Ultrasound acoustic energy transfer (UAET) is an emerging contactless technology that offers the capability to safely and efficiently power sensors and devices while eliminating the need to replace batteries, which is of interest in many applications. It has been proposed to recharge and communicate with implanted medical devices, thereby eliminating the need for invasive and expensive surgery and also to charge sensors inside enclosed metal containers typically found in automobiles, nuclear power plants, space stations, and aircraft engines. In UAET, energy is transferred through the reception of acoustic waves by a piezoelectric receiver that converts the energy of acoustic waves to electrical voltage. It has been shown that UAET outperforms the conventional CET technologies that use electromagnetic waves to transfer energy, including inductive coupling and capacitative coupling. To date, the majority of research on UAET systems has been limited to modeling and proof-of-concept experiments, mostly in the linear regime, i.e., under small levels of acoustic pressure that result in small amplitude longitudinal vibrations and linearized piezoelectricity. Moreover, existing models are based on the "piston-like" deformation assumption of the transmitter and receiver, which is only accurate for thin disks and does not accurately account for radiation effects. The linear models neglect nonlinear effects associated with the nonlinear acoustic wave propagation as well as the receiver's electroelastic nonlinearities on the energy transfer characteristics, which become significant at high source strengths. In this dissertation, we present experimentally-validated analytical and numerical multiphysics modeling approaches aimed at filling a knowledge gap in terms of considering resonant acoustic-piezoelectric structure interactions and nonlinear effects associated with high excitation levels in UAET systems. In particular, we develop a reduced-order model that can accurately account for the radiation effects and validate it by performing experiments on four piezoelectric disks with different aspect ratios. Next, we study the role of individual sources of nonlinearity on the output power characteristics. First, we consider the effects of electroelastic nonlinearities. We show that these nonlinearities can shift the optimum load resistance when the acoustic medium is fluid. Next, we consider the nonlinear wave propagation and note that the shock formation is associated with the dissipation of energy, and as such, shock formation distance is an essential design parameter for high-intensity UAET systems. We then present an analytical approach capable of predicting the shock formation distance and validate it by comparing its prediction with finite element simulations and experimental results published in the literature. Finally, we experimentally investigate the effects of both the nonlinearity sources on the output power characteristics of the UAET system by considering a high intensity focused ultrasound source and a piezoelectric disk receiver. We determine that the system's efficiency decreases, and the maximum voltage output position drifts towards the source as the source strength is increased. / Doctor of Philosophy / Advancements in electronics that underpinned the development of low power sensors and devices have transformed many fields. For instance, it has led to the innovation of implanted medical devices (IMDs) such as pacemakers and neurostimulators that perform life-saving functions. They also find applications in condition monitoring and wireless sensing in nuclear power plants, space stations, automobiles and aircraft engines, where the sensors are enclosed within sealed metal containers, vacuum/pressure vessels or located in a position isolated from the operator by metal walls. In all these applications, it is desired to communicate with and recharge the sensors wirelessly. Such a mechanism can eliminate the need for invasive and expensive surgeries to replace batteries of IMDs and preserve the structural integrity of metal containers by eliminating the need for feed through wires. It has been shown that ultrasound acoustic energy transfer (UAET) outperforms conventional wireless power transfer techniques. However, existing models are based on several assumptions that limit their potential and do not account for effects that become dominant when a higher output power is desired. In this dissertation, we present experimentally validated numerical and theoretical investigations to fill those knowledge gaps. We also provide crucial design recommendations based on our findings for the efficient implementation of UAET technology.

Thesis (MEng)--Stellenbosch University, 2014. / ENGLISH ABSTRACT: Over the past 50 years smart materials have made their appearance in many structures. The thermopiezoelectric ceramic is one of these smart materials. When thermal e ects are considered negligible, then the materials are classified as piezo-ceramic and piezoelectric materials. These so called piezo-ceramics are used as actuator and sensor components in many structures. The use of these components with composite materials is significant due to their application in the aerospace and aeronautics fields. The interaction that the piezoelectric material has with a composite body can be improved in order to reduce the energy requirement of the material for deformation. An objective in the optimisation of composite material structures is to minimise compliance or maximise sti ness uT f, with the laminate ply orientations as design variables, where u and f are displacement and force vectors, respectively. Here, the objective is not the maximisation of sti ness but the maximisation of compliance, with typical constraints being failure criteria. These failure criteria can include theories such as the maximum principle stress, the Tsai-Hill or Tsai-Wu failure theories. The compliance is maximised to accentuate any piezoelectric movement and is for theoretical treatment only. Piezoelectric materials once polarized the materials becomes quasi-isotropic. The piezoelectric materials are isotropic in the plane normal to the direction of the voltage being applied and have altered properties normal to this plane. This change in the material properties can be exploited so that the layup can be altered in orientation to improve performance. The idea is to improve the mechanical capabilities of the structure subject to an electrical input or vice versa. In the works by both Carrera et al. and Piefort, First Order Shear Deformation Theory (FSDT) is used in finite element analysis to characterise the structural and electrical behaviour of a plate or shell. FSDT, also known as the Mindlin-Reissner theory, is a plate bending theory that assumes a transverse shear distribution through the thickness of the plate. This theory is considered an improvement on the standard theories such as the Kircho or Timoshenko theories. Many optimisation techniques exist and are classed as either being direct search or gradient based methods. Particle Swarm Optimisation (PSO) is a direct search method. It mimics the behaviour of a flock of birds or school of fish in their attempt to find food. The PSO’s mathematical statement characterises a set of initial unknown particles within a designated search space that are compared to a set of local best particles and a single global best particle. This comparison is used to update the swarm each run cycle. Regression is a procedure whereby a set of testing data is used to fit a pseudo-function that represents the form the data should take in practice. The aim of this work is to optimise the piezoelectric-composite layer interaction to improve the overall compliance of a structure. Extensive modelling is performed and tested with peer reviewed literature to demonstrate its accuracy. / AFRIKAANSE OPSOMMING: Oor die afgelope 50 jaar het slim materiale hulle verskyning gemaak in verskeie strukture. Termopiezo-elektriese keramieke is een van hierdie nuwe materiale. Wanneer termiese e ekte onbeduidend is, word hierdie materiale as piezo-elektriese materiale geklassifiseer. Hierdie sogenaamde piezo-keramieke word gebruik as aandrywers en sensoriese onderdele in verskeie strukture. Die kombinasie van hierdie onderdele met saamgestelde materiale het belangrike toepassings in die ruimte- en lugvaartkunde. Die interaksie van die piezo-elektriese materiale met die saamgestelde materiaal strukture kan verbeter word om die energie-vereistes van die materiaal vir vervorming te verminder. ’n Tipiese doel in die optimering van saamgestelde materiaalstrukture is om styfheid uT f te maksimeer met die gelamineerde laag-oriëntasies as ontwerpsveranderlikes, waar u en f onderskeidelik verplasing en kragvektor voorstel. In teenstelling met die optimering van die samestelling wat voorheen gedoen is, is die doel hier nie die maksimering van styfheid nie, maar die minimering van styfheid, met falingskriteria as tipiese beperkings. Die falingskriteria sluit die volgende in: die maksimum spanningsteorie, en die Tsai-Hill of Tsai-Wu falingsteorieë. Die styfheid word geminimeer om piezo-elektriese verplasing te versterk, maar word hierin net teoreties bekyk. Sodra piezo-elektriese materiale gepolariseer word, word hulle quasi-isotropies. Die piezoelektriese materiale is isotropies in die vlak gelyk aan die rigting van die stroomspanning wat daarop toegepas word en het ander eienskappe normaal tot die vlak. Die verandering in die materiaal se eienskappe kan gebruik word sodat beide die saamgestelde materiaal en die piezoelektriese laag se oriëntasie aangepas kan word vir verbeterde werkverrigting. Die idee is om die meganiese vermoëns te verbeter van ’n struktuur wat onderwerp word aan ’n elektriese inset of vice versa. In die literatuur van beide Carrera et al. en Piefort word Eerste Orde Skuifvervormings Teorie (EOST) gebruik in eindige element analises om die strukturele en elektriese gedrag van ’n plaat of dop te karakteriseer. EOST, ook bekend as Mindlin-Reissner teorie, is ’n plaat buigings-teorie wat ’n dwarsvervormingverspreiding aanneem deur die dikte van die plaat. Hierdie teorie word gesien as ’n verbetering op die standaard teorieë soos bv. Kircho of Timoshenko se teorieë. Daar bestaan baie optimeringstegnieke wat geklassifiseer word as ’direkte soek’ of ’hellinggebaseerde’ metodes. Partikel swerm-optimering (PSO) is ’n direkte soekmetode. Dit boots die gedrag van ’n swerm voëls of ’n skool visse in hulle poging om kos te vind, na. PSO se wiskundige stelling karakteriseer ’n aanvanklike stel onbekende partikels binne ’n afgebakende soekgebied wat vergelyk word met ’n stel van die beste plaaslike partikels sowel as ’n enkele beste globale partikel. Die vergelykings word gebruik om die swerm met elke siklus op te dateer. Regressie is ’n metode waarin toetsdata gebruik word om ’n benaderde funksie te konstrueer wat ongeveer voorspel hoe die regte funksie lyk. Die doel van hierdie werk is om die piezoelektriese saamgestelde laag te optimeer en die interaksie van die totale gedrag van die struktuur te verbeter. Uitgebreide modellering word uitgevoer en getoets met eweknie-beoordeelde literatuur om die akkuraatheid en korrektheid te bewys.

Approved for public release, distribution is unlimited / Continuing U.S. Navy interest in the development of light-weight, low-volume, broadband, underwater acoustic projectors and receivers is the principal motivation for this research topic. Acoustic cymbal transducers, so named for their geometric similarity to the percussion instruments, are miniature "class V" flextensional transducers that consist of a piezoelectric ceramic drive element bonded to two opposing cymbal-shaped metal shells. Operating as mechanical transformers, the two metal shells convert the naturally large generative force of a piezoelectric ceramic in the radial mode into increased volume displacement at the metal shell surface to obtain usable source levels and sensitivities in a broad frequency range. The magnified displacement makes the acoustic cymbal element a potential alternative to acoustic transduction technologies presently used to generate and receive Navy sonar frequencies. Potential benefits to utilizing this technology are generating or receiving broadband sound, at sonar frequencies in a thin, low volume, conformable package. Applications of this technology have been limited because air-backed acoustic cymbal elements undergo degradation in performance when exposed to elevated hydrostatic pressure (i.e., deep ocean and extreme littoral water applications). This research shows that consistent and reliable acoustic performance can be achieved with cymbal-based transducers at hydrostatic pressures of interest to the Navy. / Civilian, United States Navy

Nanomagnetic logic, incorporating logic bits in the magnetization orientations of single-domain nanomagnets, has garnered attention as an alternative to transistor-based logic due to its non-volatility and unprecedented energy-efficiency. The energy efficiency of this scheme is determined by the method used to flip the magnetization orientations of the nanomagnets in response to one or more inputs and produce the desired output. Unfortunately, the large dissipative losses that occur when nanomagnets are switched with a magnetic field or spin-transfer-torque inhibit the promised energy-efficiency. Another technique offering superior energy efficiency, “straintronics”, involves the application of a voltage to a piezoelectric layer to generate a strain which is transferred to an elastically coupled magnetrostrictive layer, causing magnetization rotation. The functionality of this scheme can be enhanced further by introducing magnetocrystalline anisotropy in the magnetostrictive layer, thereby generating four stable magnetization states (instead of the two stable directions produced by shape anisotropy in ellipsoidal nanomagnets). Numerical simulations were performed to implement a low-power universal logic gate (NOR) using such 4-state magnetostrictive/piezoelectric nanomagnets (Ni/PZT) by clocking the piezoelectric layer with a small electrostatic potential (~0.2 V) to switch the magnetization of the magnetic layer. Unidirectional and reliable logic propagation in this system was also demonstrated theoretically. Besides doubling the logic density (4-state versus 2-state) for logic applications, these four-state nanomagnets can be exploited for higher order applications such as image reconstruction and recognition in the presence of noise, associative memory and neuromorphic computing. Experimental work in strain-based switching has been limited to magnets that are multi-domain or magnets where strain moves domain walls. In this work, we also demonstrate strain-based switching in 2-state single-domain ellipsoidal magnetostrictive nanomagnets of lateral dimensions ~200 nm fabricated on a piezoelectric substrate (PMN-PT) and studied using Magnetic Force Microscopy (MFM). A nanomagnetic Boolean NOT gate and unidirectional bit information propagation through a finite chain of dipole-coupled nanomagnets are also shown through strain-based "clocking". This is the first experimental demonstration of strain-based switching in nanomagnets and clocking of nanomagnetic logic (Boolean NOT gate), as well as logic propagation in an array of nanomagnets.

O uso de materiais piezelétricos no desenvolvimento de dispositivos para o aproveitamento de energia provinda de vibrações mecânicas, Energy Harvesting, tem sido largamente estudado na última década. Materiais piezelétricos podem ser encontrados na forma de finas camadas ou pastilhas, sendo facilmente integradas a estruturas sem aumento significativo de massa. A conversão de energia mecânica em energia elétrica se dá graças ao acoplamento eletromecânico dos materiais piezelétricos. A maioria das publicações encontradas na literatura exploram o uso de dispositivos eletromecânicos ressonantes, sintonizados na frequência de operação da estrutura, maximizando assim, a energia elétrica de saída dada uma certa condição de operação. O desempenho desses dispositivos ressonantes para coletar e armazenar energia é altamente dependente da adequada sintonização da sua frequência de ressonância com a frequência de operação do sistema/estrutura. Este trabalho apresenta o projeto, otimização e análise de incertezas de um dispositivo coletor/armazenador de energia que consiste em uma placa sob duas condições de contorno, engastada-livre (EL) e deslizante-livre (DL), com massa sísmica e materiais piezelétricos conectados a um circuito shunt. Um modelo em elementos finitos de placa laminada piezelétrica conectada a circuitos R e RL é utilizado combinando as teorias de camada equivalente e deformação de cisalhamento de primeira ordem. A disposição/quantidade de material piezelétrico bem como a massa sísmica acoplados à estrutura foram otimizadas utilizando-se um Algoritmo Genético, levando em conta análises mecânica (modelo mecânico, geometria, peso) e elétrica (modelo elétrico, circuito armazenador). Além disso, o efeito de incertezas dos parâmetros dielétrico e piezelétrico do transdutor, e da indutância elétrica ligada em série ao circuito coletor/armazenador de energia foi estudado. Os resultados indicam que a inclusão de uma indutância sintética ao circuito pode melhorar a coleta de energia em uma banda de frequência e, ainda, que a otimização geométrica pode reduzir a quantidade de material piezelétrico sem no entanto diminuir significativamente a energia gerada. / The use of piezoelectric materials in the development of devices to harvest energy from mechanical vibrations (Energy Harvesting) has been widely studied in the last decade. Piezoelectric materials can be found in the form of thin layers or patches easily integrated into structures without significant mass increase. The conversion of mechanical energy into electric power is provided by the electromechanical coupling of piezoelectric materials. Most publications in the literature explore the use of resonant electromechanical devices, tuned to the operating frequency of the host structure, thus maximizing the power output given a certain operating condition. The performance of these resonant devices to harvest and store energy is highly dependent on the proper tuning of its resonance frequency with the operation frequency of the system/structure. This work presents a design, optimization and uncertainty analysis of energy harvester device consisting of a plate with tip mass and piezoelectric materials connected to shunt circuits. Two boundary conditions are used for the plate, cantilever (EL) and sliding-free (DL). A coupled finite element model with R and RL circuits, combining equivalent single layer and first order shear deformation theories, was used. The distribution and volume of piezoelectric material and the tip mass coupled to the structure were optimized using a Genetic Algorithm, accounting for both mechanical (mechanical model, geometry, weight) and electric (electric model, storer circuit) analyses. Furthermore, the effect of uncertainties of transducer dielectric and piezoelectric constants and electric inductance connected in series with harvesting circuit was studied. The results indicate that the inclusion of a synthetic inductance can improve energy harvesting performance over a frequency range and also that the geometric optimization may reduce the piezoelectric material volume without diminishing significantly the harvested energy.

Esta tese apresenta uma análise numérica do controle de vibrações estruturais através de cerâmicas piezelétricas em extensão conectadas a circuitos ativo-passivos compostos por resistência, indutância e fonte de tensão. Para tal, um modelo de elementos finitos de vigas sanduíche com três camadas elásticas e/ou piezelétricas foi desenvolvido. Realizou-se também uma modelagem dos componentes do circuito elétrico e seu acoplamento à estrutura gerando assim uma equação de movimento acoplada para a estrutura com elementos piezelétricos conectados aos circuitos elétricos. Uma análise harmônica das equações obtidas foi realizada para se obter uma avaliação preliminar dos efeitos causados pelos componentes elétricos do circuito na estrutura. Observou-se que os elementos passivos do circuito, resistência e indutância, tem não somente um efeito de absorvedor dinâmico de vibrações mas, também, promovem uma amplificação da autoridade de controle no caso de se atuar através da fonte de tensão. Usando a metodologia tradicional de projeto de absorvedores dinâmicos de vibrações, derivou-se expressões para os valores de resistência e indutância de modo a maximizar o desempenho passivo do sistema. Uma análise do efeito de incertezas das constantes piezelétricas e dielétricas da cerâmica piezelétrica considerada e dos componentes de resistência e indutância do circuito elétrico no desempenho do controle passivo e ativo-passivo de estrutura tipo viga cantilever foi realizada. O objetivo desta análise foi quantificar robustez e sensibilidade do controle proposto. Em sequida, um estudo de otimização dos valores de resistência e indutância do circuito elétrico em função da tensão elétrica de controle máxima a ser aplicada em uma placa com diversos atuadores piezelétricos foi realizado. Finalmente e também para a estrutura tipo placa, uma análise de incertezas da rigidez da cola na interface entre estrutura e atuadores piezelétricos e seus efeitos no desempenho do controle passivo e ativo-passivo foi realizada. / This work presents a numerical analysis of the structural vibration control using piezoelectric materials in extension mode connected to active-passive electric circuits composed of resistance, inductance and voltage source. For that, a finite element model for sandwich beams with three elastic or piezoelectric layers was developed. A modeling of the electric circuit dynamics and its coupling to the structure with piezoelectric elements was also done. A harmonic analysis of the resulting equations was performed to yield a preliminary evaluation of the effects caused by the electric circuit components on the structure. It was observed that the passive circuit components not only lead to a dynamic vibration absorber effect but also to an amplification of the control authority in case of actuation using the voltage source. Using the standard methodology for the design of dynamic vibration absorbers, expressions were derived for the resistance and inductance values that optimize the passive vibration control performance of the system. An analysis of the effect of uncertainties of piezoelectric and dielectric constants of piezoelectric ceramic and resistance and inductance components of the shunt circuit on the passive and active-passive control performance for a cantilever beam structure was performed. The objective of this analysis was to quantify robustness and sensitivity of the proposed control. Then, an optimization study of the values of resistance and inductance of the shunt circuit as a function of the maximum control voltage to be applied on a plate with several piezoelectric actuators was performed. Finally and also for the plate structure, an analysis of uncertainties in the stiffness of the adhesive interface between structure and piezoelectric actuators and their effects on the performance of passive control and active-passive was performed.

La décroissance de la consommation électrique des dispositifs électroniques leur a permis une croissance sans précédent. Néanmoins, les éléments de stockage d’énergie (piles et batteries), bien qu’ayant initialement promus ce développement, sont devenus un frein à la prolifération des microsystèmes électroniques, de part leur durée de vie limitée ainsi que des considérations environnementales (recyclage). Pour palier à ce problème, la possibilité d’exploiter l’énergie de l’environnement immédiat du dispositif a été proposée et a fait l’objet de nombreuses recherches au cours des dernières années. En particulier, la récupération d’énergie mécanique exploitant l’effet piézoélectrique est l’une des pistes les plus étudiées actuellement pour la conception de microgénérateurs autonomes capables d’alimenter les dispositifs électroniques. Par ailleurs, dans ce domaine, il a été démontré qu’un traitement non-linéaire de la tension de sortie de l’élément actif permet d’améliorer les capacités de récupération de l’énergie vibratoire. L’une de ces approches, nommée «Synchronized Switch Harvesting on Inductor» (récupération par commutation synchronisée sur inductance) et consistant en une inversion de la tension de manière synchrone avec le déplacement, s’est montrée particulièrement efficace, pouvant augmenter la quantité d’énergie récupérée par un facteur supérieur à 10. Cette dernière conduit à un processus cumulatif qui augmente artificiellement la tension de sortie de l’élément piézoélectrique ainsi qu’à une réduction du déphasage entre tension et vitesse de déplacement ; ces deux effets conduisant à l’augmentation importante des capacités de conversion. Néanmoins, l’étude des microgénérateurs d’énergie s’est quasiment toujours faite en considérant une excitation sinusoïdale, ce qui correspond rarement à la réalité. Peu de travaux expérimentaux, et encore moins théoriques, ont été menés en considérant une excitation large bande ; ceci étant d’autant plus vrai pour les dispositifs incluant un élément non-linéaire. Ainsi l’objectif de cette thèse est d’étudier le comportement des récupérateurs d’énergie piézoélectriques interfacés de manière non-linéaire. Pour ce faire, différentes approches seront envisagées, en considérant le processus de commutation comme un « auto-échantillonnage » du signal, ou en appliquant des théories d’analyse stochastique pour quantifier les performances du dispositif. Ainsi, plusieurs formes d’excitation appliquée au système pourront être analysées, permettant d’étudier la réponse du système sous des conditions plus réalistes. Toujours dans l’optique d’une implémentation réaliste, un autre objectif de cette thèse consistera à évaluer l’impact de la récupération d’énergie par couplage sismique sur la structure hôte, démontrant la nécessité d’envisager le système dans sa globalité afin de disposer de systèmes performants capables de convertir efficacement l’énergie vibratoire sous forme électrique pour un usage ultérieur. / A nonlinear interface consisting in a switching device has been proved to improve the piezoelectric harvester performance. Although existing works are usually done under single frequency excitation. practical cases are more likely broadband and random. In addition, the coupling effect due to the harvesting process is also an interesting issue to discuss. In terms of energy conversion process in seismic piezoelectric harvesters, mechanical interactions between host structure and harvester is an essential issue as well. The purpose of this work is to analysis seismic type piezoelectric harvesters from a practical perspective and to provide an optimal design of the latter. The broadband modeling based on the concepts of self-sampling and self-aliasing is described under broadband excitations for the nonlinear interface called "Periodic Switching Harvesting on Inductor" (PSHI). For this technique, the switching device is considered to be turned on at a fixed switching frequency. Then stochastic modeling is applied to have mathematical expressions that can describe broadband performance of the harvester with power spectral density (PSD) function of signals. As the switch is turned on at a given frequency, the modeling can be derived using cyclostationary theory. The effectiveness of stochastic modeling is validated with experimental measurements and time-domain iterative calculations, and the harvester performance under a band-limited noise excitation is discussed under bell-curved spectra excitations. An optimal switching frequency slightly less than twice the harvester resonant frequency is proved to have the optimal power output under the optimal resistive load. This switching frequency is however dependent on the electromechanical coupling factor of the harvester. Another part of this work discusses the interaction between the host structure and the harvester. The analysis is conducted with a Two-Degree-of-Freedom (TDOF) model. An energy conversion loop is therefore formed between the host structure and the harvester, within the harvester and the resistive load. The TDOF model is verified with Finite Element model and experimental work. An optimal mass ratio is proved to provide the maximal power output. The modeling is further applied to a practical self-powered Structural Health Monitoring system providing the best design of the harvester. A practical consideration of the broadband excitation is also introduced showing the effect of frequency detuning between the host structure and the harvester. Compared to constant force factor case, the harvester performance with a constant electromechanical coupling factor is surprisingly with very little decreases due to the mismatching of harvester and host structure resonant.

Fundação Carlos Chagas Filho de Amparo a Pesquisa do Estado do Rio de Janeiro / As cerâmicas piesoelétricas estudadas neste trabalho (Pb1,03Zr0,53Ti0,47O3, Pb1,03Zr0,525Nb0,05Ti0,465Fe0,005O3, Pb1,03Zr0,515Nb0,015Ti0,465Fe0,005O3, Pb1,03Zr0,525Nb0,005Ti0,455Fe0,015O3 e Pb1,03Zr0,515Nb0,015Ti0,455Fe0,015O3) foram sinterizadas a 1200oC e 1250oC por 3,5 h a fim de que suas propriedades piesoelétricas fossem investigadas. Nas composições dos PZT obtidas, a matriz e os dopantes empregaram óxidos como matérias primas. As misturas dos óxidos precursores foram calcinadas a 850oC por 3,5 h para obtenção da fase PZT. Os precursores, os pós e os corpos de prova de PZT foram caracterizados quanto às microestruturas, densidades e propriedades físicas. Após a conformação dos pós e a sinterização, os materiais cerâmicos foram polarizados para caracterização de suas propriedades piesoelétricas através de um impedancímetro na faixa de freqüência de 100 KHz a 200 KHz. Os resultados de dispersão de laser dos precursores revelaram aglomeração do óxido de chumbo e óxido de zircônio. As composições calcinadas apresentaram tamanho de partícula na faixa de 0,44 μm a 0,63 μm. As análises de densidade por método de Arquimedes indicaram uma boa densificação dos corpos de prova sinterizados e pouca influência da temperatura de sinterização com uma escala de valores de 95,73 a 97,65% da densidade teórica. As análises de microscopia eletrônica de varredura revelaram que os sinterizados contendo concentrações diferentes de dopantes exibem uma correlação do tipo e teor de dopante com a natureza da fratura, sendo transgranular, quando dopante ferro for predominante e intergranular, quando o dopante Nb for predominante. Também, o aumento da temperatura de sinterização resultou em fratura transgranular independente do tipo e da concentração de dopante, exceto para baixo teor de dopante da composição equimolar, cujos resultados não foram consistentes com a literatura sobre o material. No que diz respeito às propriedades piesoelétricas, revelou-se que a combinação da variação da composição com a temperatura foi favorável para o aumento dos valores da constante dielétrica da formulação equimolar com maior percentual de dopantes. Já o efeito da temperatura com a composição surtiu um efeito muito negativo para os valores de fator de qualidade mecânica da formulação dopada com mais ferro. Para os valores de constante de freqüência da formulação com maior percentagem de nióbio, o efeito da temperatura com a composição gerou um efeito positivo. / The piezoelectric ceramics studied in this work, Pb1.03Zr0.53Ti0.47O3, Pb1.03Zr0.525Nb0.05Ti0.465Fe0.005O3, Pb1.03Zr0.515Nb0.015Ti0.465Fe0.005O3, Pb1.03Zr0.525Nb0.005Ti0.455Fe0.015O3 and Pb1.03Zr0.515Nb0.015Ti0.455Fe0.015O3, were all of them sintered between 1200oC and 1250oC for 3.5h. After that, their piezoelectric properties were investigated. In the present work, oxides were used as raw material in both, matrices and dopants. The mixture of the precursor oxides were calcinaned at 850oC during 3.5h for obtaining the PZT phase. The precursor oxides, the powders and the PZT samples went through characterization tests in order to have their microstructures, densities and physical properties correctly determined. After the powders had been conformed and performed the sinterization process, the PZT ceramics were polarized and their piezoelectric properties determined by using an impedancemeter working in the frequency from 100 KHz to 200 KHz. The obtained results from laser dispersion had revealed agglomeration of lead and zirconium oxide. The calcined samples presented particle sizes from 0.44 μm to 0.63 μm. The density analyses using the Archimedes method indicated a good densification of the sintered samples and a weak influence of the sintering temperature on the obtained density values, whose values ranged from 95.73 to 97.65 % of the theoretical density value. Analysis performed using the scanning electron microscopy technique (MEV) revealed that the sintered samples had showed a correlation between the type and concentration of the dopant with their fracture mode, which were transgranular when Fe prevails over the Nb as dopant, and intergranular, when is the Nb that prevails over the Fe as dopant. By the other side, from increasing the sintering temperature resulted transgranular fractures, independently of which type and content of dopant had been used, except for the equimolar case with relatively low content of dopant, whose results were not consistent with the literature related to this material. About the piezoelectric properties, the results had showed that the combination of the dopant composition with the sintering temperature had brought better values of dielectric constant for the equimolar formulation with more content of dopant. Relating to the mechanical quality factor, from the combination of the dopant composition with the sintering temperature had decreased the factor when Fe prevails over Nb and increased the frequency factor when is the Nb that prevails over the Fe.

Piezoelectric materials find use as actuators and sensors in automotive, aerospace and other related industries. Automotive applications such as fuel injection nozzles and engine health monitoring systems require operating temperatures as high as 300-500 oC. The commercially used piezoelectric material PbZr1-xTixO3 (PZT) is limited to operating temperatures as low as 200 oC due to the temperature induced depolarization effects. PZT, in the undoped state exhibits a piezoelectric coefficient (d33) of 223 pC/N and ferroelectric-paraelectric transition temperature (Tc) of 386 oC. The enhanced properties of PZT occur at a region between the tetragonal and rhombohedral phases, called the Morphotropic Phase Boundary (MPB). Therefore, search for new materials with higher thermal stability and better sensing capabilities were focused on systems that exhibit a PZT-like MPB. This led to the discovery of (x)BiScO3-(1-x)PbTiO3 (BSPT), which exhibits an MPB with enhanced Tc (450 oC) and exceptionally high piezoelectric response (d33 = 460 pC/N). Theoretical studies have shown that the mechanism of enhanced piezoresponse in ferroelectric systems is related to the anisotropic flattening of the free energy profiles. An alternative view point attributes the anomalous piezoelectric response to the presence of high density of low energy domain walls near an inter-ferroelectric transition. Diffraction is a versatile tool to study the structural and microstructural changes of ferroelectric systems upon application of electric field. However, characterization of electric field induced structural and microstructural changes is not a trivial task, since in situ electric field dependent diffraction studies almost invariably give diffraction patterns laden with strong preferred orientation effects, due to the tendency of the ferroelectric/ferroelastic domains to align along the field direction. Additionally, diffraction profiles of MPB compositions exhibit severe overlap of Bragg peaks of the coexisting phases, and hence, it is difficult to ascertain with certainty, if the alteration in the intensity profiles upon application of electric field is due to change in phase fraction of the coexisting phases or due to preferred orientation induced in the different phases by the electric field. The characterization of electric field induced phase transformation in MPB systems, has therefore eluded researchers and has been considered of secondary importance, presumably due to the difficulties in unambiguously establishing the structural changes upon application of electric field. In fact, majority of the in situ electric field dependent diffraction studies have been carried out on compositions just outside the MPB range, i.e. on single phase compositions. In such studies, the focus has been mainly on explaining the piezoelectric response in terms of motions of the non-180° domain walls and field induced lattice strains. In this dissertation, the BSPT system has been systematically investigated with the view to understand the role of different contributing factors to the anomalous piezoelectric response of compositions close to the MPB. Using a comparative in situ electric field dependent diffraction study on a core MPB composition exhibiting highest piezoelectric response and a single phase monoclinic (pseudo-rhombohedral) composition just outside the MPB, it is demonstrated that, inspite of the significantly large domain switching and lattice strain (obtained from peak shifts) in the single phase composition, as compared to the MPB composition, the single phase composition shows considerably low piezoelectric response. This result clearly revealed that the anomalous piezoelectric response of the MPB composition is primarily associated with field induced inter-ferroelectric transformation and the corresponding field induced interphase boundary motion. A simple strategy has been employed to establish the field induced structural transformation for the MPB compositions, by overcoming the experimental limitation of in situ electric field dependent diffraction studies. The idea stemmed from the fact that, if the specimens for diffraction study can be used in powder form instead of pellet, the problems associated with preferred orientation effects can be eliminated, and the nature of field induced structural changes can be accurately determined. A comparative study of the diffraction profiles from poled (after subjecting the specimen to electric field) and unpoled (before subjecting the specimen to electric field) powders could precisely establish the nature of electric field induced phase transformation for the MPB compositions of BSPT and provided a direct correlation between the electric field induced structural changes and the enhanced piezoelectric response. A new ‘powder poling’ technique was devised, which involves application of electric field to powder form of the specimen. Using this technique, it was possible to study separately, the effect of stress and electric field on the nature of structural transformation. A unique outcome of this study was, it could demonstrate for the first time, analogous nature of the stress and electric field induced structural transformation. A comparative study of the dielectric response of poled and unpoled samples was used to show a counterintuitive phenomenon of field induced decrease in polarization coherence for the MPB compositions. This approach was used to suggest that the criticality associated with the MPB extends beyond the composition boundary conventionally reported in literature based on bulk diffraction techniques (x-ray and neutron powder diffraction). The layout of the dissertation is as follows: Chapter 1 gives a brief introduction of the fundamental concepts related to ferroelectric materials. The theories that explain the enhanced piezoresponse of MPB based ferroelectric systems have been outlined. Detailed information of the existing literature is presented in the relevant chapters. Chapter 2 presents the details of the solid state synthesis of BSPT compositions and structural analysis using diffraction studies. The dielectric measurements were used to establish the Tc for the different compositions. The enhanced ferroelectric and piezoelectric properties were observed for the MPB compositions, which were shown to exhibit coexistence of tetragonal and monoclinic phases from structural studies. The critical MPB composition exhibiting highest piezoelectric and ferroelectric properties was established to be x = 0.3725. The thermal stability of the critical MPB composition was established to be 400 oC using ex situ thermal depolarization studies. The common approach of structural analysis in the unpoled state failed to provide a unique relationship between the anomalous piezoelectric response and the structural factors at the MPB, emphasizing the need to characterize these system using electric field dependent structural studies. Chapter 3 presents the results of in situ electric field dependent diffraction measurements carried out at Argonne National Laboratory, USA. The quasi-static field measurements could successfully quantify the non-180o domain switching fractions and the field induced lattice strains. The changes in the integrated intensities were used to obtain the non-180o domain switching fraction and the shift in peak positions were used to quantify the field induced lattice strains. The in situ studies could successfully explain the macroscopic strain response for the single phase pseudo-rhombohedral (monoclinic) composition on the basis of domain switching mechanisms and field induced lattice strains. The MPB compositions were shown to have additional contributions from interphase boundary motion, resulting from change in phase fraction of the coexisting phases. The results emphasized the need to investigate the electric field induced transformation for MPB compositions, in order to give a comprehensive picture of the various contributions to the macroscopic piezoreponse. While Rietveld analysis could be used to investigate the phase transformation behaviour upon application of electric field, textured diffraction profiles obtained using in situ studies, in addition to the severely overlapping Bragg reflections of the coexisting phases for the MPB compositions hindered reliable estimation of the structural parameters. An alternate approach to investigate the field induced phase transformation is presented in Chapter 4. The stroboscopic measurements on the MPB composition showed evidence of non-180o domain wall motion even at sub-coercive field amplitudes as low as 0.1 kV/mm. Chapter 4 presents the results of the ex situ electric field dependent structural study, wherein the diffraction profiles collected from poled powders is compared to that of unpoled powders. The diffraction profiles from the poled powders did not exhibit any field induced crystallographic texture and could successfully be analyzed using Rietveld analysis. High resolution synchrotron diffraction studies (ESRF, France) carried out on closely spaced compositions revealed that, the composition exhibiting the highest piezoelectric response is the one, which exhibits significantly enhanced lattice polarizability of both the coexisting (monoclinic and tetragonal) phases. The enhanced lattice polarizability manifests as significant fraction of the monoclinic phase transforming irreversibly to the tetragonal phase after electric poling. The monoclinic to tetragonal transformation suggested the existence of a low energy polarization rotation pathway towards the [001]pc direction in the (1 1 0)pc pseudocubic plane of the monoclinic phase. The results are discussed on the basis of the existing theories that explain piezoresponse in MPB systems and are in support of the Polarization rotation model, in favor of a genuine monoclinic phase. Chapter 5 discusses the ferroelectric-ferroelectric stability of the MPB compositions in response to externally applied stress and electric field independently. Using the newly developed ‘powder poling’ technique, which is based on the concept of exploiting the irreversible structural changes that occur after application of electric field and stress independently, it was possible to ascertain that, both moderate stress and electric field induce identical structural transformation - a fraction of the monoclinic phase transforms irreversibly to the tetragonal phase. The powder poling technique was also used to demonstrate field induced inter-ferroelectric transformation at sub-coercive field amplitudes. In addition, the analysis of the dielectric response before and after poling revealed a counterintuitive phenomenon of poling induced decrease in the spatial coherence of polarization for compositions around the MPB and not so for compositions far away from the MPB range. Exploiting the greater sensitivity of this technique, it was demonstrated that, the criticality associated with the inter-ferroelectric transition spans a wider composition range than what is conventionally reported in the literature based on bulk x-ray/neutron powder diffraction techniques. Chapter 6 presents the closure and important conclusions from the present work and summarizes the key results, highlighting the proposed mechanism of enhanced piezoresponse in BSPT. The last part of the chapter deals with suggestions for future work from the ideas evolved in the present study. vi

Made available in DSpace on 2014-06-11T19:27:13Z (GMT). No. of bitstreams: 0 Previous issue date: 2010-05-26Bitstream added on 2014-06-13T19:55:33Z : No. of bitstreams: 1 galavotti_tv_me_ilha.pdf: 4073080 bytes, checksum: 0605ef5edb68c7bc2b71f8c976c0fe09 (MD5) / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / Nos últimos anos, as indústrias têm mostrado bastante interesse no desenvolvimento de novas técnicas para o controle de vibrações. O objetivo principal é atribuir valores aceitáveis das amplitudes de vibrações nos sistemas, garantindo um bom funcionamento dos mesmos e evitando falhas que provoquem paradas abruptas, mostrando-se uma área científica muito importante e que aproxima vários campos da engenharia moderna. Atualmente essa tecnologia é crescente e grande investimento tem sido aplicado no seu desenvolvimento. Este trabalho apresenta resultados obtidos para técnicas ativas e semi-ativas de controle de vibrações, considerando que as modificações estruturais são provenientes da alteração da rigidez e amortecimento. Utiliza-se para essa análise, Amortecedores Ativos Controlados por Atuadores Piezelétricos, denominados em inglês por Piezoelectric Friction Damper (PFD). A aplicação da metodologia é realizada em máquinas rotativas modeladas pelo Método dos Elementos Finitos e em um protótipo projetado e construído em laboratório. Os resultados procuram atenuar os níveis de vibrações e demonstram a viabilidade da aplicação de PFDs em estruturas. / Nowadays industries have shown great interest in developing new techniques for vibration control. The target is getting acceptable values of the amplitudes of vibrations in systems, ensuring proper working order avoiding failures. This is a scientific area of very important and approach fields of modern engineering. Currently this technology is growing and large investments has been applied in its development. This paper presents results obtained for active and semi-active techniques vibration control, where the structural changes are from the modification of stiffness and damping. It is used for this analysis a system known by Piezoelectric Friction Damper (PFD). The methodology was applied in rotating machines modeled by finite element method and in a prototype designed and built in the laboratory. The results try to mitigate the vibration levels and demonstrate the feasibility of applying PFDs in rotating machine.