the spatial distribution of soil moisture and salts within a reclamation cover indicated the lower-slope positions are wetter due to the accumulation surface run-off and frozen ground infiltration in spring. Increased soil moisture conditions in lower-slope positions accelerate salt ingress, while drier conditions in middle and upper-slope positions attenuate salt ingress. The data indicated that fresh snowmelt water is bypassing the soil matrix higher in the cover profile. Subsurface flow and deep percolation are key mechanisms mitigating vertical salt ingress in lower and upper slope positions. The mesotopography of the cover-waste interface imposes a direct control on the depth of perched water and the downslope routing of water. Undulations in the cover-waste interface cause the depth of perched water to vary considerably (± 20 60 cm) over short distances (< 5 m), while saturated subsurface flow is routed through the lowest elevations in the cover profile. A numerical analysis of subsurface flow was able to simulate both the discharge rate and cumulative volume of flow to a weeping tile. Composite hydraulic functions were used in the simulations to account for the increased hydraulic conductivity and drainable porosity created by the macroporosity at near-saturated conditions. The transient Na+ concentration of discharge water was modelled using the concept of an equivalent porous medium. The good match between measured and modelled data verified the conceptual model, which contends that saturated subsurface flow is dominated by the fracture network and that the concentration of discharge water is function of the depth of perched water. Finally, the results from this study suggest the mesotopography of the cover-waste interface could be used to manage excess water and salts within the landscape.

Several recent projects in building science have examined the hygric performance of building materials. Most building materials adsorb from and desorb water vapour to their environments. This phenomenon could be used to help control relative humidity fluctuations in buildings, experienced during periods of moisture production such as cooking, washing or bathing. They could also be used to reduce the need for mechanical ventilation and air conditioning to remove excess moisture. To understand how a building material responds to transient changes in relative humidity, testing is required.<p> This thesis outlines the testing performed on gypsum board, a common wall and ceiling finishing material used inside buildings. The effect of paint coatings on the gypsum boards and heat and mass transfer coefficients of the air passing over the gypsum bed was tested. The data produced from these experiments was used to validate several numerical models through an International Energy Agency/Energy Conservation in Buildings and Community Systems (IEA/ECBCS), Annex 41: Whole Building Heat, Air and Moisture Response. The validated models are important for simulating the process of adsorption and desorption in building materials to predict failure in the building envelope and expected indoor air conditions.<p> A sensitivity analysis is also presented which examines the effects of the sorption isotherm and vapour permeability of the gypsum and paints as well as the heat and mass transfer coefficients the boards are exposed to. The sensitivity range used was determined from the tests performed on the gypsum boards and paints which were also performed during the work of Annex 41.<p> The results of this thesis produced a high quality data which can also be used to validate future numerical models. All information required for validation of future models is available such as dimensions of test section, test conditions, material properties and the experimental data.<p> The results show that when designing for passive humidity control in buildings using gypsum boards, the most influential factor is the type of coating or paint applied to the surface. The sensitivity analysis showed that material properties such as vapour permeability and the sorption isotherms, for the expected temperature range, should be well known for increased accuracy of the simulation. The material properties were determined from inter-laboratory testing at 14 different institutions to achieve confident values.<p> The effect of increasing the heat and mass transfer coefficients, over the range of coefficients studied in this thesis, showed negligible differences in the results. The simulated results had very good agreement between the models and were mostly within experimental uncertainty of the measurements.

Soil moisture and ground thaw state are both indicative of a hillslopes ability to transfer water. In cold regions in particular, it is widely known that the wetness of surface soils and depth of ground thaw are important for runoff generation, but the diversity of interactions between surface soil moisture and ground thaw themselves has not been studied. To fill this knowledge gap, detailed shallow soil moisture and thaw depth surveys were conducted along systematic grids at the Baker Creek Basin, Northwest Territories. Multiple hillslopes were studied to determine how the interactions differed along a spectrum of topological, typological and topographic situations (T³ template). Results did not show a simple relationship between soil moisture and ground thaw as was expected. Instead, correlation was a function of wetness such that the correlation between soil moisture and ground thaw improved with site wetness. To understand why differences in soil moisture and ground thaw state arose, water and energy fluxes were examined for these subarctic study sites to discern the key processes controlling the patterns observed. Results showed that the key control in variable soil moisture and frost table interactions among the sites was the presence of surface water. At the peatland and wetland sites, accumulated water in depressions and flow paths maintained soil moisture for a longer duration than at the hummock tops. These wet areas were often locations of deepest thaw depth due to the transfer of latent heat accompanying lateral surface runoff. Although the peatland and wetland sites had large inundation extents, modified Péclet numbers indicated that the relative influence of external and internal hydrological processes at each site were different. Continuous inflow from an upstream lake into the wetland site caused advective and conductive thermal energies to be of equal importance to ground thaw. The absence of continuous surface flow at the peatland and valley sites led to the dominance of conductive thermal energy over advective energy for ground thaw. A quantitative explanation for the shallow soil moisture-ground thaw patterns was provided by linking hydrological processes and hillslope storage capacity with the calculated water and energy fluxes as well as the modified Péclet number. These results suggest that the T&#x00B3; template and the modified Péclet number could be very useful parameters for differentiating landscape components in modeling soil moisture and frost table heterogeneity in cold regions.

Current municipal solid waste (MSW) practices have encouraged rapid waste degradation (stabilization) as an alternative to past methods of isolating the waste from the surrounding environment. There are challenges to rapid-stabilization technology, in particular, the management of the in-situ MSW moisture content.<p> The primary objective of this study was to evaluate the use of capacitance moisture probes for the purpose of measuring the moisture content within MSW. Capacitance moisture probes have not previously been used in MSW, however their use in agriculture is extensive and knowledge of their potential for monitoring MSW is limited.<p> The specific objectives of this research were to: i) establish a laboratory based correlation between sensor data and volumetric moisture content in MSW, ii) establish a correlation between field-installed capacitance sensors and moisture content derived from continuous-depth in-situ sampling of MSW, and iii) demonstrate the ability of capturing advancing/receding moisture fronts with the field-installed capacitance sensors.<p> Laboratory trials were conducted using hand-compacted MSW at volumetric moisture contents ranging from 15%-55% and a manual type of capacitance sensor. This series of laboratory trials successfully produced a correlation between sensor output and volumetric moisture content.<p> To evaluate the sensors in a real-world application, two configurations of capacitance moisture probes were installed in the field: i) an in-place, continuous-time capacitance probe, and ii) a portable, continuous-depth at discrete time, capacitance probe.<p> Field results indicated that capacitance moisture probes were able to capture the passing of both an artificially and naturally induced moisture front, though quantitative correlation between the in-situ moisture content of the sampled MSW and the readings of the sensors could not be achieved.<p> The reasons for this were a combination of three factors:<p> 1. The introduction of void-space during sensor installation significantly reduced sensor output;<p> 2. Poor MSW sampling technique resulted in 57% recovery (causing the exact origin of samples to be unknown); and<p> 3. The sampling technique disturbed the MSW samples, resulting in incorrect volumetric moisture contents in the samples.

No description available.

In recent years, amorphous oxide semiconductors have been studied due to their superior characteristics, such as transparent property, high electron mobility exceeding 10 cm2/V¡Es, and can be fabricated on plastic substrates at low temperatures. According to these advantages, a-IGZO thin-film transistors are promising as next-generation electronic devices. Although a-IGZO TFTs have such unique properties, the electrical performances are strongly dependent on its environment such as oxygen, water and visible light. In this study, the electrical characteristics of a-IGZO TFTs under positive bias stress with different ambient gases have been discussed. In particular, the total duration of the negative gate bias applied on the switching transistor is larger than that of the positive gate bias in display application. Therefore, the electrical stability under negative bias stress is vital to investigate. Moreover, a-IGZO TFT regarded as a panel switch may be exposed to visible light for the application of liquid crystal display. The electrical stability under illumination of visible light is also important to study. Experiment results show that device characteristics are affected under water-containing oxygen ambience. We indicates that the existence of water molecules can assist more oxygen to adsorb on the a-IGZO surface than the case without water assisting. That cause the variation of transfer curve under positive bias stress. However, the degradations in subthreshold swing and threshold voltage are caused by the state-related adsorption of water molecules under negative bias stress. Furthermore, adsorbed oxygen on the surface of a-IGZO can be desorbed by illumination of visible light, leading to large variation in transfer curve.

The overarching goal of this dissertation project was to address several fundamental aspects of applying site-specific crop management for fiber quality in cotton production. A two-year (2005 and 2006) field study was conducted at the IMPACT Center, a portion of the Texas A&M Research farm near College Station, Texas, to explore the spatial variability of cotton fiber quality and quantify its relationship with in-season soil moisture content. Cotton samples and in-situ soil moisture measurements were taken from the sampling locations in both irrigated and dry areas. It was found that generally low variability (CV < 10%) existed for all of the HVI (High Volume Instrument) fiber parameters under investigation. However, an appreciable level of spatial dependence among fiber parameters was discovered. Contour maps for individual fiber parameters in 2006 exhibited a similar spatial pattern to the soil electrical conductivity map. Significant correlations (highest r = 0.85) were found between most fiber parameters (except for micronaire) and in-season soil moisture in the irrigated areas in 2005 and in the dry area in 2006. In both situations, soil moisture late in the season showed higher correlation with fiber parameters than that in the early-season. While this relationship did not hold for micronaire, a non-linear relationship was apparent for micronaire in 2006. This can be attributed to the boll retention pattern of cotton plants at different soil moisture levels. In addition, a prototype wireless- and GPS-based system was fabricated and developed for automated module-level fiber quality mapping. The system is composed of several subsystems distributed among harvest vehicles, and the main components of the system include a GPS receiver, wireless transceivers, and microcontrollers. Software was developed in C language to achieve GPS signal receiving, wireless communication, and other auxiliary functions. The system was capable of delineating the geographic boundary of each harvested basket and tracking it from the harvester basket to the boll buggy and the module builder. When fiber quality data are available at gins or classing offices, they can be associated with those geographic boundaries to realize fiber quality mapping. Field tests indicated that the prototype system performed as designed. The resultant fiber quality maps can be used to readily differentiate some HVI fiber parameters (micronaire, color, and loan value) at the module level, indicating the competence of the system for fiber quality mapping and its potential for site-specific fiber quality management. Future improvements needed to make system suitable for a full-scale farming operation are suggested.