Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / Neste trabalho calculamos os fatores de forma e constantes de acoplamento para os vértices B*sBK, B*BsK e BsBK* usando as Regras de Soma da Cromodinâmica Quântica (QCD). Ainda estão incluídos os diagramas não perturbativos. Nós usamos a técnica de considerar dois mésons fora da camada de massa para obter dois fatores de forma diferentes a fim de diminuir as incertezas. Os cálculos das incertezas foram incluídos neste trabalho. / In this work, we calculate the Form Factors and the Coupling Constants for the vertices B*sBK, BsB*K and BsBK* using the QCD Sum Rules. We use the technique of considering two mesons of shell to obtaining two differents form factors in order to give less uncertainty to the obtaining of the coupling constant. The evaluation of the uncertaints were included in this work.

Orientador: Falcondes Jose Mendes de Seixas / Banca: Carlos Alberto Canesin / Banca: Luiz Carlos Gomes de Freitas / Resumo: Este trabalho propõe um novo conversor CA-CC trifásico de múltiplos pulsos com estágios CC-CC elevadores de tensão controlados pela técnica de histerese constante. Nesta proposta não são empregados indutores de interfase. A finalidade deste conversor é a de possibilitar um barramento CC regulado para aplicações embarcadas, acionamentos elétricos e afins, sempre com preocupações relacionadas aos aspectos de Qualidade de Energia Elétrica. Assim, a proposta deve apresentar elevado fator de potência, baixa distorção harmônica total de corrente drenada da rede elétrica. Ampla revisão bibliográfica, reunindo as propostas mais recentes da literatura para conversores com mesma finalidade, é feita para que sejam estudadas as estruturas de potência, técnicas de controle, versatilidade, possibilidade de isolamento galvânico e robustez. Em seguida, é detalhada a proposta principal deste trabalho por meio da apresentação do equacionamento do autotransformador, dos estágios elevadores de tensão e da técnica de controle. Esta análise permite que sejam feitas simulações com todos os elementos do conversor CA-CC e então, se desenvolva o projeto físico dos elementos magnéticos e se escolham os componentes eletrônicos do protótipo. O número reduzido de componentes de controle e a simplicidade dos circuitos de potência são grandes atrativos da proposta discutida. Todas as informações relevantes são descritas detalhadamente e, sempre que possível, meios alternativos de solucionar problemas são também apresentados, de forma que fiquem claras as possibilidades de melhoria da técnica empregada. A operação conjunta de todos os elementos mais a técnica de controle foi validada, de maneira que se comprovou, por meio de ensaios, todos os princípios de funcionamento da proposta de conversor CA-CC. Pelos resultados experimentais, obteve-se corrente drenada... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: This work proposes a new AC-DC three-phase multipulse converter with DC-DC boost stages and constant hysteresis control. The objective of this converter is to provide a reliable DC bus for on-board applications, electric motor drives and similars, always considering power quality issues. Thus, the proposal presents high power factor and low harmonic distortions in the currents from the mains. A wide revision is made on other recent proposals found in the scientific literature. Different topologies are compared considering power circuits, control techniques, isolation possibility and robustness. The second chapter presents the details on the main proposal of this work and also the mathematical equations that describe the autotransformer, boost converters and control strategy. Later, simulation results are commented and discussed and the physical design is detailed. The output filter elements, power components and control elements are specified. Experimental results including main waveforms, efficiency, voltage regulation and temperature rise are presented for the autotransformer. The boost stages are also tested and its results are discussed. Finally, the proposed AC-DC converter is tested and the control technique applied to the power stage is validated / Mestre

Le développement des mémoires dynamiques (DRAM) à haute performance basées sur la structure métal-isolateur-métal (MIM) nécessite de remplacer la couche de dioxyde de silicium par des matériaux diélectriques à haute permittivité diélectrique. L'utilisation de ces isolants dits high-k permet de réduire la taille du dispositif DRAM tout en conservant une densité de capacité élevée et un faible courant de fuite pour diminuer la fréquence de rafraichissement. Parmi les nombreux matériaux high k, le dioxyde de titane (TiO2) est l'un des candidats les plus prometteurs en raison de sa constant diélectrique relativement élevée pouvant atteindre 170 dans le TiO2 cristallisé en phase rutile. De plus, il est possible d’obtenir cette phase à basse température par le procédé ALD (< 250 °C) si le dépôt est réalisé sur un substrat RuO2 (phase rutile) grâce à une très faible différence de paramètres de maille entre les deux matériaux. L'objectif principal de cette thèse est d'étudier les mécanismes des réactions chimiques qui se produisant à l'interface RuO2/TiO2 lors du dépôt et leur influence sur les propriétés structurales et diélectriques du film TiO2, en particulier l'influence des espèces oxydantes, le plasma O2 et le H2O. L’influence des électrodes supérieure et inferieures sur les propriétés électriques et structurales de TiO2 a également été étudiée. Ensuite, la constante diélectrique, la conductivité ac et la tangente de perte des structures MIM à base d’oxyde de titane dopé aluminium ont été étudiés dans une gamme de fréquences large bande, de 1 Hz à 2 GHz. Enfin, la réalisation des MIM tridimensionnelles (3D) utilisant un substrat de silicium structuré en réseaux des trous coniques denses a été démontrée. Les structures MIM 3D réalisées ont permis d’augmenter sensiblement la densité de capacité tout en gardant de bonnes performances en termes de courant de fuite. / The development of high performance dynamic random access memory (DRAM) based on metal-insulator-metal (MIM) structure made it necessary to replace the conventional silicon dioxide layer by dielectric materials with high dielectric constants. The use of these so-called high-k insulators allows aggressive scaling of DRAM devices while keeping high capacitance density and, more importantly, low leakage current. Among the numerous high k dielectrics, titanium dioxide (TiO2) is one of the most attractive candidate due to its rather high dielectric constant (k). Rutile TiO2 is the interesting phase due to its high dielectric constant and the possibility to deposit this phase at low temperature by ALD (< 250 °C) by using RuO2 substrate thanks to a very small lattice mismatch between the two materials. The main objective of this thesis is to investigate the surface chemical reactions mechanisms at the RuO2/TiO2 interface and their influence on the ALD TiO2 film properties, especially the influence of oxidizing species, namely, H2O or O2 plasma. The influence of bottom and top electrode on electrical and structural proprieties of TiO2 MIM structure was also studied. Then, the dielectric constant, the ac conductivity and the loss tangent of aluminum doped titanium oxide are measured through a wide band frequency range, from 1 Hz to 2 GHz. Finally, the feasibility of three-dimensional (3D) MIM structures was studied by using dense array of truncated conical holes etched in a silicon substrate. The 3D MIM capacitors showed a large increase in the capacitance density while retaining very good electrical properties especially a leakage current comparable to planar MIM devices.

Doctor of Philosophy / Department of Chemistry / Daniel A. Higgins / This dissertation describes the application of wide-field single-molecule fluorescence microscopy techniques to investigations of DNA-surface interactions on chemically graded organosilane surfaces. The adsorption and desorption behaviors of double-stranded (ds) plasmid DNA along the amino-trimethoxysilane and octyl-trichlorosilane gradients were explored as a function of solution pH, solution ionic strength and surface properties. The results provide an improved fundamental understanding of DNA interactions with different surfaces and are certain to aid in the development and advancement of DNA-based biological and biomedical devices. Three distinct experiments were performed in completion of the work for this dissertation. In the first study, total internal reflection fluorescence (TIRF) microscopy was employed to study DNA interactions with aminosilane gradient surfaces under relatively acidic and basic environments. Electrical potentials were applied to assist DNA adsorption and desorption. The single-molecule data clearly showed that DNA capture and release was achieved on the monolayer and submonolayer coated regions of the aminosilane gradient surface under relatively basic pH conditions, with the help of an electrical potential. Meanwhile, DNA adsorption was found to be quasi-reversible on the multilayers at the high aminosilane end of the gradient in the relatively acidic solution. The results of these studies demonstrate the importance of manipulating the electrostatic interactions of DNA with charged surfaces in order to achieve DNA capture and release. The fundamental knowledge of the DNA-surface interactions gained in these studies will be helpful in diverse fields ranging from the layer-by-layer assembly of polyelectrolyte-based thin films to the selective electronic sensing of charged biomolecules. In the second study, the local dielectric properties of the least polar environments in dsDNA were assessed by using the solvatochromic dye, nile red, as a polarity-sensitive probe. TIRF spectroscopic imaging methods were employed in these studies. Although the dielectric constant within the least polar regions of dsDNA was previously predicted by theoretical and computational methods, no experimental measurements of its value had been reported to date. The results provide important knowledge of the factors governing the polarity of DNA microenvironments to which intercalators bind, and provide vital experimental support for the values determined in computational studies. In the third study, TIRF microscopy and single molecule tracking methods were employed to study DNA interactions with an opposed two-component C8-silane and aminosilane gradient surface as a function of solution pH. The mobility of surface-adsorbed DNA molecules was explored and quantified in these studies. The preliminary results further demonstrated the importance of electrostatic interactions over hydrophobic interactions in governing the adsorption of DNA to surfaces. The mobility of surface-adsorbed DNA was found to be largely independent of position along the two-component gradient. These studies were originally undertaken as a route to observation of cooperative effects that are believed to govern DNA-surface binding. Unfortunately, no clear evidence of cooperative effects was observed at the mixed regions of the two-component gradient surface.

The hunt for Dark Matter plays a truly critical role in contemporary physics. At both the largest and smallest scales, deep questions are being raised about the fundamental nature of the universe - questions that confirmation and then characterisation of particle dark matter will provide many answers to. This thesis presents some of the world's most sensitive searches to date for certain types of axion dark matter, axion-like particles, and two-neutrino double electron capture. These have been conducted using the Large Underground Xenon (LUX) experiment. Evidence for dark matter and physics beyond the Standard Model of particle physics is described in Chapter 1, while Chapter 2 gives an overview of proposed candidates for particle dark matter. The various experimental approaches being used to detect particle dark matter are presented in Chapter 3. Direct detection with time projection chambers plays a major role in this thesis, with particular interest in the LUX detector, that is described in its components and operations. Chapter 4 presents LUX direct searches for weakly interacting massive particles. Although I have contributed to these analyses, they are included for completeness only, as they are not part of my central work. The LUX collaboration's searches for axion dark matter and axion-like particle have delivered world-leading results on the axion-electron coupling constant. These results, that I personally led and which have been published in Physics Review Letters, are presented in Chapter 5, along with sensitivity studies, also led by me, made for the future LUX-ZEPLIN experiment. Finally, a search for two-neutrino double electron capture of 124Xe, that I performed using LUX data to extract a limit on the half life of the process, is presented in Chapter 6. Although being allowed by the Standard Model, two-neutrino double electron capture shares the matrix element calculation framework with the neutrinoless channel of the same process, becoming of great interest in the scope of neutrino physics. Conclusions follow and close the thesis.

Dans cette thèse nous étudions deux problèmes issus de la relativité générale : la construction de données initiales pour le problème de Cauchy des équations d’Einstein et le théorème de la masse positive. Nous construisons tout d’abord des données initiales en utilisant la méthode dite conforme introduite par Lichnerowicz [Lichnerowicz, 1944], Y. Choquet-Bruhat–J. York [Choquet-Bruhat et York, 1980] et Y. Choquet-Bruhat–J. Isenberg– D. Pollack [Choquet-Bruhat et al., 2007a]. Plus particulièrement, nous étudions les équations –de contrainte conforme– qui apparaissent dans cette méthode sur des variétés riemanniennes compactes de dimension n > 3. Dans cette thèse, nous donnons une preuve simplifiée du résultat de [Dahl et al., 2012], puis nous étendons et nous généralisons les théorèmes de M. Holst–G. Nagy–G. Tsogtgerel [Holst et al., 2009] et de D. Maxwell [Maxwell, 2009] dans le cas de données initiales à courbure moyenne fortement nonconstante. Nous donnons au passage un point de vue unifié sur ces résultats. En parallèle, nous donnons des résultats de non-existence et de non-unicité pour les équations de la méthode conforme sous certaines hypothèses. / The aim of this thesis is the study of two topical issues arising from general relativity: finding initial data for the Cauchy problem with respect to the Einstein equations and the positive mass theorem. For the first issue, in the context of the conformal method introduced by Lichnerowicz [Lichnerowicz, 1944], Y. Choquet-Bruhat–J. York [Choquet-Bruhat et York, 1980] and Y. Choquet-Bruhat–J. Isenberg–D. Pollack [Choquet-Bruhat et al., 2007a], we consider the conformal constraint equations on compact Riemannian manifolds of dimension n > 3. In this thesis, we simplify the proof of [Dahl et al., 2012, Theorem 1.1], extend and sharpen the far-from CMC result proven by Holst– Nagy–Tsogtgerel [Holst et al., 2009], Maxwell [Maxwell, 2009] and give an unifying viewpoint of these results. Besides discussing the solvability of the conformal constraint equations, we will also show nonexistence and nonuniqueness results for solutions to the conformal constraint equations under certain assumptions.

SILVA, Roger Ribeiro. Estudo das propriedades dielétricas do Niobato de Bismuto e Titânio dopado com PbO e Bi2O3 para aplicações em antenas. 2009. 93 f. Dissertação (Mestrado em Física) - Programa de Pós-Graduação em Física, Departamento de Física, Centro de Ciências, Universidade Federal do Ceará, Fortaleza, 2009. / Submitted by Edvander Pires (edvanderpires@gmail.com) on 2015-06-16T21:40:35Z No. of bitstreams: 1 2009_dis_rrsilva.pdf: 3731493 bytes, checksum: ea1e0ca9dd5b082cce643034649ad572 (MD5) / Approved for entry into archive by Edvander Pires(edvanderpires@gmail.com) on 2015-06-18T18:22:11Z (GMT) No. of bitstreams: 1 2009_dis_rrsilva.pdf: 3731493 bytes, checksum: ea1e0ca9dd5b082cce643034649ad572 (MD5) / Made available in DSpace on 2015-06-18T18:22:11Z (GMT). No. of bitstreams: 1 2009_dis_rrsilva.pdf: 3731493 bytes, checksum: ea1e0ca9dd5b082cce643034649ad572 (MD5) Previous issue date: 2009 / Dielectric resonators based on type structure compound Bi3TiNbO9 show singular characteristics for microwave applications, including high dielectric constants, low dissipation losses and low temperature coefficients. Single phase of the Bi3TiNbO9 powder was obtained by x-ray diffraction technique. The ceramics doped during manufacture, with lead oxide and bismuth oxide, were synthesized by solid state reaction at 950°C for two hours. Samples were analysed by Archimedes method and exhibited good levels of density for doped ceramics with bismuth and lead oxide. Grain morphology and stoichiometry of ceramics were investigated by scanning electron microscopy and energy dispersive spectroscopy technique. Far infrared spectroscopy identified large bands on the Bi3TiNbO9 structure by attenuated total reflection technique. Radiofrequency measurements showed that doped ceramics exhibited higher dielectric constants than pure phase. Microwave measurements were investigated by Hakki-Coleman and resonant cylindrical cavity. The ceramics called as BTNO3BiP, BTNO5BiP, BTNO10BiP, BTNO3PbG e BTNO5PbG, showed high dielectric constants and high quality factors demonstrating that they can be applied in dielectric antennas on microwave range. / Ressoadores dielétricos baseados na estrutura do composto Bi3TiNbO9 apresentam características singulares para aplicações em microondas, incluindo altas constantes dielétricas, baixos fatores de dissipação e baixos coeficientes de temperatura. Obteve-se a fase pura da amostra em pó de Bi3TiNbO9 pela técnica de difração de raios X. As amostras cerâmicas dopadas durante a fabricação, com óxido de chumbo e óxido de bismuto, foram sintetizadas pelo método de reação do estado sólido a 950°C por 2 horas. As amostras foram analisadas pelo método de Arquimedes e apresentaram bons níveis de densidade nas dopagens com os óxidos de bismuto e chumbo. A morfologia dos grãos e a estequiometria das amostras cerâmicas foram investigadas pelas técnicas de microscopia eletrônica de varredura e análise por energia dispersiva de raios X. A espectroscopia no infravermelho distante identificou bandas largas na estrutura do Bi3TiNbO9 pela técnica de reflexão total atenuada. As medidas de constante dielétrica e perda dielétrica em radiofreqüência demonstraram que as dopagens com chumbo e bismuto exibiram maiores constantes dielétricas em relação à cerâmica pura. As medidas em microondas foram estudadas pelos métodos Hakki-Coleman e a cavidade ressonante metálica. As cerâmicas denominadas como BTNO3BiP, BTNO5BiP, BTNO10BiP, BTNO3PbG e BTNO5PbG, apresentaram altas constantes dielétricas e altos fatores de qualidade, demonstrando que podem ser aplicadas em antenas dielétricas na faixa de micro-ondas.

Neste trabalho mostramos que dado um domínio exterior de classe C0 contido em uma superfície umb lica de H3; com curvatura média constante H 2 [0; 1); existe uma família de gracos de Killing com curvatura média constante H: O bordo de cada um destes gracos está contido nesta superfície umbílica e a norma do gradiente da função no bordo pode ser prescrita por um certo valor s 0. / In this paper we show that given an exterior domain of class C0 contained in an umbilical surface of H3; with constant mean curvature H 2 [0; 1); there exists a family of Killing graphs with constant mean curvature H: The boundary of each of these graphs is contained in this umbilical surface and the norm of the gradient of the function in the boundary can be prescribed by a certain value s 0:

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / Neste trabalho calculamos os fatores de forma e constantes de acoplamento para os vértices B*sBK, B*BsK e BsBK* usando as Regras de Soma da Cromodinâmica Quântica (QCD). Ainda estão incluídos os diagramas não perturbativos. Nós usamos a técnica de considerar dois mésons fora da camada de massa para obter dois fatores de forma diferentes a fim de diminuir as incertezas. Os cálculos das incertezas foram incluídos neste trabalho. / In this work, we calculate the Form Factors and the Coupling Constants for the vertices B*sBK, BsB*K and BsBK* using the QCD Sum Rules. We use the technique of considering two mesons of shell to obtaining two differents form factors in order to give less uncertainty to the obtaining of the coupling constant. The evaluation of the uncertaints were included in this work.

Submitted by Johnny Rodrigues (johnnyrodrigues@ufcg.edu.br) on 2018-07-24T13:50:44Z No. of bitstreams: 1 JÉSSYCA LANGE FERREIRA MELO - DISSERTAÇÃO PPGMAT 2010..pdf: 549809 bytes, checksum: d97e157afe502f81bdc9beda3a5c1489 (MD5) / Made available in DSpace on 2018-07-24T13:50:44Z (GMT). No. of bitstreams: 1 JÉSSYCA LANGE FERREIRA MELO - DISSERTAÇÃO PPGMAT 2010..pdf: 549809 bytes, checksum: d97e157afe502f81bdc9beda3a5c1489 (MD5) Previous issue date: 2010-02 / CNPq / Para visualizar o resumo recomendamos do download do arquivo uma vez que o mesmo utiliza formulas ou equações matemáticas que não puderam ser transcritas neste espaço. / To preview the summary we recommend downloading the file since it uses mathematical formulas or equations that could not be transcribed in this space.