Thesis (Ph. D.)--University of Missouri-Columbia, 2001. / Typescript. Vita. Includes bibliographical references (leaves 373-387). Also available on the Internet.

Thesis (Ph. D.)--University of Missouri-Columbia, 2001. / Typescript. Vita. Includes bibliographical references (leaves 373-387). Also available on the Internet.

Monitoring data for potable water in the R.M. of Macdonald regional water system indicates elevated levels of chlorine disinfection by-products (DBPs), trihalomethanes (THMs). Dissolved Organic Carbon (DOC) and chlorine dose are the key precursors for the formation of THMs. Currently, the DOC is not removed efficiently at the Sanford water treatment plant, which supplies the R.M.’s potable water distribution system. The raw water DOC concentration incoming to the plant varied from 8.9mg/L to 31.8mg/L during this study. Sanford treated water effluent contained an average DOC of 6.5mg/L and the THM levels ranged from 86.6ppb to 175.7ppb. One of the objectives of this study was to conduct jar tests to optimize Sanford’s water treatment process to improve removal of DOC. Optimization of the coagulation process successfully reduced the DOC level in the plant effluent by 51% during the summer and 34% in the winter. The DOC reduction resulted in a THM reduction of 73.5ppb in the summer and 59.9ppb during the winter. Results showed that removal of 1mg/L of DOC eliminates 26.8ppb of THMs in summer and 11.9ppb during the winter. Another goal of this project was to investigate the relationship between THMs and their precursors, which includes: water DOC, free chlorine residual, and the chlorine contact time. Water samples were strategically collected throughout the Sanford regional water distribution system; the samples were tested for DOC, UV254, SUVA, chlorine residual, and contact time. A linear relationship between THM formation and chlorine contact time (R2 of 0.92) was found. This indicates that the content of THMs can be decreased by reducing the amount of time the water stays in the distribution system.

Monitoring data for potable water in the R.M. of Macdonald regional water system indicates elevated levels of chlorine disinfection by-products (DBPs), trihalomethanes (THMs). Dissolved Organic Carbon (DOC) and chlorine dose are the key precursors for the formation of THMs. Currently, the DOC is not removed efficiently at the Sanford water treatment plant, which supplies the R.M.’s potable water distribution system. The raw water DOC concentration incoming to the plant varied from 8.9mg/L to 31.8mg/L during this study. Sanford treated water effluent contained an average DOC of 6.5mg/L and the THM levels ranged from 86.6ppb to 175.7ppb. One of the objectives of this study was to conduct jar tests to optimize Sanford’s water treatment process to improve removal of DOC. Optimization of the coagulation process successfully reduced the DOC level in the plant effluent by 51% during the summer and 34% in the winter. The DOC reduction resulted in a THM reduction of 73.5ppb in the summer and 59.9ppb during the winter. Results showed that removal of 1mg/L of DOC eliminates 26.8ppb of THMs in summer and 11.9ppb during the winter. Another goal of this project was to investigate the relationship between THMs and their precursors, which includes: water DOC, free chlorine residual, and the chlorine contact time. Water samples were strategically collected throughout the Sanford regional water distribution system; the samples were tested for DOC, UV254, SUVA, chlorine residual, and contact time. A linear relationship between THM formation and chlorine contact time (R2 of 0.92) was found. This indicates that the content of THMs can be decreased by reducing the amount of time the water stays in the distribution system.

Thesis (M.S. - Hydrology and Water Resources)--University of Arizona, 1988. / Includes bibliographical references (leaves 115-117).

Thesis (M.Eng.)--Memorial University of Newfoundland, 2000. / Bibliography: p. 145-150.

Thesis (M.S.)--Virginia Polytechnic Institute and State University, 1992. / Vita. Abstract. Includes bibliographical references (leaves 104-106). Also available via the Internet.

Neste trabalho desenvolveu-se uma metodologia analítica para determinação do teor de trialometanos THMs em amostras de águas potáveis, utilizando a técnica de purga e armadilha acoplada à cromatografia a gás (GCPT). Os THMs são subprodutos da cloração da água que devem possuir um limite máximo de 100 μg.L-1 segundo a legislação brasileira, estes compostos são suspeitos carcinogênicos humanos com base em estudos em animais de laboratório. A técnica de purga e armadilha extrai eficientemente estes compostos da água e a separação no cromatógrafo a gás ocorre utilizando coluna de leve polaridade e detector por captura de elétrons. Este detector é seletivo e o mais sensível para estes compostos halogenados. A metodologia desenvolvida foi validada nos itens de: linearidade, seletividade, exatidão, precisão, limite de quantificação, limite de detecção e robustez. O limite de detecção para os THMs foi menor do que 0,5 μg.L-1. A exatidão e precisão foram adequadas para ensaios de compostos traços. As amostras de água potável foram coletadas na cidade de Suzano-SP, que pertence à região do Alto do Tietê, nesta região nas margens do rio a vegetação é predominante. Entre todos os THMs, o composto encontrado na água potável em maiores concentrações foi o clorofórmio onde os resultados quantitativos, utilizando esta metodologia apresentaram teores entre 15,9 à 111,0 μg.L-1 em águas potáveis. / This work shows an analytical methodology developed and optimized to determine trihalomethanes level THMs, in drinking water samples, using purge and trap coupled to gas chromatography (GC-PT). THMs are byproducts water chlorination, these compounds must have a maximum of 100 μg.L-1 under Brazilian law, due these compounds be suspected human carcinogens base on studies in laboratory animals. The technique of purge and trap efficiently extracts these compounds from water, and the gas chromatograph separates the THMs. The GC uses a light polarity column and electron capture detector. This detector is selective and more sensitive in the detection of these compounds. The methodology was validated in terms of: linearity, selectivity, accuracy, precision, quantification limit, detection limit and robustness. The detection limit was less than 0,5 μg.L-1. The accuracy and precision were adequate for testing the trace compounds. The drinking water samples were collected in the city of Suzano-SP, which belongs to Alto do Tietê, in this region lay Tietê river with predominant vegetation. The THMs compound found in drinking water at higher concentrations was chloroform where the spread of values found between 15,9 to 111,0 μg.L-1 in drinking water.

The progress in the computing and communication industries together with the fast evolution of the semiconductor industry has made possible advances in the communications field. These advances have been used by other related applications to improve the services that they bring about. On the other hand, business crimes have increased three digits orders of magnitude in one decade, making from 20% to 30% of small businesses fail. These conditions demand new solutions to make security systems more reliable and efficient. The present work combines ISDN as a network with a security system to create a security network (SECNET). It will create intelligent and distributed security devices that communicate information from different places to a main security office by using the ISDN lines available at the premises. This work also introduces a new idea of individual equipment protection.

No description available.