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Effect of lime additions and bulk chromium content on chromium deportment in smelter matte-slag systemsDu Preez, Rudolph C. 03 1900 (has links)
Thesis (MScEng) –Stellenbosch University, 2010 / ENGLISH ABSTRACT: More mining houses are turning their attention to the processing of ore mined
from the UG2 reef. This is mainly due to the depletion of the Merensky reef
or the low availability of ore from the Platreef. With the higher UG2 ore
concentration in the process feed, companies experience more problems with
the processing of the ore due to its high chrome content. Although there are
various possible solutions to the problems experienced in the processing of UG2
ore, very little of thise solutions are actually implemented in the industry.
When smelting chrome-bearing ore, the chrome can go to any of three
phases: matte phase, spinel phase or glass phase. If it reports to the furnace
matte phase it can lead to problems in the down stream processing. When
chrome forms part of the spinel phase it forms a solid, refractory-like material
which, to an extent, is an unwanted material inside the furnace. Lastly the
chrome can report to the glass phase (liquid phase) which is the more desireable
phase to which chrome should report to since it will have little or no impact
on downstream processing.
There were four main objectives for this research project namely to conduct
a literature review to understand the problem of chrome in the smelting
process, to do an experimental simulation of a matte and slag phase in one
crucible, to interpret the experimental results and compare the experimental
results to thermodynamic predictions obtained using FactSageTM.
From literature the following aspects were found to be important:
Silica structures
Research has shown that silica incorporates different metal ions into its
structures. When the metal ions are incorporated into the silica structures
they are seen as part of the glass phase. By incorporating cations such as
chromium into the silica structure the structure is able to maintain its neutral
electrical charge.
Basicity of slag
Oxides once melted will either donate or accept oxide ions. The group of
oxides that are in excess will determine whether that specific slag is acidic or
non acidic. This is important to our study since the basicity can determine
the stability of the spinel phase. Partial pressures
The partial pressure of the system is important since it forms part of the
equilibrium constant calculations - meaning that partial pressures determine
the stability of certain species. Currently different arguments exist as to how
the sulphur pressure inside a molten bath is maintained. What is important,
however, is that for the system in this research project a log oxygen partial
pressure of -8 and a log sulphur partial pressure of -3.5 was chosen. These
values were based on previous research done on PGM and copper smelting
processes.
Chrome deportment
Previous research on chrome deportment shows a relationship between temperature
and the amount of chromium dissolving into the glass phase as well as
an increased chromium(II)oxide solubility (when compared to chromium(III)oxide)
in a silicate melt. Regarding slag chemistry and chrome deportment very little
work has been published for the system found in the PGM industry but it is
mentioned that by adjusting certain slag additives (alumina, lime and silica)
the chrome deportment can be manipulated.
The scope of this project was to investigate the effect of chromium, lime
and silica on chrome deportment. More specifically, the effect of lime. The
reason being that lime was originally added as 10%wt of the feed stream in the
processing of Merensky ore to act as a fluxing agent. With the new furnace
design and higher power densities the slag are maintained at 200oC to 350oC
higher than when Merensky ore was smelted. With these higher slag temperatures
fluxing agents will play a smaller role meaning that lime additions
become less important. Literature studies also showed that additional lime in
a slag system can stabilize the spinel structure (which is an unwanted phase).
Removing lime would be advantageous out of a chrome presepective as well as
an economic point of view.
The research was conducted in three sections namely the determination of
the time required for this particular system to reach equilibrium, the investigation
of different additives on chrome deportment using a controlled atmosphere
and synthetic slags and, lastly, a comparison of the experimental results obtained
to thermodynamic predictions.
For the equilibration studies reaction time periods of 4,7,11 and 16 hours
were used. From the results it was found that the alumina crucible dissolved
into the glass phase continually. This indicated that equilibrium was not
reached. However, a reaction time, rather than an equilibrium time, was chosen
where the species and phases had enough time to react. This was based
on literature, on observations of species diffusing between the matte and slag
phase as well as on two-point analysis (diffusion gradients). A reaction time
of nine hours was chosen With the reaction time fixed, the effect of different slag additives on chrome
deportment was investigated. For the addition of chrome it was seen that an
1.5%wt increase in the starting material increased the chrome content of the
slag phase by 0.025%wt. For the same increase in chromium in the starting
materials the chrome content of the spinel phase increased by 2.1% indicating
that chromium has a tendency to report to the spinel phase. The increase
in chromium had a minor effect on the chrome content of the matte phase,
however, since the chrome content only increased from 0.025%wt to 0.028%wt.
Plotting the results showed that increasing the lime in the starting material
decreases the chromium content in the glass phase. For the 39%wt silica system
the chromium content in the glass phase decreased from 0.75%wt to 0.46%wt
for an increase in the lime content from 1.7%wt to 7.3%wt. The same trend was
seen for the 33%wt silica system. For the spinel phase an increase of 1.27%wt
was seen when the lime content of the starting materials was increased from
1.7%wt to 10.1%wt for a 33%wt silica system. The same increase in lime
increased the chrome content of the matte phase from 0.03%wt to 0.06%wt for
a 33%wt silica system.
Silica also proved to affect chrome deportment. Increasing the silica content
of the starting materials from 25%wt to 39%wt increased the amount of
chromium in the glass phase from 0%wt to 0.46%wt for a 10%wt lime system.
The same effect is seen for a lower lime content except that more chromium
were incorporated into the silica structure. A silica increase from 32.4%wt
to 39%wt resulted in a chromium decrease from 5.2%wt to 0% in the spinel
phase for a 10%wt lime system. The same trend was seen for the 1.5%wt lime
system. An increase in the silica levels lead to an increase in the chrome level
of the matte phase. When silica is increased from 32%wt to 39%wt the chrome
content of the matte phase increased from 0.06%wt to 0.07%wt.
The last part of the research project entailed the comparison of the trends
observed with the experimental results to trends obtained from thermodynamic
predictions. FactSageTM is a program that uses model equations to predict
the Gibbs free energies for different phases. The program is therefore also able
to predict the amount of different phases present at equilibrium. This is called
thermodynamic ”optimization”.
In section 6 trends that were observed from FactSageTM results are compared
to the trends found in the experimental results. It is important to note
that it is only trends that are evaluated and not actual values since FactSageTM
calculations are for a system that is at equilibrium and (as explained above)
this system is not at complete equilibrium. The comparison however was good.
Several trends found in the experimental results were confirmed by the results
from FactSageTM. These included the relationships of chromium fed versus
chromium spinel, lime fed versus chromium spinel, lime fed versus chromium
in glass, silica fed versus chromium in glass, silica fed versus chromium in
spinel and silica fed versus chromium in matte. To conclude, slag additions can be used to manipulate chrome deportment
to an extent. Secondly, FactSageTM can be used for thermodynamic predictions
but a proper understanding as well as some form of validation of the
specific system investigated is still needed.
Due to time constraints and the difficulty of experimentally simulating this
multi-phase system in the lab, only a few parameters were investigated. In
order to obtain a more complete understanding of the system the effect of
partial pressures and temperature should also be investigated.
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Development amd implementation of a real-time observer model for mineral processing circuits.Vosloo, John-Roy Ivy. January 2004 (has links)
Mineral processing plan ts, such as LONMIN's Eastern Platinum B-stream, typically have few on-line measurements, and key measures of performance such as grade only become available after samples have been analysed in the laboratory. More immediate feedback from a dynamic observer model promises enhanced understanding of the process, and facilitates prompt corrective actions, whether in open or closed loop . Such plant s easily enter sub-optimal modes such as large , uselessly re-circulating loads as the feed conditions change. Interpretation of such modes from key combinations of the variables deduced by an observer model , using a type of expert system, would add another level of intelligence to benefit operation. The aim of this thesis was to develop and implement a dynamic observer model of the LONMIN Eastern Platinum B-Stream into one of the existing control platforms available at the plant , known as PlantStar®, developed by MINTEK. The solution of the system of differential and algebraic equations resulting from this type of flowsheet modelling is based on an extended Kalman filter, which is able to dynamically reconcile any measurements which are presented to it, in real time. These measurement selections may also vary in real time, which provides flexibility of the model solution and the model 's uses. PlantStar passes the measurements that are available at the plant, to the dynamic observer model through a "plugin" module, which has been developed to incorporate the observer model and utilise the PlantStar control platform. In an on-line situation, the model will track the plant's behaviour and continuously update its position in real-time to ensure it follows the plant closely. This model would then be able to run simulations of the plant in parallel and could be used as a training facility for new operators, while in a real-time situation it could provide estimates of unmeasurable variables throughout the plant. An example of some of these variables are the flotation rate constants of minerals throughout the plant, which can be estimated in real time by the extended Kalman filter. The model could also be used to predict future plant conditions based on the current plant state , allowing for case scenarios to be performed without affecting the actual plant's performance. Once the dynamic observer model and "plugin" module were completed, case scenario simulations were performed using a measured data set from the plant as a starting point because real-time data were unavailable as the model was developed off-site . / Thesis (M.Sc.Eng.)-University of Natal, Durban, 2004.
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An investigation into a lower temperature and low cost direct reduction process for iron-making.Chellan, Reubendran. January 2003 (has links)
The blast furnace process for the reduction of iron ore to pig iron faces problems such as
emission of air pollutants, high investment cost and the current major problem of
decreasing supplies of coke. Coke is used in large quantities to promote a combination of
direct and indirect reduction within the furnace. Due to the lack of good coking coal
within South Africa, and dwindling supplies worldwide, new iron-making processes, are
being developed using coal and/or natural gas to replace coke as the reductant.
The new processes allow efficient use of carbon, fed in the form of coal pellets (coalbased
processes) or natural gas (gas-based processes), as the reducing agent. Presently,
most coal-based processes Use an excess of coal, up to 500% stoichoimetric addition, and
are run at temperatures up to ±1200°C, although reduction tends to proceed at ±850°C.
This project developed a low temperature process using mixed pellets of fine waste iron
oxide and fine domestic coal with a natural carbonaceous binder (a by-product from local
pulping industry).
Reduction tests performed on composite pellets in a tube furnace and thermobalance
indicated, upon analysis by X-Ray Diffraction and Scanning Electron Microscope, that
reduction occurred gradually at 900°C. Implementing induction heating of bulk pellets
reduced heating times substantially. Induction heating also resulted in direct reduced iron
[DRI] containing 75 - 80% metallic iron. Energy consumption based on coal usage
amounted to 23.71 GJ/ton DRI, which compares with the calorific consumption of most
coal-based processes, i.e. coal consumption range between 15 and 25 GJ/ton DRI.
Energy consumed during induction heating amounted to 9.94 GJ/ton DRI, as electricity.
This energy consumption value does not take into account the efficiency of the primary
energy required to generate electricity. / Thesis (M.Sc.Eng.)-University of Natal, Durban, 2003.
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Métodos de desaguamento e disposição de rejeito da bauxita: estudo de caso e avaliação econômica. / Bauxite reject dewatering and disposal: case study and economic evaluation.Caio Moreira Van Deursen 10 November 2016 (has links)
Cerca de 230 milhões de toneladas de bauxita são produzidas por ano e, destas, 60 milhões são provenientes de operações que beneficiam esta bauxita usando água como meio para separar as frações mais finas. Como consequência do beneficiamento, estima-se que mais de 25 milhões de toneladas de rejeito sejam dispostas todo ano. Estas frações têm grandes quantidades de caulinita, um argilomineral de difícil desaguamento. Estes sólidos estão tipicamente em uma suspensão com água a cerca de 15% de concentração em massa antes de operações de desaguamento. As formas de desaguamento variam, bem como as opções de disposição. Este texto discorre sobre opções de desaguamento como sedimentação natural, espessamento, filtragem e centrifugação. Também se discorre sobre alternativas de disposição. Estas são condicionadas pela concentração de sólidos do material a ser disposto e são a disposição hidráulica em diques ou reaterro na mina. Após a descrição de cada uma das alternativas, são feitas análises de combinações destas formas de desaguamento e disposição, além de uma avaliação do fluxo de caixa livre descontado acumulado para cada uma. Esta abordagem, feita para um caso específico, permite avaliar qual opção implica em menor despesa financeira para a operação. Foram feitas considerações para avaliar características não econômicas de cada uma das operações, como o consumo de água, área ocupada pelo depósito, perigos de cada opção e seus descomissionamentos. A opção que apontou menor desembolso no período da operação, bem como a minimização de perigos, é o desaguamento com centrífugas e disposição do material reaterrando áreas lavradas. / More than 230 million tonnes of bauxite are produced each year and, from these, nearly 60 million come from operations that use water to beneficiate the ore, separating the finer fractions. By reason of this mineral treatment, it is estimated that more than 25 million dry tonnes of reject are disposed each year. The finer fractions have high kaolinite concentrations, a challenging to dewater mineral. These solids are typically in a suspension with about 15% solids concentration in mass before any dewatering. Both the dewatering options and disposal possibilities may vary. This text discusses dewatering options such as natural settling, thickening, filtering and centrifugation. It also describes alternatives of disposing the material. These options depend on the water concentration and consist of hydraulic disposition or using the dewatered material as mine backfill. After describing each alternative, an analysis of possible combinations among those is made along with an accumulated discount free cash flow evaluation for each one. Considerations were made to evaluate non-economic characteristics of each operation including the water consumption, surface occupied, operational hazards, decommissioning and closure. The option that has shown the lowest cost during the life of the operation, simultaneously reducing operational hazards is dewatering with centrifuges and using the material as backfill in mined out areas.
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Métodos de desaguamento e disposição de rejeito da bauxita: estudo de caso e avaliação econômica. / Bauxite reject dewatering and disposal: case study and economic evaluation.Van Deursen, Caio Moreira 10 November 2016 (has links)
Cerca de 230 milhões de toneladas de bauxita são produzidas por ano e, destas, 60 milhões são provenientes de operações que beneficiam esta bauxita usando água como meio para separar as frações mais finas. Como consequência do beneficiamento, estima-se que mais de 25 milhões de toneladas de rejeito sejam dispostas todo ano. Estas frações têm grandes quantidades de caulinita, um argilomineral de difícil desaguamento. Estes sólidos estão tipicamente em uma suspensão com água a cerca de 15% de concentração em massa antes de operações de desaguamento. As formas de desaguamento variam, bem como as opções de disposição. Este texto discorre sobre opções de desaguamento como sedimentação natural, espessamento, filtragem e centrifugação. Também se discorre sobre alternativas de disposição. Estas são condicionadas pela concentração de sólidos do material a ser disposto e são a disposição hidráulica em diques ou reaterro na mina. Após a descrição de cada uma das alternativas, são feitas análises de combinações destas formas de desaguamento e disposição, além de uma avaliação do fluxo de caixa livre descontado acumulado para cada uma. Esta abordagem, feita para um caso específico, permite avaliar qual opção implica em menor despesa financeira para a operação. Foram feitas considerações para avaliar características não econômicas de cada uma das operações, como o consumo de água, área ocupada pelo depósito, perigos de cada opção e seus descomissionamentos. A opção que apontou menor desembolso no período da operação, bem como a minimização de perigos, é o desaguamento com centrífugas e disposição do material reaterrando áreas lavradas. / More than 230 million tonnes of bauxite are produced each year and, from these, nearly 60 million come from operations that use water to beneficiate the ore, separating the finer fractions. By reason of this mineral treatment, it is estimated that more than 25 million dry tonnes of reject are disposed each year. The finer fractions have high kaolinite concentrations, a challenging to dewater mineral. These solids are typically in a suspension with about 15% solids concentration in mass before any dewatering. Both the dewatering options and disposal possibilities may vary. This text discusses dewatering options such as natural settling, thickening, filtering and centrifugation. It also describes alternatives of disposing the material. These options depend on the water concentration and consist of hydraulic disposition or using the dewatered material as mine backfill. After describing each alternative, an analysis of possible combinations among those is made along with an accumulated discount free cash flow evaluation for each one. Considerations were made to evaluate non-economic characteristics of each operation including the water consumption, surface occupied, operational hazards, decommissioning and closure. The option that has shown the lowest cost during the life of the operation, simultaneously reducing operational hazards is dewatering with centrifuges and using the material as backfill in mined out areas.
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Identification and control of wet grinding processes: application to the Kolwezi concentrator / Identification et commande de procédés de broyage humide: application au concentrateur de KolweziMukepe Kahilu, Moise 17 December 2013 (has links)
Enhancing mineral processing techniques is a permanent challenge in the mineral and metal industry. Indeed to satisfy the requirements on the final product (metal) set by the consuming market, control is often applied on the mineral processing whose product, the ore concentrate, constitutes the input material of the extractive metallurgy. Therefore much attention is paid on mineral processing units and especially on concentration plants. As the ore size reduction procedure is the critical step of a concentrator, it turns out that controlling a grinding circuit is crucial since this stage accounts for almost 50 % of the total expenditure of the concentrator plant. Moreover, the product particle size from grinding stage influences the recovery rate of the valuable minerals as well as the volume of tailing discharge in the subsequent process.<p> The present thesis focuses on an industrial application, namely the Kolwezi concentrator (KZC) double closed-loop wet grinding circuit. As any industrial wet grinding process, this process offers complex and challenging control problems due to its configuration and to the requirements on the product characteristics. In particular, we are interested in the modelling of the process and in proposing a control strategy to maximize the product flow rate while meeting requirements on the product fineness and density.<p> A mathematical model of each component of the circuit is derived. Globally, the KZC grinding process is described by a dynamic nonlinear distributed parameter model. Within this model, we propose a mathematical description to exhibit the increase of the breakage efficiency in wet operating condition. In addition, a relationship is proposed to link the convection velocity to the feed ore rate for material transport within the mills.<p> All the individual models are identified from measurements taken under normal process operation or from data obtained through new specific experiments, notably using the G41 foaming as a tracer to determine material transport dynamics within the mills. This technique provides satisfactory results compared to previous studies.<p>Based on the modelling and the circuit configuration, both steady-state and dynamic simulators are developed. The simulation results are found to be in agreement with the experimental data. These simulation tools should allow operator training and they are used to analyse the system and to design the suitable control strategy.<p> As the KZC wet grinding process is a Multi-Input Multi-Output (MIMO) system, we propose a decentralized control scheme for its simplicity of implementation. To overcome all the control issues, a Double Internal Model Control (DIMC) scheme is proposed. This strategy is a feedforward-feedback structure based on the use of both a modified Disturbance Observer (DOB) and a Proportional-Integral Smith-Predictor (PI-SP). A duality between the DOB and PI-SP is demonstrated in design method. The latter is exploited to significantly simplify the design procedure. The designed decentralized controllers are validated in simulation on the process linearized model. A progressive implementation of the control strategy is proposed in the context of the KZC grinding circuit where instrumentation might not be obvious to acquire./<p><p> Améliorer les techniques de traitement de minerais est un défi permanent dans l'industrie des minéraux et des métaux. En effet, pour satisfaire aux exigences du produit fini (métal ) fixées par le marché de consommation, la commande automatique est souvent appliquée à l'usine du traitement de minerais dont le produit, le concentré, constitue la matière première de la métallurgie extractive. Une attention particulière est donc dévolue aux unités de traitement de minerais et en particulier aux concentrateurs. Comme le processus de réduction des dimensions granulométriques du minerai est l'étape critique d'un concentrateur, il s'avère que la commande d'un circuit de broyage est cruciale, car ce stade représente près de 50 % des dépenses totales de l' usine de concentration. De plus, la dimension granulométrique du produit de l'étape de broyage influe sur le taux de récupération des minéraux utiles ainsi que sur le volume des rejets du processus ultérieur.<p> La présente thèse porte sur une application industrielle, à savoir le concentrateur de Kolwezi (KZC qui est un circuit de broyage humide à double boucle fermée. Comme tout processus industriel de broyage humide, ce procédé présente une problématique de commande complexe et difficile en raison de sa configuration et des exigences relatives aux caractéristiques du produit. En particulier, nous nous intéressons à la modélisation de ce procédé et à proposer une stratégie adéquate de commande dans le but de maximiser le débit de production tout en respectant les exigences quant à la finesse et à la densité de la pulpe produite.<p> Un modèle mathématique de chaque composant du circuit a été déterminé. Globalement, le processus de broyage de KZC est décrit par un modèle dynamique non linéaire à paramètres distribués. Dans ce modèle, une description mathématique de l'augmentation de l'efficacité du broyage en milieu humide est proposée. En outre, nous avons proposé une relation liant la vitesse de convection au débit d'alimentation de minerais dans le modèle du transport de la matière à l'intérieur des broyeurs.<p> Tous les modèles mathématiques ont été identifiés à partir de mesures prises sur le procédé en fonctionnement d'équilibre stable ou à partir des données obtenues grâce à des nouvelles expériences spécifiques, notamment en utilisant le moussant G41 comme traceur pour déterminer la dynamique de transport de la matière dans les broyeurs. Cette technique a produit des résultats cohérents par rapport aux études antérieurs réalisées au moyen du traceur colorant ou radioactif.<p> Les simulateurs statique et dynamique ont été développés sur la base de la modélisation mathématique et de la configuration du circuit. Les résultats des simulations sont en accord avec les données expérimentales. Ces outils de simulation devraient permettre la formation des opérateurs et ont été utilisés pour analyser le système et concevoir la stratégie de commande la plus appropriée.<p> Comme le processus de broyage humide de KZC est un système à plusieurs grandeurs d'entrée et plusieurs grandeurs de sortie, nous avons proposé une structure de commande décentralisée en raison de sa simplicité de mise en œuvre .Afin de surmonter tous les problèmes de commande, un schéma de commande à double modèle interne (CDMI) est proposée. Cette stratégie est une structure à anticipation - rétroaction basée sur l'utilisation d'un observateur de perturbations (OBP) et d'un Prédicteur de Smith doté d'un régulateur Proportionnel-Intégral (PS-PI). Une dualité entre l'OBP et le PS-PI est démontrée dans la méthode de conception. Cette propriété est exploitée pour simplifier considérablement la procédure de conception. Les régulateurs décentralisés ainsi conçus sont validés en simulation sur le modèle linéarisé du procédé. Une mise en œuvre progressive de la stratégie de commande est proposée dans le contexte du circuit de broyage de KZC où l'instrumentation peut ne pas être évidente à acquérir.<p> <p> / Doctorat en Sciences de l'ingénieur / info:eu-repo/semantics/nonPublished
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