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The Global ETD Search service is a free service for researchers
to find electronic theses and dissertations. This service is
provided by the
Networked Digital Library of Theses and Dissertations.
Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
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Showing 1 to 10 of 100 (0.049 seconds)Spelling suggestions: "subject:"organosilicon"" "subject:"organosilicone""
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The Preparation, Properties, and Reactions of Silenes, Silenoids, and 2-SilanobornenesPierce, Richard A. (Richard Austin), 1918-2004 12 1900 (has links)
The reaction of chlorodimethylvinylsilane with tertbutyllithium was investigated in the presence of several conjugated dienes. In all cases except with 2,5-dimethylfuran, [2+4] cycloadducts of a silene intermediate are obtained in hydrocarbon solvents. The presence of THF in the reaction mixture suppresses the formation of cycloadducts in favor of 1,3-disilacyclobutanes. In the reaction of dimethylethoxyvinylsilane or dimethylmethoxyvinylsilane with tert-butyllithium the main product is the 1,1-dimethyl2-neopentyl-4-(dimethylalkoxysilyl)silacyclobutane. It is concluded that lithium chloride elimination to give silene intermediates occurs in hydrocarbon solvents. In the presence of strong Lewis bases or when the leaving group on silicon is an alkoxy group, the addition reaction giving a-lithiosilanes occurs and products arising from their coupling reactions are obtained.
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| 2 |
The preparation of acyloxysilanes, their reaction with Grignard reagents, and the preparation of some Si-N bonded compoundsEmmanuel, Victor Krishniah. January 1961 (has links)
Call number: LD2668 .T4 1961 E54
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| 3 |
Chemical and biological applications of organosilicon chemistry : palladium-catalysed cross-coupling of disiloxanes and hydrosilylation as a bioorthogonal reactionFrye, Elizabeth Catherine January 2014 (has links)
No description available.
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| 4 |
Approaches to carbons 6-14 of ebelactone A, using siliconWare, Anne Carole January 1989 (has links)
No description available.
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| 5 |
Vinylsilane and silyl hydride complexes of platinum group metalsHeaton, Stephen Nicholas January 1995 (has links)
No description available.
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| 6 |
The chemistry of silylaziridinesKyle, Patricia Ann January 1993 (has links)
No description available.
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| 7 |
Models for coordination and reactivity at siliconBorbaruah, Moheswar January 1991 (has links)
No description available.
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| 8 |
The theoretical study of silylamidesLane, Thomas Howard January 1990 (has links)
No description available.
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| 9 |
The preparation of silane oligomers and their use as coupling agentsMeehan, Elizabeth January 1989 (has links)
No description available.
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| 10 |
Polyhedral oligometallasilsesquioxanesHoulton, David Joseph January 1995 (has links)
No description available.
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