In the scope of this diploma thesis the optical properties of organic multilayers and mixed layers were investigated by means of spectroscopic ellipsometry und infrared spectroscopy. The samples were prepared by organic molecular beam deposition in high vacuum on hydrogen passivated Silicon(111) substrates. The structures consist either of N,N-Di(naphthalene-1-yl)-N,N`-diphenyl-benzidine (a-NPD) and tris(8-hydroxyquinoline) aluminium (Alq3) or 3,4,9,10-perylene-tetracarboxylic dianhydride (PTCDA) and copper phthalocyanine (CuPc). The optical response of the multilayers consisting of Alq3 and a-NPD could be modelled using the isotropic dielectric functions of single layers assuming sharp interfaces. The planar structure of PTCDA and the CuPc molecules and their orientation in the stack lead to an overlapping of the p-orbitals strongly influencing the optical properties and the orientation of the molecules. It was found that in multilayers as well as in mixed layers the CuPc molecules adopt the orientation of PTCDA molecules with the molecular plane parallel to the substrate. The multilayers were described using the anisotropic dielectric functions of the constituents including intermixing and roughness at the interfaces. The deviation between the simulation and the experiment suggests an electronic interaction due to coupling between the p-orbitals of CuPc and PTCDA at the interfaces. The simulation of the mixed layers reveals a change in line shape of the Q-band of CuPc. Beside ellipsometry and infrared spectroscopy techniques like x-ray reflectometry and AFM were used for investigations. Additionally in this diploma thesis a special sample holder and manipulator was designed with which in-situ-ellipsometry measurements in ultra high vacuum can be performed. / Im Rahmen dieser Diplomarbeit wurden die optischen Eigenschaften von organischen Multilayern und Mischschichten untersucht. Die Schichtstrukturen wurden im Hochvakuum nach dem Verfahren der organischen Molekularstrahldeposition (OMBD) auf H-passivierten Silizium(111)-Substraten hergestellt. Die optische Charakterisierung erfolgte mit dem Verfahren der spektroskopischen Ellipsometrie und der Infrarotspektroskopie. Dabei wurden zwei verschiedene Materialienpaarungen untersucht, die zum einen aus den organischen Substanzen Aluminium 8-Hydroxichinolat (Alq3) und N,N'-Di(1-naphthyl)-N,N'-diphenylbenzidin (a-NPD) und zum anderen aus Perylentetracarbonsäuredianhydrid (PTCDA) und Kupferphthalocyanin (CuPc) bestanden. Das optische Verhalten der Multilayer und der Mischschichten bestehend aus Alq3 und a-NPD konnte mit den isotropen dielektrischen Funktionen der Einzelschichten simuliert werden. In den PTCDA/CuPc-Schichtsystemen führt die planare Struktur der Moleküle zu einer starken Überlappung der p-Orbitale, was einen großen Einfluss auf die optischen Eigenschaften und die Orientierung der Moleküle hat. Es wurde festgestellt, dass sowohl in den Multilayern als auch in den Mischschichten die CuPc-Moleküle die Anordnung der PTCDA-Moleküle annehmen. Die Multilayer wurden unter Verwendung der anisotropen dielektrischen Funktionen der beteiligten Materialien und unter Berücksichtigung von Grenzflächenrauhigkeit simuliert. Die Unterschiede zwischen Experiment und Modell sind auf eine Kopplung zwischen den p-Orbitalen zurückzuführen. Die Simulationen der Mischschichten zeigten eine Veränderung der Linienform des Q-Bandes von CuPc. Als Untersuchungsmethoden kamen neben der Ellipsometrie und der Infrarotspektroskopie auch die Röntgen-Reflektometrie und das AFM zum Einsatz. Darüber hinaus wurde in dieser Arbeit eine Messeinrichtung aufgebaut, mit der in-situ-Ellipsometriecharakterisierung von Proben im Ultrahochvakuum möglich ist.

Univ., Akad. avh.--Göteborg, 2006.

Texte remanié de : Dissertation : ? : ? : 1997. / Comprend : Text ; Plates. Bibliogr. p. 258-266 (vol. 1). Index.

No description available.

Because of their abundance and because of the insight into the ancient world offered by the depictions on their decorated surfaces, Attic painted ceramics are an extremely valuable source of material evidence. Knowing the identities and personalities of the artists who painted them not only helps us understand the paintings, but also helps in the process of dating them and, in the case of sherds, reconstructing them. However, few of the artists signed their wares, and the identities of the artists have to be revealed through a close analysis of the style in a process called attribution. The vast majority of the attributions of archaic Attic vases are due to John Beazley whose monumental works set the stage for the dominance of attribution studies in the scholarship of Greek ceramics for most of the 20th century. However, the number of new scholars trained in this arcane art is dwindling as new avenues of archaeological research have gained ascendency. A computer-aided technique for attribution may preserve the benefits of the art while allowing new scholars to explore previously ignored areas of research. To this end, the present study provides a theoretical framework for computer-aided attribution, and using the corpus of the Princeton Painter - a painter active in the 6th century BCE - demonstrates the principal that, by employing pattern recognition techniques, computers may be trained to serve as an aid in the attribution process. Three different techniques are presented that are capable of distinguishing between paintings of the Princeton Painter and some of his contemporaries with reasonable accuracy. The first uses shape descriptors to distinguish between the methods employed by respective artists to render minor anatomical details. The second shows that the relative positions of cranial features of the male figures on black-figure paintings is an indicator of style and may also be used as part of the attribution process. Finally a novel technique is presented that can distinguish between pots constructed by different potters based on their shape profiles. This technique may offer valuable clues for attribution when artists are known to work mostly with a single potter. / Thesis (Ph.D.)-University of KwaZulu-Natal, Durban, 2009.

The aim of this dissertation was to investigate the representation of specific types of animals as they occurred in Homer and archaic Attic black figure vase painting with a view to understanding bow they were most likely perceived in antiquity. This involved determining the underlying concepts around which each animal was constructed by comparing and contrasting the imagery presented in the Homeric works and archaic Attic black figure vase painting. The primary objective was to suspend modern and westernized conceptions and to attempt to approach the animal as from an ancient perspective. The Homeric works were chosen as representative of the literary evidence since these poems offer the most complete, oldest extant literature and are the result of a dynamic and continuous oral tradition. Similarly, archaic Attic black figure vase painting was considered the most suitable corpus of artistic evidence since the 6th century BC was a time when the artists actively engaged with and manipulated their themes and subject matter within an established tradition; this artistic fabric presents a parallel with the Homeric evidence. As a result of this investigation, clear and discrete concepts and images were determined for each animal. / Thesis (M.A.)-University of Natal, Durban, 2000.

Ce travail aborde la problématique des systèmes de refroidissement ou de contrôle thermique industriels. Nous avons particulièrement mis l'accent sur le refroidissement des serveurs informatiques. Une première partie consiste en l'étude des moyens d'amélioration des techniques de refroidissement existantes, tandis que la deuxième partie est une réflexion sur des techniques de refroidissement alternatives potentiellement plus efficaces et répondant aux demandes actuelles du contrôle thermique industriel. Dans le premier chapitre, nous analysons la bibliographie et la théorie relatives aux phénomènes physiques derrière les techniques de refroidissement étudiées. Ensuite, une classification des techniques de refroidissement est proposée en fin de chapitre. Ce chapitre a servi de base pour l'amélioration des technologies de refroidissement existantes et à la réflexion sur de nouvelles techniques plus efficaces. Le second chapitre porte sur l'optimisation d'une plaque froide, destinée au refroidissement des serveurs informatiques, en s'aidant d'un outil numérique et d'essais expérimentaux. Nous avons noté une augmentation des transferts de chaleur dans la plaque froide en utilisant des inserts, notamment ceux en forme de losange disposés en quinconce. A l'inverse, l'utilisation de certains nanofluides en tant que fluides caloporteurs ne semble pas apporter de gain significatif. Dans le troisième chapitre nous détaillons la démarche suivie pour la conception d'un dissipateur de chaleur basé sur une technologie caloducs, destiné au refroidissement des cartes électroniques. En premier lieu, nous présentons le modèle thermohydraulique de dimensionnement d'un caloduc cylindrique ; une étude paramétrique (géométrique, type de fluide,...) nous a permis d'identifier le jeu de paramètres donnant la meilleure performance du caloduc. En second lieu, nous évoquons les tests réalisés sur le dissipateur de chaleur à caloduc qui nous amènent à valider en partie le modèle thermohydraulique développé. Le dernier chapitre porte sur la réalisation et l'étude d'un démonstrateur pour le refroidissement des cartes électroniques par immersion dans un liquide à basse température de saturation. On commence par la mise en place et l'utilisation d'un modèle numérique pour la conception du démonstrateur, puis des tests expérimentaux sont réalisés. Les premiers résultats obtenus en utilisant le SES-36 comme fluide de travail sont assez prometteurs.Mots clés : modélisation, transfert de chaleur, refroidissement, datacenter, liquid-cooling, caloducs, échangeurs, nanofluides, ébullition en vase, simulation numérique

Acacia holosericea A. Cunn. Ex G. Don (Velvet Leaf Wattle, Family Mimosaceae) is indigenous to Australia and holds promise as a novel cut foliage crop due to its silvery green silky phyllodes. Insufficient water uptake, possibly due to low stem hydraulic conductivity (Kh), is potentially responsible for early wilting and desiccation of phyllodes and limiting vase life. This study aimed to characterize the anatomy of stem xylem conduits and determine cation (K+ and Ca2+) mediated stem Kh. Differential localization of Ca2+ in xylem vessels and the effects of KCl and CaCl2 salts as cation contributors in vase solutions were also evaluated for their effects on cut foliage longevity. Anatomical characteristics of stem xylem conduits were studied using light, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Tracheids and vessels with simple perforation plates were the principal water conducting cells. SEM and TEM revealed bordered vestured intervessel pits in xylem conduits. Vestures were branched and coralloid-like structures. Xylem conduit lengths were assessed by ink perfusion. The majority of conduits (89%) were short (1 to 5 cm), and only ~ 2% were long (15 to 16 cm). Mean conduit diameter was 77 ± 0.9 µm, with 29% of conduits in the range 70 to 80 µm. Effects of S-carvone (0, 0.318, and 0.636 mM), a monoterpene inhibitor of wound-healing enzyme inhibitor found in caraway (Carum carvi) and dill (Anethum graveoleus) seeds, on several native Australian, non-proteaceous cut flower and foliage species including A. holosericea (Mimosaceae), Baeckea frutescens (Myrtaceae), Chamelaucium uncinatum cv. ‘Mullering Brook’ (Myrtaceae), and the non-native Chrysanthemum sp. cv. ‘Dark Splendid Reagan’ (Asteraceae) were examined. As comparator treatments regular recutting of stem ends and use of standard tap water (STW: 0.7 mM CaCl2, 1.5 mM NaHCO3, and 0.05 mM CuSO4 in vases) were tested. S-Carvone treatments significantly (P≤0.05) extended the vase life of B. frutescens and C. uncinatum, constituting the first report of positive S-carvone effects on the vase life of Myrtaceous species. S-Carvone at 0.318 and 0.636 mM did not have antibacterial effects against Bacillus cereus (the main vase solution microbe) either in vitro or in the vase solution. Regular recutting of stem ends consistently improved all vase life parameters [viz. relative fresh weight (RFW), solution uptake, and vase life] in the three native species examined. STW had a positive effect on RFW and solution uptake only for A. holosericea cut foliage. Effects of di- and monovalent cations (Ca2+ as CaCl2 and K+ as KCl) on stem Kh of cut stem segments were studied. Abundance of Ca2+ on pit membranes versus xylem lumen wall surfaces was investigated using a novel low vacuum (LV) SEM plus energy dispersive X-ray (EDX) microanalysis technique. Both salts (0.1, 1, 10, and 100 mM KCl or CaCl2) did not significantly increase stem Kh compared to the corresponding deionised (DI) water controls (experiment 1). Highest increase in Kh was with KCl and CaCl2 at 10 and 1 mM, respectively. Increases in Kh with 100 mM KCl and CaCl2 were significant over DI water (experiment 2) for long (10 and 20 cm) and short (2 and 5 cm) stem segments, respectively. Increases in Kh of 1.2- and 2.4-fold for 100 mM KCl over DI water were found with increasing stem length from 2 to 20 cm. Kh decreased as stem segment length increased from 5 to 20 cm. However, contrasting results were found with 100 mM CaCl2, where ΔKh was larger in shorter (2 cm) than longer (20 cm) segments. To prevent dislocation of ions and distortion damage to the specimens, stem pieces were first LV freeze-dried, and then carbon-coated, viewed under SEM, and analysed for elemental composition and distribution by EDX. However, the method could not identify specific calcium peaks in xylem vessels perhaps because background signals were too high, and tissue topography interfered with signal detection. Effects of KCl and CaCl2 on vase life were also tested. RFW, solution uptake, and vase life were higher with 10 mM KCl and CaCl2 in the vase solution than with 0, 1, and 100 mM. STW had a significant (P≤0.05) positive effect on RFW and solution uptake rate when tested against deionised water, 10 mM KCl and 10 mM CaCl2. Different combinations of 0.05 mM CuSO4, 10 mM CaCl2, and 10 mM KCl were also tested as vase solutions. A significant positive effect on RFW and vase life was obtained with CuSO4 alone, CaCl2 alone, and CuSO4 plus KCl. Only CuSO4 and CaCl2 gave a significant positive effect on solution uptake rate. None of the eight treatments tested showed a consistent effect on stomatal conductance or stem Kh. Overall, the research revealed that tracheids and vessels with simple perforation plates and bordered vestured intervessel pits are the principal water conducting cells in A. holosericea. LV-SEM-EDX technique was unable to assess the spatial distribution of Ca2+ on xylem vessels, but this was the first attempt to apply this technique. Also, this is the first report on the extension of vase life of B. frutescens and C. uncinatum (Myrtaceous species) using S-carvone. In vase solutions, 0.05 mM CuSO4, 10 mM KCl plus 0.05 mM CuSO4 and 10 mM CaCl2 should have positive influences on the water balance of A. holosericea cut foliage stems.

Teilw. zugl.: Erlangen-Nürnberg, University, Habil.-Schr., 2003.

Univ., Diss--Münster (Westfalen), 1999.