No description available.

No description available.

A study on the slag dispersion in bath smelting converter was undertaken. The aim was mainly to investigate the behaviour of the dispersed slag phase at high gas flow rate and low slag volume (10%) systems. For simulations purposes, water; paraffinoil and air were used in a one fifth model of the commercial 100 ton Creusot-Loire- Uddeholm converter to represent bulk steel, molten slag and gas respectively. Emulsion samples were collected by means of the specially made syringe. The experimental results revealed that the dispersed slag phase decreased with the vertical distance from the original interface between the liquid phases. The dispersed phase decreased also with the radial distance in the water plume zone towards the wall side. The holdup was apparently much observable on the right side than on the left side. Four dimensionless numbers defined the dispersion phenomenon through the dimensional analysis. The modified Froude Number ensured the correlation between both model and prototype. The standard error of the estimate and R-squared between the experimental and the calculated results were 3.7 ´10-4 and 0.97 respectively.

Hydrochloric acid leaching of saprolite nickel ores has been proposed as an effective means of recovering nickel and cobalt. However, the leach produces a concentrated brine of magnesium chloride which must be hydrolyzed to recover the HCl lixiviant. The processing of carnallite similarly produces a concentrated MgCl2 brine; converting this brine into HCl and MgO provides an attractive way of adding value while effectively disposing of this waste product. Direct pyrohydrolysis of magnesium chloride brines by the reaction, MgCl2,a + H2Oa  MgOs + 2HClg is energy-intensive as large volumes of water must be evaporated. The energy cost is high, and the HCl stream produced is limited to approximately 20 wt% HCl. This thesis explores alternative methods of obtaining HCl from aqueous magnesium chloride solutions. Two methods are considered: the hydrolysis, under autogenous pressure, of concentrated MgCl2 molten salt hydrates; and the precipitation of magnesium hydroxychloride compounds such as 2MgO·MgCl2·6H2O and 3MgO·MgCl2·11H2O, which are subsequently decomposed at high temperature. Considerable experimental difficulties were encountered in studying pressure hydrolysis of molten salt hydrates, despite extensive equipment modifications. Ultimately, the work moved on to precipitation and decomposition of hydroxychlorides. This was found to bear promise, and conceptual flowsheets based on these reactions are presented. A phase stability diagram giving the areas of predominance of the different hydroxychloride phases is presented, and fundamental thermochemical data are derived. The results of a kinetic study on magnesium hydroxychloride thermal decomposition are also presented. / Thesis (Ph.D, Mining Engineering) -- Queen's University, 2011-03-11 10:14:53.455

<p>  </p> <p>Due to the difficulty in physically observing the phenomena inside the actual ladle furnace in the industry, to ascertain optimized methodology for high-grade steel production, an investigation was carried out using numerical modeling to simulate the behavior of alloying elements within the liquid steel bulk using ANSYS Fluent 2020 R1 (ANSYS Inc., Pittsburgh, PA, USA). The model solves the governing equations utilized in computing the trajectories of each particle in the discrete phase. Furthermore, a user defined (UDF) code maps the mass of each parcel based on the total amount of alloy injected. The code also defines the total time it takes for the shell formed around the added materials to melt or dissolve. The study consists of a two-step procedure: ladle stirring by argon inert gas injection and mixing study by injecting micro-alloying elements to capture the flow field, turbulence, and species transport occurring during the refining process. A generic dual plug ladle metallurgy furnace, dimensions, and data obtained from Nucor Steel is used to validate the CFD simulation results. Concise parametric studies consist of ladle geometry design adjustments, variations of argon gas flow rates, and different alloying elements. Though the efficiency of the LMF process is quantified using the mixing time, which decreases as initial gas flow rates increase, results from this study show that extremely high charging of ladles is optional in obtaining shorter mixing. Also, particles behave substantially differently when their densities are below or above that of steel, and their melting points and specific heat capacities influence the time it takes for them to melt or dissolve. The overall potential outcome for this study is to improve the mixing practices due to different optimal procedures required by some materials than others.</p>

This report recommends a strategy for the introduction of aviation style Crew Resource Management (CRM) to the offshore drilling industry. The purpose of this study was to investigate ways CRM could be applied to the offshore drilling industry as a means of mitigating the risks of human error, and in particular risks to health and safety. Research has been conducted in accordance with accepted social science research methodologies. Key processes involved a formal literature review plus the formation of a Nominal Reference Group and application of the Delphi Technique as the primary data gathering method. Case studies have been used throughout this report to provide examples of key points and to illustrate the need for effective management of human error in both the aviation and drilling industries. Results from this study provided the basis for the development of a preferred implementation plan as a practical means for adopting the principles of CRM to the offshore drilling industry. Recommendations for furthering this work include the need to benchmark training as a means of providing better evidence that CRM leads to improved safety and operational performance, the need to develop a business plan to justify the cost and effort, the need to further involve key stakeholders in the process, and they need to solicit endorsement for this project from influential industry bodies.

The project undertook a systematic study of chlorination of titanium oxycarbide and oxycarbonitride with the aim to develop further understanding of kinetics and mechanisms of the chlorination reactions. The project studied titania, ilmenite ores, and synthetic rutile reduced by carbon in argon and nitrogen and chlorinated at different temperatures, gas flow rates and compositions. Chlorination of titanium suboxides, iron and impurities in ilmenite was also examined. Chlorination of titanium oxycarbide Ti(O,C) or oxycarbonitride Ti(O,C,N) can be implemented at 200 to 400 deg.C, while the commercial chlorination process in the production of titanium metal or titania pigment requires 800 to 1100 deg.C. This makes chlorination of Ti(O,C) or Ti(O,C,N) an attractive technology in processing of titanium minerals. Chlorination reaction is strongly exothermal, which increased the sample temperature up to 200 deg.C above the furnace temperature. The chlorination of Ti(O,C) or Ti(O,C,N) was ignited at 150 deg.C to 200 deg.C depending on the sample composition. Their chlorination at 235 deg.C to 400 deg.C was close to completion in less than 30 min. The chlorination rate of titanium oxycarbide or oxycarbonitride increased with increasing gas flow rate. Sample composition had a significant effect on the extent of chlorination. The optimum results were obtained for titanium oxycarbide or oxycarbonitride produced with carbon to titania molar ratio of 2.5; these samples contained no detectable excess of carbon or unreduced titanium suboxides. In chlorination of reduced ilmenite ores and synthetic rutile, Ti(O,C) or Ti(O,C,N), metallic iron and Ti2O3 were chlorinated. The rate and extent of chlorination of titanium increased with increasing carbon to TiO2 ratio. Chlorination of Ti2O3 was slow relative to Ti(O,C) or Ti(O,C,N) and iron; chlorination of impurity oxides such as MgO, SiO2 and Al2O3 was not observed. The project also examined chlorination of Ti(O,C) or Ti(O,C,N) in ilmenite ore and synthetic rutile after removal of iron, which was achieved by aerated leaching of reduced samples in heated flask containing 0.37 M of ammonium chloride solution. Iron removal from the ilmenite ore or synthetic rutile resulted in higher rate and extent of chlorination of titanium oxycarbide or oxycarbonitride.

No description available.

No description available.

The project undertook a systematic study of chlorination of titanium oxycarbide and oxycarbonitride with the aim to develop further understanding of kinetics and mechanisms of the chlorination reactions. The project studied titania, ilmenite ores, and synthetic rutile reduced by carbon in argon and nitrogen and chlorinated at different temperatures, gas flow rates and compositions. Chlorination of titanium suboxides, iron and impurities in ilmenite was also examined. Chlorination of titanium oxycarbide Ti(O,C) or oxycarbonitride Ti(O,C,N) can be implemented at 200 to 400 deg.C, while the commercial chlorination process in the production of titanium metal or titania pigment requires 800 to 1100 deg.C. This makes chlorination of Ti(O,C) or Ti(O,C,N) an attractive technology in processing of titanium minerals. Chlorination reaction is strongly exothermal, which increased the sample temperature up to 200 deg.C above the furnace temperature. The chlorination of Ti(O,C) or Ti(O,C,N) was ignited at 150 deg.C to 200 deg.C depending on the sample composition. Their chlorination at 235 deg.C to 400 deg.C was close to completion in less than 30 min. The chlorination rate of titanium oxycarbide or oxycarbonitride increased with increasing gas flow rate. Sample composition had a significant effect on the extent of chlorination. The optimum results were obtained for titanium oxycarbide or oxycarbonitride produced with carbon to titania molar ratio of 2.5; these samples contained no detectable excess of carbon or unreduced titanium suboxides. In chlorination of reduced ilmenite ores and synthetic rutile, Ti(O,C) or Ti(O,C,N), metallic iron and Ti2O3 were chlorinated. The rate and extent of chlorination of titanium increased with increasing carbon to TiO2 ratio. Chlorination of Ti2O3 was slow relative to Ti(O,C) or Ti(O,C,N) and iron; chlorination of impurity oxides such as MgO, SiO2 and Al2O3 was not observed. The project also examined chlorination of Ti(O,C) or Ti(O,C,N) in ilmenite ore and synthetic rutile after removal of iron, which was achieved by aerated leaching of reduced samples in heated flask containing 0.37 M of ammonium chloride solution. Iron removal from the ilmenite ore or synthetic rutile resulted in higher rate and extent of chlorination of titanium oxycarbide or oxycarbonitride.