I samarbete med Sherwin-Williams AB, utvecklades en metod med kontaktvinkelmätning för att teoretiskt uppskatta vätbarhet och vidhäftningsförmåga av industriella färger på stålsubstrat. Optisk tensiometer och Youngs ekvation kombinerat med OWRK beräkningsmodell användes för att bestämma ytenergier. Det föreslogs att kontaktvinkelmätning bör inkludera bestämning av ytenergi av det fasta substratet, ytspänning av färgen samt beräkning av polaritet och gränssnittsenergi mellan de två bindande ytorna, för att stämma bra överens med färgens praktiskt uppskattade vidhäftningsförmåga. Det konstaterades att kontaktvinkel är en nödvändig faktor för att få information om teoretisk bindningsstyrka mellan två bindande ytor, men stämde någorlunda bra med praktiskt uppskattad vidhäftningsförmåga från mekanisk testmetod. Vidare studier utfördes för att identifiera styrkor och svagheter med kontaktvinkelmätningen och förstå inverkan av olika huvudegenskaper av färger på dess vidhäftning. Fem olika lösningsmedelsbaserade färger av typen två-komponentsystem tillverkades i syfte att studera effekter från två olika vidhäftningsfrämjande additiv, ett epoxysilan och ett aminosilan samt två olika fyllnadsmedel, kieseldioxid (SiO2) pulver och CaCO3/BaSO4 pulverblandning. Det konstaterades att silan inte förbättrade vidhäftning av färgerna på metallsubstraten, på grund av den snabba exoteriska reaktion som sker mellan silan och isocyanat härdare komponent B, när det blandas med färgen (komponent A). Till följd fås hastig viskositets- och temperaturökning som ökade avdunstning av lösningsmedlet och orsakade försämrad utplaning och flöde av färgen på metallytan. Det konstaterades även att fyllnadsmedlet CaCO3/BaSO4 var bättre än kiseldioxid (SiO2), delvis på grund av lägre oljeabsorptionsvärde som resulterar i lägre viskositetökning och bättre flöde av färgen. Rekommendationer för framtida studier är att analysera effekter av silan i ett en-komponentsystem för att eliminera effekter av snabb avdunstning av lösningsmedel och härdningskinetik mellan färg (komponent A) och härdare (komponent B). Reologi studier med reometer kan användas för att få mer information om varför CaCO3/BaSO4 visades vara ett bättre fyllnadsmedel än kiseldioxid. / In collaboration with Sherwin-Williams AB, a method with contact angle technique was developed to theoretically predict wettability and adhesive bonding between industrial paint coatings and steel substrates. The technique used was optical tensiometer and Young’s equation combined with OWRK calculation model was used to determine surface and interfacial energetics. It was suggested that the contact angle measurements must include measurements of the surface energy of the solid, surface tension of the liquid paint and calculation of polarity and interfacial tension between the bonding surfaces, to best correlate with practically estimated adhesion property of the paint coatings. It was stated that though contact angle proved to be a prerequisite factor to acquire information about adhesive bonds between two bonding surfaces, it did not entirely correlate with the findings from practically estimated adhesion performance from pull-off investigations. Work was dedicated to identifying strengths and weaknesses with the contact angle measurements and understanding the impact of other key properties of the paint coatings on adhesion performance. Five different solvent-based, two-component paint systems were manufactured to be able to see the effects on adhesion performance from two adhesion promoting additives, an epoxysilane and an aminosilane, as well as two different filler packages: silicon dioxide SiO2 (silica) filler package and CaCO3/BaSO4 filler package, respectively. It was concluded that the silanes did not improve adhesion performance of the paint coatings because of fast exothermic reaction that takes place between silane and isocyanate hardener component B when added to the liquid paint component A. Rapid viscosity rise and temperature rise was observed, which increased the evaporation rate of the solvent and impaired the leveling and flowing of the paint coating to the steel substrates. It was also unexpectedly observed that the CaCO3/BaSO4 filler package outperformed the silica filler package, partly because of its lower oil absorbance, which resulted in lower viscosity rise and better flowing of the paint coating. For future studies, it was recommended to analyze effects of the silanes in a one-component paint system to eliminate unfavored effects from evaporation of the solvent and cure kinetics of paint component A and isocyanate hardener component B. The superior paint quality contributed from the CaCO3/BaSO4 filler package could be better understood by rheology investigations with rheometer.

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This project is an in-depth investigation on the impact of lighting, marking and paint schemes on the operational aspects of police vehicles. This investigation consisted of two phases that ultimately consisted of four experiments. An array of lighting and marking schemes were implemented on police vehicles in a variety of jurisdictions for evaluation. The study then investigated the change in the visibility of police officers, the public reaction to these schemes, and the operational impacts of these systems. The first phase of the project was a naturalistic observation study where the goal was to better understand how traffic behaved around traffic stops. Test vehicles were positioned in simulated traffic stops and patrol locations to determine how traffic behavior was affected by various configurations of police lighting and markings. Camera and radar systems were used to measure the changes in driver speed and when drivers responded to the move over law. Based on the results of the naturalistic studies, the impact of the lighting system on officer visibility was investigated in a controlled human factors test where the ability of a driver to see a police officer outside of their vehicle was measured in the presence of the lighting systems. The purpose of this interjected effort was to verify that the experimental schemes would not increase risk to law enforcement despite data from the first phase indicating the vehicles were more visible. A second part to that study evaluated conventional methods of bolstering an officer's visibility outside of their vehicle at night. The second phase took the findings of the first phase and implemented changes to several police vehicles from local and state agencies to be in operation for at least 18 months. This was to assess the rate of near-misses and crash rate to relate the vehicle changes to law enforcement safety. Additionally, rates of citations were assessed, and surveys offered an opportunity for law enforcement to provide their own feedback on the implementations. The lighting systems evaluated included a completely blue lighting system, an enhanced all blue lighting system with twice the light output, a red and blue system, and a single flashing blue beacon. In terms of markings, retroreflective markings along the side of the vehicle, a retroreflective contour line, chevrons on the rear of the vehicle and unmarked vehicles were evaluated. Finally, a variety of vehicle colors were used to investigate the impact of the base vehicle paint color. The results indicate that both the red and blue lighting system and the high output blue lighting system increase the distance at which drivers moved over significantly. In general, at least 95% of traffic attempted to merge away from an actively lighted police vehicle, when possible. In terms of the speed change, drivers began reducing their speed by approximately 600 m from the police vehicle. Similarly, the addition of retroreflectivity to the rear of the vehicle showed an additional benefit for causing drivers to move over sooner. However, these benefits came at a cost to the officer's visibility. When outside of their vehicle, the high output blue system significantly reduced officer detectability while the red and blue configuration only impacted detection distance by 3 meters. The investigation did find that these impacts could be overcome with retroreflective vests worn by the officers. In the second phase, a preference revealed by officers favored the red-blue configuration. They stated that this configuration provided greater comfort for them and less glare to approaching drivers. The study also revealed that the alternative configurations did not impact the operational activities of police authority. / Doctor of Philosophy / This project evaluated how lighting, marking and paint schemes on police vehicles affected their visibility and how traffic responded to them. An observational study positioned police vehicles with alternative lighting and markings in simulated traffic stops and patrol locations to evaluate traffic behavior. Camera and radar systems were used to measure the changes in driver speed and when drivers responded to the Move Over law. A second study evaluated how the lighting systems on a police car affect the visibility of an officer at night in a traffic stop scenario. A followup experiment looked into methods for bolstering the visibility of officers at night through conventional implementations such as body worn LED lighting, the use of a retroreflective vest, or by using lighting on the police vehicle's light bar to increase illumination of the police officer. A third study took the findings of the previous experiments and outfitted 64 Virginia State Police vehicles for 18 months. Another 64 Virginia State Police vehicles participated in a control condition where no changes were made to their vehicles. Data collected included the rate of near-misses or crashes and the rates of written citations. Surveys were administered to each participating officer regarding their perception of safety and comfort and allowed their open feedback and suggestions. The lighting systems evaluated included a completely blue lighting system, an enhanced all blue lighting system with twice the light output, a red and blue system, and a single flashing blue beacon. In terms of markings, retroreflective markings along the side of the vehicle, a retroreflective contour line, chevrons on the rear of the vehicle, and unmarked vehicles were evaluated. Finally, a variety of vehicle colors were used to investigate the impact of the base vehicle paint color. The results indicate that both the red and blue lighting system and the high output blue lighting system increase the distance at which drivers moved over significantly. In general, at least 95% of traffic attempted to merge away from an actively lighted police vehicle, when possible. In terms of the speed change, drivers began reducing their speed by approximately 600 m from the police vehicle. Similarly, the addition of retroreflectivity to the rear of the vehicle showed an additional benefit for causing drivers to move over sooner. However, these benefits came at a cost to the officer's visibility. When outside of their vehicle, the high output blue system significantly reduced officer detectability while the red and blue configuration only impacted detection distance by 3 meters. The investigation did find that these impacts could be overcome with retroreflective vests worn by the officers. In the second phase, a preference revealed by officers favored the red-blue configuration. They stated that this configuration provided greater comfort for them and less glare to approaching drivers. The study also revealed that the alternative configurations did not impact the rate of citations.

<p dir="ltr">This study investigates the dynamics of oblique shock wave interactions impinging on a flat plate within the Purdue University Research and Innovation Optical Testing (RIOT) Tunnel, employing novel pressure sensitive film (PSF) to visualize and quantify global surface pressure distributions. Complementary diagnostics, including static and dynamic pressure sensors and high-speed imaging, were used to provide a comprehensive analysis of the shocks spatial and temporal behavior.<br>Experimental campaigns were conducted in a supersonic wind tunnel equipped with a rated Mach 1.86 nozzle, characterizing the nominal conditions required for PSF application. Test campaigns spanned a range of stagnation pressures, revealing the dependence of shock-induced pressure distributions on flow conditions. Calibration using the Stern-Volmer relationship provided robust intensity-pressure correlations, incorporating temperature corrections to address quenching effects. Spectral analysis of pressure measurements identified low- and mid-frequency fluctuations associated with turbulent boundary layers and shock oscillations.</p>

No / An opportunity was afforded to analyse pigment specimens from an unrestored oil painting in the style of the English School of the mid-18th Century prior to conservation being undertaken. Raman spectroscopy was adopted to characterise the pigments and indicated the presence of a novel red pigment which was assigned to the complex chromium mineral, hemihedrite, in addition to other interesting materials found in combination. This is the first recorded identification of hemihedrite spectral signals in an art context in a range of mineral pigments that are otherwise typical of this period and some hypotheses are presented to explain its presence based on its occurrence with associated mineral pigments. It is suggested that the presence of powdered glass identified in certain areas of the painting enhanced the reflectivity of the pigment matrix.

Web page loading time is one of the critical challenges on the Internet. This topic attracts more researchers as it largely reflects the user satisfaction. A web page resources typically consists of Hyper Text Markup Language (HTML), Cascading Style-Sheet (CSS), JavaScript (JS), media files, etc. As the complexity of the web page increases, the size of files fetched from server also increases which causes delay in transmitting, loading, parsing and rendering the web page. The web page is not rendered until HTML, CSS and JS files are loaded and parsed. Not all such files are needed to be rendered for the first page. Optimizing and loading only critical les required for the first page, can considerably reduce time taken to load the web page. After the first page is rendered, the rest of the files can be loaded and executed. In this thesis, we focus on improving the time taken for First Meaningful Paint(FMP) of website by loading the critical files initially. We used Design Science Research( DSR) methodology and created a PhantomJS application, to identify and segregate used and unused CSS for the first meaningful paint of the web page. We also analyzed script files to load only critical files required for FMP and the rest later. We evaluated our experiment by studying a case on Axis Communications AB and measured its website's performance to find if our experiment reduced FMP time. It showed improvement in time taken for FMP from 1284ms to 372.6ms. Based on the results, we suggest to web developers to separate and load the files required for FMP and load the rest of the files needed for the website later, so that the first page is rendered quickly.

This thesis explores the multi-faceted role of plants, specifically Wituk and Manduru, in Amazonian protests and environmental advocacy. By examining the communicative and relational ontologies inherent in Runa culture, the study elucidates how plants influence social movements and contribute to environmental protection. Wituk and Manduru create paint. Paint facilitates good communication which creates good relationality. Good relationality allows for increased capacities and inhibits greedy consumption allowing for a balanced world order. Through the use and agency of Wituk and Manduru, movements become multi-species phenomena in which ecological entities combine with Runa bodies. The relationships shared between Runa, Wituk, and Manduru are powerful and result in desired environmental outcomes that oppose the consumptive practices that have the potential to end the world.

The focus of this study was analytical investigations of Egyptian paintings, mainly Coptic icons and Islamic wooden ceilings, dating from 1300-1900 using multi-instrumental techniques. Twenty three Coptic icons and three wooden ceilings dated from different periods and painted by different painters in case of icons were examined. The materials used including pigments, media, varnishes, ground layers and gold layers. The surface stratigraphy of paint samples, their layered structured and the composition of materials used in each layer were analysed. Variations in painting techniques, pigments palettes, paint media and varnishes applied in Egyptian paintings according to painters, time and type of paintings were revealed. A total of twenty-eight organic and inorganic pigments were identified in this study, of which nine have never been previously included as a part of the Egyptian pigment palettes, namely; smalt, lapis lazuli, indigo, pararealgar, Prussian blue, chrome yellow, barium yellow, barium white and hydromagnesite. The identification of hydromagnesite, which has never been to date considered as a pigment either in Egypt or elsewhere and the identification of smalt from the mid-14th century, whose reported earliest large scale use was in the 16th century. Two types of resins were identified as a constituent of the oil/resin varnish applied on Coptic icons of which Venice turpentine has been identified for the first time as an ingredient of Egyptian varnishes. The identification of mosaic gold in an 18th C. icon, a novel usage of dammar resin and the multilayered structure of the white ground layers were revealed.

Graduate school has been a time of travel through experimentation. The journey has almost always been a search for materials and sources that match my need for working with the self-referential narrative within the framework of a process. Repeatedly, I would venture out and turn back, only to venture out again, packed with new materials and image sources, in search of a complete process. In retrospect, there have been no dead ends, only quenched curiosities that sometimes cleanly, often clumsily, lead one to the other. What is left is a series of explorations from which I can pluck similarities, clues to my core interests and methods. In the end, I believe I have found a place of clarity, where interests and process converge.

Hip Hop graffiti has been marking our urban landscapes for decades. However street art, a much less researched topic, has claimed notoriety in recent years. Much of the existing research groups hip-hop graffiti, gang graffiti and street art together and calls for a uniform response from communities, city officials and law enforcement. While street artists have made their mark in the urban landscapes of the United States as well as internationally, it is important to define the terms "street art"and "graffiti" and where they deviate from one another in order for cities to begin to address these expressions with any level of success. As municipalities grapple with visual public expression--street art and graffiti--a framework must be established taking into consideration legal parameters for both cities and artists.