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A limiting factor in the digitization of dental devices is the availability of materials suitable for use in both dentistry and the new digital technologies. As a rapidly growing industry, three-dimensional printing (3DP) has the potential to disrupt traditional manufacturing and prototyping methods. A review of both restorative materials and the current 3DP materials has lead to a focus on fiber- reinforced composites in the exploration for a new 3DP material. In addition, another area worth exploring and investing in would be 3D bioprinting as it opens up the possibility of regenerative dentistry.

This thesis presents the study of films derived from the reduction of aryldiazonium salts at gold surfaces. The properties of bare polycrystalline surfaces were investigated via the observation of the electrochemical oxidation and reduction of the gold. Films derived from diazonium salts were electrochemically grafted to the gold surface. The structure and stability of these interfaces was examined through the use of redox probes, gold oxide electrochemistry and water contact angle measurements. The spontaneous reduction of aryldiazonium salts at gold surfaces was investigated and the possible applications it presented towards printing and patterning of the gold surface with films were explained. Polycrystalline gold surfaces were prepared and subjected to various treatments, to observe the behaviour of gold oxide formation and reduction at the surface. Various effects on the surface structure were observed after treatment in solvents and electrolyte solutions. The surface structure of the gold atoms frequently changed due to the high mobilities of the gold atoms, and it is difficult to achieve a reproducibly stable surface. The electrochemical modification of gold surfaces via the reduction of aryldiazonium salts was investigated. Surfaces were modified with methylphenyl and carboxyphenyl films and exposed to various treatments. Monitoring the gold oxide reduction changes enabled the surface coverage of modifier directly attached to the surface to be calculated. The films appear to be stable, loosely packed and porous. The films are flexible in nature; redox probe responses showed reversible changes after repeated sonication in solvents of differing polarities and hydrophilicities. Contact angle measurements further support the notion of films that can reorganise in response to their environment. The spontaneous reduction of aryldiazonium salts at gold surfaces was observed. Film coverage was significantly lower at the spontaneously grafted surface than for films grafted electrochemically. Gold surfaces were successfully modified via microcontact printing, and surface coverages similar to the spontaneously grafted film were achieved. Microcontact printing was also used to pattern surfaces with films derived from diazonium salts. Feature sizes down to 100 µm were successfully achieved.

This bachelor degree work explores the interrelation between print and surface in fashion design and aims to investigate the expressional possibilities in merging of techniques. With focus on creating an irregular surface through embroidery and fringing, three-dimensional expressions are created, resulting in an illusion of depth and movement within the motifs. The work is textile-driven, hence the main focus has been to find materials, applicational techniques and motifs that interact with each other without conflicts. Through the use of heat sensitive yarns within the transfer printing process a clear relationship between texture and motif occur where the different aspects affect each other and are equally important for the final visual expression. It is the heat-press used to transfer print from paper to surface that is the most vital step of the process. This work strives to propose a transposed order of applying techniques within a design process. Whilst the act of embellishing existing prints has been investigated by a range of designers, this project propose an order where the print is added post additive surface-manipulation. Therefore this work is to be seen as a suggestion of new ways of approaching the use of prints within the fashion field. Balancing between fashion design and textile design, the collection is based on generic prints and shapes which are affected by the surface manipulations used.

The study was an investigation of the effect of different developers on contrast, grain, tonal range, density and sharpness in 35mm film and their effect on contrast and density in photographic paper.It was theorized that all normal developers do not react exactly the same, Therefore, merely changing developers would cause a significant visual change in each of the above-mentioned areas.To test the hypotheses a tightly controlled experiment was conducted using eleven normal film developers and ten normal paper developers. These developers were tested on Tri-X film, and on Oriental, Polycontrast and Polycontrast RC paper.All processing steps, except the developer, for both film and paper were standardized. A still life was used as the subject for all pictures. A densitometer was used to measure the actual differences in base density, contrast range and overall density caused by changing from one developer to the next. Prints were then made using a standard exposure time determined by zone system tests, and these prints were given to three groups of coders representing experts, advanced photo students and amateurs, for visual ranking in each of the areas being tested. The rankings obtained from these three groups were then statistically checked for a significant similarity at the .05 level.For the photographic paper tests, one negative was chosen from the film tests and used for all prints. Pictures were made on each of the three papers and developed in each of the ten normal developers under strict controls. These prints were then ranked for contrast and density changes by the three groups of coders. The rankings were subjected to the same statistical tests used for the film rankings.The film rankings proved significant at the .01 level in all areas except grain. This indicates just changing developers will cause a visually significant change in contrast, density, tonal range and sharpness. The grain tests were inconclusive, but they indicated under extreme enlargement changing developer alone will not have significant effect on the actual amount of grain.The results of the film tests were charted so that the effect of each developer could be compared directly with each of the other developers.The rankings on paper developers proved to be significant at the .01 level for density and at the .05 level for contrast, indicating there is a significant visual change in both areas caused just by changing the developer. The tests also indicated the density change is controlled by the photo paper itself, while the contrast change is controlled by the developer. These results were also charted for easy comparison.The study led the researcher to accept the hypotheses stated at the beginning, with a slight modification concerning changes in the actual amount of grain.

Surface plasmon microscopes are mostly built around the prism based Kretschmann configuration. In these systems, an image of a sample can be obtained in terms of an intensity map, where the intensity of the image is dependent on the coupling of the light into the surface plasmons. Unfortunately the lateral resolution of these systems relies on the ability of plasmons to propagate along the metallised layer and is usually limited to a few microns unless special measures are taken. The widefield surface plasmon microscope (WSPR), used here enables surface plasmon imaging at significantly higher lateral resolutions than prism based systems. In this study we demonstrate the functionality of the WSPR by imaging a sequence of binding events between micro-patterned extracellular matrix proteins and their specific antibodies. Using the WSPR system a change in contrast was observed with each binding event. Images produced via the WSPR system were analyzed and compared qualitatively and quantitatively. Consequently, we confirm that the WSPR microscope described here can be used to study sequential monomolecular layer binding events on a micron scale. These results have significant implications in the development of new micron scale bioassays.

Large Area Maskless Photopolymerization (LAMP) is a novel additive manufacturing technology currently being developed at Georgia Tech in collaboration with the University of Michigan at Ann Arbor and PCC Airfoils. It is intended for the fabrication of integrally cored ceramic molds for the investment casting of precision components such as high-pressure turbine blades. This dissertation addresses the digital data processing and computational design needs for this technology. Several data processing schemes like direct slicing, STL slicing, post-processing schemes like error checking, part placement and tiling etc. were developed in order to enable the basic functionality of the LAMP process. A detailed overview of these schemes and their implementation details are given in this dissertation. Several computational schemes to improve the quality and accuracy of parts produced through the LAMP process were also implemented. These include a novel volume deviation based adaptive slicing method to adaptively slice native CAD models, a gray scaling and dithering approach to reduce stair stepping effect on downward facing surfaces and a preliminary experimental study to characterize the side curing behavior of the LAMP photo-curable suspension for pre-build image compensation. The implementation details and a discussion of the results obtained using these schemes are given. A novel approach for addressing the “floating island” problem encountered in additive manufacturing was also developed. The need for supports specific to the kind of parts being built through LAMP is evaluated and a support generation strategy different from the previously reported approaches in the literature is presented. Finally, a few novel film cooling schemes that are extremely challenging to fabricate using existing manufacturing technologies but possible to fabricate using LAMP are chosen and analyzed for their cooling performance. It is shown that such novel schemes perform much better in cooling the blade surface than the conventionally implemented schemes and hence this final component of work gives a better appreciation of the impact LAMP technology has in disrupting the state of the art in turbine blade manufacturing and truly taking the blade designs to the next level.

This work presents a novel means of producing thin-film light-emitting devices, functioning according to the principle of electroluminescence, using an inkjet printing technique. This study represents the first report of a light-emitting device deposited completely by inkjet printing. An electroluminescent species, doped zinc sulfide, was incorporated into a polymeric matrix and deposited by piezoelectric inkjet printing. The layer was printed over other printed layers including electrodes composed of the conductive polymer poly(3,4-ethylenedioxythiophene), doped with poly(styrenesulfonate) (PEDOT:PSS) and single-walled carbon nanotubes, and in certain device structures, an insulating species, barium titanate, in an insulating polymer binder. The materials used were all suitable for deposition and curing at low to moderate (<150°C) temperatures and atmospheric pressure, allowing for the use of polymers or paper as supportive substrates for the devices, and greatly facilitating the fabrication process. The deposition of a completely inkjet-printed light-emitting device has hitherto been unreported. When ZnS has been used as the emitter, solution-processed layers have been prepared by spin-coating, and never by inkjet printing. Furthermore, the utilization of the low-temperature-processed PEDOT:PSS/nanotube composite for both electrodes has not yet been reported. Device performance was compromised compared to conventionally prepared devices. This was partially due to the relatively high roughness of the printed films. It was also caused by energy level misalignment due to quantization (bandgap widening) of the small (<10 nm) nanoparticles, and the use of high work function cathode materials (Al and PEDOT:PSS). Regardless of their reduced performance, inkjet printing as a deposition technique for these devices presents unique advantages, the most notable of which are rapidity of fabrication and patterning, substrate flexibility, avoidance of material wastage by using drop-on-demand technology, and the need for only one main unit operation to produce an entire device.

This work presents a novel means of producing thin-film light-emitting devices, functioning according to the principle of electroluminescence, using an inkjet printing technique. This study represents the first report of a light-emitting device deposited completely by inkjet printing. An electroluminescent species, doped zinc sulfide, was incorporated into a polymeric matrix and deposited by piezoelectric inkjet printing. The layer was printed over other printed layers including electrodes composed of the conductive polymer poly(3,4-ethylenedioxythiophene), doped with poly(styrenesulfonate) (PEDOT:PSS) and single-walled carbon nanotubes, and in certain device structures, an insulating species, barium titanate, in an insulating polymer binder. The materials used were all suitable for deposition and curing at low to moderate (<150°C) temperatures and atmospheric pressure, allowing for the use of polymers or paper as supportive substrates for the devices, and greatly facilitating the fabrication process. The deposition of a completely inkjet-printed light-emitting device has hitherto been unreported. When ZnS has been used as the emitter, solution-processed layers have been prepared by spin-coating, and never by inkjet printing. Furthermore, the utilization of the low-temperature-processed PEDOT:PSS/nanotube composite for both electrodes has not yet been reported. Device performance was compromised compared to conventionally prepared devices. This was partially due to the relatively high roughness of the printed films. It was also caused by energy level misalignment due to quantization (bandgap widening) of the small (<10 nm) nanoparticles, and the use of high work function cathode materials (Al and PEDOT:PSS). Regardless of their reduced performance, inkjet printing as a deposition technique for these devices presents unique advantages, the most notable of which are rapidity of fabrication and patterning, substrate flexibility, avoidance of material wastage by using drop-on-demand technology, and the need for only one main unit operation to produce an entire device.