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Synthesis and Characterization of Gd5Si2Ge2-Al Composite for Automobile ApplicationsBarkley, Brady C. 2010 May 1900 (has links)
This thesis research synthesizes a new class of composite materials and investigates their properties, performance, and potential applications. The new materials that are multi-phase and multifunctional are considered for use in car cooling systems, internal combustion engine waste-heat-power generators, and engine crack healing which are major problems plaguing the auto industry. This research uses primarily experimental approaches to study the magnetocaloric compound, Ge5Si2Ge2 (GSG), that has large strain effects. Such a material was formed into a composite using Al as a substrate. The newly developed composite, GSG-Al, is the first material of its kind that possesses self-healing effects in cracks.
X-ray diffraction was used to determine the crystal structures that existed within the material. It is found that the sintering process used to create the composite caused the formation of GdAlGe that is a magnetic compound with a high Curie temperature. The GSG-Al has a wide variety of crystal structures, ranging from face centered cubic for aluminum phases to monoclinic and orthorhombic phases for GSG. The discovery of GdAlGe confirmed that alpha-ThSi-type tetragonal and YAlGe-type orthorhombic crystal structures existed. Transmission electron microscopy (TEM) was used to analyze the wear debris collected during tribo-testing. The debris were also analyzed using energy-dispersive X-ray spectroscopy (EDS) for chemical analysis.
The GSG-Al was put through tribological studies at several different temperatures to determine the thermal effects on the composite. The GSG-Al, although found to be ductile, showed high resistance to wear when compared to a common aluminum alloy, Al 6061-T651. The wear rate decreased with increasing temperature when the temperature was increased from the room temperature to 150 degrees C. Results showed that with GSG, the composite did not show cracking common in Al alloys. This was due to the unique thermal expansion properties of the GSG-Al. The phase transformation induced a significant volume expansion in the material and thus a giant strain effect.
This research opens new approaches in energy conversion and improving efficiency of automobile engines. The composite developed here is important for future scientific investigation in the area of multifunctional materials as well as materials that exhibit self-healing tendencies.
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Revêtement anti-usure déposé par projection plasma sur matériaux composites fibres de carbones/matrice époxy pour applications aéronautiques / Air plasma spraying of wear resistant coatings on carbon fiber reinforced polymers for aeronautical applicationsElrikh, Axelle 15 December 2016 (has links)
Les matériaux composites à matrice polymères renforcés aux fibres de carbone (PRFC) sont de plus en plus utilisés dans les avions, en raison de leur faible densité et de leurs propriétés mécaniques comparables aux alliages généralement utilisés. Ils sont cependant sensibles aux impacts répétés des particules solides et liquides intervenant au cours du cycle de vol d’un avion, et nécessitent d’être protégés. Cette thèse est inscrite dans ce contexte de protection des PRFC, plus particulièrement ceux à matrice époxy, par le biais de dépôts anti-usure réalisés par projection plasma sous air. De tels recherche ont été menées auparavant avec pour résultats des dépôts céramique et métallique peu adhérents, sur des composites fortement endommagés par le procédé. Les travaux de cette thèse ont donc été organisés autour de deux objectifs :- Objectif fondamental : comprendre les interactions entre les particules fondues et le composite. Grâce à une étude multiéchelles d’impacts de gouttes sur le composite, la résine époxy et sa dégradation thermique ont été identifiés comme responsable de la mauvaise adhérence des dépôts projetés par plasma sur les PRFC.- Objectif expérimental. Déterminer la faisabilité de réaliser un revêtement anti-usure par projection plasma sur PRFC. Deux traitements de surface avant dépôt ont été choisis puis testés, en conditions d’impacts de particules isolées et de formation de dépôts. Des dépôts d’alumine ont pu être obtenus, sans dégradation thermique ou mécanique du composite. / Carbon fiber reinforced polymers (CFRP) are increasingly used in aircraft structures, due to their good strength to weight ratio. However, they are more sensitive to the impacts of solid and liquid particles, occurring during the aircraft flight cycle, and thus need to be protected. This work focuses on the protection of carbon fiber reinforced epoxy by air plasma spraying (APS). Numerous studies have been conducted on applying such coatings, but the obtained metallic and ceramic coatings show poor adhesion strength, and the underlying composite material is damaged by the APS process. This PhD is organized around two objectives:- Fundamental objective: understand the interactions between molten particles and the composite. A multi-scale study of droplets impacts on the composite led to identify the epoxy resin as responsible for the poor adhesion strength of air plasma sprayed coatings on CFRPs.- Experimental objective: determine the feasibility of producing an anti-wear coating by plasma spraying on CFRP. Two surface treatments prior to APS were chosen and tested in single particles impacts and coating formation. Alumina coatings have been obtained, without thermal or mechanical degradation of the underlying composite.
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Microstructure characteristics and tribological behaviour of plasma sprayed ceramic coatingsFadini, Luigi January 2023 (has links)
Surface engineering is increasingly becoming inevitable for meeting the high-performance requirements constantly expected from modern engineering components. Higher demands for combined functionalities, which a base material alone cannot provide, motivate intensive academic studies on various types of coatings, with the ultimate objective of their practical utilisation in industries. Especially the study of wear has become of critical importance for the industry development of new components, as wear-related mechanisms frequently compromise the durability and reliability of machines. Consequently, the need for effective wear control has become progressively vital in pursuing advanced and dependable technology for the future. Different coating technologies are being developed to forestall the wear of engineering components. More specifically, the thermal spraying technique of atmospheric plasma spraying (APS) has been proven particularly efficient in implementing thick film coating for aeronautic, automotive and medical applications. However, advanced coatings are required for improved performance and extended durability in harsh operating environments. These developments have stimulated research on developing novel coating through optimised deposition parameters and modified feedstock characteristics to achieve a more redefined microstructure. The primary scope of the research associated with this thesis is to target the study and research of plasma-sprayed ceramic coatings designed to provide exceptional wear resistance to targeted components as well as improved mechanical properties. The presented work involves an investigation of varying feedstock powder particle-size distributions, different coating chemistries and comparing the suspension plasma injection technology to its more traditional powdered feedstock variant. The result obtained suggested that the influence of powder-size particles affects the resultant microstructure with a finer composition, denoted by a lower porosity of 1.3% compared to the coarser powder fed 1.9% (both presenting a standard deviation of 0.2%). However, it could be seen that both the presence of optimised spraying parameters and finer feedstock particles were significant in obtaining improved mechanical properties. Furthermore, an examination of the powder-fed coating revealed slightly improved hardness properties to the newly developed suspension-sprayed samples. However, the powder-fed coatings distinctly exhibited superior resistance to sliding wear with an average specific wear of 5.7 (± 0.9 standard deviation) compared to the 12.8 (± 1 standard deviation) × 10-6 mm3∙N-1∙m-1of suspension-based coatings. In conclusion, it was observed that the chemical composition of the alumina-chromia composite coating demonstrated exceptional hardness properties among the analysed samples (1603 Vicker Hardness 0.2) and superior sliding wear resistance (0.59 × 10-6mm3∙N-1∙m-1).
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Vibromechaninio apdirbimo įtakos Cr-Ni-Co dangų savybėms tyrimas / Investigation of vibromechanical treatment influence on Cr-Ni-Co coatings characteristicsRadionovienė, Jolita 30 September 2008 (has links)
Daugelis svarbių konstrukcijų po tam tikro naudojimo laiko, veikiant aplinkai, nebetinka naudoti ir, svarbiausia, gali suirti ir sukelti įvairias avarines situacijas. Norint pailginti detalių ilgaamžiškumą yra naudojamos apsauginės dangos, kurios garantuoja gaminio patikimumą ir kokybę. Tyrimais siekiama išsiaiškinti, ar vibromechaninis apdirbimas terminio purškimo metu turi įtakos Cr-Ni-Co dangos savybėms. Šiuo atveju, siekiant užnešti paviršiaus dangą ant pagrindo yra naudojamas terminio purškimo būdas, t. y. išlydytą purškiamą medžiagą dujų srautas suskaido į smulkius lašelius (atomizuoja), įgreitina juos ir didele kinetine energija bloškia į substrato paviršių. Purškiamas Eutalloy 10611 miltelių mišinys, kuriame yra Cr, Ni, Co ir tankių, kietų volframo karbidų dalelių, suteikiančių dangai didelį atsparumą dilimui. Tyrimų metu nustatyta, kad vibromechaninis apdirbimas turi įtakos tokioms dangos savybėms, kaip adhezija, porėtumas, mikrokietumas ir išdilimas. / A lot of important constructions are not exploitable any more, because of environmental influence and, even worse, can cause emergency situations after decomposition. Protective coatings are used in order to extend the durability and guarantee high quality of component parts. The objective of this research is to verify if vibromechanical treatment during thermal spraying has any influence on characteristics of Cr-Ni-Co coatings. Thermal spraying is used in order to coat a surface in this case, i.e. gas flow dissolves the sprayed molten material into small drops (atomizes), accelerates and flings it on a surface with large amount of kinetic energy. Eutalloy 10611 powder compound is being sprayed, which contains Cr, Ni, Co and dense, hard wolfram carbide particles, giving the coating good attrition resistance. In accordance with experimental data, it is determined, that vibromechanical traetment has particular influence on adhesive, porous, microhardness and attrition properties of coating, with various vibromechanical modes applyed.
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Effect of Humidity and Temperature on Wear of TiN and TiAIN CoatingsGovindarajan, Sumanth January 2017 (has links) (PDF)
When loss of material due to sliding of two solids is promoted/prevented, in the presence of chemically reacting liquid or gas, tribochemical wear is said to occur. Tribochemical wear, in which corrosive media promotes material loss, is a serious concern in a variety of applications like machining, bio-implants, gas turbine engines etc. The most pervasive corrosive media encountered in applications are water and air. Air also contains water vapour along with oxygen, both of which adsorb and react with most materials, thus influencing their wear behaviour. The need for higher operating temperatures and compression ratios in gas turbine engines require development of high temperature wear resistant coatings to protect their soft metallic components. Ti based nitride coatings with Ti, Al, Si, Cr, Ta, Nb, V are known for wear resistance because of their high hardness which is second only to diamond and c-BN. High O affinity of these elements, induce the coatings to form passive oxide scale up to reasonably high temperatures and offer superior corrosion and oxidation resistance. However, sliding can remove the passivating layer, exposing the native surface to the environment which can lead to enhanced tribochemical wear. Oxidation resistance under static conditions does not guarantee low tribochemical wear; however, the tribochemical reactions causing the corrosion are of interest. Another concern is that sliding in unison with high temperatures can activate processes like enhanced diffusion, phase transformations in nitride coatings as well as in the substrate. Hence one of our objectives is to perform wear tests at high temperatures to understand the dominant mechanisms that affect wear in nitride coatings. Wear tests in the range of room temperature up to the oxidation limit of these coatings are designed.In this study TiN and high aluminium containing TiAlN coatings are chosen to study understand the wear behaviour as function of temperature up to 800°C [1]–[3].
In order to study wear of coatings, it is necessary to identify the best possible materials and methods. Though under the targeted application the coatings have to perform under fretting tests, pin on disk configuration is used which simplifies the analysis and gives deeper insight into the wear mechanism. Coated ball is used as the pin which is stationary unlike many earlier studies where the coating is applied on the rotating disk. The purpose of keeping the pin stationary is to minimize the counter-face wear and, instead, accelerate wear in these hard coatings. This method also enables easy and accurate measurement of wear depth and volume by using an optical microscope, while the conventional coated disk method requires profilometry and statistically sound measurements. To enable coating performance, substrate should not undergo much loss of strength before 800°C and hence aerospace grade IN718 alloy is chosen as the substrate which softens slowly beyond 650°C. Alumina is used as counter-face, since it has high hardness, excellent mechanical, chemical and thermal stability.
In the current study, TiAlN coating is tested for wear in the range of room temperature to 800°C. Figure 1 represents the data obtained from the wear experiments. It is found that the wear is higher with large scatter at room temperature while it remains constant from 200- 750°C. Two important observations are made, firstly that the TiAlN is susceptible to some kind of a corrosive wear at room temperature which depended on the timing of the tests and secondly that the coating shows a surprisingly constant wear behaviour over the temperature range of 200-750°C.
The scatter at room temperature is found to be linked with seasonal fluctuation of humidity which is verified by performing tests under controlled humidity conditions. Water vapour and oxygen are potential reacting gases present in air. Oxidation and oxidative wear is known to occur in many materials as temperatures increase which seem to be linked to thermal activation of oxidation. However lower wear at 200°C and above compared to room temperatures suggests something else to be happening .It is evident then that between room temperature and 200°C lies a transition of some kind in the tribochemical reaction which is responsible for the observed wear behaviour of TiAlN. A detailed study to understand this transition is then undertaken for the composition of TiN coatings so that benchmarking and comparison with TiAlN is possible. Also if the wear behaviour of TiN is found similar to TiAlN then it would indicate a general phenomenon which can be extended to Ti based nitrides.
Figure 1 Wear rate as a variation of temperature for TiAlN coatings
In contrast to low temperature wear behaviour of TiAlN, a constant wear in the range of 200-750°C is surprising because the primary suspect which is oxidation is thermally activated. The oxide scale though expected to be thin at low temperatures, has to increase in thickness with temperature due to increased diffusion and reaction rates. The oxide scale also undergoes a change in morphology and composition which indicate a lower oxidation resistance as temperature increases. A preliminary characterization of the wear scar on the ball shows that the oxide inside the worn region is thinner than the oxide outside at 750°C. The amount of O within the wear scar is similar to levels observed on as deposited surface while the surface outside the wear scar shows oxidation and discolouration. The results suggest that oxidation inside worn region at high temperatures might be slower than the expected parabolic oxidation occurring outside the wear region. It is speculated that a double layer oxide is formed with TiO2 towards the surface and Al2O3 towards the nitride which is responsible for the lower wear at high temperature. This is supported by the fact that larger amount of Ti is found in the wear debris as temperature inceases. Superficial surface cracks appear at higher loads at temperatures as low as 600°C but they affect wear only above 800°C due to substrate softening. This shows that the coatings are still limited by the substrate softening temperature and could be used at higher temperatures.
Tribo-reaction in metals, nitrides and carbides can be brought about in the presence of O2 or water vapour. Tribochemical wear of SiN, SiC, TiN, TiAlN, alumina and most other ceramics at room temperature are found to depend on humidity[4]–[6]. But only tribo-oxidation due to O2 is found to operate at high temperatures[7], [8]. Notwithstanding, it is known that SiC and SiN are more resistant to attack from O2 above 800°C than from steam. Hence the role played by water vapour is found to be convoluted. Moreover, relative humidity is the frequently mentioned quantity with regard tribochemical wear at room temperatures. It should be noted that relative humidity is not a measure of chemical activity of water vapour. Rather the water vapour pressure which represents the chemical activity of water, is not given much importance in the earlier studies. In this study, the importance of humidity, water vapour pressure and temperature in influencing wear, is studied by performing controlled wear tests on TiN.
To explore the effect of temperature and water vapour pressure, TiN is tested varying temperature range of 28 °C to 90°C and water vapour pressure in the range of 3-35 mm-of-Hg. Wear tests are conducted keeping temperature constant with varying water vapour pressure and vice versa. The results show that, wear increased with humidity/vapour pressure at a fixed temperature but wear dropped drastically with increase in temperature at constant vapour pressure up to a critical temperature beyond which wear remained constant. This is one of the major unexpected findings since temperature is expected to increase wear volume. Also the critical temperature is found to shift to higher temperatures as water vapour pressures increased. It was suspected that capillary condensation was playing a role in the wear which was later verified. The whole wear behaviour is shown to be correlated with the amount of capillary condensed water. The large radius of curvature of the asperities on the polished coating surface and the smooth surface formed on the counter-face due to debris compaction form conditions favourable for capillary condensation. Any two hydrophilic surfaces which come in contact can form capillary condensation to occur at the cusps formed around the contact. However a threshold pore size of about 1nm existed below which condensation did not influence wear.
Another observation is that the water vapour did not affect wear significantly in the absence of condensation for TiN coatings. As temperatures increased condensation became unfavourable, but the high vapour pressure present showed no signs of wear enhancement. This is surprising and unexpected compared to earlier reports.[9], [10] On contrary tests in liquid water showed expected behaviour for tribochemical reaction i.e wear increased with temperature. The wear in liquid water is highest when compared studies in air at any given temperature. The X-ray electron emission spectroscopy (XPS) analysis is performed to understand the surface reactions. It appears that O2 forms a barrier oxide which protects the nitride from reacting with water vapour. However when condensation occurs or in water, the oxygen and water collude into forming softer hydroxide layer which is easily removed. Though chemically water and water vapour are same, they affect wear in TiN very differently.
Summarising the synopsis, exploration into high temperature wear of TiAlN reveals that it can handle oxidative wear upto 750°C showing constant wear over the temperature range of 200-750°C. Reduction in residual stresses and substrate softening may be responsible for higher wear at higher loads since the cracking is observed at 5N is absent at 3N. The substrate is expected to soften above 650°C but this does not necessarily affect wear until the load is increased or the temperature is sufficiently high. However TiAlN and TiN coatings showed susceptibility to tribo-corrosion in water and high humidity at room temperature. At high humidity, condensation of water leads to increase in wear. The dependence of wear on humidity is found to be because of capillary condensation. The negligible dependence of wear on humidity in the absence of condensation is ascribed to formation of oxide layer due to reaction with O2 and coating. The oxide barrier formed due to atmospheric O2 protects the coating from reacting with the water vapour. The oxide barrier on TiN forms faster indicating O2 reaction to be faster than the reaction with water vapour. In the presence of capillary condensation or water, O2 is depleted from contacting surfaces thus hindering the formation of the barrier oxide, increasing wear. As temperature increases the condensation becomes unfavourable and barrier oxide dominates the wear mechanism upto high temperatures which is dominated by oxidative wear.
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WEAR RESISTANT MULTI FUNCTIONAL POLYMER COATINGSParsi, Pranay Kumar January 2023 (has links)
This study aims to develop coatings which show wear resistant behaviour along with multiple functions such as improved ice adhesion, better freezing delay etc which help in improving the effectiveness of the wind turbine efficiency. The significance of anti-icing/de-icing solutions for wind turbines is emphasized since ice accretion can cause serious issues in generation of power and might lead to damage of blades. The use of active and passive anti-icing/de-icing technologies in wind turbine blade applications is reviewed. The discrepancy between passive anti-icing, which depends on surface treatment, coatings, de-icing fluids and active anti-icing, which uses heating devices, sensors such as actuators, transducers, is explored along with the current challenges in industry. In this study we’ve developed interesting methods for improving the anti-icing/de-icing capabilities of wind turbine blades by using gelcoat coatings in which are filler particles (boron nitride and graphene) and oils (vegetable and paraffin oil) are incorporated. Evaluating the impacts of type of fillers, oils, their concentrations on anti-icing efficacy, as well as the prospects for this technique to enhance wind energy production's reliability and productivity will be explored. In summary, this study aims to develop multi-functional polymer coatings for anti-icing/de-icing application in wind turbine blades. The coatings with boron-nitride and graphene showed an increase in the surface roughness and contact angles, while there’s no change in the chemical composition in comparison with pure gelcoat. The thermal conductivity of the coatings was increased with addition of fillers. For the wear test, the operating parameters chosen are a load of 5N and 1Hz frequency of slider, which is run for a duration of 10 min. The COF for both the coatings is lesser than baseline coatings whereas graphene provided better wear resistance. The hardness was increased for boron-nitride coatings and it remained almost same for graphene coatings. The ice adhesion strength, freezing delay and thermal analysis (TGA) for these coatings showed better performance than pure gelcoat. Whereas for coatings with vegetable and paraffin oils, the contact angles were increased and surface roughness was increased in case of paraffin oil coatings whereas it reduced for vegetable oil coatings. Both the coatings offered better wear resistance and reduced COF, whereas the hardness was reduced. The ice adhesion strength and freezing delay improved drastically and are much better than both pure gelcoat as well as coatings with boron-nitride and graphene. There is slight increase in the glass transition temperature than pure gelcoat coating.
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Mechanically Driven Reconstruction of Materials at Sliding Interfaces to Control WearShirani, Asghar 05 1900 (has links)
To minimize global carbon emissions, having efficient jet engines and internal combustion engines necessitates utilizing lightweight alloys such as Al, Ti, and Mg-based alloys. Because of their remarkable strength/weight ratio, these alloys have received a lot of attention. Nonetheless, they have very poor tribological behavior, particularly at elevated temperatures beyond 200 °C, when most liquid lubricants begin to fail in lubrication. Over the last two decades, there has been a lot of interest in protecting Al, and Ti-based alloys by developing multiphase solid lubricants with a hard sublayer that provide mechanical strength and maintain the part's integrity while providing lubricity. The development of novel coatings with superior lubricity, high toughness, and high-temperature tolerance remains a challenging and hot topic to research and provide new engineered solutions for. To address and provide solutions to protect light-weight, i.e., Al, and Ti alloys at high-temperature and bestow superior tribological properties to such alloys, three types of adaptive lubricious coatings have been studied in this thesis: Nb-Ag-O self-healing lubricious ternary oxide, PEO-chameleon a self-adaptive multi-phase coating, and Sb2O3-MSH-C lubricious adaptive coatings to address this challenge. The development of the Nb-Ag-O ternary resulted in a coefficient of friction as low as 0.2 at 600 °C and crack healing at 900 °C. PEO-chameleon coatings demonstrated a remarkably low COF, as low as 0.07 at 300 °C and 1.4 GPa applied pressure. Finally, the Sb2O3-MSH-C multi-phase lubricious solid lubricant revealed superlubricity, with a CoF of 0.008 at 300 °C, providing a potentially promising contender for high-temperature, high-load applications.
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High Temperature Tribology of Exhaust Components in Alternative Fuel EnginesZaheer, Muhammad Hashir January 2023 (has links)
Internal Combustion Engine (ICE) exhaust components are exposed to extreme operating temperatures. Thus, it is necessary that they are designed with materials that can sustain thermal and vibrational stresses. This study investigates the wear mechanisms and tribological performance of the exhaust manifold joint in Scania CV diesel trucks, focusing on the lip seal ring between the exhaust and turbo manifolds. The joint is prone to wear due to thermal and vibrational stresses, impacting its service life and raising environmental concerns. The manifold material, ductile cast iron SiMo51, offers good thermal resistance, while the lip seal ring, made of Inconel 718c, provides excellent thermal fatigue and corrosion resistance, coated with AlTiN for wear and oxidation resistance. However, the tribological performance of this joint and material combination remains unknown, necessitating further research. This work aims to understand wear initiation mechanisms and their relationship with temperature. Test setups were established using an oscillating cylinder on disc configuration in the SRV 3 tribometer. SiMo51 uncoated/coated with Tribaloy 400 and Inconel 718c uncoated/coated with AlTiN were tested against each other to identify the best material pair. Analysis involved coefficient of friction, visual inspection, wear volume measurements, SEM micrographs, and EDS for surface chemical composition. Results indicated that friction behaviour is temperature-dependent, with oxide layer formation reducing the coefficient of friction when the manifold is uncoated, while the opposite occurs when coated with Tribaloy 400. Wear behaviour varied based on material combinations and temperature. Uncoated manifold exhibited dominant adhesion (galling) accompanied by tribo-oxidation at higher temperatures, with maximum wear volumes at room temperature. Introduction of T-400 on the manifold initiated galling on the lip seal, leading to abrasion on the manifold surface, accompanied by tribo-oxidation at elevated temperatures. Wear increased until 500°C, followed by a decrease at 700°C. Further explanations of T-400 wear behaviour are lacking in the literature.
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Effect of temperature on early stage adhesion during TiAlN sliding against Inconel 718 and Stainless steel 316L : High temperature tribologyAli, Ahsan January 2023 (has links)
High-performance materials such as stainless steels and nickel based super alloys are widely used in demanding applications where high mechanical and thermal properties are required. The applications of super alloys are mainly found in jet engines, power plants and gas turbines demanding high fatigue strength, corrosion and oxidation resistance as well as wear resistant properties. In order to use them, they go through various machining processes such as milling, turning, cutting, polishing etc. until the final product is achieved. Modern manufacturing industries employs various machining tools and technologies to improve the machining process of heat resistant super alloys. However, there are still challenges which needs to be addressed. Among them, adhesive wear of the machining tools is one of the main wear mechanism during the tribological interaction of tool and workpiece, preventing them to achieve the desired quality and surface finish of the end product. Moreover, it damages the tool reducing its lifecycle and in return, increasing the production cost. Among the cutting tools tungsten carbide (WC/Co) tools coated with TiAlN coating due to their good high temperature performance are extensively used. Nonetheless, these coatings still face issue like adhesive wear, abrasion, oxidation at higher temperature damaging the tools and subsequent machining. Therefore, it is imperative to understand the initiation mechanism of adhesive wear during the tribological interaction of super alloys and coated cutting tool material. In this research work, the tribological response of two coatings deposited by physical vapour deposition (PVD), having the composition Ti60Al40N and Ti40Al60N have been studied against two super alloys material, i.e. Inconel 718 and stainless steel 316L. A high temperature SRV (Schwingung (Oscillating), Reibung (Friction), Verschleiß (Wear)) reciprocation friction and wear test set up was employed to investigate the friction behaviour, wear rate and dominant wear mechanisms. For Ti60Al40N coating, the experimental results revealed that generally, friction increases in case of sliding against Inconel 718 up to 400 °C and drops at 760 °C. A high wear volume at room temperature and a decrease to a minimum at 760 °C has been observed for Inconel 718. On the other side, Stainless steel 316L (SS 316L) faces a continuous rise in friction coefficient with highest value at 760 °C during sliding against Ti60Al40N coating. Wear is highest at 400 °C for SS 316L pin. The worn surfaces shows that both workpiece materials experience increase in material transfer due to adhesive wear with rise in temperature. At 400 °C, adhesion is the primary wear mechanism for both workpiece materials. A further rise in temperature to 760 °C promotes the adhesive wear through oxides formation on both material surfaces. Similarly, Ti40Al60N coating shows the same friction behaviour with change in average steady state friction values for both material of Inconel 718 and SS 316L. Both workpiece materials responds in a similar way to wear volume loss, i.e. lowest at room temperature and highest at 760 °C. For Inconel 718, transfer of coating constituents on to the Inconel 718 pin surface was detected and associated with coating rupture and peeling, exacerbating with rise in temperature. Adhesion, abrasion, and oxidation are primary wear mechanisms at 400 °C and 760 °C. For SS 316L, coating transfer only happen at 400 °C. No damage of coating at 40 °C, a complete damage at 400 °C, and formation of dense porous oxides layers at 760 °C have been noticed. At 400 °C, adhesion, abrasion, and chipping while at 760 °C, adhesion, three body abrasion, ploughing and oxidation are the main wear mechanisms.
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