Evaporators separate liquids from solutions. For maximum efficiency, designers reduce the temperature difference between the heating and heated media using multiple-stage evaporators. This efficiency requires increased size and bulk. A vendor claimed its thermal compression evaporator achieved high efficiency with only two stages. It did not function as claimed. This project investigated the evaporator's design to identify its problems and propose an alternative design with a minimized footprint. The analysis showed theoretical flaws and design weaknesses in the evaporator, including violation of the first law of thermodynamics. An alternative thermal compressor design was created through computational fluid dynamics using spreadsheet methods developed in house, aided by the software product FLUENT. Detailed component sizing was done using the software product HYSYS. The proposed redesign achieved four to one efficiency with two stage thermal compression, using one half of the space of a traditional system of similar performance.

Chan Chun Wai = 納米鈀硅合金的熱性質 / 陳進偉. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2000. / Includes bibliographical references (leaves 18-20). / Text in English; abstracts in English and Chinese. / Chan Chun Wai = Na mi ba gui he jin de re xing zhi / Chen Jinwei. / Acknowledgements --- p.III / Abstract --- p.IV / 摘要 --- p.V / Chapter Chapter One ´ؤ --- Introduction / Chapter 1.1 --- Novel materials in the 21st century --- p.1 / Chapter 1.2 --- What are Nanocrystalline Materials? --- p.1 / Chapter 1.3 --- The superior properties of Nanocrystalline Materials --- p.2 / Chapter 1.4 --- Fabrication of Nanocrystalline Materials --- p.3 / Chapter 1.5 --- Flaws of the as-produced Nanophase Materials --- p.4 / Chapter 1.6 --- Theory of Phase Separation --- p.4 / Chapter 1.7 --- Nucleation and Growth --- p.6 / Chapter 1.7.1 --- Homogeneous nucleation / Chapter 1.7.2 --- Heterogeneous nucleation / Chapter 1.8 --- Spinodal Decomposition / Chapter 1.8.1 --- How SD differs from the classical diffusion process? / Chapter 1.8.2 --- Dynamics of SD / Chapter 1.8.3 --- How can we distinguish SD from Nucleation and Growth? / Chapter 1.8.4 --- Pore-free nanophase materials produced by Liquid Phase SD / Chapter 1.9 --- Thermal properties of the pore-free nanostructured Pd82Si18 Alloy --- p.12 / Chapter 1.9.1 --- A review of grain growth in nanophase materials / Chapter 1.9.2 --- Grain growth study on LSD Pd82Si18 alloy 一 aim and prospect / References --- p.18 / Figures --- p.21 / Chapter Chapter Two 一 --- Experimental / Chapter 2.1 --- Introduction --- p.28 / Chapter 2.2 --- From preparation of samples to microstructure analysis --- p.28 / Chapter 2.2.1 --- Alloying / Chapter 2.2.2 --- Fluxing / Chapter 2.2.3 --- Rapid Solification / Chapter 2.2.4 --- Annealing / Chapter 2.2.5 --- Microstructure analysis / Figures --- p.31 / Chapter Chapter Three ´ؤ --- Results and discussions / Thermal stability of bulk nanostructured alloys prepared by liquid phase spinodal decomposition --- p.34 / References --- p.40 / Table --- p.43 / Figures --- p.44 / Chapter Chapter Four ´ؤ --- Conclusions --- p.61

Chapter 1 briefly introduces the theoretical background of the association and dissociation of polymer chains or colloidal particles are briefly introduced, including thermodynamic consideration and viscoelastic effect on the formation of mesoglobular phase in dilute polymer solutions, as well as some basic theories and universal models of fractal aggregates. / Chapter 2 details the theories of static and dynamic laser light scattering (LLS) as well as the instrumental set-up. In addition, the invention and set-up of differential refractometer are briefly discussed. / Chapter 3 summarizes laser light-scattering (LLS) and stopped-flow studies of association of cyclic- and linear-poly( N-isopropylacrylamide) (c-PNIPAM and l-PNIPAM) chains in dilute aqueous solutions. Dynamic and static LLS results reveal that the heating leads to a microphase transition. Resultant structures of interchain aggregates depend on the heating rate and the chain structure. In comparison with l-PNIPAM chains, a slow heating of c-PNIPAM chains in the solution results in stable mesoglobules with a lower average aggregation number, a looser structure and a smaller average size (∼290 nm). The temperature-jump induced association of c -PNIPAM chains in the stopped-flow measurement reveals two kinetic stages; namely, the loose packing of contracted c-PNIPAM chains and further contraction-induced fragmentation of initially packed c-PNIPAM chains due to the lack of interchain entanglements. On the other hand, for l-PNIPAM chains, the intrachain contraction and interchain penetration/entanglement simultaneously occur as the temperatures increases, leading to larger and more compact aggregates whose size increases with the solution temperature. / Chapter 4 discusses the association of water-soluble PNIPAM-monolayer-protected gold particles in dilute dispersions induced by heating the dispersions to different final temperatures higher than the lower critical solution temperature (LCST) of PNIPAM chains via the slow and fast processes. LLS was used to trace and characterize the association process, supplemented by transmission electron microscopy (TEM) measurements. The slow heating-and-cooling cycle reveals that the association and dissociation of PNIPAM-protected gold nanoparticles can be easily induced by altering the solution temperatures and the association and dissociation are fully reversible. Fast heating the dispersion to three different temperatures reveals that both the aggregation rate and average aggregation number increase with the dispersion temperature. Furthermore, the fast heating leads to the formation of fractal aggregates. The fractal dimensions of such formed aggregates continuously increases as the time evolves, which can be ascribed to the simultaneous dissociation that leads to the restructuring and rearrangement of the aggregates, resulting in denser structures. It is interesting to note that the structure of aggregate always remains fractal during the whole process. / Chapter 5 shows how water-dispersible nanosized semiconductor CdS particles (quantum dots, QDs) can be synthesized with a protective layer of covalently grafting linear thermally sensitive PNIPAM chains as well as how these CdS particles can be induced into reversible association and dissociation via an alteration of the dispersion temperature. The formation and fragmentation of these QDs aggregates were systematically investigated by laser light scattering (LLS) and confirmed by transmission electron microscopy (TEM). There exists a hysteresis in one heating-and-cooling cycle. The CdS particles stabilized with shorter PNIPAM chains (Mn = 15,000 g/mol) can associate to form larger and denser spherical aggregates with a much higher aggregation number than those grafted with longer PNIPAM chains ( Mn = 31,000 g/mol) in the heating process. The dissociation (fragmentation) in the cooling process has two stages: initially, the aggregates dissociate as the temperature decreases, and then, the fragmentation stops over a wider temperature range before its final complete dissociation at a lower temperature. We attribute such a two-stage fragmentation to a balanced effect of inter- and intra-chain hydrogen bonding as well as to the hydrophobic interaction between PNIPAM chains and CdS particles. / In this Ph.D. thesis, temperature-induced association and dissociation of various polymeric systems were systematically investigated by a combination of static and dynamic laser light scattering (LLS), supplemented by other methods, such as stopped-flow temperature jump, transmission electron microscopy (TEM), and Fourier transform infrared spectroscopy (FTIR). / Ye, Jing. / Adviser: Wu Chi. / Source: Dissertation Abstracts International, Volume: 70-06, Section: B, page: 3533. / Thesis (Ph.D.)--Chinese University of Hong Kong, 2008. / Includes bibliographical references. / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Electronic reproduction. [Ann Arbor, MI] : ProQuest Information and Learning, [200-] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Abstracts in English and Chinese. / School code: 1307.

by Chua Lai Fei Joseph. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1996. / Includes bibliographical references. / by Chua Lai Fei Joseph. / ACKNOWLEDGMENTS --- p.2 / ABSTRACT --- p.3 / Chapter CHAPTER 1: --- INTRODUCTION --- p.5 / Chapter 1.1 --- METALLIC GLASS --- p.5 / Chapter 1.2 --- SOLIDIFICATION PROCESS OF AN ALLOY --- p.7 / Chapter 1.2.1 --- COOLING PATH --- p.7 / Chapter 1.2.2 --- FREE VOLUME MODEL --- p.8 / Chapter 1.2.3 --- NUCLEATION --- p.9 / Chapter 1.2.4 --- LIQUID PHASE SEPARATION --- p.10 / Chapter 1.3 --- IDEAS ON SOME CHARACTERISTIC PARAMETER OF GLASS AND GLASS FORMING ABILITY OF AN METALLIC ALLOY --- p.11 / Chapter 1.3.1 --- CORRELATION FOR THE EXPANSION COEFFICIENT AND THE GLASS TRANSITION TEMPERATURE --- p.11 / Chapter 1.3.2 --- CORRELATION FOR THE GLASS FORMING ABILITY WITH CRYSTALLINE COMPOUNDS/SOLID-SOLUTIONS --- p.12 / REFERENCES --- p.13 / Chapter CHAPTER 2: --- EXPERIMENTAL --- p.17 / Chapter 2.1 --- SAMPLE PREPARATION --- p.17 / Chapter 2.2 --- EXPERIMENTAL DETAILS FOR ALPHA MEASUREMENT --- p.17 / Chapter 2.3 --- EXPERIMENTAL DETAILS FOR FINDING EQUILIBRIUM PHASES AND GLASS FORMING ABILITY OF AN ALLOY --- p.20 / Chapter 2.3.1 --- FINDING EQUILIBRIUM PHASES --- p.20 / Chapter 2.3.2 --- FINDING GLASS FORMING ABILITY --- p.21 / Chapter CHAPTER 3: --- CORRELATION FOR THERMAL EXPANSION COEFFICIENTS OF MOLTEN GLASS FORMING SYSTEMS --- p.28 / REFERENCES --- p.37 / Chapter CHAPTER 4: --- CORRELATION FOR THE GLASS FORMING ABILITY OF PD83.5-XCUXSI16.5 WITH CRYSTALLINE COMPOUNDS/SOLID- SOLUTIONS --- p.38 / Chapter 4.1 --- INTRODUCTION --- p.39 / Chapter 4.2 --- EXPERIMENTAL --- p.39 / Chapter 4.3 --- RESULTS --- p.41 / Chapter 4.4 --- DISCUSSION --- p.43 / REFERENCES --- p.54 / Chapter CHAPTER 5: --- CONCLUSION --- p.55

The failure of integrated circuit due to Silicon fracture is one of the problems associated with the production of a semiconductor device. The thermal stresses, which result in die cracking, are for the most part induced during the cooling process after attaching the die with Gold-Silicon solder. Major factors for stress generation in material systems are commonly large temperature gradients and substantial difference in coefficients of thermal expansion.

Pure aluminum deformed in torsion (shear) at elevated temperatures reaches a broad "peak" stress and then undergoes about a 17% decrease in flow stress with deformation to roughly 1-2 equivalent uniaxial strain. Beyond this strain the flow stress is approximately constant. The sources for this softening are unclear. The suggested basis includes texture softening, microstructural softening, and enhanced dynamic recovery. Experiments were performed where specimens were deformed in torsion to various strains within the softening regime followed by compression tests at ambient and elevated temperature. Analysis of the compressive yield strengths indicate that the softening is at least substantially explained by a decrease in the average Taylor factor due to the development of texture. / Graduation date: 2002

Graduation date: 2004

Graduation date: 2004

By the investigation of the bulk metallic glass-forming liquids that have very low critical cooling rates, the thermodynamics of metallic glasses can be clarified. For studying thermodynamic properties, such as the specific heat capacity, calorimetry (DSC) is utilized and one of the most used instruments is the differential scanning calorimeter. In this study calorimetry was used to investigate the thermodynamics of the Pd������Ni������Cu������P������ alloy. The specific heat capacity of the liquid and crystalline state, enthalpy, entropy, as well as Gibbs free energy difference between the liquid and crystalline state were measured and evaluated in comparison with previous studies of the alloy. The Pd������Ni������Cu������P������ alloy is known as a metallic glass-forming alloy that has high ability for vitrification without crystallization. By observing the onset of heat flux of the exothermic reactions in the DSC, the time-temperature-transformation diagram can be constructed, and the diagram confirms the high ability for the vitrification for the sample. In addition, the effect of fluxing by B���O��� to reduce heterogeneous nucleation is determined by the TTT-diagram. The enthalpy change during the crystallization was directly measured in experiments in which the sample was held isothermally in the DSC. Both enthalpies, calculated from the specific heat capacity measurements and direct measured enthalpy exactly match each other. The very interesting effect in these experiments is an effect of heat treatment in the samples. Two glass transition temperatures can be noticeably recognized by scanning the exothermic event of the sample with the DSC. The material separates into two undercooled liquids. The two phases that are separated during heat treatment can be described by two different fragility parameters. / Graduation date: 2001

Thesis(M.S.)--Case Western Reserve University, 2009 / Title from PDF (viewed on 2010-01-28) Department of EMC - Mechanical Engineering Includes abstract Includes bibliographical references and appendices Available online via the OhioLINK ETD Center