Enhanced interest in biofuel production has renewed interest in bioenergy crop production within the United States. Agriculture’s role in biofuel production is critical because it has the potential to supply renewable energy while minimizing greenhouse gas (GHG) emissions. However, agronomic management practices influence direct and indirect GHG emissions, and both can have a significant impact on biofuel production efficiency. Our overall objective was to determine the carbon (C) footprint of bioenergy sorghum (Sorghum bicolor L.) production in central Texas. Specifically, we determined the impacts of crop rotation, nitrogen (N) fertilization, and residue return on direct and indirect GHG emissions, theoretical biofuel yield, C pools, and life cycle GHG emissions from bioenergy sorghum production in 2010 and 2011. An experiment established in 2008 near College Station, TX to quantify the impacts of crop management practices on bioenergy sorghum yield and soil properties was utilized, and included two crop rotations (sorghum-sorghum or corn-sorghum), two fertilization levels (0 or 280 kg N ha^(-1) annually), and two residue return rates (0 or 50% biomass residue returned) to assess management impacts on sorghum production, C cycling, and life cycle GHGs. Corn production was poor under moderate drought conditions, while bioenergy sorghum produced relatively large yields under both moderate and severe drought conditions. Nitrogen addition increased crop yields, and rotated sorghum had higher yield than monoculture sorghum. Fluxes of CO_(2) and N_(2)O were higher than those reported in literature and highest soil fluxes were frequently observed following precipitation events during the growing season. Residue return increased cumulative CO_(2) emissions and N fertilization increased N_(2)O emissions. Residue return also increased soil microbial biomass-C, an important indicator of soil quality. Continuous sorghum significantly increased soil organic C (SOC) concentrations near the soil surface and at two depths below 30 cm. Analysis of change in SOC across time to estimate net CO_(2) emissions to the atmosphere revealed bioenergy sorghum production accrued high amounts of SOC annually. Most treatments accrued more than 4 Mg C ha^(-1) yr^(-1) from 2008 to 2012, which indicated great potential for C sequestration and offsetting GHG emissions. Life cycle GHG emissions (as g CO_(2)-eq MJ^(-1)) were all negative due to high SOC increases each year and indicated all bioenergy sorghum production treatments sequestered atmospheric CO_(2) per unit of theoretical energy provided. Despite its relatively low production efficiency, rotated sorghum with N addition and residue return was selected as the ideal bioenergy sorghum production scenario due to a number of sustainability factors. Bioenergy sorghum may offer great benefit as a high-yielding biofuel feedstock with minimal impacts to net GHG emissions.

The purpose of this dissertation is to provide an effective approach to design the supply chain (SC) of the cellulosic biofuel industry in order that it will support and accelerate the successful commercialization of the cellulosic biofuel industry. The methods of approach to this problem are (1) to assess the state-of-the-art biofuel SC studies, (2) to provide a decision support tool based on a mixed integer programming (MIP) model for the cellulosic biofuel supply chain design problem (BSCP), (3) to devise an exact solution method to solve large-scale instances of BSCP, (4) to evaluate a biomass logistics system based on biomass modules, by using new simulation elements for new machines, and (5) to compare several biomass logistics systems based on biomass module, bale, and silage, using simulation models. The first part of this dissertation broadly reviews the literature on biofuel SCs, analyzing the state-of-the-art biofuel and petroleum-based fuel SC studies as well as relating generic SC models that have been published over the last decade to the biofuel SC (An et al., 2010a). The resulting analysis proposes fertile opportunity for future research to contribute to improving biofuel SC. The second part of this dissertation formulates BSCP as a MIP model, which is a time-staged, multi-commodity flow, network design problem with an objective of maximizing profit (An et al., 2010b). The model prescribes strategic level decisions (i.e., facility locations, capacities, and technology types) as well as plans for transportation routes and material flows (i.e., quantities produced, stored, and transported) in each time period. A case study demonstrates managerial use in application to a region in Central Texas. The third part of this dissertation provides an exact solution method to solve BSCP. An embedded structure can be transformed to a generalized minimum cost flow problem, which is used as a sub-problem in a CG approach. This study proposes a dynamic programming algorithm to solve the sub-problem in O(m), generating improving path-flows. To accelerate branch-and-bound (B&B) search, it develops an inequality, called the partial objective constraint (POC), which is based on the portion of the objective function associated with binary variables. The fourth part of this dissertation evaluates a biomass module system, which is a conceptual logistics system based on large packages of chopped biomass with sufficient size and density to provide maximized legal highway loads and quick load/unload times. The last part of this dissertation evaluates economic benefits of the biomass module system, comparing it to bale and silage systems.

New Zealand has ratified the Kyoto Protocol and agreed to reduce greenhouse gas emissions to 1990 levels in the first commitment period 2008-2012. Energy generated from renewable sources, such as New Zealand plantation forests and wood processing sites, is considered greenhouse gas neutral. But the use of biomass for bioenergy in New Zealand is very small. Some of the reasons for this include a lack of information about the future fuel supply and delivered cost. This thesis aims to provide a methodology to estimate biomass fuel availability and the delivered cost, of a range of forest and wood processing sources within a district, and to analyse the impact of harvest age, harvesting practices, terrain, collection and chipping costs, opportunity cost and transport costs on the availability and delivered cost of biomass for bioenergy. The six biomass streams included were chiplogs, forest landing residues, cutover residues, sawdust, bark and chip. The methodology was developed based on an area in Canterbury, and tested on an area in the Nelson/Marlborough region. It utilises forest growth models, Geographic Information Systems and Microsoft Excel. Growth models allow the analysis to be customised to a particular area or region, while the use of GIS allows the model to take spatial aspects (for example slope and transport distance) into consideration. Developing the overall framework within Excel allows easy analysis of the results and changes to the underlying assumptions. Opportunity costs make up a large proportion of the total cost of delivery for the chiplog, sawdust, bark and chip biomass and need to be included in any estimate of cost for these biomass streams. The logistic system chosen for collecting and chipping the forest residues has a large impact on their delivered cost as do the transport costs. However transport cost is not the most significant influence on the delivered cost of other biomass streams. The use of biomass for electricity generation only is not currently economic in either of the areas analysed. The use of biomass for heat production is currently economic if compared to the electricity purchase price.

京都大学 / 新制・課程博士 / 博士(農学) / 甲第23958号 / 農博第2507号 / 新制||農||1092(附属図書館) / 学位論文||R4||N5393(農学部図書室) / 京都大学大学院農学研究科応用生命科学専攻 / (主査)教授 伊福 健太郎, 教授 梅澤 俊明, 准教授 小林 優 / 学位規則第4条第1項該当 / Doctor of Agricultural Science / Kyoto University / DFAM

Thailand is one of the largest rice producing nations in the world. Moreover, there is a trend for Thai rice exports to increase. This could imply that if the trend continues, there will be an increased quantity of rice husk in the future. Rice husk is a co-product of rice products generated in the rice milling process, accounting for about 23 percent of the total paddy weight. To make use of this large quantity of rice husk, the husk has traditionally been used as an energy source in the rice mills themselves. More recently, the Thai government has promoted the use of biomass to substitute for fossil fuel consumption and to reduce the environmental impacts caused by using fossil fuels. Therefore, rice husk, which is one of the main sources of biomass in Thailand, has already been used on a commercial scale. However, the environmental impacts associated with different rice husk applications have not yet been widely investigated in the Thai context. While there is a need to find ways of dealing with rice husk disposal, it is also important to ensure that this husk is used in ways that harm the environment least. This research aims to identify the most environmentally friendly use of rice husk for Thailand. To achieve this, the research is divided into three main stages; identification of main current and potential uses of rice husk in Thailand; data collection; and data analysis using Life Cycle Analysis approach. A range of methods such as literature review, questionnaires with rice mill owners, and interviews with industry personnel, were used to help in identifying the current and potential uses of rice husk. The major current and potential rice husk uses chosen to be examined in this research are those uses of rice husk in electricity generation, in cement manufacture and in cellulosic ethanol production. The second stage is to collect detailed data about the processes of the selected rice husk uses to be examined. This was undertaken by literature review, questionnaires and interviews with involved industry personnel. The last stage is to analyse the data collated. Life Cycle Assessment (LCA) approach and the L CA software package SimaPro (version 7.1.6) were used to assess the environmental impacts of the selected rice husk uses. Results from the LCA are reviewed in the context of critical policy issues, including the Thai government biomass policies; the capacity of the production process of rice husk use options; and the infrastructure availability and practicality of the rice husk use options. Based on the goal and scope of the study, the data available for this study and the review of the issues just mentioned, it is concluded that, in the short term, the most practical environmentally friendly use of rice husk across the three uses investigated is the use of rice husk in electricity generation. However, with expected oil shortages in the future, rice husk should also be considered for use in cellulosic ethanol production, as this option helps to save some amount of petrol.

Diss. (sammanfattning) Uppsala : Sveriges lantbruksuniv. / Härtill 4 uppsatser.

Diss. (sammanfattning) Uppsala : Sveriges lantbruksuniv., 2001. / Härtill 5 uppsatser.

Diss. (sammanfattning) Uppsala : Sveriges lantbruksuniversitet, 2005. / Härtill 4 uppsatser.

The aim of this thesis is to enhance the extracellular electron transfer rates (exoelectrogenesis) in cyanobacteria, to be utilised for photo-bioelectricity generation in biophotovoltaics (electrochemical cell). An initial cross comparison of the cyanobacterium Synechococcus elongatus PCC7942 against other exoelectrogenic cultures showed a hindered exoelectrogenic capacity. Nonetheless, in mediatorless biophotovoltaics, it outperformed the microalgae Chlorella vulgaris. Furthermore, the performance of S. elongatus PCC7942 was improved by constructing a more efficient design (lower internal resistance), which was fabricated with carbon fibres and nitrocellulose membrane, both inexpensive materials. To strategically obtain higher exoelectrogenic rates, S. elongatus PCC7942 was conditioned by iron limitation and CO2 enrichment. Both strategies are novel in improving cyanobacteria exoelectrogenesis. Iron limitation induced unprecedented rates of extracellular ferricyanide reduction (24-fold), with the reaction occurring favourably around neutral pH, different to the cultural alkaline pH. Iron limited cultures grown in 5% and 20% CO2 showed increased exoelectrogenic rates in an earlier stage of growth in comparison to air grown cultures. Conveniently, the cultural pH under enriched CO2 was around neutral pH. Enhanced photo-bioelectricity generation in ferricyanide mediated biophotovoltaics was demonstrated. Power generation was six times higher with iron limited cultures at neutral pH than with iron sufficient cultures at alkaline pH. The enhanced performance was also observed in mediatorless biophotovoltaics, especially in the dark phase. Exoelectrogenesis was mainly driven by photosynthetic activity. However, rates in the dark were also improved and in the long term it appeared that the exoelectrogenic activity under illumination tended to that seen in the dark. Proteins participating in iron uptake by an alleged reductive mechanism were overexpressed (2-fold). However, oxidoreductases in the outer membrane remain to be identified. Furthermore, electroactive regions in biofilms of S. elongatus PCC7942 were established using cyclic voltammetry. Double step potential chronoamperometry was also successfully tested in the biofilms. Thus, the electrochemical characterisation of S. elongatus PCC7942 was demonstrated, implying that the strategies presented in this thesis could be used to screen for cyanobacteria and/or electrode materials to further develop systems for photo-bioelectricity generation.

Det blir allt viktigare med fler hållbara och miljövänliga lösningar för att kunna ta itu med dagens miljökris och för att kunna ersätta de fossila bränslena. Pelletseldning är en lösning som anses vara koldioxid neutralt och går att elda året runt. För att pelleten ska vara lätthanterlig och tålig så är de b.la. viktigt med en bra bulkdensitet och hållfasthet. Där spelar kylning av pellets roll och därför skall detta examensarbete undersöka hur olika kylningsmetoder påverkar pelletsen kvalité.   Ett antal prover av pellets tillverkades på Karlstad universitetet med en pelletsmaskin under två olika labbsessioner. Tre av dessa prover kyldes sedan på olika effekt på en fläkt i en mindre kylanläggning. Två andra prover kyldes i en hink och utspridda i en stor låda/plåt. Dessa stod under natten och kyldes till omgivningstemperaturen. Efter att proverna hade kylts så gjordes olika kvalitétstester på varje kylt prov; bulkdensitet, hållfasthet, hårdhet, fukthalt och andel fabriksmul mättes. En analys av insamlad data gjordes, efter det så kunde en slutsats dras.   En fältundersökning gjordes även för att utröna hur olika pelletsföretag går tillväga med deras kylningsprocess och hur tekniken på deras kylning ser ut.   Den kylningsmetod från första sessionen som hade bäst resultat i alla kvalitétstester var pelletsen som kyldes naturligt och utspridda i en låda, med en bulkdensitet på 646 kg/m3 och en hållfasthet på 96,6% samt minimalt fabrikssmul. Pelletsen som kyldes på lägsta effekt på kylanläggningen visade också bra resultat på testerna. De mindre bra kylningsmetoderna var pellets som kyldes i hink under natten samt pellets som kyldes på maxeffekt på kylanläggningen. Från andra sessionen så fick pelletsen som kyldes med 30Hz bäst hållfasthet på 98,6%  men lägst bulkvikt på 693 kg/m3. Pelletsen som kyldes med max effekt fick sämre hållfasthet och lägst hårdhet. Högst bulkvikt på 737 kg/m3 fick det provet som var utspritt på en plåt och kyldes naturligt. Inget tydligt samband kunde ses mellan resultaten från de olika labsessionerna.