Thesis (M.Sc.). / Written for the Dept. of Bioresource Engineering. Title from title page of PDF (viewed 2008/12/10). Includes bibliographical references.

Thesis (M.App.Sc.) - Carleton University, 2005. / Includes bibliographical references (p. 114-116). Also available in electronic format on the Internet.

Thesis (M.S.)--Washington State University, May 2008. / Includes bibliographical references (p. 18-19).

Thesis (M.S.)--Virginia Polytechnic Institute and State University, 1990. / Vita. Abstract. Includes bibliographical references (leaves 96-102). Also available via the Internet.

Thesis (M.S.)--Montana State University--Bozeman, 2005. / Typescript. Chairperson, Graduate Committee: James W. Bauder. Includes bibliographical references (leaves 75-84).

Thesis (M.S.)--Virginia Polytechnic Institute and State University, 1994. / Vita. Abstract. Includes bibliographical references (leaves 78-86). Also available via the Internet.

Abstract Agriculture is the main source of nitrogen (N) and phosphorus (P), which are the nutrients accelerating the eutrophication of waters in Finland. Hence, mitigation measures are needed to reduce the nutrient loading from the arable land. Since Finland's accession to the EU in 1995 and the subsequent adaptation to its agri-environmental policy, constructed wetlands (CWs) have been one of the mitigation measures for which farmers may receive agri-environmental subsidies. The aim of this study was to find out how efficiently such CWs are able to retain the loading and how they should be designed and dimensioned in order to optimize their performance. Particular attention was paid to CW hydrology and hydraulics, since the dynamics of the water flowing through a CW is the major factor governing retention. Water quality and flow measurements were made in three CWs located in agricultural watersheds in southern Finland during 1999-2002. Hydraulic properties were examined in 2 of the CWs by simulations with 2-dimensional hydrodynamic and water quality models. According to the calculations of material fluxes, the maximum annual retention was 72% for solid material (TSS), 67% for total P and 40% for total N. The lowest retentions were slightly negative, because the CW with the smallest CW-to-watershed area ratio (0.5% in the Alastaro CW) sometimes acted rather as a source than a sink of nutrients. The highest percent retentions were found in the Hovi CW with the largest CW-to-watershed area ratio (5%). In terms of mass per CW area, the Hovi CW retained 25 kg of total P and 300 kg of total N per one hectare per one year. In the Hovi CW also dissolved reactive P retention was high (49% in situ and 34% in laboratory microcosm experiments), obviously due to high contents and low P saturation of Al and Fe oxides of the CW soil. The basic underlying reason behind the high retentions of both dissolved nutrients and particulate matter in the Hovi CW was the long water residence time coupled with high hydraulic efficiency. In the deep part of the Hovi CW, near-bottom increase of dissolved O2 was found in phase with diurnal temperature changes. The oxygen transport by this kind of convective circulation of CW water inhibited near-bottom anoxia and thus decreased the risk of P desorption. According to the hydrodynamic simulations coupled with simulated tracer tests made for the Hovi CW, a 40% improvement in hydraulic efficiency was achieved by baffles directing the main flow to optimally exploit the CW area. The rectangular, elongated shape of the Alastaro CW also showed fairly high hydraulic efficiency. Hydrodynamic simulations were also coupled with a sediment transport model, which proved to be a useful method in predicting the change of TSS concentrations in CWs. Hourly datasets of inflow and outflow revealed high attenuation of runoff peaks in the well-designed and -dimensioned Hovi CW. The hourly outflow modeled with the reservoir routing method corresponded to the observed with a reasonable accuracy. When carefully designed, painstakingly implemented and wisely located, CWs may – even in cold climate – efficiently contribute to agricultural water pollution control.

Philosophiae Doctor - PhD / As a consequence of various cellar activities the wine industry produces copious volumes of potentially hazardous wastewater each year. South Africa is one of the top ten wine-producing countries, making the successful treatment of cellar effluent an important environmental obligation in this country. Constructed wetlands (CWs) are resilient to the seasonal input fluxes associated with agri-industrial waste and are ideal systems for the in-situ treatment of cellar effluent in small to medium-sized wineries not connected to municipal reticulation systems. In a project sponsored by the Water Research Commission of South Africa, a number of studies were undertaken to assess the remediation of winery wastewater and common components of winery wastewater in sand-filled pilot-scale constructed wetlands operated in batch mode. This thesis contains the results of three studies. The first study evaluated the temporal aspects of CW equilibration as a basis for future studies of system response to amendment. Microbial biomass and hydraulic conductivity values were monitored and microbial community fingerprints were obtained using denaturing gradient gel electrophoresis. The study showed that microbial community fingerprinting provides a valuable tool to assess the time-scales of microbial equilibration, which was found to be in the order of 100 days. In the second study, the biodegradation and mineralization of ethanol by acclimated and non-acclimated microbial populations in CWs were compared. By increasing the influent ethanol concentration at incremental intervals (incremental priming), the biodegradative capacity was significantly enhanced. At an influent COD concentration of 15 800 mg/L, no volatile fatty acids were detected in the effluent of an incrementally primed system and the maximum effluent COD measured was 180 mg/L. In contrast, an identical, unprimed system, amended with a lower concentration of COD (7587 mg/L), exhibited a maximum effluent COD concentration of 1 400 mg/L, with the metabolites butyrate and propionate accounting for up to 83% of the effluent COD. It was conclusively demonstrated that the use of incremental priming, together with the batch mode of operation enhanced long-term function of the CWs. In the third study, the removal of the phenolic component of winery wastewater was evaluated in CWs, as well as in sand columns and microcosms. It was found that at low influent phenolic concentrations in CWs, complete organic removal was accomplished, but at high concentrations, there was incomplete substrate removal and an accumulation of potentially toxic metabolites, including catechol. The sand provided a suitable substrate for the treatment of phenolic-laden waste, and both biotic (48%) and abiotic (52%) removal mechanisms effected the removal of model phenolics. Prior acclimation of microbial communities increased the biodegradation rate of phenolic acids significantly.

Triclosan and triclocarban are antimicrobial compounds added to a variety of consumer products that are commonly detected in waste water effluent. The focus of this study was to determine whether the bioconcentration of these compounds in wetland plants and sediments exhibited species specific and site specific differences by collecting field samples from a constructed wetland in Denton, Texas. The study showed that species-specific differences in bioconcentration exist for triclosan and triclocarban. Site-specific differences in bioconcentration were observed for triclosan and triclocarban in roots tissues and sediments. These results suggest that species selection is important for optimizing the removal of triclosan and triclocarban in constructed wetlands and raises concerns about the long term exposure of wetland ecosystems to these compounds.

The future projection of climate change suggests the strong need of improved systems to the re-source management systems. In Syria, the current water resource management systems are weak, and the country has no resilience to the scarcity of water resources in the region. In 2007 a drought has crippled the Syrian economy and impacted the life of millions of Syrian People, the devastating occurrence of the drought had larger impacts due to the lack of water resource management sys-tems and irresponsibility of use. This study investigates the current management systems that Syria has, and the supply and demand of the country, of which is aimed for with the term (water balance) that refer to the flow of water in and out of the system. Furthermore, a constructed wetland design is introduced as a system to treat municipal wastewater of the town Al-Haffah, located east of Latakia city of which is situated at the Mediterranean coast, on the Costal basin. All the data avail-able relevant to the investigation has been used in the case study, nevertheless some assumptions has been made due to lack of available data. The introduced system is later evaluated in regards of water need for agricultural purposes in Al-Haffah. The design with the assumed current value, in worst case scenario could save annually (48.57%) of the groundwater abstraction for agricultural purposes, Or (29.14%) of the total water demand for the agricultural practices in Al-Haffah. Whilst, in best case scenario, if two third of the required water for agriculture is met with rainfall the system saves (145.7%) of the assumed groundwater abstraction, Or (87.43%) of the total an-nual required water. / <p>2020-06-05</p>