Epithermal gold deposits are the product of large-scale hydrothermal systems in tectonically active regions. They form at shallow crustal levels where the physico-chemical conditions change abruptly. Two major groups of epithermal gold deposits can be distinguished based on their genetic connection with: A) Copper-molybdenum porphyry systems and B) Geothermal systems related to volcanic centres and calderas. Epithermal gold deposits connected with geothermal systems encompass three major types: adularia-sericite, acid-sulphate and disseminated replacement (the Carlin-type). Their essential ingredients are: high heat source which leads to convection of groundwater in the upper crust; source of hydrothermal fluid, metals and reduced sulphur; and high-permeability structures which allow fluid convection and metal deposition. Mixing of these ingredients leads to the formation of epithermal gold deposits throughout crustal history, without any restriction on age. The ores were deposited from near-neutral (adularia-sericite type and some of the Carlin-type) to acidic (acid-sulphate type and porphyry-related epithermal gold deposits), low-salinity, high C0₂ and high H₂S fluids, which were predominantly meteoritic in origin. The transport capability of deep fluids in epithermal hydrothermal systems may be shown to be dependent largely on their H₂S content and, through a series of fluid mineral equilibria, on temperature and on C0₂ content. The most common mechanisms of ore deposition are boiling (phase separation), mixing of fluids of different temperatures and salinities, reaction between them and wall rocks, dilution and cooling. An understanding of genetic models for epithermal gold deposits provides the basis for the selection of favourable areas for regional to prospect-scale exploration.

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A thesis submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Doctor of Philosophy. Johannesburg, December 2014. / During the acid leaching of uranium, gangue-reagent interactions have both negative and positive consequences. Gangue dissolution increases reagent costs, and in some cases can prevent the economic acid leaching of an ore, but can also increase uranium mineral exposure and improve recoveries. Due to rapid dissolution kinetics, the acid consumption characteristics of the various carbonate species are readily predicted, however the same is not true of silicate gangue. Due to factors including slower leach rates, incongruent dissolution, parabolic kinetics, and surface area, pH and temperature dependence, the gangue acid consumption characteristics of silicate minerals are significantly more complex. A detailed mineralogical investigation and acid leach tests were conducted on sandstone- and granite-hosted uranium ore samples. The dissolution characteristics of the more common gangue phases were determined. The study demonstrated that gangue-reagent interactions and U dissolution can be predicted from mineralogical data. A model was developed which allows for the use of mineralogical and geochemical data to predict gangue reagent consumption. The basic framework of the model is universally applicable, but may require calibration, depending on the mineral assemblage and complexity of a specific uranium deposit.

Thesis (Professional Degree)--University of Missouri, School of Mines and Metallurgy, 1940. / The entire thesis text is included in file. Typescript. Title from title screen of thesis/dissertation PDF file (viewed March 8, 2010)

Thesis (M. Sc.)--University of Adelaide, 1984. / Some mounted ill. Includes bibliographical references (leaves 123-141).

Thesis (Ph.D.) - James Cook University of North Queensland, 1992. / Typescript (photocopy) Includes bibliography.

Thesis (M.S.)--University of Nevada, Reno, 2008. / "December, 2008." Includes bibliographical references (leaves 95-101). Online version available on the World Wide Web.

A mapping project of the surface geology of the Lavino chrome mine and its surroundings was initiated in order to establish the surface geological relationships in the area. In so doing the chromitite layer presently being mined has been identified and potential exploration targets in the area have been outlined. The Lavino Chrome mine field area is situated within the eastern lobe of the Bushveld Igneous Complex. The area is bounded by in the north by the Steelpoort Lineament, in the west by the Dwars River fault and in the east by the contact with the Transvaal Sequence floor rocks. Layered igneous rocks (pyroxenites, norites and anorthosites) of the Rustenburg Layered Suite dominate the geological landscape at the Lavino mine. The fact that outcropping igneous rocks of the Critical Zone abut directly against the quartzite floor rocks on the mine property makes this area unique in the Bushveld Complex. The hills in the field area are capped by mafic/ultramafic iron-rich sheet - like bodies. Extensive strike-slip faulting is seen in outcrop in the area to the north/northwest of present mining operations. On the basis of field relationships, the main chromitite layer presently being mined at Lavino is identified as the Middle Group chromitite layer MG 1. Three other prominent chromitite layers stratigraphically associated with MG 1 are identified as the Middle Group chromitites MG 2, MG 3 and MG 4. Several other less prominent outcropping chromitite layers are tentatively identified as those belonging to the Lower and Upper group of chromitites. The disconformable nature of the contact between the layered igneous rocks and the Transvaal Sequence floor rocks has resulted in the development of a wedge of undifferentiated pyroxenites in the north of the field area. The economically important LG 6 chromitite layer may be developed in subcrop within this wedge.

Lateritisation is associated with tropical climates and geomorphic conditions of peneplanation where hydromorphic processes of weathering predominate. Laterites are products of relative (residual) and absolute(chemical) accumulation after leaching of mobile constituents. Their major element chemistry is controlled by the aluminous character of bedrock and drainage. Bauxitisation is characterised by residual gibbsite neoformation and lateritisation, by both residual accumulation and hydromorphic precipitation of goethite controlled by the redox front at the water table. The laterite forms part of a weathering profile that is underlain by saprock, saprolite, the mottled zone and overlain by a soil horizon. The secondary gold in laterites has its source invariably with mineralised bedrock. The distribution of secondary gold is controlled by mechanical eluviation and hydromorphic processes governed by organic, thiosulphate and chloride complexing. The precipitation of secondary gold is controlled by pH conditions, stability of the complexing agent and ferrolysis. Gold-bearing laterites are Cainozoic in age and are best developed on stable Archean and Proterozoic cratons that have suffered epeirogenesis since lateritisation. Mechanical eluviation increases in influence at the expense of hydromorphic processes as a positive function of topographic slope and degradation rate. Gradients greater than 10⁰ are not conducive for lateritisation, with latosols forming instead. High vertical degradation rates may lead to the development of stone lines. In the Western Australian case, post-laterite aridification has controlled the redistribution of secondary gold at levels marked by stabilisation of the receding palaeowater table. Mineable reserves of lateritic ore are located at Boddington, Westonia and Gibson toward the south-west of the Yilgarn Block. A significant controlling variable appears to be the concentration of chloride in the regolith. Based on the Boddington model, the laterite concentrates the following elements from bedrock gold lodes: i) Mo, Sb, W, Hg, Bi and Au as mobile constituents. ii) As and Pb as immobile constituents. Geochemical sampling of ferruginous lag after bedrock and laterite has provided dispersed anomalies that are easily identifiable. "Chalcophile corridors" up to 150 km in length are defined broadly by As and Sb but contain more discrete anomalies of Bi, Mo, Ag, Sn, W, Se or Au, in the Yilgarn Block. The nature of the weathered bedrock, the tabular distribution of secondary gold ore deposition and the infrastructural environment lends the lateritic regolith to low cost, open-cut mining. The western Australian lateritic-gold model perhaps can be adapted and modified for use elsewhere in the world.

Abstract The gold mineralization event within Archaean granite-greenstone terranes occurred during the late Archaean, and followed the intrusion of syn- to late-tectonic granitic plutons into previously deformed greenstone belts. An Archaean granite/gneiss-hosted gold deposit, in terms of this project, is classified as having a gold-assay cutoff of 1g/metric ton over widths of at least several metres, or higher grades over narrower widths and/or verbal descriptions that indicate such values. Fluid inclusion studies and isotopic data identify two possible origins for the auriferous fluids; namely magmatic and metamorphic. The exploration target according to the magmatic model, is a late-Archaean, hydrothermally altered, mineralized and fractured granitic intrusion preferably with a granodioritic or quartz-dioritic composition. The exploration target according to the metamorphic replacement model is a granitic stock that has intruded a zone of crustal weakness such as a shear zone, active during the late Archaean. Alternatively, the granitic intrusion should be affected by regionally extensive late-Archaean shearing. It should be hydrothermally altered, deformed and mineralized. Five areas within the Pietersburg granite-greenstone terrane were selected for the 'Regional Area Selection' phase of exploration for Archaean granite/gneiss-hosted gold deposits; namely Roodepoort, Waterval, Ramagoep, Moletsie and Matlala. Roodepoort contains a known granodiorite-hosted gold deposit; the Knight's Pluton, and served as an orientation survey for this project. The use and interpretation of LANDSAT images formed an integral part of exploration techniques; to assess their usefulness in the exploration of Archaean granite/gneiss-hosted gold deposits. Area selection criteria for granite/gneiss-hosted gold mineralization at Roodepoort are the major ENE-trending shear zone, the NNW-trending lineament and hydrothermal alteration, shearing, quartz-stockworks and sulphide mineralization within the Knight's Pluton. The origin of the gold within the Knight's Pluton is uncertain; both magmatic and metamorphic models are possibilities. Ongoing exploration is in progress at Roodepoort. The only area selection criterion for granite/gneiss-hosted gold mineralization at Waterval is the sericitized, subcropping granites located within trenches. Gold mineralization is insignificant. No area selection criteria for Archaean granite/gneiss-hosted gold mineralization were located at Ramagoep, Matlala and Moletsie. No further exploration is recommended for all these areas. The MES image interpretations were successful in identifying lineaments, granitic outcrops, greenstones, vegetation and soil cover. The Clay-iron images adequately differentiated betweeen iron-rich and clay-bearing areas. However, not all clay-bearing areas were associated with hydrothermal alteratian; field checks were necessary to discriminate between weathered granites and hydrothermally altered granites. The Wallis images served to locally enhance the contrasts of the MES and Clay-iron images.