Graduation date: 1999

Nitrate contamination in ground and surface waters is of great concern to environmentalists. A two-dimensional model of water and solute movement in soils was used to test the usefulness and relative advantages of a two-dimensional model over a one dimensional model for analysis of deep percolation and nitrate leaching in furrow irrigation. The predictive ability of the model was evaluated using data collected in a series of preliminary field studies. Two methods were used to calibrate the model. First, the cumulative infiltration simulated by the model was compared with an infiltration curve derived from field data. Secondly, soil water potential data were used to compare the observed movement of a wetted front in the soil profile. The calibration results closely followed the two dimensional flow pattern in furrow irrigation. The model was used both in a one-dimensional mode and a two-dimensional mode. Comparison of one-dimensional and two-dimensional models was accomplished using the two-dimensional model, with uniform infiltration across the surface boundary to represent the one-dimensional case, and with infiltration only across the furrow surface for the two-dimensional case. Evaluation of water and nitrate leaching was observed for alternate furrow irrigation as well as every-furrow irrigation with three different furrow spacings; 76, 86, and 102 cm. These results showed that the one-dimensional model always under estimates the leaching amount in comparison to the two-dimensional model. In some cases the one-dimensional model predicted no leaching of water and nitrate below the root zone though leaching was predicted by the two-dimensional model. Evaluation of alternate and every furrow irrigation with different furrow spacing indicated that the leaching amount increased rapidly with the increase of furrow spacing. Under furrow irrigation, attempts to irrigate the soil profile to a level less than, but close to, field capacity will result in leaching. Therefore different irrigation management is needed to minimize leaching. Additionally, the model suggests that the sealing layer which forms in the bottom of the furrow drastically reduced the infiltration rate because of the very low saturated hydraulic conductivity in that area. Sealing layer had a significant effect on the performance of SWMS_2D model, and made the model unusable where high input volume were required. / Graduation date: 1995

Groundwater contamination on irrigated land is of concern in this nation and around the world. In order to reduce the potential of groundwater contamination by agricultural practices such as irrigation, fertilizer and pesticide application, vadose-zone monitoring and sampling are needed. The main objective of this study was to evaluate impacts of current irrigation treatments and soil structures on the migration of pollutants to groundwater. Passive CAPillary wick pan Samplers (PCAPS) and suction cups were installed in two cracking clays and one sandy soil under the pear tree root zone. PCAPS and suction cups were used to collect nitrate-nitrogen and tracer samples. Tracers were applied to track the spatial and temporal patterns of compounds that mimic nitrate-nitrogen and pesticide movement. The observed magnitude of water leaching over 3 months differed between irrigation methods and soil structures and decreased in this order: flooding over 3 months in clay soil (22.8 cm) > micro-sprinkler in clay soil (16.1 cm) > over-head sprinkler in sandy soil (4.1 cm). Leaching patterns were varied spatially; soil structures, irrigation methods, preferential flow, and high water table may have been responsible for the spatial variation of leaching. Mass recovery of all three tracers, including bromide, blue dye, and rhodamine had the same decreasing order: flooding in clay soil > micro-sprinkler in clay soil > over-head sprinkler in sandy soil. Average blue dye and rhodamine concentrations had the following order: flooding in clay soil > micro-sprinkler in clay > over-head sprinkler in sandy soil. Since blue dye and rhodamine have similar properties to some moderately adsorbed pesticides, we may infer that the risk of pesticide movement in three sites should also decrease in this order. Presumably pesticide movement in clay soil would have been more pronounced for flooding than sprinkler irrigation. On the annual/seasonal basis, the total mass of nitrate-nitrogen leaching differed between irrigation methods and soil structures and decreased in the following order: over-head sprinkler in sandy soil > flooding in clay soil > micro-sprinkler in clay soil. The annual average nitrate-nitrogen concentration observed under over-head sprinkler in sandy soil was 15 mg/l over the maximum allowed concentration level (10 mg/l) by the EPA while seasonal nitrate-nitrogen concentration was low in clay soil under current irrigation practices. Strong evidence suggested the occurrence of preferential flow in this study. Preferential flow may contribute to high water leachate, nitrate and pesticide migration. High correlation coefficients between paired PCAPS indicated that PCAPS have similar responses to water and solute leaching. Several improvements in PCAPS are needed to obtain representative samples under severe flooding conditions. Limited data suggested that ultra-low rate irrigation devices could reduce the water leaching and the potential of pollutant migration to the groundwater because ultra-low rate application devices minimize the soil macropore flow. / Graduation date: 1995

The use of agricultural chemicals often results in water pollution. This research, comprising three parts, was designed to investigate the role of soil and grass strips and water table management in reducing pesticide and nitrate residues in drainage waters. / The first part of the research was made on lysimeters to investigate the effects of soil and grass cover under two water table management regimes. Four treatments were involved: subsurface drainage, controlled drainage, grass cover, and bare soil. Each treatment consisted of three replicates. Contaminated water containing atrazine, metolachlor, and metribuzin residues was applied to the lysimeters and samples of drain effluent were collected. Significant reductions in pesticide concentrations were found in all treatments. / In the first year (1993), herbicide levels were reduced significantly, from an average of 250 mug/L to less than 10 mug/L. In the second year (1995), water polluted at a concentration of 50 mug/L, was applied to the lysimeters, and herbicide residues were reduced significantly to less than 1 mug/L. Subsurface drainage and grass cover lysimeters (SDG treatment) reduced herbicide concentration levels to a greater extent than the other treatments and the controlled drainage lysimeters reduced nitrate concentration levels to a greater extent than the free drainage lysimeters. / The second part of the research was a field study that reports the development and testing of an on-farm pollution control system using soil as a biological filter for trapping herbicide residues. A field site with four shallow surface ditches, underlain with four perforated drain pipes, was used to carry-out field measurements. Polluted water with concentration levels of 30 mg/L of nitrate and 100 mug/L of three commonly-used herbicides was applied to the ditches for 10 days continuously; and no water was applied for the following ten days. This cycle was repeated three times. Water samples were collected both before application and after the water came out of the drains. Herbicide levels were reduced significantly in drainage waters. The average concentration level of nitrate in drainage water was found to be 17 mg/L in comparison to 30 mg/L in applied water. Also, the bio-degradation of herbicide residues in the soil was found to occur between water applications. Thus, it appears that the system would be self-sustainable in the long term. / The third part of the research utilizes a water table model, DRAINMOD, for simulating drainage waters from agricultural land and a solute transport model, PRZM2, for simulating pesticide concentrations in the drain effluent coming out of the grass filter area. DRAINMOD was used to estimate the daily drain outflows that would occur in a 100 ha subsurface drained field in the for a 1-in-20 year annual rainfall period. It was found that 6% of the farm area could be used to bring down the concentrations in drainage water from 50 mug/L to less than 1 mug/L for the three herbicides. (Abstract shortened by UMI.)

No description available.

Vita. / Digitized by Kansas Correctional Industries

The agricultural production of peppermint has been shown to contribute significant quantities of nitrate-nitrogen to groundwater recharge. In an effort to provide new tools for increasing nitrogen efficiency within peppermint production, three research questions were proposed: i) How should plant tissue samples be collected to achieve the greatest precision when using the mint stem nitrate test for nitrogen management?; ii) What is the consumptive use of water by peppermint in the post-harvest period?; and iii) How does irrigation uniformity affect nitrate loading to groundwater when N is supplied through chemigation? In the first investigation, structured field experiments were designed and conducted on commercial peppermint fields to isolate potential environmental, management, and sampling influences on stem nitrate test results. The most significant effects observed were those of the type of stem material collected (a 441% effect at p<0.001) and the number of stems collected to estimate the field mean concentration. It was found that the variance of the sample population and the number of stems required for a given sampling error could be greatly reduced by only collecting stems from within the plant canopy. Less pronounced but statistically significant differences in stem nitrate concentrations were produced by variations in solar radiation on hourly (a 17% effect at p<0.05) and daily (a 29% effect at p<0.01) scales. In an analysis of stem nitrate spatial variability, a purely random distribution of stem nitrate concentrations was observed on the 1-150 m scale. For the second investigation, a field study was conducted to measure the consumptive use of peppermint in the post-harvest period and to develop crop coefficients (Kc) used to predict evapotranspiration rates. The soil water balance was measured on two fields with a neutron moisture probe over an 80 day period. Over the 49 days following harvest, a cumulative consumptive use of 96 mm was observed. Basal crop coefficients increased from near zero to approximately 0.40 within 40 days post-harvest. The third, and final, investigation developed a simple heuristic statistical model to explore the effective adequacy of chemical application as influenced by the uniformity of irrigation. To perform this analysis, an expression was presented whereby irrigation distribution parameters for the normal, or Gaussian, model could be derived from common irrigation design terms. The results of this model indicate that the effective chemical adequacy is greatly compromised when the irrigation uniformity coefficient is low and/or the design irrigation adequacy is high. / Graduation date: 1998

Land application of industrial wastewater with high levels of nitrogen requires adequate management practices to prevent groundwater pollution by nitrates. In this study a predictive computerized model was developed for nitrate leachate concentrations resulting from land application of wastewater onto crop systems including poplars. The study included a literature review, development of a computer program that could serve this purpose, and a field investigation to test the validity of the computed predictions. The literature review focused on poplar water and nitrogen uptakes, and suggested that mature poplars could uptake up to 400 lb of nitrogen /acre/year and 2 3 million gallons of water per acre per year. The computer model, based on 10-day water and nutrient balances, takes into account a number of parameters such as wastewater quality, evapotranspiration and precipitation data, irrigation volumes, soil water holding capacities, fertilization, crop nutrient uptakes and crop coefficients. This study involves a number of assumptions selected to give conservative (i.e., worst case approach) model predictions. Attempts to validate the model were conducted through soil and groundwater sampling along with precipitation data collection in four distinct fields in Brooks, Oregon, from October 1996 to April 1997. The variations in nitrogen soil profiles from October to April helped determine the amount of nitrogen leaving the soil, and groundwater samples from 5 feet deep wells gave nitrate concentrations in groundwater below the root zone. A sensitivity analysis of the program demonstrated how important nitrogen and water uptakes values were to the model predictions. An increase of 1% in nitrogen uptake or of 0.4% in crop coefficients generated 1% decrease in nitrogen concentration of the leachate. These results are important to consider when adopting highly uncertain literature values for crop uptakes -especially with poplars. The field validation of the model showed promising results in terms of estimating average yearly leachate concentrations in nitrogen resulting from land application of wastewater, but also suggested that more groundwater wells were needed to obtain a statistically significant validation of the model. These preliminary field results indicate that the model can provide an indication of groundwater nitrogen concentration trends but needs to further verified to be used confidently as a predictive tool. / Graduation date: 1998

No description available.

Estuaries, the interface of interaction of fluvial discharge and marine action serve as temporary repositories of materials (solid and dissolved) before finally exporting them to sea. This interchange of material is dependent on a range of factors such as tidal range, prism, and symmetry; fluvial flows and estuarine morphodynamics. The efficacy of transfer of materials to the marine environment is important for estuarine health particularly in estuaries located in highly developed areas such as the major coastal metropolitan areas of many countries. This study assesses the efficacy of the export of nitrates from three estuaries of the eThekwini Municipality of the city of Durban, South Africa which maintain an open mouth status, ensuring tidal exchange throughout the year. The focus of this study was to determine and analyze the net flux of nitrates between the Isipingo, Mgeni, and Tongati estuaries of the eThekwini Municipality, and their adjacent nearshore environments. It questioned whether the Isipingo, Mgeni, and Tongati estuaries were efficient at exporting nitrates to their adjacent marine environments. The abovementioned estuaries are classified as temporarily open/closed estuaries, and were chosen for this study, as they maintain an open mouth status for most of the year. An open mouth condition was critical in order to conduct this study, as tidal exchange, and the resulting nitrate fluxes, could occur. The net flux of nitrates was measured for these estuaries on a seasonal basis for both spring and neap tides. Measurements were taken over the tidal cycle, ensuring that the peak high and low tides were sampled. To determine the values of net flux, the cross-sectional area of the estuary mouths were measured; average flow velocities of water were measured; and average concentrations of nitrates were obtained. Results indicate that although there is a net export of nitrates to the nearshore environment, there were instances, particularly on the spring tide, when a net import of nitrates into the estuary occurred. The origin of the latter is likely derived from nearshore upwelling; unusually high biotic decomposition at sea and/or the longshore drift transport of decomposing sewage outfall. This creates an added dimension for consideration in estuarine management plans. Taking all three estuaries studied into consideration, a net export of nitrates for all seasons for the eThekwini Municipality was measured with a clear seasonal influence detected where high rainfall seasons led to greater export as a consequence of greater fluvial flows, erosion and leaching of agricultural lands and longer ebb duration. / Thesis (M.Sc.)-University of KwaZulu-Natal, Westville, 2011.