O presente trabalho apresenta um estudo de quimioestratigrafia isotópica (C, O, Sr) de detalhe, realizado numa sucessão carbonática de idade ediacariana da porção extremo norte da Faixa Paraguai, Estado do Mato Grosso. A pesquisa se justifica já que durante o Neoproterozóico a Terra sofreu profundas mudanças climáticas, as quais foram registradas em enigmáticas sucessões compostas de depósitos glaciais recobertos por rochas carbonáticas de clima quente. Estudos recentes mostram que ocorreram, pelo menos, três glaciações neste período, denominadas Sturtiana (ca. 725 Ma), Marinoana (ca. 635 Ma) e Gaskierana (580 Ma). Na tentativa de estabelecer uma correlação global entre as sucessões depositadas neste período, os geopesquisadores têm usado diversas ferramentas, principalmente a quimioestratigrafia isotópica de C, O e Sr. Na região de estudo, ocorrem diamictitos da Formação Puga recobertos por rochas carbonáticas do Grupo Araras, sobre a qual se depositam os diamictitos e carbonatos da Formação Serra Azul, definida neste trabalho. A sucessão carbonática do Grupo Araras apresentou valores de d13C variando de ? 1,7? (base) a + 4? (topo) e razões 87Sr/86Sr entre 0,7075 (na base) e 0,7084 (no topo). Estes valores são semelhantes àqueles encontrados em outras sucessões carbonáticas Marinoanas. Os calcários da Formação Serra Azul apresentaram um valores de d13C entre ? 7,5% e ? 3,2% e razões 87Sr/86Sr de ca. 0,7086, típicas das sucessões carbonáticas Gaskieranas. Os resultados isotópicos obtidos neste trabalho, associados às evidências sedimentológicas, sugerem que na história geológica de deposição da Faixa Paraguai ocorreram, pelo menos, duas importantes glaciações. / This work presents a detailed isotopic (C, O, and Sr) chemostratigraphic study carried out on the Ediacaran carbonate succession from the northernmost part of the Paraguay Belt, in Mato Grosso, Brazil. The importance of this study is related to the Earth´s profound climate changes that took place during the Neoproterozoic, which have been recorded by enigmatic sequences composed of glacial deposits immediately overlain by carbonate rocks typical of warm climate. At least three glaciations are recognized: Sturtian (ca. 725 Ma), Marinoan (ca. 635 Ma), and Gaskiers (580 Ma). In order to correlate worldwide the successions deposited in this period and to understand the complex depositional environments, isotopic tools, especially chemostratigraphy, have been widely used. In the study area diamictites of the Puga Formation are overlain by carbonates of the Araras Group, and these, in turn, are covered by diamictites and carbonates of the Serra Azul Formation, which is defined here. The Araras Group carbonates exhibited d13C values between ? 1.7? at the base and + 4 ? at the top and 87Sr/86Sr ratios ranging from 0.7075 at the base to 0.7084 at the very top. These values are similar to those of post-glacial, non-cap Marinoan carbonate successions. The limestones of the Serra Azul Formation yielded d13C values between ? 7.5 and ? 3.2 ?, and 87Sr/86Sr ratios of ca. 0.7086, typical of post-Gaskiers cap carbonates. These isotopic results, together with sedimentological evidence, suggest that two important glaciations occurred during the depositional history of the northernmost Paraguay Belt.

A faixa Araçuaí, de idade neoproterozóica, caracteriza-se por apresentar em seu domínio alóctone, uma grande quantidade de intrusões magmáticas, uma crosta parcialmente fundida e rochas de facies granulítica, características de uma geoterma elevada, configurando trata-se de um orógeno quente. A suíte tonalítica Galiléia, alojada em metassedimentos, deformada no estado magmático, representa um grande batólito que influenciou de maneira significativa o comportamento mecânico desta crosta mediana. A Anisotropia de Suscetibilidade Magnética (ASM) medida nesse batólito e usada para um estudo de petrotrama, combinado com uma investigação detalhada sobre a mineralogia magnética, permitiu caracterizar o comportamento paramagnético da Suíte Galiléia e, adicionalmente, trazer informações sobre uma deformacão complexa em 3D. As estruturas observadas se desenvolveram em um magma viscoso resultado de uma combinação da tectônica tangencial induzidas por compressão e forças gravitacionais devido ao peso da crosta sobrejacente. A cinemática do batólito é compatível com aquela descrita para as rochas dúcteis da faixa. Datações U/PB em zircões e monazitas e 40Ar/39Ar em anfibólios, moscovitas e biotitas permitiram definir a evolução termal do batólito Galiléia e de seus metassedimentos hospedeiros e trazer informações sobre o período deformacional. O batólito Galiléia colocouse durante um importante evento magmático, termal e tectônico a ~ 580 Ma. A temperatura permaneceu alta durante os primeiros ~ 50Ma da evolução termal, promovendo uma deformação quase constante do batólito no estado magmático durante várias dezenas de milhões de anos. Tais condições de alta temperatura e cinemática deformacional, estável durante períodos prolongados de tempo, são característicos de orógenos quentes. A taxa de resfriamento vagarosa de ~ 10°C/Ma sugere que após ~500Ma a taxa de exumação foi muito lenta, provavelmente ocasionada apenas pela erosão. / The allochtonous domain of the Neoproterozoic Araçuaí belt involves large amounts of magma, widespread partial melting, granulitic facies and high geotherm, characterising this belt as a hot orogen. The Galiléia tonalitic suite, emplaced within host metasediments and deformed at magmatic state, represents a huge batholith that strongly influenced the mechanical behaviour of this middle crust. The anisotropy of magnetic susceptibility (AMS) measured through this batholith and used as a petrofabric proxy, combined to a detailed magnetic mineralogy investigation, permitted to characterize the paramagnetic behaviour of the Galiléia suite and therefore to highlight a complex 3D strain deformation. The observed structures developed within the viscous magma resulted from a combination of tangential tectonics induced by the compression, and gravitational forces arising from the load of the overlying crust. The kinematics of the batholith is compatible with that already described for ductile rocks of hot orogens. U/Pb dating on zircons and monazites together with 40Ar/39Ar dating on amphiboles, muscovites and biotites permitted to define the thermal evolution of the Galiléia batholith and its host metasediments and constrain the timing of the deformation. The Galiléia batholith emplaced during an important magmatic, tectonic and thermal event at ~580 Ma. Temperature remained high during the first ~50 Ma of the thermal evolution, promoting a seemingly constant deformation of the batholith at magmatic state during several tens of millions years. Such high temperature conditions and stable deformation kinematics during protracted periods of time are supposed to be characteristic of hot orogen. The slow cooling rate of ~10°C/Ma evidenced after ~500 Ma probably indicate a very slow exhumation probably only conducted by erosion.

Orientador: Elson Paiva de Oliveira / Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Geociencias / Made available in DSpace on 2018-08-12T03:34:56Z (GMT). No. of bitstreams: 1 Ruggiero_Alberto_M.pdf: 5764806 bytes, checksum: cdadd28e98d86c8738fcf5955bd71eea (MD5) Previous issue date: 2008 / Resumo: Novos dados geoquímicos nas rochas vulcânicas andesíticas e dacíticas da Unidade Maria Preta (UMP), Greenstone Belt do Rio Itapicuru, revelaram a presença de dois grupos geoquímicos distintos: um de rochas com afinidade adakítica e outro com caráter cálcio-alcalino. A suíte adakítica (ADK), localizada nas porções oeste da UMP, é caracterizada pelos altos valores de Sr/Y (Sr ~900 ppm, Y~5ppm); Na2O ~ 4,5ppm (K2O/Na2O ~0,3). É caracterizada também pelo enriquecimento de LILE (elementos litófilos de alto raio iônico) relativos aos HFSE (elementos de elevado potencial iônico) e também pelo moderado fracionamento dos elementos terras-raras (La/Yb ~ 12). A suíte cálcio-alcalina (CA) apresenta baixas razões Sr/Y (Sr ~ 170 ppm, Y~ 22 ppm), menor fracionamento de elementos terras-raras (La/Yb ~8) e anomalias negativas de Eu. No entanto apresenta maiores concentrações de elementos incompatíveis (Y ~22ppm, Zr ~142ppm, Th ~6ppm) e também Cr e Ni. Foi revelado, através de modelagem geoquímica que as duas suítes não se relacionam por cristalização fracionada. Contudo a suíte Adk apresenta indícios de cristalização fracionada de hornblenda enquanto que na CA a cristalização fracionada de plagioclásio desempenhou papel importante. O ambiente mais provável para a formação das rochas vulcânicas cálcioalcalinas é fusão em baixas profundidades da cunha do manto metassomatizado por fluídos liberados a partir de uma crosta oceânica subductada, seguida por fracionamento de plagioclásio. A geoquímica dos adakitos requer fusão de meta-basaltos hidratados em pressões elevadas, onde granada+hornblenda são estáveis e constituem o restito da fusão. Em geral, as rochas adakíticas apresentam indícios de pouca interação do magma original com uma coluna de manto peridotitico, como visto em adakitos atuais, dados os baixos valores de Cr e Ni em relação aos adakitos cenozóicos. A suíte cálcio-alcalina apresenta menores valores de fugacidade de oxigênio no sítio de extração do magma (entre -3 e -1 FMQ). Ao contrário, os adakitos apresentam maiores valores (entre -1 e +0,5 FMQ), semelhantes aos valores encontrados em adakitos modernos formados por fusão de crosta oceânica subductada. Dados de isótopos de Sm-Nd forneceram idades modelo TDM para a suíte adakítica de 2.213 a 2.010 Ma, com valores de eNdT de +3,9 a +1,7. A suíte cálcio-alcalina revelou idades modelo mais antigas, entre 2.330 e 2.279 Ma e menores valores de eNdT de +0,7 a + 1,3. Estes valores indicam magmatismo juvenil para ambas as suítes, porém com maior tempo residência crustal para a fonte das rochas cálcio-alcalinas, ou interação do magma com crosta mais antiga. Datação U-P SHRIMP em andesito adakítico revelou idade de cristalização de 2.081 ±9 Ma e a presença de zircões herdados arqueanos (3364, 3017, 3064 Ma), evidenciando que o magma gerado em zona de subducção interagiu com crosta arqueana, provavelmente o embasamento do Greenstone Belt do Rio Itapicuru, sugerindo então um provável arco continental como origem da Unidade Maria Preta. Esses dados sugerem que o vulcanismo intermediário a félsico do Greenstone Belt do Rio Itapicuru foi formado ou teve relação direta com subducção. Esta possivelmente teve uma vergência de leste para oeste, evidenciada pela zonalidade na geoquímica das rochas vulcânicas (adakitos à oeste e cálcio-alcalinas a leste). / Abstract: New geochemical data on andesites and dacites of the Maria Preta Unit, Rio Itapicuru Greenstone Belt, revealed two distinct geochemical groups: one of adakitic affinity and another of typical calc-alkaline. The adakitic suite, localized west in the unit, is characterized by high values of Sr/Y and Ti/YN >1. It shows enrichment in LFSE (Low Field Strength Elements) relative to HFSE (High Field Strength Elements) and a moderate rare earth element fractionation. The calc-alkaline suite (CA) shows low Sr/Y ratios, less rare earth elements fractionation and negative Eu anomalies. On the other hand it shows higher incompatible elements abundances (Y, Zr, Th) and high Cr and Ni concentrations. The two suites cannot be linked by fractional crystallization and are derived from different sources (distinct initial Nd ratios). The most probable setting for the formation of CA is partial melting of mantle peridotite modified by hydrous fluids released from a subducting slab, followed by low pressure plagioclase fractionation. The adakite geochemical features require partial melting of hydrous metabasalts at depths high enough to stabilize garnet+hornblende as the residual phase. This suite does not reveal significant interactions with the mantle, as shown by its lower Cr and Ni values than Cenozoic adakites. For an assumed 2170 Ma age, the Sm-Nd isotope data show higher eNd(t) for the adakites (+4,8 to +2,5) than for the calc-alkaline suite (+1,9 to +1,4). These data indicate a juvenile source for the UMP volcanic rocks. U-Pb SHRIMP dating indicates a crystallization age of 2,081 ± 9 Ma for the adakitic volcanic. Inherited Archean zircons (3364, 3017, 3064 Ma) evidence a magma generated at a subduction zone followed by interaction with Archean lithosphere, probably the basement of the Rio Itapicuru Greenstone Belt. The calc-alkaline suite shows low oxygen fugacities at the magma extraction site (between -3 e -1 FMQ). On the other side, the adakites shows higher values (between -1 e +0,5 FMQ), similar to modern adakites formed by a subducting slab melt. This results suggests that the UMP volcanism was formed or was directly connected to a subduction. The geographic position of the two suites, i.e. adakites to the west of the calc-alkaline volcanics, suggests subduction of an oceanic plate to the west. / Mestrado / Geologia e Recursos Naturais / Mestre em Geociências

D.Phil. / Lode-gold deposits usually occur in granite-greenstone terranes of low- to medium-grade of metamorphism. Such deposits are well studied in terms of their petrogenesis, ore mineralogenesis and structural control. Gold occurrences associated with high-grade terranes are, however, also known from the Yilgam Block in Australia (Griffin's Find) and Northern Marginal Zone of the Limpopo Belt in Zimbabwe (Renco), but the genesis of these deposits are not as well understood as that of their lower grade counterparts. The Doornhoek lode-gold deposit, situated in the granulite terrane of the Southern Marginal Zone of the Limpopo Belt in South Africa displays an important sequence of structural and metamorphic events that proved to be very useful in understanding the formation of metamorphic gold deposits formed under upper-amphibolite - granulite facies conditions. Structurally the Doornhoek gold deposit is situated in a large low-angle D, fold plunging towards the west at 10-15 °. The fold structure and the mineralised zone are affected by D2-strike-slip shear zones which occur both within and along the outer contacts of the ore zone. The gold deposit is also affected by southward verging D3 shear zones which thrusted Baviaanskloof Gneiss over and onto the Doomhoek Ore Body. The Doomhoek Gold Deposit is also situated in a highly altered zone of metasomatised rocks within the zone of rehydration of the Southern Marginal Zone. The actual Ore Body is represented by a remnant of BIF, mafic and ultramafic rocks surrounded by Baviaanskloof Gneiss. The alteration process, caused by high-temperature fluids channeled along the D2 shear zones was responsible for the formation of the different metasomatic lithologies. These altered rocks initially experienced a regional hydration event followed by the high-temperature metasomatic event. The very intense metasomatic activity was synchronous with the growth of prograde-zoned garnet and gold mineralisation associated with quartz veins. This scenario is suggested by the fact that gold associated with Zn, Ge, As, Y, Zr and Ni was trapped in the mineralised inner-ring of the zoned garnet, by the REE pattern and presence of Th232 and U238 in the biotite-garnetiferous formation, and by the mobility of major elements such as A1 203, K2O, SiO2 and TiO2 associated with the metasomatic activity. The alteration is probably related to externally derived magmatic fluids mixed with metamorphic aquitards that were active in both open and close system conditions along deep seated D2 shear zones. These fluids are characterised by the presence of high-density CO 2-rich and high salinity fluid inclusions. The gold mineralisation is closely associated with pyrrhotite, magnetite, lollingite, arsenopyrite, chalcopyrite, ilmenite, pentlandite, sphalerite and gold. The gold has a very low fineness (520), typical of gold precipitated from hydrothermal solutions at high-grade conditions. The textural relationships of the ore minerals hosted by the quartz veins, furthermore demonstrate a prograde pattern of mineralisation, similar as in the case of mineralisation trapped within different zones of the zoned garnet porphyroblast. The dark inner-ring of the garnet is characterised by high concentrations of sulphides, oxides and gold. The mineralising event initially deposited sphalerite and arsenopyrite at low temperatures of up to 569 °C with temperatures increasing to 673 °C, and even up to 750°C when lollingite was formed. Most of the gold is related to As-rich arsenopyrite, lollingite and graphite at temperatures ranging from upper-amphibolite facies to lower-granulite facies metamorphic conditions. The Doornhoek gold deposit is an example of a high-grade lode-gold deposit formed during a prograde hydrothermal event and demonstrates unequivocally the possibility of economic gold mineralisation during granulite facies conditions. This observation has important implications for gold exploration in high-grade geological terranes that to date have been mostly ignored by the gold mining industry.

Announced in 2013, the One Belt One Road(OBOR) Initiative is considered the most important geopolitical development strategy of the 21st-century in the country. The Chinese government aims to promote trade and investment with more than 63 OBOR countries. In this paper, I analyze the impact of One Belt One Road Initiative on China’s foreign direct investment for a period of 2003-2015 with a country level panel data. Other determinants frequently used in the FDI literature such as market size, geographical distance, resources, trading effects and political risks are also considered in the model. The empirical results show that OBOR policy is positively associated with China’s outward FDI flow. I believe the research result indicates a policy related trend for Chinese firms’ overseas investments.

Au sein de la croûte terrestre, une grande partie des processus de mobilisation et redistribution des métaux résulte de circulations de fluides à grande échelle. Par conséquent, c’est un paramètre clé dans la formation de nombreux types de gisements variés. Les zones de déformation étant les vecteurs principaux des circulations de fluides, la plupart des gisements d’or (Au) et d’antimoine (Sb) se retrouvent localisés au sein des ceintures orogéniques. Le Massif Armoricain constitue un segment de la chaîne varisque ouest-européenne et contient de nombreux gisements à Sb-Au. L’objectif de cette thèse est à la fois de fournir de nouvelles contraintes sur la genèse des minéralisations varisques à Sb-Au et d’améliorer l’état des connaissances sur les processus critiques à l’origine des circulations de fluides minéralisatrices. Ainsi, une analyse des relations spatiales et des analyses structurales, géochronologiques et géochimiques ont été réalisées sur les gisements à Sb-Au du Domaine Centre Armoricain (DCA) et sur le gisement du Semnon en particulier. Une grande partie des gisements à Sb-Au est spatialement associée à des zones denses et relativement magnétiques suggérant la présence de corps mafiques/ultramafiques en profondeur. Cela est supporté par les nombreuses occurrences de dykes et sills de dolérites à travers toute la région. Ces dykes et sills sont issus d’un important évènement magmatique mafique mis en place à 360 Ma durant un changement drastique de la dynamique de convergence, passant de la subduction continentale à l’initiation de la collision. Les minéralisations à Sb-Au du DCA sont précoces dans l’histoire Carbonifère de la chaîne varisque armoricaine. Par conséquent, la plupart des minéralisations du DCA ne sont pas associées à l’évènement hydrothermal minéralisateur tardi-Carbonifère, bien connu dans la chaîne varisque européenne, en particulier au sein des zones internes de la chaîne tel que le Massif Central français. Au-delà du fait que cet évènement hydrothemal à Sb-Au soit précoce, la mise en place d’un magmatisme mafique généralisé dans la croûte supérieure du DCA est synchrone avec les minéralisations à Sb-Au et apparait comme un paramètre essentiel dans la mobilisation de circulations de fluides minéralisateurs advectifs. A plus grande échelle, la mise en place d’un magmatisme mafique couplée à la circulation de fluides hydrothermaux à Sb-Au met en lumière et améliore nos connaissances sur les processus hydrothermaux, magmatiques et tectoniques d’échelle lithosphérique gouvernant l’hydrothermalisme porteur de métaux. Par conséquent, ces résultats ouvrent de nouvelles perspectives pour l’exploration minière, notamment dans la recherche de nouveaux gisements d'antimoine et d'or au sein de la chaîne varisque européenne. / Through the Earth’s crust, a major part of the mobilization and the redistribution processes of metals are the result of large-scale fluid flows. Consequently, it is a key factor in the formation of various types of mineral deposits. Because deformation zones are the principal vector for fluid flows, most hydrothermal antimony (Sb) and gold (Au) deposits are localized in orogenic deformed belts. As a western part of the European Variscan belt, the Armorican Massif hosts several Sb-Au deposits. The purpose of this work is to provide new constraints on the genesis of these Variscan Sb-Au mineralization and to improve our knowledge about critical processes for hydrothermal mineralizing fluid flows. For these reasons, spatial relationships, structural, geochemical and geochronological investigations were performed on the Sb-Au deposits from the Central Armorican Domain (CAD), the Le Semnon Sb-Au deposit in particular. A major part of Sb-Au deposits are spatially associated with high-density and magnetic zones reflecting the presence of mafic/ultramafic bodies at depth and that is supported by numerous occurrences of dolerite dykes and sills throughout the region. These dykes and sills are issued from an important mafic magmatic event at ca. 360 Ma emplaced during a plate dynamic shift from continental subduction to incipient collision stage. Sb-Au mineralization from the CAD belongs to the early Carboniferous history within the Variscan framework. Consequently, most of Sb-Au mineralization (at least in the CAD) is not related to the Late Carboniferous hydrothermal mineralizing event, well-identified in the Variscan southernmost internal zones and especially in the French Massif Central. Beyond that early hydrothermal event, the widespread emplacement of a mafic magmatism in the CAD upper crust is coeval with Sb-Au mineralization and appears as a major trigger for highly advective mineralizing fluid flows. At a larger scale, mafic magmatism emplacement coupled with early Carboniferous Sb-Au hydrothermal fluid flows highlights and improves our knowledge of lithospheric-scale tectonics, magmatic and hydrothermal processes governing such metal-bearing hydrothermalism. As a consequence, those results provide a new framework for future mining exploration of antimony and gold deposits in the European Variscan belt.

M.Sc. / The Limpopo Complex (LC) of southern Africa is one of the best-studied Precambrian granulite facies terrains in the world, yet workers still disagree on fundamental aspects of the geological evolution of this complexly deformed high-grade terrain. Most workers agree that the two marginal zones were exhumed in the late-Archaean, but disagree on the timing of major tectono-metamorphic events that affected the Central Zone (CZ) of Limpopo Belt, and the mechanism/s of its formation. There are currently two main schools of thought: The first school regards the LC as a late-Archaean orogenic zone that resulted from a north-south collision of the Zimbabwe and Kaapvaal cratons. Granitic plutons throughout the entire LC are considered to be accurate time-markers for this orogeny. The second school suggests that the CZ evolved as a result of a major Paleoproterozoic tectono-metamorphic event based mainly on the interpretation of metamorphic mineral ages. The present study focuses on two aims, namely (i) to provide a synthesis of published data as a basis to understand the ongoing age controversy concerning the evolution of the CZ, and (ii) to show that specific fold types in the CZ can be related to either the late-Archaean or the Paleoproterozoic event. New age, structural, metamorphic, and petrographic data are presented to show that (i) major sheath folds reflect the peak tectono-metamorphic event that affected the CZ in the late-Archaean, while (ii) major cross folds developed as a result of a transpressive event in the Paleoproterozoic. The age of formation of the Avoca sheath fold located about 40 km west of Alldays is accurately constrained by the age of emplacement of different structural varieties of precursors to the Singelele Gneiss: penetratively deformed syn- to late-tectonic Singelele gneisses with a zircon SHRIMP age of 2651 ± 8 Ma, date the time of formation of the sheath fold that is characterized by a single population of linear elements that define the central fold axis. The Avoca sheath fold documents top-to-the-NNE movement of material during the exhumation of the high-grade CZ rocks. Weakly foliated late-tectonic L-tectonites with a zircon SHRIMP age of 2626.8 ± 5.4 Ma, outcrop near the centre of the sheath fold, and provide a minimum age for the shear deformation event. An almost undeformed (post-tectonic) variety of the Singelele Gneiss was emplaced after the shear event. A detailed metamorphic study of metapelitic gneisses from the large Baklykraal cross fold, located about 20 km east of the Avoca sheath fold, documents a single decompression-cooling (DC) P-T path for the evolution of this structure. Three studied metapelitic samples characterized by a single generation of garnet provide a Pb-Pb age of 2023 ± 11 Ma, that accurately constrain the time of formation of this major fold to the Paleoproterozoic. A metapelitic sample characterized by two generations of garnet provide a slightly older Pb-Pb age of 2173 ± 79 Ma, that is interpreted to also reflect the late-Archaean event. The Baklykraal cross fold is characterized by two populations of linear elements: the one population defines the shallow N-S oriented fold axes, while the second population is associated with top-to-the-NNE movement of material during exhumation, resulting in folds with a nappe-like geometry. A DC P-T path for the Campbell cross fold (Van Kal, 2004) located just west of Musina, suggests that cross folds developed under significantly lower P-T conditions than is the case with sheath folds, providing an explanation for the lack of significant anatexis associated with the Paleoproterozoic event. The late-Archaean orogeny in contrast, was accompanied by widespread anatexis during a major magmatic event that is characterized by an abnormal high radiogenic signature. This study, for the first time, provides evidence that link specific fold types, and thus deformational events, to different tectono-metamorphic events. The main conclusion is that the CZ was exhumed as the result of two distinct orogenies, one in the late-Archaean, and the other in the Paleoproterozoic.

An existing furnace oil fired boiler is used to supply process steam to an instant tea manufacturing factory. The instant tea is manufactured the Broken Mixed Fannings (BMF) through extraction and other required processes. The average steam consumption of the plant is 6000 kg/h at 10 barg pressure. During the process, tea waste is generated at a nominal rate of 50,000 kg/day, about 2000 kg/h at around 70% MC content on wet basis. At the moment this waste tea is either dumped in the surrounding area by spending money or sent to landfilling purposes, which create environmental issues.   The tea waste coming out at 70% MC wet basis, is looked at to press through continuous belt press to reduce the moisture content to about 55% on wet basis. The water removed from this pressing process is sent to effluent treatment plant at the factory. The output from the belt press is sent to a steam operated  The average generation of tea waste from the instant tea manufacturing process process is about 2000 kg/h, after pressing in the belt press an output rate of about 1,400 kg/h at 55% MC. This amount of tea waste at 55% MC is sent to a rotary steam tube dryer and the MC is reduced from 55% to 30% and the output rate from the steam tube dryer is about 857 kg/h. The amount of steam consumed by the rotary steam tube dryer at 6 barg pressure is 760 kg/h. Then the tea waste from the rotary tube dryer is mixed with firewood of 30% MC and fed to the boiler to generate process steam, out of which 857 kg/h steam at 6 barg pressure is sent back to the rotary steam dryer. From tea waste alone, a steam amount of 2,472 kg/h can be supplied after giving steam to the rotary steam dryer. The balance steam amount of 3,528 kg/h for the process requirement is supplied by burning additional firewood at 30% MC content. The tea waste fuel and firewood in combination have an overall moisture content of 30% on wet basis. The boiler is rated at 10,000 kg/h F & A 100 deg C with an actual generating capacity of about 9000 kg/h at 10 barg operating pressure at 70 deg C feed water temperature. By implementing the combination of belt press, rotary steam tube dryer and firewood boiler in place of the existing furnace oil fired boiler, an annual monetary saving of 168 Mn SLR/year can be achieved with a simple payback period of 21 months which is a highly feasibly project.

The study area comprises the Archaean Manica Greenstone Belt and the Vumba Granite Gneiss, the Proterozoic Messica Granite Gneiss of the Zimbabwe Craton, the possibly allochthonous metasedimentary sequence of the Frontier Formation, the granitoids of the Mozambique Metamorphic Province, which are subdivided into Vanduzi Migmatite Gneiss, the Chimoio Granodiorite Gneiss, the Nhansipfe Granitic Orthogneiss and the Pan-African Tchinhadzandze Granodiorite Gneiss. The rock sequences in the two provinces are cut by mafic intrusions. The greenstone belt comprises mafic to ultramafic and pelitic schists and serpentinites of the Macequece Formation and metasediments ofthe M'BezaNengo Formation. The mafic to ultramafic schists and the serpentinites have chemical signatures of komatiites. The Vumba Granite Gneiss comprises the northern and southern Vumba granitoids dated at 3885±255 Ma, and 2527±632 Ma respectively. They vary from metaluminous to peraluminous, have normative QAP compositions of granodiorites and monzogranites and chemical signatures of mantle fractionates and volcanic-arc granitoids. The Early Proterozoic Messica Granite Gneiss is 2348±267 Ma old, is metaluminous and has QAP compositions of monzogranites and chemical signatures suggesting a crustal source and a volcanic-arc environment. The Frontier Formation comprises quartzite and pelitic schists. The Vanduzi Migmatite Gneiss comprises stromatic and stictolithic types. Two mineral assemblages are distinguished as they contain either garnet or hornblende. The Mid-Proterozoic Chimoio Granodioritic Gneiss is 1236±201 Ma old. It is granodioritic and metaluminous with a chemical signature of volcanic-arc granitoids. The Late Proterozoic Nhansipfe Granitic Orthogneiss is dated at 981 ±83 Ma and varies from metaluminous to peraluminous. The Rb, Nb and Y contents are typical of within-plate granitoids, whereas Ga, Zr, AI, Ce andY are typical of A-type granitoids. The age of the mafic intrusions falls between ~500 and ~11 00 Ma. The rocks typically contain plagioclase, hornblende and clinopyroxene with or without garnet and orthopyroxene. The chemistry of the rocks is typical of sub-alkaline tholeiites. The Tchinhadzandze Granodiorite Gneiss may be part of a Pan African event which lasted till ~450-~500 Ma. The normative feldspar compositions and Rb, Ba and Sr contents are typical of granodiorites. It is metaluminous and has Rb, Y and Nb contents typical of volcanic arc granitoids. The planar fabrics in the Archaean granite-greenstone belt are characterized by E-W to SW-NE strikes and steep dips to N and S and to NW and SE. The mineral lineations and fold axes plunge 60° and 30° respectively towards the E. Within the Mozambique belt, around the central part and in the extreme east of the study area, the planar fabrics have essentially N-S strikes and steep dips to E and Win contrast with complex deformation observed in the migmatites and megacrystic granitoids. The study area can be subdivided into three metamorphic blocks, namely, one of low-grade greenschist facies, one of medium-grade amphibolite facies and a third block of high-grade metamorphism. / Dissertation (MSc)--University of Pretoria, 2012. / Geology / unrestricted

Mean motion resonances (MMRs) play an important role in the formation and evolution of planetary systems and have significantly influenced the orbital properties and distribution of planets and minor planets in the solar system and in. exoplanetary systems. Most previous theoretical analyses have focused on the low- to moderate-eccentricity regime, but with new discoveries of high-eccentricity resonant minor planets and even exoplanets, there is increasing motivation to examine MMRs in the high-eccentricity regime. Here we report on a study of the high-eccentricity regime of MMRs in the circular planar restricted three-body problem. Numerical analyses of the 2: 1 and the 3: 2 interior resonances are carried out for a wide range of planet-to-star mass ratio mu, and for a wide range of eccentricity of the test particle. The surface-of-section technique is used to study the phase space structure near resonances. We find that new stable libration zones appear at higher eccentricity at libration centers that are. shifted from those at low eccentricities. We provide physically intuitive explanations for these transitions in phase space, and we present novel results on the mass and eccentricity dependence of the resonance widths. Our results show that MMRs have sizable libration zones at high eccentricities, comparable to those at lower eccentricities.