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The effect of boron on phase relations in the granite-water system.Chorlton, Lesley B. January 1973 (has links)
No description available.
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A Study of the Flow Patterns in the Gas Phase of a Bubbling ColumnHill, Peter 12 1900 (has links)
The gas phase flow patterns in a bubbling column were investigated, using tracer methods to establish the residence time distributive An analogue computer obtained the moments if this distribution directly. The air flow rate and column height were varied. The results showed that as the air flow rate increased, although the voidage increased, the mean residence tine decreased. Thus an increasing proportion if the gas phase behaved as a stagnant volume. The results are correlated in terms of a mixed region model. Other work showed that an increase of liquid viscosity, or the inhibition of coalescence, affected only the stagnant volume. The rate of coalescence was investigated and an estimate of its magnitude was obtained. / Thesis / Master of Engineering (ME)
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THE RELATIONSHIP BETWEEN SOME KINEMATIC PARAMETERS WITH THESwedan, Ziad Saleh Ali January 2013 (has links)
The aim of this study was to determine how the performance of the Egyptian high jumpers is depending on the kinematic parameters of a take-off phase. The sample of the study has been selected from competitors of the high jump event - three jumpers representing the Egyptian international athletic team. The researcher has studied the sample using a direct measurement by a synchronized 3D video system to measure the kinematic parameters. The researcher has found a relation between record level and vertical velocity components with improvement in technique and better fitness levels, thus the Egyptian jumpers can achieve further progress in their results. This raises optimism because Omer Samir (A2) is very young and his current record 2.02m gives hope for future World - Class. Key words High jump, kinematic parameters, take-off phase.
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Lights, Clock, Action! Circadian Rhythms of Locomotor Activity in Larinioides cornutus Indicate Extreme Flexibility in Photo-entrainmentMiller, Madeleine K, Jones, Thomas C, Moore, Darrell 12 April 2019 (has links)
Circadian clocks are responsible for scheduling many behavioral and physiological processes to occur at the most appropriate time of day. The resulting daily rhythms also synchronize (entrain) to external environmental cues, known as zeitgebers. This phenomenon of entrainment enables organisms to anticipate daily changes in environmental conditions such as sunrise/sunset, temperature variations, availability of prey, etc. Given the critical nature of entrainment to survival, it is no surprise that the mechanism is conserved across taxa. The misalignment of the intrinsic clock with the external environment results in a plethora of negative consequences, made apparent by studies involving shift work and jet lag. The focus of the present study is to investigate the chronobiology of Larinioides cornutus (Araneidae), a nocturnal orb-weaving spider, with an emphasis on its entrainment to light:dark cycles. Because spiders have received scarce attention with respect to their chronobiology, it is instructive to compare the properties of spider circadian systems with those of the more established circadian model systems, such as Drosophilaand Murines. We found that both lights-off and lights-on are equally influential zeitgeber cues for (determines the phasing of) both activity onset and offset. Locomotor activity typically begins within a half hour after nightfall, continues throughout the night, and ceases just prior to dawn. Phase shifting experiments show that these spiders can re-entrain within 2 days to a light/dark cycle shifted by 6 hours, and within 3 days when shifted by 12 hours. These rates of re-entrainment occur at an extremely accelerated rate compared to mammals, which readjust to a time shift at a rate of around 1 day/ 1 hour of phase shift. In other words, spiders have a minimal jet-lag response. This suggests an increased level of plasticity in the spider circadian clock that has yet to be observed in other organisms. Typical of circadian rhythms in nearly all organisms, activity also persisted (free-runs) under constant conditions. However, in constant darkness (DD), a drastic change in periodicity was revealed in 66% of individuals, from 23.4 to 25.2. This particular phenomenon is rare and likely indicates the possible interaction of multiple oscillators. Further evidence to support this interpretation is the consistent periods of the rhythm displayed before and after the change. In contrast, under constant light (LL) conditions, 65% of spiders were arrhythmic, with 4 individuals ceasing activity completely. Significant periods detected in LL were normally distributed over an unusually broad range, from 16.7 to 34.9 hours, suggesting a high sensitivity to light. Because of the unusual rates of re-entrainment to light/dark cycles, the spontaneous changes in free-running period under DD, and arrhythmicity in LL, we propose that spiders are valuable comparative model organism for elucidating fundamental mechanisms of circadian clocks.
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Development, Evaluation and Improvement of Correlations for Interphase Friction in Gas-Liquid Vertical UpflowClark, Randy R. Jr. 15 October 2015 (has links)
In this study, liquid-vapor vertical upflow has been research with the intent of finding an improved method of modelling the interphase friction in two-phase vertical flow in nuclear thermal-hydraulic codes. An improved method of modelling interphase friction should allow for better prediction of pressure gradient, void fraction and the phasic velocities.
Data has been acquired from several available published resources and analyzed to determine the interphase friction using a force balance between the liquid and vapor phases. Using the Buckingham Pi Theorem, a dimensionless interphase friction force was tested and refined before being compared against seven other dimensionless parameters. Three correlations have been developed that establish a dimensionless interphase friction force as a function of the Weber number, the Froude number and the mixture Froude number. Statistical analysis of the three correlations shows that the mixture Froude number correlation should be the most accurate correlation. The correlations have a weakness that makes them ineffective mostly for bubbly flow and some slug flow scenarios, while they should perform significantly better for annular flow cases.
Comparisons have been made against the interphase friction calculations published in the manuals of RELAP5/MOD2, RELAP5/MOD3.3, RELAP5-3D and TRACE. The findings have generally shown that the equations in the manuals provide very inaccurate approximations of the interphase friction compared to the interphase friction that was found via force balance. When analyzing the source code of RELAP5/MOD3.3, several differences were noticed between the source code and manual, which have been discussed. Calculations with the source code equations reveal that the source code provides a modestly improved prediction of the interphase friction force, but still has significant errors.
Despite the fact that the manual and source code equations indicate that RELAP5/MOD3.3 should perform poorly in modelling interphase friction, actual RELAP5/MOD3.3 model runs perform very well in predicting pressure gradient, void fraction, the liquid and vapor velocities and the interphase friction force. This is largely due to RELAP5/MOD3.3 being able to adjust parameters to converge to a solution that fits within the boundary conditions established in the input file.
Modifications to the RELAP5/MOD3.3 code were first made with the three correlations developed using dimensionless parameters, and were tested with data points that the RELAP5/MOD3.3 flow regime map had predicted would be annular flow. While the mixture Froude number correlation has been analyzed to be the most statistically accurate of the three correlations, it was found that the Weber number correlation performed best when implemented into RELAP5/MOD3.3. In a parametric study of the Weber number correlation, it performed optimally at 150% of the original correlation, improving upon the original RELAP model in almost every metric examined.
Additional investigations were performed with individual annular flow correlations that model specific physical parameters. Results with the annular flow physical models were inconclusive as no particular model provided a significant improvement over the original RELAP5/MOD3.3 model, and there was no clear indication that combining the models would provide significant improvement. / Ph. D.
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A Thermal Switch from Thermoresponsive Polymer Aqueous SolutionsMa, Yunwei 29 November 2018 (has links)
Thermal switch is very important in today’s world and it has varies of applications including heat dissipation and engine efficiency improving. The commercial thermal switch based on mechanical design is very slow and the structure is too complicated to make them smaller. To enable fast thermal switch as well as to make thermal switch more compact, I try to use second-order phase transition material to enable our thermal switch. Noticing the transition properties of thermoresponsive polymer for drug delivery, its potential in thermal switch can be expected. I used Poly(N-isopropylacrylamide) (PNIPAM) as an example to show the abrupt thermal conductivity change of thermoresponsive polymer solutions below and above their phase transition temperature. A novel technique, transition grating method, is used to measure the thermal conductivity. The ratio of thermal switch up to 1.15 in transparent PNIPAM solutions after the transition is observed. This work will demonstrate the new design of using second-order phase transition material to enable fast and efficient thermal switch. / Master of Science / Controllable thermal conductivity (thermal switching) is very important to thermal management area and useful in a wide area of applications. Nowadays, mechanical thermal conductivity controller device suffers from large scale and slow transition speeds. To solve these problems, I tired the phase transition thermoresponsive polymers to create quick thermal switching because the thermal conductivity will change with the phase. Thermoresponsive polymers show sharp phase changes upon small changes in temperature. Such polymers are already widely used in biomedical-like applications, the thermal switch applications are not well-studied. In this work, I tested Poly(N-isopropylacrylamide) (the abbreviation is PNIPAM) as an example to show the quick thermal conductivity changing ability of thermoresponsive polymer when the transition was happened .I used a novel approach, called the TTG, transient thermal grating. It has easy setup and high sensitivity. The thermal conductivity switching ratio as high as 1.15 in transparent PNIPAM solutions after transition is observed. This work will give new opportunities to control thermal switches using the phase change of thermoresponsive material or abrupt other phase change material in general.
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Modeling Two-Phase Flow in the Downcomer of a Once-Through Steam Generator using RELAP5/MOD2Clark, Randy Raymond 31 January 2012 (has links)
The purpose of this study is to develop an accurate model of the downcomer of the once-through steam generator (OTSG) developed by Babcock & Wilcox, using RELAP5/MOD2. While the physical model can be easily developed, several parameters are left to be adjusted to optimally model the downcomer and match data that was retrieved in a first-of-a-kind (FOAK) study conducted at Oconee Unit I in Oconee, South Carolina. Once the best-fit set of parameters has been determined, then the model must be tested for power levels exceeding that for which the steam generator was originally designed, so as to determine the power level at which a phenomenon known as flood-back becomes a concern.
All known previous studies that have been conducted using RELAP5/MOD2 have shown that RELAP over-predicts interphase friction. However, all of those studies focused on heated two-phase upflow, whereas the downcomer is modeled as adiabatic two-phase downflow. In this study, it is found that the original slug drag model for RELAP5/MOD2 developed by Idaho National Engineering Laboratory (INEL) under-predicts the interphase friction between the liquid and vapor phase within the downcomer. Using a modified version of the original slug drag model created by Babcock & Wilcox (B&W), an optimum multiplier is found for each power level. An increase of 1181% in interphase friction over the INEL slug drag model, which equals an increase of 4347% for the default B&W model provides the most accurate results for all power levels studied.
Emphasis is also placed on modeling the orifice plate of the OTSG downcomer which has been added to stabilize pressure fluctuations between the downcomer and tube bundle of the OTSG. While several different schemes are explored for modeling the orifice plate, a branch connection with an inlet area 14.22% of that of the downcomer is used to model the orifice plate along with the volume that transitions the two-phase downflow to horizontal flow into the tube nest of the OTSG.
Power levels exceeding that for which the steam generator was designed are tested in RELAP using the slug drag multiplier to determine at which power level a liquid level would occur and would flood-back become a concern. In this study, it is determined that a liquid level would form at 135% power and that at any higher power level, flood-back would be of concern for any user of the steam generator. / Master of Science
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Performance measurements of a flashing flow nozzleBunch, Thomas K. 04 March 2009 (has links)
The performance of a flashing flow nozzle was quantified by efficiency and metastability measurements. Efficiency was calculated over a range of operating conditions, by using both inlet and exit conditions and the nozzle thrust. Metastability was quantified by a parameter that compared the experimental mass flow rate with homogeneous equilibrium and frozen state flow rates. The efficiency of the flashing flow nozzle was found to be less than half the efficiency of the nozzle while operating at near thermodynamic equilibrium. Attempts were made to improve nozzle performance by lowering the piping diameter immediately upstream of the nozzle to increase flow turbulence and encourage a uniform bubbly flow. Bubbly flow helps two-phase flows become less metastable, by generating a uniform distribution of bubbles that act as nucleation sites for flashing inception. Low flow metastabilities were found with high inlet qualities and small upstream piping diameters. These conditions also resulted in the highest flashing flow nozzle efficiencies; however, the efficiency showed a much less pronounced response to upstream piping diameter. The homogeneous equilibrium model was found to be an inaccurate predictor of nozzle performance. To satisfy this model, a shock must be positioned in the nozzle's divergent section, severely limiting nozzle efficiency. The effects of phase slip on nozzle efficiency were investigated with recommendations made for further research in this area. / Master of Science
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On the convergence of the heat balance integral methodMosally, F., Wood, Alastair S., Al-Fhaid, A. 28 July 2009 (has links)
No / Convergence properties are established for the piecewise linear heat balance integral solution of a benchmark moving boundary problem, thus generalising earlier results [Numer. Heat Transfer 8 (1985) 373]. A convergence rate of O(n¿1) is identified with minor effects at large values of the Stefan number ß (slow interface movement). The correct O(n¿1/2) behaviour for incident heat flux is recovered for ß ¿ 0 (pure heat conduction) as previously found [Numer. Heat Transfer 8 (1985) 373¿382]. Numerical illustrations support the theoretical findings.
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Tunable Multifunctionalities in Oxide-based Phase Change Nanocomposite Thin FilmsZihao He (14190335) 06 December 2022 (has links)
<p>Phase change materials (PCMs) has emerged as advanced functional materials for efficient thermal energy storage and release. Compared to other organic and inorganic PCMs, oxide-based PCMs have attracted growing interest because of small volume expansion, minor leakage issue, and moderate latent heat. In this dissertation, two special cases of oxide-based PCMs is discussed, i.e., vanadium dioxide (VO<sub>2</sub>), and Bi-based perovskite/supercell structures. Specifically, VO<sub>2</sub> emerges as a focus of research because of its well-known semiconductor-to-metal transition (SMT) upon heating close to 68 °C. The intrinsic coupling of SMT and R-M1 structural change makes VO<sub>2</sub> a favorite material both scientifically interesting and technologically important for potential sensor and memory device applications. On the other hand, BFMO supercell structure originates from the double-perovskites, while the substrate-induced epitaxial strain induces the stacking and commensurate modulations of Fe/Mn double layers. The significantly enhanced multiferroic response is attributed to its non-centrosymmetric structure.</p>
<p>In this dissertation, a comprehensive study on the FM integration and novel approaches to achieve broad range transition temperature (<em>T</em><sub><em>c</em></sub>) tuning is explored in VO<sub>2</sub> thin films. Specifically, three novel metal/VO<sub>2</sub> nanocomposite designs are discussed, i.e., Pt/VO<sub>2</sub>, Ni/VO<sub>2</sub> and Li/VO<sub>2</sub>, with different morphology and Tc tuning mechanisms. First, by reconstructing the energy band structure at the metal/VO<sub>2</sub> interface, bidirectional <em>T</em><sub><em>c</em></sub> tuning in Pt/VO<sub>2</sub> nanocomposites can be achieved owing to the size dependent work function of Pt NPs. Next, by engineering the morphology by lattice matching, diffusion kinetics, and interfacial mixing, the exploration on Ni/VO<sub>2</sub> nanocomposites achieve the combined goals of Tc tuning and magnetic incorporation/magneto-optical (MO) coupling. Finally, by varying Li concentration during the metal-ion intercalation, <em>T</em><sub><em>c</em></sub> of both VO<sub>2</sub>(B) and VO<sub>2</sub>(M1) thin films can be systematically tailored because of structural deformation and the change in charge carrier density. The demonstration of metal/VO<sub>2</sub> nanocomposite thin films reveals a promising approach to fulfill various working environments for VO<sub>2</sub>-based novel electronics, photonics, and spintronics. Furthermore, the microstructure evolution of the ultrathin BFMO supercell structure as well as its physical properties is first studied. The robust ferromagnetic and ferroelectric response is preserved in the ultrathin structure less than 10 nm, making it an attractive candidate for next-generation spintronics based on 2D materials.</p>
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