Dans le cadre de la sécurité incendie, et de la prévention de départ d'un feu en environnement confiné, un objectif majeur consiste en l'amélioration des procédés d'extinction et plus précisément de la pulvérisation de brouillards d'eau qui est un moyen de lutte largement utilisé. Les simulations numériques doivent prévoir l'efficacité des brouillards en évaluant précisément l'évolution spatiotemporelle des caractéristiques du foyer incendie en présence d'un champ pulvérisé de gouttelettes. Pour déterminer les fractions massiques d'eau sous forme liquide ou vapeur, les concentrations des produits formés ainsi que les niveaux de températures en tout point du local, nous présentons ici le développement d'un modèle apte à décrire un milieu réactif dans lequel la stabilité de la flamme est altérée par la présence de gouttelettes d'eau. Un formalisme diphasique eulérien-eulérien est utilisé pour modéliser le transport des gouttelettes qui interagissent avec le milieu réactif en le refroidissant et en le diluant via l'introduction de vapeur d'eau issue du processus d'évaporation. Le modèle sousjacent est une approche de combustion à multi-fractions de mélange avec un diagramme de reconstitution des espèces mettant en compétition un domaine inflammable et un domaine non inflammable. Les modèles finalement obtenus ont été implantés dans Code_Saturne, un logiciel de mécanique des fluides qui a récemment été adapté à l'étude des incendies. La validation de ces modèles a été effectuée à partir de données expérimentales issues de la littérature, et sur des cas test d'échelle intégrale.

De multiples analyses géochimiques (isotopes du carbone et du soufre, spéciation du fer, contenu en carbone et soufre dans le sédiment et éléments traces) ont été effectuées pour étudier les influences environnementales sur la diversification de la faune d'Édiacara (~570 Ma), à l'Ordovicien inférieur et moyen (~470 Ma), aux extinctions de masse de l'Ordovicen (~445 Ma) et de la limite Permien-Trias (~251 Ma). Les enregistrements haute-résolution de o13 Cet de o13 C org d'une section provenant de Honghuayuan (Sud de la Chine) ont montré une élévation de +8%o du o13 C dans le Floian de l'Ordovicien. Cela implique une hausse du taux d'enfouissement de la matière organique pendant la première partie de l'Ordovicien récent qui aurait pu contribuer au refroidissement climatique et déclencher cet évènement. Les deux valeurs positives du o13Corg correspondent aux deux pulses de l'extinction de masse de l'Ordovicien. Cela implique des changements dans le cycle biogéochimique du carbone qui sont associés à ['extinction de masse de l'Ordovicien. Les valeurs élevées de o34S de la pyrite, le bref passage à des valeurs négatives du o34S de 20%o, associés à un ralentissement de la glaciation traduiraient des conditions anoxiques dans l'océan profond pendant la période hirnantienne. Ces conditions anoxiques pourraient avoir pris part à l'extinction de masse à la fin de l'Ordovicien dans le Sud de la Chine et probablement ailleurs. La spéciation des isotopes du Fe et du S, les données de pyrite provenant de la formation de Sheepbed (Canada) et de Doushantuo (Chine) ont suggéré que J'oxygénation progressive des eaux de fond pourrait avoir permis l'apparition burtale des animaux au début de l'Édiacarien et avoir déclenché leur diversification.. Les données isotopiques de C et S, à la limite Pr-T de Nhi Tao (Vietnam), exposent un appauvrissement en 34S, des valeurs négatives du o13 C des carbonates, et une variation positive significative entre les horizons pyriteux (proxy : [S]py et o34Spy) et o13 C de carbonate (10-20 cm). Ces données isotopiques suggèrent que la remontée des eaux profondes anoxiques pourrait avoir servie comme mécanisme de déclenchement pour l'extinction de masse du Permien. ______________________________________________________________________________ MOTS-CLÉS DE L’AUTEUR : diversification, extinction de masse, isotope du carbone, isotope du soufre, spéciation du Fe, procédé de refroidissement, oxique, anoxique

Not many of the abundant freshwater bacterial groups have a representative cultured isolate. In this master thesis project, some abundant bacterioplankton from two lakes (Lake Ekoln and Lake Erken) could be isolated by a dilution-to-extinction approach. Sterilized lake water which was obtained through an ultrafiltration system was used resembling a natural medium. Specific fragments of 16s rRNA of the isolates were amplified by universal bacterial primers (27f and 1492r, 341f and 805r.) for genotyping against a freshwater sequence database and RDP training set (Version 7). A total of 33 isolates from the two lakes were taxonomically classified and revealed the isolation of typical and abundant freshwater bacteria. Original bacterial community of Lake Ekoln was also analyzed by 16S rRNA clone library construction for diversity study. Phylogenetic trees were built through neighbor-joining method by Mega (Version 5) to reveal the evolutionary relationships among database entries, obtained isolates and clones.

The Hirnantian mass extinction was the second largest of the Phanerozoic. A global sea level fall resulting from a glaciation on Gondwanaland caused significant changes in ocean circulation patterns and nutrient cycling that is recorded as a worldwide positive δ13C excursion.<p> In chapter 2, carbon and nitrogen isotope profiles were reconstructed from two North American carbonate platforms in Nevada and one in the Yukon with the purpose of gaining a better understanding of proximal to proximal gradients in δ13C values from Hirnantian epeiric seaway sediment. Positive δ13C excursions are recorded in bulk inorganic and organic carbon fractions from all three sections, and in graptolite periderms from one section. A larger positive excursion is recorded in the proximal sediment (7) compared to proximal sediment (3-4). This gradient appears to reflect differences in surface water dissolved inorganic carbon δ13C values across epeiric seas. These findings are consistent with the carbonate weathering hypothesis, that predicts larger positive δ13C shifts in proximal settings of tropical epeiric seas resulting from changes in the local carbon weathering flux caused by the exposure of vast areas of carbonate sediment during glacioeustatic sea level fall and restricted shelf circulation. A 2 positive excursion in δ15N is interpreted to result from increased ocean ventilation, greater partitioning of atmospheric oxygen into downwelling surface waters, oxygen minimum zone shrinkage, and declining denitrification rates. This allowed for upwelling of recycled nitrogen with high 15N values into the photic zone that forced exported organic matter from the photic zone to higher 15N values, consistent with the observed positive shift in 15N during the Hirnantian glaciation. This study presents a conceptual model to explain secular changes in δ13C and δ15N during the transition from a greenhouse to icehouse climate.<p> The second focus of this research, presented in chapter 3, was on improving the chemical and analytical methods for δ18O analysis of biogenic apatites. The technique applies cation exchange chromatography that allows for small sample sizes of apatite (200 µg) to be used for chemical conversion to Ag3PO4. The precision (0.15, 1) of δ18O analysis obtained using a Thermal Conversion Elemental Analyser Continuous Flow Isotope Ratio Mass Spectrometer (TC/EA CF-IRMS), and the ability to collect multipe isotopes (O, Ca, Sr, REE) using a cation exchange column, makes this technique valuable for high-resolution, multi-isotope studies of biogenic apatites.

<p>Biodiversity conservation issues are complex and contentious. In this dissertation, I focus on Indian mammal conservation science, management, as well as policy issues that shape these factors. I am particularly interested in, where and which mammals are extinction prone, and what factors promote species persistence in human-dominated landscapes. I examine patterns of extinction, range contraction and current distribution of 25 species of large mammals in India in Chapters 2 and 3. I apply occupancy models to data from a sub-continental scale expert opinion survey. I model species occurrence in relation to ecological and social covariates based on a priori hypotheses about the determinants of mammalian distribution patterns. </p><p>I find that all 25 large mammal species are extinction prone. I find time affects extinction, and conservation initiatives of the last four decades have allowed some species to re-colonize some areas. I find protected wildlife reserves are critically important for persistence of species. Many species with much of their habitat outside existing protected areas will require new protected areas to persist. I find that human population density negatively influences survival probability for species, and human cultural tolerance positively affected persistence of species. Most large-bodied animals, habitat specialists, and rare species had higher extinction probabilities. I find that in addition to protected areas, land use, and human population densities, regionally rooted cultural and religious factors have allowed some species to survive. Conservation strategies must integrate all these factors to ensure the survival of India's large mammals in the future.</p><p>Conservation efforts to protect wildlife in human-dominated landscapes, often requires relocation of people. This policy has rarely been examined in detail. In Chapter 4, I focus on a reserve in India's Western Ghats of India to assess resettlement experiences of people during and after implementation of a relocation project. </p><p>Lastly, the success or failure of conservation policies and management interventions be they for protecting wildlife or addressing needs of local communities, depends substantially on the attitudes of conservation practitioners. In Chapter 5, I examine the attitudes, perspectives and opinions of Indian conservationists towards conservation issues and policies in India.</p> / Dissertation

Combustor blowout is a very serious concern in modern land-based and aircraft engine combustors. The ability to sense blowout precursors can provide significant payoffs in engine reliability and life. The objective of this work is to characterize the blowout phenomenon and develop a sensing methodology which can detect and assess the proximity of a combustor to blowout by monitoring its acoustic signature, thus providing early warning before the actual blowout of the combustor. The first part of the work examines the blowout phenomenon in a piloted jet burner. As blowout was approached, the flame detached from one side of the burner and showed increased flame tip fluctuations, resulting in an increase in low frequency acoustics. Work was then focused on swirling combustion systems. Close to blowout, localized extinction/re-ignition events were observed, which manifested as bursts in the acoustic signal. These events increased in number and duration as the combustor approached blowout, resulting an increase in low frequency acoustics. A variety of spectral, wavelet and thresholding based approaches were developed to detect precursors to blowout. The third part of the study focused on a bluff body burner. It characterized the underlying flame dynamics near blowout in greater detail and related it to the observed acoustic emissions. Vorticity was found to play a significant role in the flame dynamics. The flame passed through two distinct stages prior to blowout. The first was associated with momentary strain levels that exceed the flames extinction strain rate, leading to flame holes. The second was due to large scale alteration of the fluid dynamics in the bluff body wake, leading to violent flapping of the flame front and even larger straining of the flame. This led to low frequency acoustic oscillations, of the order of von Karman vortex shedding. This manifested as an abrupt increase in combustion noise spectra at 40-100 Hz very close to blowout. Finally, work was also done to improve the robustness of lean blowout detection by developing integration techniques that combined data from acoustic and optical sensors.

In the 1960s a movement by the National Audubon Society encouraged growing communities to set aside a portion of undeveloped land to be used as nature centers to teach conservation and natural history while allowing people to cultivate an understanding and appreciation of nature. This research responds to the need for a greater understanding of who is visiting nature centers in the 21st century and why. A key question is whether or not nature centers have kept up with changing times and advancing technologies. No research has been conducted to determine if nature centers are still relevant today to a society accustomed to living and learning electronically in a virtual reality. In order to determine who visits nature centers and why, a questionnaire was developed and administered to Members and Non-members of the Fort Worth Nature Center & Refuge (FWNC) of Fort Worth, TX. It was determined that visitors to the FWNC were not representative of the general population of the surrounding area. They were older, predominantly white, and had higher education levels. Using the membership in a Friends organization as a representative population of nature center visitors, it was determined that the Non-member visitors were similar to the Members except that they were younger. Members visited the FWNC with a higher degree of frequency than Non-members, but there was no difference in degree of visitation to other nature centers. Both groups identified "lack of time" as the primary barrier to increased visitation. Members appeared to be seeking specific, educational experiences compared to Non-members who tended to seek more general, recreational experiences. Members had more specific knowledge about benefits and services that the FWNC provided the community. Overall, both groups were satisfied with their visits, with Members having a more defined set of expectations and a higher level of satisfaction. This preliminary assessment suggests that nature centers continue to be a relevant source for education, recreation and relaxation, and continue to remain a unique resource in keeping 21st century society connected to the nature world.

We use the adaptive probabilities of crossover and mutation, elitist strategy, and extinction and immigration strategy to improve the simple genetic algorithm in this study. We expect that the search technique can avoid falling into the local maximum due to the premature convergence, and the chance of finding the near-optimal parameter in the larger searching space could be obviously increased. The accelerometer is then taken as the sensor for output measurement, and the designed actuator and digital PID controller is implemented to actively suppress the vibration of the plain that is due to the excitation effect of the high-speed and precision positioning of the linear motor. From the computer simulations and the experimented results, it is obvious that the near-optimal digital PID controller designed by modified genetic approach can improve the effect of vibration suppression; the settling time is also decrease. For the vibration suppressions of high-speed precision positioning problems, the vibrating plain system can fastly be stabilized.

Amplitude and Phase Shift Keying (APSK) format is one of the most attractive advanced modulation formats because of its good spectral efficiency. As the information bandwidth of the current optical fiber communication system is limited by the optical amplifier bandwidth, it is important to utilize the limited bandwidth effectively. This master thesis focuses on to study the transmission performance of the APSK format both theoretically and experimentally. At first, a theoretical study was conducted using a numerical simulation. As the Extinction Ratio (ER) of the Amplitude Shift Keying (ASK) signal affects the performances of both the ASK and the Phase Shift Keying (PSK) signals, the effect of the ER upon the transmission performance of the APSK format was studied. A clear trade-off between the performance of the ASK signal and the PSK signal due to the change of the ER was observed. Then, in order to improve the performance of the APSK format, a method to improve the transmission performance was proposed. This method was named as ¡§zero-nulling method¡¨, and it solved the trade-off issue caused by the ER. The effectiveness of this method was confirmed through the numerical simulation. Next, an experimental study was conducted. An experimental setup including 330km optical fiber transmission line was prepared, and it was used to confirm the results of the theoretical simulation. The performance trade-off between the ASK and the PSK signals due to the ER was confirmed experimentally. Finally, another experimental study was conducted. An experimental setup of 500km transmission line was used for this study. By adopting the recirculating loop experimental setup, the transmission length could be extended to a few thousand kilometers. The applicability of the ¡§zero-nulling method¡¨ was confirmed using this experimental setup.

In the present study syngas-air diffusion flames are simulated using LES with artificial neural network (ANN) based chemical kinetics modeling and the results are compared with previous direct numerical simulation (DNS) study, which exhibits significant extinction-reignition and forms a challenging problem for ANN. The objective is to obtain speed-up in chemistry computation while still having the accuracy of stiff ODE solver. The ANN methodology is used in two ways: 1) to compute the instantaneous source term in the linear eddy mixing (LEM) subgrid combustion model used within LES framework, i.e., laminar-ANN used within LEMLES framework (LANN-LEMLES), and 2) to compute the filtered source terms directly within the LES framework, i.e., turbulent-ANN used within LES (TANN-LES), which further dicreases the computational speed. A thermo-chemical database is generated from a standalone one-dimensional LEM simulation and used to train the LANN for species source terms on grid-size of Kolmogorov scale. To train the TANN coefficients the thermo-chemical database from the standalone LEM simulation is filtered over the LES grid-size and then used for training. To evaluate the performance of the TANN methodology, the low Re test case is simulated with direct integration for chemical kinetics modeling in LEM subgrid combustion model within the LES framework (DI-LEMLES), LANN-LEMLES andTANN-LES. The TANN is generated for a low range of Ret in order to simulate the specific test case. The conditional statistics and pdfs of key scalars and the temporal evolution of the temperature and scalar dissipation rates are compared with the data extracted from DNS. Results show that the TANN-LES methodology can capture the extinction-reignition physics with reasonable accuracy compared to the DNS. Another TANN is generated for a high range of Ret expected to simulate test cases with different Re and a range of grid resolutions. The flame structure and the scalar dissipation rate statistics are analyzed to investigate success of the same TANN in simulating a range of test cases. Results show that the TANN-LES using TANN generated fora large range of Ret is capable of capturing the extinction-reignition physics with a very little loss of accuracy compared to the TANN-LES using TANN generated for the specific test case. The speed-up obtained by TANN-LES is significant compared to DI-LEMLES and LANN-LEMLES.