Thesis (Ph. D.)--University of Texas at Austin, 2007. / Vita. Includes bibliographical references.

Thesis (Ph. D.)--Ohio State University, 2007. / Title from first page of PDF file. Includes bibliographical references (p. 169-172).

U.S. Energy Research and Development Administration under Contract no. E(49-18) 2295, Task Order no. 14

U.S. Energy Research and Development Administration under Contract no. E(49-18) 2295, Task Order no. 14

U.S. Energy Research and Development Administration under Contract no. E(49-18) 2295, Task Order no. 14

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V-Th-Pb fractionation trends, and the associated variations in Pb-isotopes, provide important constraints on the nature, and age, of a wide range of geological processes. This thesis presents three detailed case studies from a carbonatite intrusive complex, lower crustal granulite xenoliths, and young volcanic rocks which represent a range of processes that fractionate V, Th and Pb. New major, trace element and Sr, Nd and Pb isotope results are presented for carbonatites and pyroxenites from the 130 Ma old Jacupiranga complex in southern Brazil. The data preclude simple models in which the Sr-Nd and Sr-Pb isotope arrays are the result of crustal contamination processes, or liquid immiscibility between the carbonatites and magmas similar to those from which the pyroxenites crystallised. The initial Sr, Nd and Pb isotope ratios in the Jacupiranga complex are similar to those in the Parana high-Ti basalts and to the oceanic basalts of the Walvis Ridge and Tristan da Cunha, and were apparently inherited from the mantle source regions associated with incipient magmatism of the Tristan da Cunha hotspot and the opening of the South Atlantic. Most carbonatites have high V/Pb and low Rb/Sr ratios and infiltration and/ or metasomatism by such melts is one process that may be responsible for the negative correlation of U/Pb and Rb/Sr inferred for the source of certain oceanic basalts such as Tristan da Cunha. Correlations between trace and major elements in mostly mafic granulite xenoliths from southern Africa probably result from magmatic processes such as fractional crystallisation and crystal accumulation. From Pb and Nd isotope systematics it can be inferred that the northern Lesotho xenoliths are Proterozoic in age, whereas Cape province xenoliths appear to have been fonned in the Archaean and to have had their Nd isotopes reset in the Proterozoic. Most Pb isotope ratios from the granulites xenoliths are unradiogenic relative to the Geochron, which indicates relatively low V /Pb ratios in the later parts of their histories. The correlation between Pb isotope ratios and K₂O/A1₂O₃ in the granulites from Markt is considered to reflect magmatic control of the V /Pb fractionation. The Archaean, and some of the younger mantle derived rocks on the Kaapvaal craton, plot on similar Pb isotope trends. It is argued that segments of the crust and uppennost mantle beneath southern Africa stabilised together in the Archaean, and that both were remobilised in subsequent magmatic and orogenic events. Volcanic rocks in the Northland-Auckland peninsula, New Zealand, range from silica-undersaturated basanites to tholeiites and andesites. Although all the volcanic fields are in intraplate settings, two types of mantle source enrichment can be recognised. One is subduction-related and characterised by high Sr and low Nd isotope ratios and negative Nb anomalies. The other type has geochemical features characteristic of intraplate enriched mantle sources with Sr and Nd isotope ratios and Nb/Ba, Ba/La, similar to HIMV OIB, which has been attributed to the deep recycling of oceanic crust. The differences in Pb isotopes between the two mantle sources, i.e. higher /lB/4 and 7/4, but lower ²⁰⁶Pb/²⁰⁴Pb in the subduction-related material than in the inferred HIMU source, indicate that V/Pb in shallow recycled crustal material tend to be lower than in the deeper recycled material. These case studies confirm that (i) metasomatism by small degree melts can have significant effects on mantle trace element characteristics, (ii) the lower crust is a relatively low 11 environment and crystal accumulation may be an important mechanism in the fractionation of Th and U from Pb, cUld (iii) incorporation of recycled crustal material at different levels can result in different V-Th-Pb fractionation and so, with time, different Pb isotope ratios.

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