<p>The demand for heat pumping technologies is expected to see tremendous growth over the next century. Traditional vapor compression cycles are approaching practical limits of efficiency and running out of possibilities for environmentally friendly and safe refrigerants. As a result, there is an increasing interest in pursuing non-vapor compression technologies that can achieve higher efficiencies with alternative working fluids. The chemical looping heat pump (CLHP) investigated here utilizes a chemical reaction to alternate a working fluid between more and less volatiles states. This allows the main compression to take place in the liquid phase and enables the utilization of a range of different working fluids that would not be appropriate for vapor compression technology. </p> <p> </p> <p>Thermodynamic models were developed to assess the potential performance of a chemical looping heat pump driven by electrochemical cells. A number of potential working fluids were identified and used to model the system. The thermodynamic models indicated that the chemical looping heat pump has the potential to provide 20% higher COPs than conventional vapor compression systems. </p> <p> </p> <p>An experimental test stand was developed to investigate the efficiency with which the electrochemical reactions could be performed. The working fluids selected were isopropanol and acetone for reasons of performance and availability. The test stand was designed to measure not only the power consumed to perform the conversion reaction but also the concentration of products formed after the reaction. The experimental tests showed that it was possible to perform the reactions at the voltages required for an efficient chemical looping heat pump. However, the tests also showed that the reactions proceed much slower than expected. To increase the rates of the reactions, an optimization effort on the membrane and catalyst selections was performed. </p> <p> </p> <p>Traditional catalyst materials used by solid polymer electrochemical cells, like those used in the testing, perform best in hydrated environments. The fluids isopropanol and acetone tend to displace water in the membranes, reducing the system conductivity. Multiple membrane types were explored for anhydrous operation. Reinforced sPEEK membranes were found to be the most suitable choice for compatibility with the CLHP working fluids. Multiple catalyst mixtures were also tested in the experimental setup. Density functional theory was used to develop a computational framework to develop activity maps which could predict the performance of catalyst materials based on calculated parameters. </p> <p> </p> <p>A detailed model of the CLHP electrochemical cell was developed. Built on open-source tools, the model was designed to determine the charge, mass, and heat transfers within the cell. The conversion of reactants along the channel of the cell as well as overall power consumption are predicted by the model. The model was validated against measurements and used to determine parameters for a CLHP cell that would have improved conversion performance and energy efficiency compared with the tested cell. </p> <p> </p> <p>The cell model was integrated into an overall system model which incorporates the effect of concentration changes throughout the entire cycle. Compared to the early-stage thermodynamic modeling, consideration of incomplete reactions provided more accurate predictions of the potential performance of CLHP systems. Different cell and system architectures were investigated to boost system performance. The model predictions demonstrated that the CLHP has the potential to provide high heat pumping efficiencies, but more work is still needed to improve the energy density of the system. </p>

A numerical investigation, based on mathematical modelling of some important phenomena relating to the chemical vapour deposition (CVD) process in a furnace, has been undertaken. This thesis is concerned with investigating the furnace design which results in the maximum possible recovery of the material in the form of flat deposition flux profiles. A finite difference technique is used to solve the Navier-Stokes and the diffusion equations which arise from the CVD process. In Chapter One, the main ideas of the problem are introduced. The investigation of the rectangular duct furnace is discussed in Chapter Two, and the importance of the axial diffusion term is studied. Chapter Three deals with the Plane Parallel wall furnace and the effect of varying certain parameters (i.e. Re, Pe and a) on the deposition flux profiles and the percentage recovery of the material. In Chapter Four, we investigate the impingement jet furnace, while in Chapter Five we study several furnace designs including the cylindrical furnace, the Plane Parallel wall furnace with various outlet configurations and the angled wall furnace. Also the effects of surface kinetics are discussed. Chapter Six describes the multigrid method as a fast method to solve the Navier-Stokes and the diffusion equations.

Vita. / Digitized by Kansas Correctional Industries

Energy consumption by human enhanced activities has led to distinctive environmental problems; in particular, climate change and global warming. In hot regions, the main reason for energy consumption comes from the cooling of many buildings. The intensity and duration of the sunshine in hot regions have a direct relation with the usage of cooling systems. The energy used for cooling purpose is continuously increasing and expected to increase in the following years. Evaporative cooling is one of the passive cooling method which has been used throughout history. As it is cheaper, environmentally-friendly and simpler compared to vapour compression systems, it is more widely used in residential, commercial and industrial buildings in hot and dry regions. Since this method is less efficient and limited under hot and humid climate, the desiccant based evaporative cooling system is preferred in such areas in order to dehumidify the air. The pad material used for evaporative cooling system is important as it helps to evaporate the water. Therefore, the material should be porous enough to absorb water which enhances the rate of evaporation. Moreover, the material should be available and cheap. This study shows the potential of using different materials for evaporative cooling systems. The aim of this study is to investigate the feasibility, suitability and potential of using local materials such as eucalyptus fibres, as cooling pads for evaporative cooling system in hot and dry regions. In addition to this, the liquid desiccant evaporative cooling systems by using potassium formate is also studied for hot and humid areas in Cyprus. Since Cyprus has multi-climate regions due to the topography and different weather condition, different cooling systems can be used for each region. The results are reported in terms of temperature difference, cooling output, COP, etc. The wind tunnel is used to test the eucalyptus fibres with an inlet air temperature of 35 °C to simulate the climate in Cyprus. It was found that the maximum reduction of air temperature was between 11.3 °C and 6.6 °C, while the maximum cooling efficiency was in the range of 71% and 49% at 0.1 and 0.6 m/s air velocity respectively. Corresponding cooling capacities were also calculated as 108 and 409 W indicating a directly proportional relation between air velocities and cooling performance. Following this, the conceptual design ideas of integrated eucalyptus fibres based evaporative cooling panel (EFECP) into building elements are considered to meet the demand for cooling and the architectural requirements of the building. These design ideas were developed for shutter, fenestration, toplighting elements, wind catcher-solar chimney and wall design of the building. The cooling performances of the hollow fibre integrated by using potassium formate desiccant based evaporative cooling system were experimentally investigated under the incoming air temperature in the range of 35 ˚C to 40 ˚C. The cooling capacity is increased as the air velocity is increased. At 3.5m/s, the cooling capacity is 1340 W, 1530 W and 1920 W respectively for incoming air relative humidity of 60%, 65% and 70%. Both evaporative cooling systems performances are discussed and clearly presented in this study. From the experimental testing in this thesis, it is concluded that local eucalyptus fibres can be used for hot-dry areas and liquid desiccant evaporative cooling systems can be used for hot-humid areas of Cyprus. Since using of eucalyptus fibres for evaporative cooling system is locally available, simple construction and easy to apply, the design ideas for integrating eucalyptus fibres with evaporative cooling system are developed within the scope of the thesis. The usage of local eucalyptus fibres and Polyvinylidene fluoride (PVDF) hollow fibres as evaporative cooling pad, the evaporative cooling process designed by using fibres and the conceptual building design ideas integrated local eucalyptus fibres combined with evaporative cooling system are all the novel ideas of this thesis.

No description available.

The characteristics of thermofluid flow cycle for natural refrigerants R-600a and R-290 applying to an air-conditioning system are studied in this project. In system performance analysis, The exergy analysis incorperated with heat transfer and fluid mechanics are also adopted to analyze the exergy transfer and destroy of each component and the whole system. The simulation parameters in this research include room temperatures, outdoor temperatures, and the types of refrigerants. If all the conditions remain constant except room temperature, the numerical results show that the coefficient of performance (COP) and the energy efficiency ratio (EER) will increase when the room temperature increases, or the outdoor temperature decreases. If all simulation conditions are the same, COP and EER with R-600a is better than those with R-290. By using exergy analysis, the numerical results show that the flow exergies through compressor and expansion valve will decrease due to the friction of the fluid flow. However, the flow exergies through condenser and evaporator will decrease due to finite-temperature heat transfer and energy carried away by exterior air. The destruction of the flow exergy due to the irreversibility of the frictional fluid flow is relative small to heat transfer. By using the exergy analysis, we can clearly understand the exergy change within each component of an air-conditioning system. This treatment is very useful in the design of air-conditioning systems and its optimum analysis.

Due to the energy crisis in 1970, the energy saving is more important for the human civilization. The energy-saving policy is important for the economic growth and competition of Taiwan. The energy of daily life and business consumes 17% of the total energy, especially the air conditioning of architectures on the peak hours occupying a third in summer. So the building energy-saving policy is the most important in Taiwan. The main of theme building energy saving is not only to save energy but also to consider the comfortable and healthy of the living environment. So that, the optimal design of the building energy saving of commercial buildings in Taiwan has been established in this paper. In this study, theoretical analysis and a full scale experiment has been performed to validate this design. Results showed this design is suitable for the NPTC building in the weather condition of south Taiwan, which also complies with the energy code of Taiwan.

Thesis (Ph. D.)--School of Mechanical Engineering, Georgia Institute of Technology, 2004. Directed by Sheldon M. Jeter. / Vita. Includes bibliographical references (leaves 195-201).

No description available.

In this thesis, heat powered ejector cooling systems was investigated in two ways: to store the cold energy with energy storage system and to utilize low grade energy to provide both electricity and cooling effect. A basic ejector prototype was constructed and tested in the laboratory. Water was selected as the working fluid due to its suitable physical properties, environmental friendly and economically available features. The computer simulations based on a 1-0 ejector model was carried out to investigate the effects of various working conditions on the ejector performance. The coefficients of performance from experimental results were above 0.25 for generator temperature of lI5°C-130 °C, showing good agreements with theoretical analysis. Experimental investigations on the operating characteristics of PCM cold storage system integrated with ejector cooling system were conducted. The experimental results demonstrated that the PCM cold storage combined with ejector cooling system was practically applicable. The effectiveness-NTU method was applied for characterizing the tube-in-container PCM storage system. The correlation of effectiveness as the function of mass flow rate was derived from experimental data, and was used as a design parameter for the PCM cold storage system. In order to explore the possibility of providing cooling effect and electricity simultaneously, various configurations of combined power and ejector cooling system were studied experimentally and theoretically. The thermal performance of the combined system in the range of 0.15-0.25 and the turbine output between 1200W -1400W were obtained under various heat source temperatures, turbine expansion ratios and condenser temperatures. Such combined system was further simulated with solar energy as driving force under Shanghai climates, achieving a predicted maximum thermal efficiency of 0.2. By using the methods of Life Saving Analysis, the optimized solar collector area was 30m2 and 90m2 respectively for the system without and with power generation. The environmental impacts and the carbon reductions of these two systems were discussed.