An investigation to assess the anthropogenic pollutant loads, transport and impact on shallow groundwater in one of Kampala’s peri-urban areas (Bwaise III Parish) was undertaken. Bwaise III is a densely populated informal settlement with a high water table (<1.5 m) and inadequate basic social services infrastructure (e.g, sanitation, safe water supply, roads, etc). Field surveys were undertaken to identify, locate and quantify various pollutant sources. Information on the usability and operational aspects of the excreta and solid waste management systems was obtained from consultations with the residents. Water from installed monitoring wells and one operational protected spring and wastewater (sullage) characteristics (quality, discharges for drains and spring, water levels for the wells) as well as soil characteristics (soil stratigraphy, physical and chemical) were determined through field and laboratory measurements. Laboratory batch experiments were undertaken to estimate phosphorus sorption potential of the soils. The results reveal that excreta disposal systems, solid waste and sullage are the major contributors to shallow groundwater contamination. High contaminant loads from these sources accumulate within the area resulting in widespread contamination. The water table responds rapidly to short rains (48hr) due to the pervious and shallow (<1 m) vadose zone, which consists of mostly organic fill material. Rapid water quality deterioration (increased thermotolerant coliforms, organic content in the form of total kjedahl nitrogen, phosphorus) following rains potentially follows from leaching, desorption and macropore flow. Spatial variation of the water quality in the area is largely related to anthropogenic activities within the vicinity of the well sources. Animal rearing, solid waste dumps and latrines are seen to result in increased localised microbial and organic content during the rains. The spring discharge with high nitrate levels does not respond to short rains suggesting that this source is fed by regional baseflow. The corresponding high microbial contamination in this case is a result of observed poor maintenance of the protection structure leading to direct ingress of contaminated surface runoff. Natural attenuation of contaminants is very limited. Estimated bacteria die-off rates are very low, about 0.01hr-1, suggesting a high risk for microbial contamination. The soils still have potential to retain additional phosphorus, whose sorption is largely a function of iron, available phosphorus and moisture content of the soils. This is also seen with the model results in which the phosphorus contaminant plume sticks to the surface irrespective of the rainfall infiltration rates. Simulation results show that continuous heavy intense rains (> 0.25mm/min) result in rapid flooding occurring within 1hr to 2 days. With lower rains, the water table does not rise to the surface, and no flooding takes place. Protection of the shallow groundwater in the area requires socio-technical measures targeting reduction of pollutant loads within the area as well as a wider spring catchment. Re-protection of the spring, coupled with awareness creation, should be immediately addressed so as to reduce microbial contamination. Community participation in solidwaste management should be encouraged. Resource recovery systems such as composting of the mostly organic waste and use of ecological sanitation toilet systems should be piloted in the area. Successful operation of the systems however depends on continuous sensitisation of the communities. / QC 20101207

Here the nature of gas phase processes and their implications for flow and transport were examined using a pilot-scale, 2-dimensional, laboratory tank instrumented for direct, in situ trapped gas measurements. Experimental conditions mimicked an unconfined, homogeneous sand aquifer with horizontal flow. Key areas of investigation included i) trapped gas dissolution following a water table fluctuation; and ii) gas phase dynamics within a hydrocarbon plume experiencing dissolved gas production via biodegradation. In the first experiment, dissolution occurred as a diffuse, wedge-shaped front propagating down-gradient in the tank over time, with enhanced dissolution at depth. Front advancement at the deepest monitoring point was 4.1 - 5.7x faster. This dynamic, depth-dependent pattern was mainly attributed to increased dissolved gas solubility. An estimated 12% increase in quasi-saturated hydraulic conductivity (Kqs) also contributed to greater dissolution at depth. Overall, the dissolution front near the water table advanced 1 m down-gradient in 344 days, suggesting that gas trapped shallowly will likely persist for significant periods of time. The utility of total dissolved gas pressure sensors for simple in-well measurements to detect trapped gas and monitor its dissolution were also demonstrated. During the second experiment, biodegradation occurred under variable redox conditions, ranging from denitrification to methanogenesis. Significant in situ increases in trapped gas were observed within the tank over 330 days. Maximum gas saturations never exceeded 27% of pore volume even during continued dissolved gas production, indicating ebullition upon reaching a gas phase mobilization threshold. Consequently, associated reductions in Kqs were restricted to a factor of 2 or less, but still appeared to alter the groundwater flow field. While trapped gas increases within the biodegradation plume were expected, declines in gas saturations were also observed. Thus, the overall pattern of trapped gas growth exhibited high spatial and temporal variability. Influencing factors included changes in hydrocarbon inputs and microbial controls on redox zonation, in addition to ebullition and changes in groundwater flow; emphasizing that gas phase growth in contaminant plumes will be highly complex and dynamic in the natural systems. Given the impacts on hydraulic conductivity, and the fate and transport of volatile compounds, an improved understanding of quasi-saturated conditions will be beneficial for various groundwater applications, from recharge and paleoclimate studies to site characterizations and remediation strategies. / Dissertation / Doctor of Philosophy (PhD)

Potatoes (Solanum tuberosum) were grown in a fine sandy loam soil in southern Manitoba in a three-year field study comparing four water management treatments: No Drainage with No Irrigation (NDNI), No Drainage with Overhead Irrigation (NDIR), Free Drainage with Overhead Irrigation (FDIR), and Controlled Drainage with Subirrigation (CDSI). The objectives of the study were (i) to evaluate the effect of the four treatments on yield and quality of potatoes, (ii) to evaluate the effect of water management on the environment, (iii) to estimate the shallow groundwater contribution to potato water requirement, and (iv) to simulate the shallow groundwater hydrology using the DRAINMOD and HYDRUS 1-D model. Subsurface drains were installed at 0.9 m depth and at spacings of 15 m (FDIR) and 8 m (CDSI). Subirrigation was done by pumping water back into the tiles through the drainage control structures. Overhead irrigation was carried out using a travelling gun. Water table depth, soil water content, drainage outflow, nutrient concentration in drainage water, irrigation rate, weather variables, potato yield and quality parameters, and biomass were measured. Compared to the NDNI treatment, the potato yield increase in the other treatments ranged between 15-32% in 2011 and 2-14% in 2012. In 2011, potato yield from FDIR was higher than CDSI (p = 0.011) and NDNI (p = 0.001), and yield from NDIR was higher than NDNI (p = 0.034). In 2012, potato yield was higher in FDIR in comparison to NDNI (p = 0.021). In 2012, the NDIR gave higher dark ends (p = 0.008) compared to other treatments. Under dry conditions, up to 92% of the potato crop water demand could be met by shallow groundwater contribution. Compared to free drainage, controlled drainage was able to lower the nitrate export by 98% (p = 0.033) in 2010 and by 67% (p = 0.076) in 2011, and the phosphate export decreased by 94% (p = 0.0117) in 2010. A major part of the drainage flow and nutrient export took place between April and June in southern Manitoba. DRAINMOD was able to accurately predict the shallow groundwater hydrology for this particular research site.