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Characterization and Processing Evaluation of Starch/High-Density Polyethylene Materials in Extrusion Blow MoldingBacigalupi, Bradley Dale 01 December 2013 (has links) (PDF)
The growing negative impacts of non-biodegradable plastics derived from non-renewable materials have created increasing interest throughout the world for new materials that are both biodegradable and renewable, that can be combined with or replace traditional plastics. Plant-based thermoplastic starch (TPS), a promising alternative material to traditional petroleum based resin, is both biodegradable and renewable and has great potential for use in plastic manufacturing processes. Two major obstacles that prevent more widespread use of TPS include; TPS base material, which is typically manufactured in a flake or powder, is incompatible with standard plastics production equipment that require pelletized resin, the second reason is that TPS is difficult to mix with standard plastic materials such as High Density Polyethylene (HDPE). BiologiQ of Blackfoot Idaho through a unique manufacturing process has created a new type of TPS called EcoStarch™ Resin (ESR) that overcomes these two obstacles the material can be both pelletized and combined with various standard base plastics such as HDPE. This study evaluated and characterized the processability materials properties of ESR and HDPE blends in the Extrusion Blow Molding (EBM) by measuring wall thickness, tensile strength, tensile elongation, modulus of elongation and formability compared to 100% HDPE bottles. As the ESR content increased the uniformity of the wall thickness increased. The tensile strength increased from ESR content of 30% to 50% while the elongation decreased. Bottles were successfully extrusion blow molded with ESR content of 50%.
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