1 |
Investigation of calculated adiabatic temperature change of MnFeP1-xAsx alloysCampbell, David Oliver 30 April 2015 (has links)
Magnetic refrigeration is an alternative cooling technology to vapour compression. Due to the large operating space of magnetic refrigeration devices, modelling is critical to predict results, optimize device parameters and regenerator design, and understand the physics of the system. Modeling requires accurate material data including specific heat, magnetization and adiabatic temperature change, . For a reversible material can be attained directly from measurement or indirectly through calculation from specific heat and magnetization data. Data sets of nine MnFeP1-xAsx alloys are used to compare calculated against measured . MnFeP1-xAsx is a promising first order material because of a tunable transition temperature, low material cost and large magnetocaloric properties. Because MnFeP1-xAsx alloys exhibit thermal hysteresis there are four possible calculation protocols for adiabatic temperature change; , , and . deviates the most from measured data and therefore it is assumed that this case is not representative of the material behavior. Results show and align with measured data as well as . The three protocols that align best with measured data have two consistent errors including a colder peak and a larger . With more data sets and analysis a preferred calculation protocol may be found. / Graduate
|
2 |
Magnetic Properites in Alloy SystemsStrandqvist, Nanny January 2017 (has links)
The attention for materials displaying high magnetocaloric effect (MCE) has grown during the past 30 years. One of the most important properties of MCE is the adiabatic temperature change ( ). The main aim of this work was to develop a method to measure the temperature change ( ) for magnetocaloric materials in a changing magnetic field. A technique was developed where maximum reached for Gadolinium was 1.19 K in a changing magnetic field of 1.3 T, however, this is lower value in comparison with previous studies (3.3 K in a changing magnetic field of 1 T, Bjørk, et al., 2010) which makes the developed method not sufficient enough to measure . Furthermore, finding novel materials displaying high MCE is of great interest. MnFePSiB alloys display promising MCE properties but processing method is expensive and time consuming. Therefore, a MnFePSiB compound was simply remelted several times and heat treated to enhance its properties. The MnFePSiB alloy was remelted 1, 2 and 3 times after initial casting. Melting the material 3 times resulted improvement in both the magnetic and magnetocaloric properties due to enhanced homogeneity. The material melted 3 times was further heat treated to improve its magnetic magnetocaloric properties. Heat treating the material for 5 hours at 1373K improved the magnetic entropy change more than 10 times compared to the as cast sample, was moved closer to room temperature and maximum of 0.71 K was obtained.
|
Page generated in 0.0991 seconds