This Ph.D. work is dedicated to advancements in burst-mode laser technology and their applications in MHz-rate high-speed gas-phase environments. A comprehensive computational model for simulating experimental burst-mode systems is discussed. Direct comparison of the modeled results to the output of a constructed nanosecond (ns) burst-mode laser shows agreement within a factor of 2 for output energy, the temporal domain skews positively in an appropriate manner, and the spectral domain correctly remains unchanged. The modeled output of a femtosecond (fs) burst-mode laser displays near perfect agreement with its hardware, generating only a 1.7% deviation for output energy, an 11% deviation in spectral bandwidth, and a temporal profile that correctly remains unchanged. The experimental ns to fs burst-mode lasers systems used to compare with the aforementioned model are described in detail and demonstrated for use in measurements of temperature, species, and velocity at high repetition rates. In the ns regime, a compact-footprint (0.18 m2 ) flashlamp-pumped, burst-mode Nd:YAGbased master-oscillator power-amplifier (MOPA) laser is developed with a fundamental 1064 nm output of over 14 J per burst. This portable laser system uses a directly modulated diode laser seed source to generate 10 ms duration arbitrary sequences of 500 kHz doublet or MHz singlet pulses for flow-field velocity or species measurements, respectively. In the fs regime, a flashlamp-pumped burst-mode laser system with high peak power and a broad spectral bandwidth of >10 nm is constructed without the use of nonlinear compression techniques. A mode-locked, 1064.6 nm fundamental-wavelength broadband master oscillator, a fiber amplifier/pulse stretcher, and four Nd:glass power amplifiers are used to generate a sequence of high-repetition-rate, transform-limited 234 fs pulses over a 1 ms burst duration at a 0.1 Hz burst repetition rate. The generated peak powers are 1.24 GW at 100 kHz and 500 MW at 1 MHz with M2∼1.5. An adaptation of the fs burst-mode laser is used for femtosecond laser electronic excitation tagging (FLEET) of nitrogen for tracking the velocity field in high-speed flows at kilohertz– megahertz (kHz–MHz) repetition rates without the use of added tracers. The fs burst-mode laser is used to produce 500 pulses per burst with pulses having a temporal separation as short as 1 µs, an energy of 120 µJ, and a duration of 274 fs. This enables 2 orders of magnitude higher measurement bandwidth over conventional kHz-rate FLEET velocimetry. 15 The fs burst-mode system was further improved to include a picosecond (ps) leg for hybrid fs/ps rotational coherent anti-Stokes Raman scattering (RCARS) at MHz rates. Using a common fs oscillator, the system simultaneously generates time synchronized 1061 nm, 274 fs and 1064 nm, 15.5 ps pulses with peak powers of 350 MW and 2.5 MW, respectively. The system is demonstrated for two-beam fs/ps RCARS in N2 at 1 MHz with a signal-to-noise ratio of 176 at room temperature. This repetition rate is an order of magnitude higher than previous CARS using burst-mode ps laser systems and two to three orders of magnitude faster than previous continuously pulsed fs or fs/ps laser systems. As a continuation of the above advances in fs regime, a regenerative fs burst-mode laser is discussed in detail with motivations, design layouts, and cavity physics laid out. Preliminary construction of the system with a ns seed source is underway to assess the detailed system design and evaluate the potential for optical damage due to Kerr lensing or other nonlinear effects. This system and other potential follow-on research topics are discussed.

<p dir="ltr">From transonic to hypersonic regimes, the characterization of high-speed flow dynamics is critical for the development, testing, and improvement of launch and reentry vehicles, boost-glide vehicles, and thermal protection systems. The design of this technology often relies on computational/empirical models for predictions which make quantitative thermodynamic measurements crucial for numerical validation. Laser diagnostic techniques facilitate non-intrusive, <i>in situ</i> measurements of fluid dynamic properties as well as visualization of flows, shocks, and boundary layer interactions. However, many diagnostics rely on seeding the flow with foreign materials to make measurements, such as the application of particle image velocimetry (PIV), Doppler global velocimetry (DGV), and planar laser-induced fluorescence (PLIF). Molecular filtered Rayleigh scattering (FRS) diagnostics are attractive for flow characterization due to the fact that pressure, temperature, density and velocity measurements can be made directly from air or N₂ molecules without the need for seeding materials. The development of the burst-mode laser (BML) has enabled high-energy pulses generated at the rates necessary to resolve phenomena such as instabilities in boundary-layers and shock-wave evolution using Rayleigh scattering methods. The goal of this dissertation is to advance molecular burst-mode FRS for quantitative, high resolution, multi-parameter measurements. For fixed-wavelength FRS measurements, the spectral characteristics of a BML system were investigated and improved by integrating an etalon for spectral-gating. For multi-parameter measurements, two strategies for wavelength-agility, the ability to quickly switch between two or more laser wavelengths, of the BML were explored: frequency-scanning and frequency-shifting. The frequency-scanning FRS (FS-FRS) technique measurement rate was increased to 1 kHz and demonstrated for 1-ms pressure, temperature, and radial velocity measurements in an underexpanded jet flow. Building upon this, an acousto-optic modulator-based method was implemented to generate frequency-shifted pulses. The rapid frequency-shifting increased the effective FRS multi-parameter measurement rate to 25 kHz and planar pressure, temperature, and radial velocity measurements were captured in an overexpanded jet flow. Finally, design tools for the laser configuration of wavelength-agile FRS were developed for the optimization of relative absolute measurement errors.</p>