This dissertation describes our study on different physical properties of passivated and chemically modified hybrid metal halide perovskite materials and development of highly efficient charge transport layers for perovskite solar cells. We first developed an efficient electron transport layer via modification of titanium dioxide nanostructure followed by a unique chemical treatment in order to have clean interface with fast electron injection form the absorber layer in the perovskite solar cells. We then explored monovalent cation doping of lead halide perovskites using sodium, copper and silver with similar ionic radii to lead to enhance structural and optoelectronic properties leading to higher photovoltaic performance of the resulting perovskite solar cells. We also performed thorough experimental characterizations together with modeling to further understand the chemical distribution and local structure of perovskite films upon monovalent cation doping. Then, we demonstrate a novel passivation approach in alloyed perovskite films to inhibit the ion segregation and parasitic non-radiative losses, which are key barriers against the continuous bandgap tunability and potential for high-performance of metal halide perovskites in device applications, by decorating the surfaces and grain boundaries with potassium halides. This leads to luminescence quantum yields approaching unity while maintaining high charge mobilities along with the inhibition of transient photo-induced ion migration processes even in mixed halide perovskites that otherwise show bandgap instabilities. We demonstrate a wide range of bandgaps stabilized against photo-induced ion migration, leading to solar cell power conversion efficiencies of 21.6% for a 1.56 eV absorber and 18.3% for a 1.78 eV absorber ideally suited for tandem solar cells. We then systematically compare the optoelectronic properties and moisture stability of the two developed passivation routes for alloyed perovskites with rubidium and potassium where the latter passivation route showed higher stability and loading capacity leading to achieve substantially higher photoluminescence quantum yield. Finally, we explored the possibility of singlet exciton fission between low bandgap perovskites and tetracene as the triplet sensitizer finding no significant energy transfer between the two. We then used tetracene as an efficient dopant-free hole transport layer providing clean interfaces with perovskite layer leading to high photoluminescence yield (e.g. ~18%). To enhance the poor ohmic contact between tetracene and the metal electrode, we added capping layer of a second hole transport layer which is extrinsically doped leading to 21.5% power conversion efficiency for the subsequent solar cells and stabilised power output over 550 hours continuous illumination.