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Thermal decomposition of (presumed) bismethylene diazeneHawke, David H. Dervan, Peter B. January 1977 (has links)
Thesis (Masters)--California Institute of Technology, 1977. / Advisor names found in the Acknowledgments pages of the thesis. Title from home page. Viewed 02/09/10. Includes bibliographical references.
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Solid state decomposition of alkyloxy furoic acidsKothari, Rohit Chunilal. January 1900 (has links)
Thesis (Ph. D.)--University of Wisconsin--Madison, 1982. / Typescript. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 153-167).
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The thermal decomposition of methyl vinyl etherHarris, Jack Edward January 1942 (has links)
[No abstract submitted] / Science, Faculty of / Chemistry, Department of / Graduate
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Quantum yields of decomposition in the photolytic oxidation of methyl mercaptan, dimethyl sulphide and dimethyl disulphideSheraton, Donald Frederick January 1979 (has links)
The Kraft pulping process produces vast quantities of sulphide vapours which are released to atmosphere. The major components are methyl mercaptan, hydrogen sulphide, dimethyl sulphide and dimethyl disulphide. The fate of these compounds in the atmosphere and the kinetics of their degradation processes in the atmosphere are useful in the modeling of the environment of areas proximate to Kraft pulp mills. The information may also be useful in developing pollution abatement processes.
The photolytic oxidation of methyl mercaptan, dimethyl sulphide and dimethyl disulphide was studied in a batch photolysis apparatus. Short wavelength ultra-violet light was provided by a deuterium discharge lamp and monitored by a monochromator equipped with an extended response photo-multiplier tube. Sulphide concentrations were determined on a gas chromatograph equipped with a flame photmetric detector having 365 nm sulphur response.
The rate of reaction of methyl mercaptan was found to be a linear function of the photon absorption rate and exhibited a quantum yield of decomposition of 13.9. The methyl mercaptan photo-oxidation rate was found to be unaffected by increased oxygen concentration, decreased atmospheric pressure or the presence of excess sulphur dioxide.
The quantum yield of dimethyl sulphide decomposition was found to be dependent upon atmospheric pressure. A pressure of one atmosphere gave a quantum yield of 4 and the yield increased to 8 at one-quarter atmosphere. The quantum yield of dimethyl disulphide.was found to be 1.9 at atmospheric pressure at a concentration of 7.04 x 10⁻⁵M.
The apparatus was also operated in a configuration which allowed the detection of light emitted at 90° to the path of illumination. A slow developing emission was found for dimethyl sulphide, hydrogen sulphide and •sulphur dioxide. Only slight emission was found for methyl mercaptan and dimethyl disulphide.
The emission from dimethyl sulphide was found to be linearily dependent upon the nitrogen pressure of a dry nitrogen atmosphere. The emission is attributed to aerosol formation and is due to the light scattered from particles in the reaction matrix. / Science, Faculty of / Chemistry, Department of / Graduate
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Preparation and characterization of SrTiO₃ thin films by modified metalorganic decomposition technique.January 2002 (has links)
by Ng Tsz Bun. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2002. / Includes bibliographical references. / Abstracts in English and Chinese. / Abstract --- p.i / Acknowledgements --- p.iv / Table of contents --- p.v / List of Figure captions --- p.vii / List of Table captions --- p.xii / Chapter Chapter 1 --- INTRODUCTION --- p.1 / Chapter 1.1 --- Sol-gel synthesis / Chapter 1.2 --- Ceramic Structures / Chapter 1.3 --- Dielectric Behaviour / Chapter 1.4 --- Ferroelectricity and Piezoelectricity / Chapter 1.5 --- Metal-Insulator-Metal system / Chapter 1.6 --- Space Charge Limited Currents / Chapter Chapter 2 --- Sample Preparation and Characterisation Methods --- p.27 / Chapter 2.1 --- Preparation of Precursor Solution bya New Chemical Route / Chapter 2.2 --- Preparation of Precursor Solution for SrTi(1_x)Nbx03 Thin Films / Chapter 2.3 --- Sample Preparation / Chapter 2.4 --- Chemistry of the Sol-gel Process / Chapter 2.5 --- Rutherford Backscattering Spectrometry (RBS) / Chapter 2.6 --- X-ray Diffraction (XRD) / Chapter 2.7 --- X-ray Photoelectron Spectroscopy (XPS) / Chapter 2.8 --- Atom Force Microscopy (AFM) / Chapter 2.9 --- Transmission Electron Microscopy (TEM) / Chapter Chapter 3 --- Characterization of composition and thickness of SrTi03 thin Films --- p.48 / Chapter 3.1 --- Composition Characterization / Chapter 3.2 --- Thickness Characterization / Chapter Chapter 4 --- Structural Properties of STO Thin Films --- p.57 / Chapter 4.1 --- Effects of Annealing Method on STO Thin Film Structure / Chapter 4.2 --- Substrate Effects on Structure of STO Thin Films / Chapter 4.3 --- Effects of Si02 Buffer Layer on Structure of STO Thin Films / Chapter 4.4 --- Effects of STO Film Thickness on Structure of STO Thin Films / Chapter 4.5 --- Surface Morphology of STO Thin Films / Chapter Chapter 5 --- Electrical Characterization of STO Thin Films --- p.78 / Chapter 5.1 --- C-V characteristics / Chapter 5.2 --- I-V characteristics / Chapter Chapter 6 --- Effect of Niobium Doping on The STO Thin Films --- p.100 / Chapter Chapter 7 --- Conclusions and Future Work --- p.109 / Chapter 7.1 --- Conclusions / Chapter 7.2 --- Future Work / Publications --- p.112 / Appendix --- p.113 / Preparation of Cross-sectional TEM Specimen
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Study of the effect of gold, platinum and vanadium oxide additives on the activity of TiO₂-ZrO₂ mixed oxide for the decomposition of CFC-22Zhang, Hongxia 01 January 2002 (has links)
No description available.
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A study of the determination of fluorine and other constituents in fluorsparGrantham, Robert Knowlton. January 1929 (has links) (PDF)
Thesis (M.S.)--University of Missouri, School of Mines and Metallurgy, 1929. / Page number 23 is repeated twice in the paging. The entire thesis text is included in file. Typescript. Illustrated by author. Title from title screen of thesis/dissertation PDF file (viewed Dec. 11, 2009). Includes bibliographical references (p. 35).
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Alkaliczna degradacja 2,3-0-podstawionych mono i olìgocukrówPawlak, Zofia. January 1973 (has links)
Rozprawa habilitacyjna--Warsaw. / Bibliography: p. [111]-114.
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A quantitative study of the photochemical decomposition of acetoneDamon, G. H. January 1932 (has links)
Thesis (Ph. D.)--University of Wisconsin--Madison, 1932. / Typescript. Vita. With this is bound: The photolysis of gaseous acetone and the influence of water / By Glenn H. Damon and Farrington Daniels. Reprinted from Journal of the American Chemical Society, vol. 55 (1933), p. [2363]-2375. Includes bibliographical references (leaf [68]).
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Novel radical peroxyester photoinitiators decomposition mechanisms and potential applications /Polyansky, Dmitry E. January 2005 (has links)
Thesis (Ph.D.)--Bowling Green State University, 2005. / Document formatted into pages; contains xvi, 135 p. : ill. Includes bibliographical references.
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