<p>Hot-melt adhesives have been commercially available for a long time and they are used in a wide range of applications. The adhesive performance is governed by the adhesive material property as well as the application conditions for each type of substrate. In order to achieve a good bond between the adhesive and the designated substrate, both wetting ability and open time of the adhesive material have to be considered. Three commercial hot-melts were used in this study in order to examine the relationship between the material property and the adhesive performance. The thermal properties of the materials were obtained through Differential Scanning Calorimetry while Dynamic Analysis (DA) described their viscoelastic behaviour, and the hysteresis loop helped to characterize the flow regime from which the application conditions for the adhesive could be chosen. The adhesive performance was evaluated in term of the force required to break the bond between the adhesive and the substrate through a series of standardized pull-off tests. The effect of the time-temperature trade-off on the adhesive performance by varying the application temperature as well as prolonging the available bond-formation time was also examined. In most cases, the adhesive performance improved with extended open time. However, improved adhesive performance was also shown to be the response of shorter Maxwell characteristic time which was evaluated from the DA data. By providing the characteristic time as a linkage, a relationship between the adhesive performance and the material properties could be established. These results also offer a basis for the formulation of adhesives using structure-property parameters derived from DA.</p> / Master of Applied Science (MASc)

This master thesis is focused on the binary and ternary systems with connective purposeful ettringite formation for fast hardening adhesive for ceramic tiles. It deals with the durability of these materials after exposure to the corrosive environment. It examines the physical and mechanical properties and mineralogy changes after exposure to corrosive environments. Within processing of this paper provides basic information concerning the connective concept of purposeful formation of ettringite.

<p>In this dissertation, we show three approaches towards selective vagus nerve stimulation (VNS). First, we investigated VNS using microelectrode with circle and Vicsek fractal shape. Our rat study shows that fractal microelectrode can activate C-fibers in cervical vagus nerve with higher energy efficiency compared to circle microelectrode. Secondly, we developed stretchable and adhesive cuff device for a compliant neural interface for a long-term stability. We designed Y-shaped kirigami thin-film device for stretchable neural interface and applied a tissue-adhesive hydrogel to enable tough adhesion of the cuff electrode, which can be potentially used to fix the position of microelectrode for a reliable selective stimulation with minimal mechanical mismatch. Lastly, we developed a microchannel electrode array device to potentially measure high-quality of single fiber action potential (SFAP) from the abdominal vagal trunk of rat to explore natural patterns selective organ activities which can be used for a fine-tuned selective VNS. Our results show the potential of measuring C-fiber activities evoked by cervical VNS.</p>