The objective of this research was to evaluate the treatment efficiency of a nitrate-contaminated soil by combined technologies of the injection of palladized nanoiron slurry and electrokinetic remediation process. First, nanoiron was prepared by two synthesis processes based on the same chemical reduction principle yielding products of NZVI-A and NZVI-B, respectively. Then they were characterized by various methods. Micrographs of scanning electron microscopy have shown that a majority of these nanoparticles were in the range of 50-80 nm and 30-40 nm, respectively. Results of nitrogen gas adsorption-desorption show that NZVI-A and NZVI-B are mesorporous (ca. 30-40 Å) with BET surface areas of 128 m2/g and 77 m2/g, respectively. Results of X-ray diffractometry have shown that both types of nanoiron were poor in crystallinity. Results of zeta-potential measurements indicated that NZVI-A and NZVI-B had the same isoelectric point at pH 6.0. Although NZVI-A and NZVI-B were found to be superparamagnetic, their magnetization values were low. Poly acrylic acid (PAA), an anionic dispersant, was employed for stabilizing various types of nanoiron. Then Palladium¡]ca. 1 wt% of iron¡^ was selected as catalysis to form palladized nanoiron¡]Pd/Fe¡^. Results have demonstrated that an addition of 1 vol. % of PAA during the nanoiron preparation process would result in a good stabilization of nanoiron and nanoscale Pd/Fe slurry. Batch tests were carried out to investigate the effects of pH variation on degradation of nitrate aqueous solutions. Experimental results have indicated that palladized nanoiron outperformed nanoiron in treatment of nitrate in this study. Apparently, an employment of catalyst would enhance the treatment efficiency. Further, an exponential increase of the reaction rate was found for the systems at low pH. The final stage of this study was to evaluate the treatment efficiency of combined technologies of the injection of palladized nanoiron¡]Pd/Fe¡^ slurry and electrokinetic remediation process in treating a nitrate-contaminated soil. Test conditions used were given as follows: (1) slurry injection to four different positions in the soil matrix; (2) electric potential gradient: 1 V/cm; (3) daily addition of 20 mL of palladized nanoiron (4 g/L) slurry to the injection position; and (4) reaction time: 6 days. Test results have shown that addition of palladized nanoiron slurry to the anode reservoir yielded the lowest residual nitrate concentration in soil. Namely, about 99.5% removal of nitrate from soil. On the other hand, the acidic condition of soil matrix around the anode reservoir would enhance the degradation of nitrate therein. Based on the above findings, the treatment method employed in this work was proven to be a novel and efficient one in treating nitrate contaminated soil.

The effects of the deregulation of the electricity market 1996 in Sweden on short-term hydropower regulation are unknown. This report investigates patterns in subdaily regulation in the Ångerman River Basin during the period 1993-2011. Differences in subdaily flows and zero flow events between the periods 1993-1995 and 1996-2011 were studied by analyzing hourly data from 8 regulated and 8 unregulated locations with four subdaily flow variation indices. No correlations between the market deregulation and the regulation intensity in the Ångerman River basin were detected. The number of days natural ranges of variability were exceeded and the magnitude of subdaily variation were significantly higher at regulated locations. Zero flow events increased substantially when the periods 1993-2007 and 2008-2011 were compared. Significant correlations were detected in the summer periods between dry years and high magnitudes for the indices that measured variation in volume and low magnitudes for subdaily flow reversals. Zero flow events in the summer periods increased during dry years if the period 2008-2011 were excluded. The major conclusions are that the deregulation of the electricity market has not affected the subdaily regulation of the Ångerman River and that the regulated sites show highly unnatural subdaily variations. Regulation intensity and zero flows events increases during summertime in dry years and the latter also increased substantially after 2007. The current regulation regime is considered harmful for riverine ecosystems and the high and increasing levels of subdaily flow alteration shows the urgent need of national directives for subdaily hydropower operation.

Flax is one of the major cash crops in Canada. Approximately seventy percent of Canadian flaxseed was exported to European Union (EU) annually until 2009. In 2009, the EU imposed an import ban on Canadian flaxseed due to the adventitious presence of a GM flax variety - CDC Triffid was identified in Canadian flaxseed exported to the EU. The EUs decision to apply zero tolerance on CDC Triffid flax has been based on its interpretation of the precautionary principle. According to the World Trade Organisations Agreement on the Application of Sanitary and Phytosanitary Measures (SPS), however, precautionary measures are subject to a scientific risk assessment. As the EU did not base its zero tolerance for CDC Triffid flax on any scientific risk assessment, the EU is in violation of the SPS Agreement. Moreover, the EU has ignored the available scientific information regarding CDC Triffid flax. The EU did not consider the possibility of following the guidelines given by Codex Alimentarius Commission in the case of CDC Triffid flax. There are non-scientific reasons behind the EUs zero tolerance on CDC Triffid flax and they overweigh the available scientific information. The EU position would be unlikely to be supported if a complaint was brought to the World Trade Organisation Disputes Panel. A partial equilibrium model was used to provide a theoretical background to examine the changes in the flaxseed industry and the linseed oil industry due to the CDC Triffid event. A model of the supply chain of Canadian flaxseed was developed to illustrate the operationalisation of the Protocol developed by the EU and Canada to address the zero tolerance policy. Empirical estimation suggests that the operationalisation of the Protocol incurred additional cost of $7.5 million to the flax seed industry of Canada in 2009/ 2010. Out of that, cost of testing was approximately $1.2 million and cost of segregation was $4.2 million. Estimation of changes in revenue suggests that there was a loss of revenue in flaxseed trade between the EU and Canada in 2009/2010. Imports of Canadian flax by China provided an alternative market, at a considerably lower price than typically realised from the EU market. Interestingly, the EUs zero tolerance policy on CDC Triffid flax has resulted in a larger additional cost on the EU than Canada.

This analysis is concerned with the spatially-anchored hierarchies of power that organize Ontario’s current schooling model. Using the experiences of four young Latina girls, it questions how current school safety discourses function as barriers to educational success, vis-à-vis their role in reconfiguring these students’ identities through narratives of danger, menace, and unruliness. Specific safety and security related practices are explored as sites through which marginalized students are produced as dangerous bodies who are undeserving of full educational opportunities. It is argued that these practices (as manifest in current approaches to surveillance, policing, discipline and punishment, and the restriction of educational mobility) all work to produce the school space as dominant space. Rather than offering youth the opportunity to overcome inequalities, schools and education instead play a definitive role in their continued propagation by sanctioning the control, containment, and eviction of those who are deemed to be deviant.

Livestock keeping has been the essential source of livelihood in Babati District for many hundreds of years. The traditional ecological knowledge about this semi-arid environment has influenced the general view on livestock management. This essay discusses the measures that are, or could be taken in Babati District to prevent overstocking and overgrazing in the woodlands. With the continuing population density increase also the livestock population grows. More houses and roads are built and the grazing lands diminish. To avoid overgrazing forest management programmes restrict grazing in forests. This additionally decreases availability of grazing land. My conclusion is that minimizing number of livestock is necessary to not exceed carrying capacity of pasture during drought. Hence this is not free from problems since it is traditionally rooted to have a large number of livestock as a buffer of energy and wealth. One solution for both how to prevent overstocking and how to survive with small number of livestock is to practise zero-grazing. Zero-grazing is to keep a small number of healthy big cattle e.g. exotic cows or crossbreeds in stables or tied up. However, when tying cattle on the spot the fact that cattle have four legs is disregarded.

The use of computers for handling image data in the healthcare is growing. The amount of data produced by modern image generating techniques, such as CT and MR, is vast. The amount of data might be a problem from a storage point of view or when the data is sent over a network. To overcome these problems data compression techniques adapted to these applications are needed. There are an abundant number of compression schemes for the compression of images, but few that are geared towards compression of image stacks. Though these 2D techniques can be applied to the image stacks they do not fully exploit the three-dimensional nature of the stacks. In this thesis ideas from the image compression area are extended to exploit the 3D nature of image stacks. Attention is directed to MR and CT stacks. The compression schemes in this thesis are based on the relatively new notion of wavelets, used in the JPEG2000 standard. The schemes also providea quality progressive transmission, which allows intermediate low-quality results to be constructed. Two different coders are presented in this thesis both developed for the compression of image stacks containing medical data. They are evaluated and compared and a top performer is chosen. Advantages and drawbacks of the schemes and future enhancements are also discussed.

This analysis is concerned with the spatially-anchored hierarchies of power that organize Ontario’s current schooling model. Using the experiences of four young Latina girls, it questions how current school safety discourses function as barriers to educational success, vis-à-vis their role in reconfiguring these students’ identities through narratives of danger, menace, and unruliness. Specific safety and security related practices are explored as sites through which marginalized students are produced as dangerous bodies who are undeserving of full educational opportunities. It is argued that these practices (as manifest in current approaches to surveillance, policing, discipline and punishment, and the restriction of educational mobility) all work to produce the school space as dominant space. Rather than offering youth the opportunity to overcome inequalities, schools and education instead play a definitive role in their continued propagation by sanctioning the control, containment, and eviction of those who are deemed to be deviant.

The Qweak experiment at Thomas Jefferson National Accelerator Facility (Jefferson Lab) will measure the proton's weak charge by measuring the parity violating asymmetry in elastic electron-proton scattering at very low momentum transfer, with the aim of determining the proton's weak charge with 4% combined statistical and systematic errors. The experimental apparatus includes a longitudinally polarized electron beam, a liquid hydrogen target, a room temperature toroidal magnetic spectrometer, and a set of precision detectors for the scattered electrons. The toroidal magnetic spectrometer, which will deflect away the inelastic scattered electrons and focus the elastic scattered electrons onto the detectors, plays a crucially important role in the experiment. In this thesis, in order to meet the requirements for the installation and calibration of the toroidal magnetic spectrometer, the numerical simulation of the spectrometer's magnetic field based on a realistic magnet model is discussed, a precise 3D field mapping is introduced, and some simulation results are provided. The zero-crossing analysis technique, which can be used to precisely infer the individual coil locations of the toroidal magnet, is presented and explored in detail. / October 2007

Phosphorus (P) is one of the essential nutrients for living organisms; however, excess P in aquatic systems often causes environmental and ecological problems including eutrophication. Removal of P from domestic wastewater, industrial wastewater, and agricultural organic-waste systems is required to minimize loading of P to receiving water bodies. A variety of sorbents or filter materials have previously been evaluated for P removal, including natural materials, industrial byproducts, and synthetic products. Among these materials industrial byproducts were reported as most effective. However, only a few of these studies were based on field experiments. Pharmaceutically active compounds (PhACs) and acesulfame-K (an artificial sweetener) are emerging contaminants observed in wastewater. The removal of PhACs in conventional wastewater treatment systems has been studied; however, few studies on alternative treatment systems are available. Studies related to the removal of acesulfame-K are even more limited. This thesis was focused on evaluation of basic oxygen furnace slag (BOFS), a byproduct from the steel manufacturing industry, as a potential reactive media for P removal from surface water and wastewater. The removal of PhACs and acesulfame-K in wastewater treatment systems containing BOFS as a treatment component was also evaluated. The effectiveness of BOFS for removing P from lake water was evaluated in a three year pilot-scale hypolimnetic withdrawal P treatment system at Lake Wilcox, Richmond Hill, Ontario. Phosphate concentrations of the hypolimnion water ranged from 0.3 to 0.5 mg L-1. About 83-100% P was removed during the experiment. The reactive mixtures were changed each year to improve the performance of the treatment system. Elevated pH (9-12) at the effluent of the treatment system was adjusted by sparging CO2(g) to near neutral pH. Elevated Al was removed through this pH adjustment. Elevated concentrations of V were removed in a column containing 5 wt% zero valent iron (ZVI) mixed with sand (0.5 m3) at the end of the BOFS based column. Removal of P in the BOFS based media is attributed to adsorption and co-precipitation at the outer layer of BOFS. Geochemical modeling results showed supersaturation with respect to hydroxyapatite, ß-tricalciumphosphate, aragonite, and calcite. Solid phase analyzes of the BOFS based reactive media collected after completion of the year 2 experiment (spent media) through combination of scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), and X-ray absorption near edge structure spectroscopy (XANES) support the presence of calcium phosphate minerals on the outer layer of the spent media. A multistep wastewater treatment experiment was carried out in an indoor facility at the Center for Alternative Wastewater Treatment, Fleming College, Lindsay, Ontario, Canada. This experiment evaluated the removal of P, ammonia, cBOD5, COD, E. coli, total coliform, and trace metals in a series of treatment cells including a mixing cell, a vertical subsurface flow aerobic cell, a vertical subsurface flow P treatment cell containing BOFS, and a horizontal subsurface flow anaerobic cell. About 97-99% removal of P, NH3, cBOD5, E. coli, and total coliform; and ~72% removal of COD were achieved in the treatment system. The mixing cell and the aerated cell reduced the concentrations of P, ammonia, cBOD5, E. coli, and total coliform significantly and the P treatment cell provided additional treatment. However, the primary objective of the P treatment cell was to reduce P concentrations to the acceptable range according to the water quality guidelines. The P treatment cell had successfully fulfilled this objective. Elevated concentration of Al and V were also observed in the P treatment cell effluent. The concentration of Al decreased to below the guideline value of 0.075 mg L-1 after introducing a pH adjustment unit between the P treatment cell and the anaerobic cell. The concentration of V was decreased in the anaerobic cell effluent. However, the effluent concentration of V was much higher than the guideline value. Geochemical speciation modeling results showed supersaturation with respect to hydroxyapatite, ß-tricalciumphosphate, aragonite and calcite along the flow path. Accumulation of P on the outer layer of the spent BOFS media was identified by energy dispersive X-ray spectroscopy (EDX). Although X-ray photoelectron spectroscopy (XPS) can provide information to a depth of 5-7 nm from the outer layer of the spent media, both Ca and P were positively identified in some of the samples. Accumulation of P at the edge of the grains of the spent media was clearly identified on the element map of polished cross-sections and corresponding FTIR spectra. The phosphate and carbonate functional groups were identified by the distribution of different vibrational frequencies through FTIR spectroscopy. The presence of calcite and hydroxyapatite were inferred based on the wave numbers assigned for these minerals in the literature. Finally, X-ray absorption near edge structure spectroscopy (XANES) on the outer layer samples from the spent BOFS media and corresponding linear combination fitting analysis indicated the presence of ß-tricalciumphosphate, hydroxyapatite, and calcium phosphate dibasic. Based on the observations from the indoor wastewater treatment experiment, a multistep demonstration-scale outdoor wastewater treatment experiment was conducted to investigate the applicability of the integration of the P treatment technology and engineered wetland technology at a relatively large scale prior to a full-scale field installation. The anaerobic treatment cell was not included in this outdoor system because this unit did not efficiently remove ammonia and metals (e.g. V) from the Cell 4 effluent in the indoor system. A 10 cm layer of zero valent iron was placed at the bottom part of the down flowing P treatment cell to address the elevated V in the P treatment cell effluent observed in the indoor system and also to treat PhACs in the effluent. More than 99% removal of P, E. coli, and total coliform; >82, >98, and >76% removal of ammonia, cBOD5, and COD were achieved in this treatment system. The effluent pH (10.88±1.47) was neutralized and the concentration of V remained < 0.006 mg L-1. The Al concentration was adjusted to <0.075 mg L-1 with the neutralization of pH. Geochemical speciation modeling results showed the supersaturation of hydroxyapatite, ß-tricalciumphosphate, octatricalciumphosphate, aragonite, and calcite. The FTIR and XANES spectra showed the presence of calcium phosphate minerals on the outer layer of the spent media. Removal of the PhACs, including caffeine, ibuprofen, carbamazepine, naproxen, and sulfamethoxazole, and acesulfame-K was monitored in the demonstration-scale outdoor wastewater treatment system, which consisted of five different treatment cells including a horizontal subsurface flow constructed wetland, a vertical subsurface flow aerated cell, a vertical subsurface flow BOFS cell, and a pH neutralization unit. Significant removal of caffeine (>75%) and ibuprofen (50-75%), and moderate removal of sulfamethoxazole and naproxen (25-50%) were observed. The removal of carbamazepine was less effective with <25% removal observed. Acesulfame-K was also persistent along the flow path with <25% removal. This study demonstrated that removal of P from lake water and wastewater in excess of 95% could be achieved using BOFS as a reactive media. Integration of this media into an engineered wetland system enhances its performance in removing nutrients and other wastewater contaminants.

We study reducibility for nowhere-zero flows. A reducibility proof typically consists of showing that some induced subgraphs cannot appear in a minimum counter-example to some conjecture. We derive algebraic proofs of reducibility. We define variables which in some sense count the number of nowhere-zero flows of certain type in a graph and then deduce equalities and inequalities that must hold for all graphs. We then show how to use these algebraic expressions to prove reducibility. In our case, these inequalities and equalities are linear. We can thus use the well developed theory of linear programming to obtain certificates of these proof. We make publicly available computer programs we wrote to generate the algebraic expressions and obtain the certificates.