Considerando aspectos relacionados ao conforto térmico nas edificações e redução da demanda de energia para resfriamento, a utilização de revestimentos frios (que refletem boa parcela da radiação solar recebida e emitem calor) no envelope construtivo pode ser uma alternativa viável para alcançar estas condições. No entanto, a sua durabilidade é o caminho crítico. O presente estudo tem o objetivo de determinar a durabilidade de revestimento multifuncional que reúne as propriedades: fria e autolimpante. Para alcançar esta meta foi formulado um revestimento cimentício monocamada, com e sem a adição de pigmento, ambos com elevada refletância solar e emissividade iniciais. Para manter a refletância ao longo do tempo foi realizada a aplicação de TiO2 anatásio aos revestimentos de duas formas, na primeira as partículas foram adicionadas à matriz cimentícia, enquanto na segunda foram aplicadas superficialmente como pós-tratamento. A exposição à radiação UV proporciona a fotoativação do anatásio que possui capacidade de oxidação da matéria orgânica e alteração do ângulo de contato entre a água e a superfície, facilitando o arraste das sujidades quando esta é molhada tornando-a autolimpante. A manutenção das propriedades frias e a permanência das partículas de TiO2 sobre a superfície foram avaliadas após 6 e 12 meses de exposição natural em estações localizadas nas cidades de Ubatuba, Pirassununga e São Paulo. Após o envelhecimento observou-se a influência determinante das características dos sítios de exposição no comportamento dos materiais. Dentre as formas de aplicação do anatásio verificou-se uma melhora sutil no desempenho dos revestimentos com adição de TiO2 à matriz cimentícia em relação à aplicação superficial do pós-tratamento. O processo de lixiviação observado em ambos os revestimentos expôs as partículas encapsuladas na argamassa com adição de TiO2, enquanto no pós-tratamento houve a remoção da camada superficial de anatásio. Por esse motivo o revestimento com adição apresentou interação com a radiação UV e material a ser degradado por mais tempo. Entretanto os resultados sugeriram que o tempo de exposição foi insuficiente para afirmar este comportamento, pois os resultados são próximos entre si. / Considering aspects related to the indoor thermal comfort in buildings and reducing energy demand for cooling, the use of cool coatings (have high reflectance and emittance of solar radiation) can be a reasonable alternative to achieve these conditions. However, its durability is the critical path. This study aims to measure the durability of multifunctional coating that combines cool and self-cleaning properties. To attain this goal a single-layer cement coating was formulated, with and without pigment added, both with high initial reflectance and emissivity. To maintain these properties over time a coating of TiO2 in crystalline form of anatase was applied to the coating in two ways: in the first way, the particles were mixed to the cementitious layer, and in the second, they were applied superficially as a post-treatment layer. The exposure to UV radiation provides the photoactivation of anatase, activating the oxidation of organic matter and altering the contact angle between water and surface, facilitating the drag of dirt when wet making it self-cleaning. The performance of cool properties and the permanence of TiO2 particles on the surface were evaluated at 6 and 12 months of natural exposure in Ubatuba, Pirassununga and São Paulo. After aging the determinant influence of the sites\' exposure characteristics in the materials performances was observed. A small tendency of improved performance with TiO2 added to the cement layer was verified. In addition, it was noted that these coatings presented higher durability in comparison to the post-treatment layer due to the leaching process, which exposes encapsulated particles in the cementitious mix, providing longer interaction with UV radiation and the organic matter to be degraded. On the other hand leaching caused the partial removal of anatase in the post-treated surfaces. Despite better performance of the TiO2 added coating, the exposure time was insufficient to affirm this behavior because the results are too close to each other.

Vertical-cavity surface-emitting lasers (VCSELs) are complex multi-layer structures whose operating characteristics are highly sensitive to variations in layer thickness and composition. They contain an active region of one or more quantum wells sandwiched between highly reflecting mirrors. Non-destructive optical characterisation techniques including reflectance spectroscopy, spectroscopic ellipsometry and photomodulated reflectance have been used to examine these structures and various components of them. In addition, the relatively novel technique of photomodulated spectroscopic ellipsometry has been examined in comparison with photomodulated reflectance in the characterisation of bulk, multi-layer and quantum well material. The distributed Bragg reflectors of VCSELs provide the high reflectance required over a selected wavelength range. Optical measurements were used to determine important information concerning layer thicknesses and compositions, which were confirmed with X-ray diffraction and transmission electron microscopy. The techniques were also used to provide important information concerning growth and uniformity, which could be readily applied for feedback to growers or for device fabrication. Novel reflectance and photomodulated reflectance measurements made on a range of laser structures designed to operate over a range of wavelengths from 650 nm to 1 ?m were used to examine the characteristics of the reflectors and the active region of the lasers. The cavity mode observed clearly indicates the lasing wavelength, and the interaction of the cavity and quantum well has been interpreted using new lineshapes. The cavity mode and quantum well resonance observed in photomodulated reflectance has been shown to provide a clear indication of where devices can be fabricated successfully from non-uniform material. The identification of the cavity and quantum well features has also enabled important information concerning the changes in structure and therefore in device performance with temperature and pressure. Measurements have also been able to provide important information to explain the variation in performance of some devices.

Doctor of Philosophy / Food Science Institute / Jayendra K. Amamcharla / Lactose is commercially produced from whey, whey permeate, or milk permeate as α-lactose monohydrate in crystalline form. Focused Beam Reflectance Measurement (FBRM) as a potential tool for in situ monitoring of lactose crystallization at concentrations relevant to the dairy industry was evaluated. Applicability of FBRM at supersaturated lactose concentrations 50%, 55%, and 60% (w/w) was reported in comparison with Brix values obtained from a Refractometer during isothermal crystallization at temperatures 20ºC and 30ºC. FBRM technique was shown to be a valuable tool for monitoring chord length distributions during lactose crystallization. In a different study, the influence of cooling rate during crystallization of lactose in concentrated permeates was studied. Three cooling rates accounting for approximately 17, 11, and 9 h were applied during lactose crystallization to evaluate the lactose crystal yield and quality of lactose crystals. There was no significant difference (P>0.05) found in lactose crystal yield, mean particle size obtained at the end of crystallization. This study suggested that increasing the cooling rate during lactose crystallization within the range explained in this study can save approximately 8 h of crystallization time. These studies evaluated FBRM as a potential tool to monitor lactose crystal chord lengths and counts. Also, process improvements were suggested to increase the productivity of lactose crystallization process by reducing the crystallization time. In chapters 5 and 6, calcium-reduced milk protein concentrates (MPCs) were used as an ingredient to improve the stability of high-protein dairy beverages. Heat stability increased significantly (P>0.05) in 8% protein solutions made from 20% calcium-reduced MPC. A significant increase in heat stability was observed in beverages formulated with 20% calcium-reduced MPC in the absence of chelating agent. In another study, it was evident that the dairy beverage formulation with 20% calcium-reduced MPC showed no sedimentation and age gelation indicating an improved storage stability. These studies confirmed that 20% calcium reduced MPC contributed towards improved heat stability and storage stability of the high-protein beverages.

Many systems for field-based, high-throughput phenotyping (FB-HTP) quantify and characterize the reflected radiation from the crop canopy to derive phenotypes, as well as infer plant function and health status. However, given the technology's nascent status, it remains unknown how biophysical and physiological properties of the plant canopy impact downstream interpretation and application of canopy reflectance data. In that light, we assessed relationships between leaf thickness and several canopy-associated traits, including normalized difference vegetation index (NDVI), which was collected via active reflectance sensors carried on a mobile FB-HTP system, carbon isotope discrimination (CID), and chlorophyll content. To investigate the relationships among traits, two distinct cotton populations, an upland (Gossypium hirsutum L.) recombinant inbred line (RIL) population of 95 lines and a Pima (G, barbaderise L.) population composed of 25 diverse cultivars, were evaluated under contrasting irrigation regimes, water-limited (WL) and well-watered pm conditions, across 3 years. We detected four quantitative trait loci (QTL) and significant variation in both populations for leaf thickness among genotypes as well as high estimates of broad-sense heritability (on average, above 0.7 for both populations), indicating a strong genetic basis for leaf thickness. Strong phenotypic correlations (maximum r = -0.73) were observed between leaf thickness and NDVI in the Pima population, but not the RIL population. Additionally, estimated genotypic correlations within the RIL population for leaf thickness with CID, chlorophyll content, and nitrogen discrimination (r(gij) = -0.32, 0.48, and 0.40, respectively) were all significant under WW but not WL conditions. Economically important fiber quality traits did not exhibit significant phenotypic or genotypic correlations with canopy traits. Overall, our results support considering variation in leaf thickness as a potential contributing factor to variation in NDVI or other canopy traits measured via proximal sensing, and as a trait that impacts fundamental physiological responses of plants.

Accurately assessing the extent of myocardial tissue injury induced by Myocardial infarction (MI) is critical to the planning and optimization of MI patient management. With this in mind, this study investigated the feasibility of using combined fluorescence and diffuse reflectance spectroscopy to characterize a myocardial infarct at the different stages of its development. An animal study was conducted using twenty male Sprague-Dawley rats with MI. In vivo fluorescence spectra at 337 nm excitation and diffuse reflectance between 400 nm and 900 nm were measured from the heart using a portable fiber-optic spectroscopic system. Spectral acquisition was performed on - (1) the normal heart region; (2) the region immediately surrounding the infarct; and (3) the infarcted region - one, two, three and four weeks into MI development. The spectral data were divided into six subgroups according to the histopathological features associated with various degrees / severities of myocardial tissue injury as well as various stages of myocardial tissue remodeling, post infarction. Various data processing and analysis techniques were employed to recognize the representative spectral features corresponding to various histopathological features associated with myocardial infarction. The identified spectral features were utilized in discriminant analysis to further evaluate their effectiveness in classifying tissue injuries induced by MI. In this study, it was observed that MI induced significant alterations (p < 0.05) in the diffuse reflectance spectra, especially between 450 nm and 600 nm, from myocardial tissue within the infarcted and surrounding regions. In addition, MI induced a significant elevation in fluorescence intensities at 400 and 460 nm from the myocardial tissue from the same regions. The extent of these spectral alterations was related to the duration of the infarction. Using the spectral features identified, an effective tissue injury classification algorithm was developed which produced a satisfactory overall classification result (87.8%). The findings of this research support the concept that optical spectroscopy represents a useful tool to non-invasively determine the in vivo pathophysiological features of a myocardial infarct and its surrounding tissue, thereby providing valuable real-time feedback to surgeons during various surgical interventions for MI.

No description available.

The microstructures of the near-surface layers on AA3104 aluminium alloys and their evolution through rolling and deep drawing processes have been investigated. The effect of the near-surface layers on the optical property of AA3104 aluminium alloy has also been assessed. It was revealed that two types of near-surface deformed layers, both with different microstructures different from the underlying bulk alloy, were generated on the surface of AA3104 aluminium alloy during rolling. Both of them are characterized by ultrafine, equiaxed grains, with diameters <100 nm for type A near-surface deformed layer and <200 nm for type B near-surface deformed layer. A high population density of nano-sized, oxygen-rich particles is present along grain boundaries within type A deformed layer. But type B deformed layer is free of oxygen-rich particles. Type A deformed layer was generated through two mechanisms, i.e. geometric dynamic recrystallization and mechanical alloying. Rolling introduced plastic strain in the surface/near-surface region of aluminium sheet was of sufficient magnitude to cause geometric dynamic recrystallization and thus microstructure refinement. In addition, the incorporation of oxides into the near-surface region was also involved in the formation of type A deformed layer. However, the formation of type B deformed layer was only attributed to severe strain induced geometric dynamic recrystallization. Type A deformed layer was mainly formed at the early stages of hot rolling. The subsequent rolling and deep drawing reduced the thickness of type A deformed layer by distributing it over a larger surface area. During cold rolling, type A deformed layer broke into patches with the extension of alloy surface. Type B deformed layer may be generated on the nascent surface if the strain is sufficiently severe to cause geometric dynamic recrystallization. For the hot rolled alloy sheets, the surface/near-surface region is mainly covered by type A deformed layer. However, for the alloys after cold rolling, only limited area is covered with type A deformed layer. The thicknesses of the near-surface deformed layers are not uniform across the surface of AA3104 aluminium alloy. The maximum thickness of type A deformed layer on transfer slab is approximately 4 µm, while that on re-roll gauge sheet is ~1 µm, and ~0.8 µm on the final gauge sheet, ~400 nm on formed cup and ~100 nm on formed can. Type A deformed layer is randomly distributed as patches on the cold rolled aluminium sheet. The reflectivity of oxygen-rich particles is lower compared with the reflectivity of aluminium. As a result, the type A deformed layer patches absorb more incident light than the area without type A deformed layer. Further, there are plenty of micro-scale mini-cracks present on type A deformed layer, their opening sizes are in the equivalent scale of the wavelength of visible light. The incident light may not able to be reflected out if they go into these mini-cracks. It is more prone to happen for short wavelength light since it is easier for them to go into the mini-cracks than long wavelength light. As a result, less short wavelength visible light is reflected from the type A deformed layer patches. Thus, such patches exhibit a yellow appearance while the surrounding area appears the original silver white aluminium appearance. The aluminium sheet with a high coverage of type A deformed layer exhibits a low total reflectance. Further, its total reflectance is with a significant “red shift”. Neither the macro-scale surface roughness nor the ultrafine grain size affects the total reflectance of aluminium alloys. The total reflectance of aluminium alloys is primarily dependent on the presence of type A deformed layer.

Nous introduisons un algorithme de décomposition intrinsèque multi-vue qui permet de ré-éclairer une scène extérieure en utilisant quelques images en entrée. Plusieurs applications comme l’architecture, jeux et films exigent de manipuler un modèle 3D d’une scène. Cependant, la modification de telles scènes est limitée par les conditions d’éclairage de capture. Notre méthode estime les images intrinsèques prises dans des conditions d’éclairage identiques avec des ombres. Nous utilisons conjointement une reconstruction 3D automatique et la direction du soleil pour obtenir la décomposition de chaque image en calques de réflectance et d’éclairage malgré l’inexactitude des données du modèle 3D. Notre approche est basée sur deux idées principales. Tout d’abord, nous raffinons l’estimation des paramètres de notre modèle de formation d’image en combinant la simulation d’éclairage 3D avec des méthodes d’optimisation basée image. Deuxièmement, nous utilisons ce modèle pour exprimer la réflectance en fonction de valeur de visibilité discrète pour l’ombre et la lumière, ce qui nous permet d’introduire un classificateur d’ombre robuste pour des paires de points dans une scène. Nos calques intrinsèques sont de qualité suffisante pour manipuler les images d’entrée. Nous déplaçons les ombres portées en créant une géométrie qui préserve les silhouettes d’ombre. Notre méthode est compatible avec les approches de rendu basé image et réduit les coûts de création de contenu 3D. Enfin, nous présentons une étude sur les limites du modèle de réflectance diffus et la difficulté d’appliquer les approches existantes dans le cadre de reconstruction 3D multi vue où les données sont imprécises. / We present a multi-view intrinsic decomposition algorithm that allows relighting of an outdoor scene using just a few photographs as input. Several applications such as architecture, games and movies require a 3D model of a scene. However, editing such scenes is limited by the lighting condition at the time of capture. Our method computes intrinsic images photos taken under the same lighting condition with existing cast shadows by the sun. We use an automatic 3D reconstruction from these photos and the sun direction as input and decompose each image into reflectance and shading layers, despite the inaccuracies and missing data of the 3D model. Our approach is based on two key ideas. First, we progressively improve the accuracy of the parameters of our image formation model by performing iterative estimation and combining 3D lighting simulation with 2D image optimization methods. Second we use the image formation model to express reflectance as a function of discrete visibility values for shadow and light, which allows us to introduce a robust shadow classifier for pairs of points in a scene. Our multi-view intrinsic decomposition is of sufficient quality for relighting of the input images. We create shadow-caster geometry which preserves shadow silhouettes and using the intrinsic layers, we can perform multi-view relighting with moving cast shadows. Our method allows image-based rendering with changing illumination conditions and reduces the cost of creating 3D content for applications. Finally, we present an initial study on the limitation of diffuse reflectance models for these computations.

The cerebral microcirculation consists of a complex network of small blood vessels that support nerve cells with oxygen and nutrition. The blood flow and oxygen delivery in the microcirculatory blood vessels are regulated through mechanisms which may be influenced or impaired by disease or brain damage resulting from conditions such as brain tumors, traumatic brain injury or subarachnoid hemorrhage (SAH). Monitoring of parameters relating to the microvascular circulation is therefore needed in the clinical setting. Optical techniques such as diffuse reflectance spectroscopy (DRS) and laser Doppler flowmetry (LDF) are capable of estimating the oxygen saturation (SO2) and tracking the microvascular blood flow (perfusion) using a fiber optic probe. This thesis presents the work carried out to adapt DRS and LDF for monitoring cerebral microcirculation in the human brain. A method for real-time estimation of SO2 in brain tissue was developed based on the P3 approximation of diffuse light transport and quadratic polynomial fit to the measured DRS signal. A custom-made fiberoptic probe was constructed for measurements during tumor surgery and in neurointensive care. Software modules with specific user interface for LDF and DRS were programmed to process, record and present parameters such as perfusion, total backscattered light, heart rate, pulsatility index, blood fraction and SO2 from acquired signals. The systems were evaluated on skin, and experimentally by using optical phantoms with properties mimicking brain tissue. The oxygen pressure (pO2) in the phantoms was regulated to track spectroscopic changes coupled with the level of SO2. Clinical evaluation was performed during intraoperative measurements during tumor surgery (n = 10) and stereotactic deep brain stimulation implantations (n = 20). The LDF and DRS systems were also successfully assessed in the neurointensive care unit for a patient treated for SAH. The cerebral autoregulation was studied by relating the parameters from the optical systems to signals from the standard monitoring equipment in neurointensive care. In summary, the presented work takes DRS and LDF one step further toward clinical use for optical monitoring of cerebral microcirculation.

Orientador: Carlos Roberto de Souza Filho / Tese (doutorado) - Universidade Estadual de Campinas, Instituto de Geociências / Made available in DSpace on 2018-08-26T19:58:27Z (GMT). No. of bitstreams: 1 CorreaPabon_RosaElvira_D.pdf: 10125024 bytes, checksum: 73b222e9787711d668d1cc3b8a2845ba (MD5) Previous issue date: 2015 / Resumo: Essa pesquisa compreende a aplicação de técnicas de espectroscopia de refletância e imageamento hiperespectral aeroportado visando o aprimoramento de métodos e sistemas de monitoramento de solos expostos à vazamentos de hidrocarbonetos (HCs), em instalações petrolíferas. O trabalho compreendeu um experimento em ambiente de laboratório, onde contaminações controladas foram realizadas buscando-se simular, em escala reduzida, solos impactados por vazamentos de HCs. Os principais objetivos do experimento foram os seguintes: (i) caracterizar as assinaturas espectrais dos solos impregnados com HCs, em diferentes proporções, no intervalo do espectro visível e infravermelho (350 ¿ 2500 nm); (ii) descrever as principais feições de absorção espectral diagnósticas da presença do HC; (iii) estabelecer os limites de detecção do HC na mistura; (iv) gerar modelos matemáticos de simples aplicação, que permitam estimar o tipo e volume de HCs envolvido na contaminação. Considerando a base gerada nas investigações experimentais, em um segundo passo, técnicas digitais de extração de informações espectrais foram aplicadas a um conjunto de imagens hiperespectrais adquiridas sobre instalações petrolíferas e áreas experimentais de vazamentos de HCs líquidos em escala real. Como resultado, foi possível identificar a distribuição espacial de solos e outros alvos potencialmente contaminados nessas áreas, cujos principais focos foram comprovados no campo. O estudo sugere o grande potencial de aplicação destas tecnologias ultraespectrais e hiperespectrais no monitoramento de solos em torno das linhas de transporte de petróleo e de refinarias, o que pode contribuir para aquilatar a segurança e desempenho operacional de dutos de transporte e armazenamento de HCs na indústria do petróleo / Abstract: This research involves the application of reflectance and imaging spectroscopy techniques to improve methods and systems to monitor bare soils contaminated by hydrocarbon (HC) leaks in petroleum refinaries and pipelines. The study involves an experiment, conducted under laboratory conditions; where controlled contaminations were made aiming to simulate, in a small scale, soils contaminated with hydrocarbon leaks. The main objectives of the experiment are the following: (i) to characterize the spectral signature of contaminated soils, with several proportions of HCs, within visible and infrared wavelengths (350 ¿ 2500 nm); (ii) to describe the main, diagnostic absorption bands linked to the presence of HCs, (iii) to establish concentration limits for the detection of HCs in substrate mixtures; (iv) to generate simple models to estimate the HC type and impregnation level involved in the contamination. The comprehensive spectral libraries yielded during the laboratory experiments were used, in a second step, as an input for the application of digital information extraction techniques to hyperspectral image datasets acquired on real petroleum facilities and field experimental areas of liquid HC leaks. Given such representative scenarios, it was possible to identify the spatial distribution of soils and other potentially contaminated targets in these areas, which were verified further in the field and corresponded to sites with leaks. The study suggests the great potential for intelligent use of ultraspectral and hyperspectral technologies for monitoring soils around pipelines and refineries, adding to the safety and operational performance of oil pipelines and storage in the petroleum industry / Doutorado / Geologia e Recursos Naturais / Doutora em Ciências