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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

ATRP with a light switch: photoinduced ATRP using a household fluorescent lamp

Zhang, Tao, Chen, Tao, Amin, Ihsan, Jordan, Rainer 06 December 2019 (has links)
Photoinduced atom transfer radical polymerization (ATRP) was achieved using a simple household fluorescent lamp as the light source. In solution, methyl methacrylate could be polymerized to welldefined polymers; the photoinduced ATRP system did only convert monomers during irradiation and was inactive in the dark. In situ monitoring by UV-vis spectroscopy revealed the photoredox cycle between Cuᶦᶦ and Cuᶦ species. The linear development of the polymer number average molar mass with monomer conversion, the low dispersity as well as chain extension experiments showed the controlled nature of the polymerization. Photoinduced ATRP was also used to prepare homo- and block copolymer brushes and patterned brushes on surfaces by photoinduced surface-initiated ATRP (PSI-ATRP).

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