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Electrical imaging of groundwater that interacts with surface watercourses provides detail on the extent of intervention needed to accurately manage both resources. It is particularly important where one resource is saline or otherwise polluted, where spatial quantification of the interacting resources is critical to water use planning and where losses from surface waterways need to be minimized in order to transport water long distances. Geo-electric arrays or transient electromagnetic devices can be towed along watercourses to image electrical conductivity (EC) at multiple depths within and beneath those watercourses. It has been found that in such environments, EC is typically related primarily to groundwater salinity and secondarily to clay content. Submerged geo-electric arrays can detect detailed canal-bottom variations if correctly designed. Floating arrays pass obstacles easily and are good for surveying constricted rivers and canals. Transient electromagnetic devices detect saline features clearly but have inferior ability to detect fine changes just below beds of watercourses. All require that water depth be measured by sonar or pressure sensors for successful elimination of effects of the water layer on the data. The meandering paths of rivers and canals, combined with the sheer volume of data typically acquired in waterborne surveys, results in a geo-referencing dilemma that cannot be accommodated using either 2D imaging or 3D voxel imaging. Because of this, software was developed by the author which allows users to view vertical section images wrapped along meandering paths in 3D space so that they resemble ribbons. Geo-electric arrays suitable for simultaneous imaging of both shallow and deep strata need exponentially spread receiver electrodes and elongated transmitter electrodes. In order to design and facilitate such arrays, signed monopole notation for arrays with iv segmented elongated electrodes was developed. The new notation greatly simplified generalized geo-electric array equations and led to processing efficiency. It was used in the development of new array design software and automated inversion software including a new technique for stable inversion of datasets including data with values below noise level. The Allen Exponential Bipole (AXB) array configuration was defined as a collinear arrangement of 2 elongated transmitter electrodes followed by receiver electrodes spaced exponentially from the end of the second transmitter electrode. A method for constructing such geo-electric arrays for use in rivers and canals was developed and the resulting equipment was refined during the creation of an extensive set of EC imaging case studies distributed across canals and rivers of the Australian Murray- Darling Basin. Man made and natural variations in aquifers connected to those canals and rivers have been clearly and precisely identified in more than 1000 kilometres of EC imagery.

Electrical imaging of groundwater that interacts with surface watercourses provides detail on the extent of intervention needed to accurately manage both resources. It is particularly important where one resource is saline or otherwise polluted, where spatial quantification of the interacting resources is critical to water use planning and where losses from surface waterways need to be minimized in order to transport water long distances. Geo-electric arrays or transient electromagnetic devices can be towed along watercourses to image electrical conductivity (EC) at multiple depths within and beneath those watercourses. It has been found that in such environments, EC is typically related primarily to groundwater salinity and secondarily to clay content. Submerged geo-electric arrays can detect detailed canal-bottom variations if correctly designed. Floating arrays pass obstacles easily and are good for surveying constricted rivers and canals. Transient electromagnetic devices detect saline features clearly but have inferior ability to detect fine changes just below beds of watercourses. All require that water depth be measured by sonar or pressure sensors for successful elimination of effects of the water layer on the data. The meandering paths of rivers and canals, combined with the sheer volume of data typically acquired in waterborne surveys, results in a geo-referencing dilemma that cannot be accommodated using either 2D imaging or 3D voxel imaging. Because of this, software was developed by the author which allows users to view vertical section images wrapped along meandering paths in 3D space so that they resemble ribbons. Geo-electric arrays suitable for simultaneous imaging of both shallow and deep strata need exponentially spread receiver electrodes and elongated transmitter electrodes. In order to design and facilitate such arrays, signed monopole notation for arrays with iv segmented elongated electrodes was developed. The new notation greatly simplified generalized geo-electric array equations and led to processing efficiency. It was used in the development of new array design software and automated inversion software including a new technique for stable inversion of datasets including data with values below noise level. The Allen Exponential Bipole (AXB) array configuration was defined as a collinear arrangement of 2 elongated transmitter electrodes followed by receiver electrodes spaced exponentially from the end of the second transmitter electrode. A method for constructing such geo-electric arrays for use in rivers and canals was developed and the resulting equipment was refined during the creation of an extensive set of EC imaging case studies distributed across canals and rivers of the Australian Murray- Darling Basin. Man made and natural variations in aquifers connected to those canals and rivers have been clearly and precisely identified in more than 1000 kilometres of EC imagery.

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Made available in DSpace on 2014-10-09T12:30:27Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T14:06:20Z (GMT). No. of bitstreams: 1 01078.pdf: 10573405 bytes, checksum: c8df8c77eed2626c40e7867725895422 (MD5) / Tese (Doutoramento) / IPEN/T / Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP

Electrical and thermal conductivities of the yttria-stabilised zirconia/alumina (YSZ/Al2O3) composites and the yttria-zirconia-ceria (YSZ-CeO2) solid solutions are studied in this thesis. The electrical conductivity of the YSZ/Al2O3 composites decreases with an increase in the volume fraction of Al2O3 and exhibits typical percolation behaviour. The electrical conductivity of the YSZ/Al2O3 interface is higher than that of the YSZ grain boundary, but lower than that of the YSZ grains. The thermal conductivity of the YSZ/Al2O3 composites increases with an increase in the Al2O3 volume fraction, and it can be fitted well to the Maxwell theoretical model, which indicates the absence of obvious interfacial thermal resistances in the composites. The low interfacial thermal resistance of the YSZ/Al2O3 interface is due to the 'clean' and coherent nature of the YSZ/Al2O3 interface, along with the small difference between the elastic properties of YSZ and Al2O3. The electrical conductivity of the [(ZrO2)1-x(CeO2)x]0.92(Y2O3)0.08 (0 ≤ x ≤ 1) solid solutions has a 'V-shape' variation as a function of the mole ratio of CeO2 (x). In the ZrO2-rich region (x < 0.5), CeO2 doping increases the concentration of defect associates which limits the mobility of the oxygen vacancies; in the CeO2-rich region (x > 0.5), the increase of x increases the lattice parameter, which enlarges the free channel for oxygen vacancy migration. A comparison of the YSZ-CeO2 solid solutions with the YSZ-HfO2 series indicates the ionic radius of the tetravalent dopant determines the composition dependence of the ionic conductivity of the solid solutions.The thermal conductivity of the [(ZrO2)1-x(CeO2)x]0.92(Y2O3)0.08 (0 ≤ x ≤ 1) solid solutions also has a 'V-shape' variation as a function of the mole ratio of CeO2 (x), which indicates an incorporation of Zr4+ and Ce4+ can effectively decrease the thermal conductivity of the end members YSZ and yttria-doped ceria (YDC). In the ZrO2-rich region (0 ≤ x ≤ 0.5), the thermal conductivity is almost temperature independent; in the CeO2-rich region (0.5 ≤ x ≤ 1), it decreases obviously with increasing temperature. By calculating the phonon scattering coefficients, it is concluded that the composition dependence of the thermal conductivity in the ternary solid solutions is dominated by the mass difference between Zr and Ce at the cation sites, whereas the temperature dependence is determined by the order/disorder of oxygen vacancies at the anion sites.

京都大学 / 新制・課程博士 / 博士(理学) / 甲第23458号 / 理博第4752号 / 新制||理||1681(附属図書館) / 京都大学大学院理学研究科化学専攻 / (主査)教授 北川 宏, 教授 吉村 一良, 教授 竹腰 清乃理 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DGAM

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