published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy

This study represents the first detailed geological, geophysical and geochronological investigation of the continental shelf surrounding the Aliwal Shoal, ~5 km offshore of Scottburgh, in southern KwaZulu-Natal. Mapping of the seafloor geology using geophysics and direct observations from SCUBA diving transects were integrated with the seismic stratigraphy and constrained by new geochronological data. Four seismic stratigraphic units (A to D) were identified and interpreted with the subsequent sequence stratigraphic model consisting of four incompletely preserved stratigraphic sequences separated by three sequence boundaries (SB1 - SB3) comprising complex reworked subaerial unconformity surfaces. Sequence 1 is the deepest, subdivided by a basin-wide marine flooding surface (MFS1) into a lower Campanian (and possible Santonian) TST and an upper Maastrichtian combined regressive systems tract comprising HST/FRST deposits. SB1 follows Sequence 1 and spans most of the Tertiary representing multiple erosional events. Shelf sedimentation resumed during the Late Pliocene to early Pleistocene with deposition of Sequence 2, the shelf-edge wedge, which again was followed by erosion and non-deposition during the high frequency and amplitude Early to Middle Pleistocene sea-level fluctuations resulting in the formation of SB2. Sequence 3 consists of coast-parallel, carbonate cemented aeolianite palaeo-shoreline ridges of various ages overlying Sequence 1 and 2. Sequence 4 unconformably overlies all the earlier sequences and comprises a lower TST component displaying characteristic retrogradational stacking patterns and an upper local HST clinoform component showing progradation and downlapping. Inner and middle shelf TST units constrained between Sequence 3 ridges form thick sediment deposits showing a progression from lagoonal and lower fluvial-estuarine deposits, overlain by foreshore and shoreface sands, documenting the changing depositional environments in response to a sea-level transgression. Laterally, in the absence if Sequence 3 ridges, TST sediments comprise only a thin transgressive sand sheet. The upper HST component comprises a prograding shore-attached subaqueous-delta clinoform sediment deposit, the Mkomazi Subaqueous-Delta Clinoform (MSDC) which evolved in four stages. An initialization and progradation stage (Stage 1) (9.5 to 8.4 ka cal. B.P.) was interrupted by retrogradation (Stage 2) and backstepping of the system due to rapid sea-level rise between 8.4 to 8.2 ka cal B.P. Stage 2 backstepping of the clinoform controlled the subsequent overlying topset morphologies resulting in later stages inheriting a stepped appearance upon which shoreface-connected ridges (SCR’s) are developed. Stages 3 (8.2 to 7.5 ka cal. B.P.) and 4 (7.5 to 0 ka cal. B.P) show a change from ‘proximal’ topset aggradation to ‘distal’ foreset progradational downlap, linked to a change in the dominant sedimentary transport mechanism from aggradational alongshore to progradational cross-shore related to variations in accommodation space and the rate of sediment supply. Morphologically the MSDC is characteristic of sediment input onto a high energy storm-dominated continental shelf where oceanographic processes are responsible for its northward directed asymmetry in plan-view, for the lack of a well defined bottomset and for the re-organisation of its topset into very large SCR’s. The SCR’s are 1 - 6 m in height, spaced 500 to >1350 m apart and vary from 3 km to >8 km in length, attached on their shoreward portions to the shoreface between depths of -10 m to -15 m (average at -13 m) and traceable to depths exceeding -50 m, although the majority occur on the inner shelf between -20 m to -30 m. Several individual crests can be identified forming a giant shoreface-connected sand ridge field with a sigmoidal pattern in plan-view postulated to be a surficial expression of the subjacent retrogradational phase (MSDC Stage 2). SCR’s development occurred in two stages. Stage 1 involved deposition of sediment on the shoreface and ridge initiation during the MSDC Stage 2 retrogradational event. Sediment was reworked during sea-level rise generating clinoforms with proximal along-shore aggradation and distal across-shore progradation. This occurred during the last post-glacial sea-level rise from ca. 8.4 ka cal. B.P. SCR Stage 2 represents modern maintenance of the SCR system which is continually modified and maintained by shelf processes and consists of two physical states. State 1 considers SCR maintenance during fair-weather conditions when transverse ridge migration is dominant and driven by the north-easterly flowing counter current shelf circulation. State 2 considers SCR development during storm conditions when longitudinal ridge growth is suggested to occur as a result of storm return flows. Following the storm, the regional coast-parallel current system is restored and the fair-weather state then moulds the SCRs into a transverse bedform. Deposition on the MSDC is ongoing on a continental shelf that is still in a transgressive regime. The exposed seafloor geology comprises late Pleistocene to Holocene aeolianite and beachrock lithologies, deposited as coastal barrier and transgressive shoreface depositional systems. Extensive seafloor sampling was combined with a multi-method geochronological programme, involving the U-series, C14 and optically stimulated luminescence (OSL) to constrain the evolution of the aeolianite and beachrock complex. The Aliwal Shoal Sequence 3 ridge comprises three distinct aeolianite units (A1 to A3) which represent different types of dune morphologies deposited during the climatic and associated sea-level fluctuations of MIS 5. Units A1 and A2 deposited during the MIS 6/5e (~134 to ~127 ka cal. B.P.) transgression represent contemporaneous evolution of a coastal barrier system which consisted of two different dune forms associated with a back-barrier estuarine or lagoonal system. Unit A1 most likely originated as a longitudinal coastal dune whilst Unit A2 comprised a compound parabolic dune system that migrated into the back-barrier area across an estuary mouth/tidal inlet of the back-barrier system. The coastal barrier-dune configuration established by Unit A1 and A2 was most likely re-established during similar subsequent MIS 5 sea-level stands which during MIS 5c/b resulting in the formation of the back-barrier dune system of Unit A3. Palaeoclimatic inferences from Units A1 and A2 aeolianite wind vectors indicate a change from cooler post-glacial climates (lower Unit A1) to warmer interglacial-like conditions more similar to the present (upper Unit A1 and Unit A2). Unit A3 palaeowind vector data show variability interpreted to be related to global MIS 5c climatic instability and fluctuations. For Units A1, A2 and A3 pervasive early meteoric low-magnesium calcite (LMC) cementation followed shortly after deposition protecting the dune cores from erosion during subsequent sea-level fluctuations. Sea-spray induced vadose cementation in Units A1 and A2 may have been a key factor in stabilising dune sediment before later phreatic meteoric cementation. The final preserved Late Pleistocene depositional event in the study area was that of the storm deposit of beachrock Unit B5. Induration followed shortly after deposition by marine vadose high-magnesium calcite (HMC) cementation. Following deposition and lithification, Units A1, A2, A3 and B5 underwent a period of cement erosion associated with decementation and increased porosity due to either 1) groundwater table fluctuations related to the high frequency MIS 5 sea-level fluctuations and/or 2) carbonate solution due to complete subaerial exposure related to the overall MIS 4 - 2 sea-level depression towards the LGM lowstand. In addition to the decementation and porosity development Unit B5 also experienced inversion of the original unstable HMC cement to LMC. During MIS 4 to 2 the Aliwal shelf comprised an interfluve area which was characterised by subaerial exposure, fluvial incision of coast-parallel tributary river systems and general sediment starvation. Beachrock Units B1 to B4 were deposited in the intertidal to back-beach environments and subsequently rapidly cemented by marine phreatic carbonate cements comprising either aragonite or HMC. Unit B1 was most likely deposited at 10.8 ka cal. B.P., B2 at 10.2 ka cal. B.P, B3 at 9.8 ka cal. B.P and B4 <9.8 ka cal. B.P. thereby indicating sequential formation during the meltwater pulse 1b (MWP-1b) interval of the last deglacial sea-level rise. Unit B3 marks the change from a log-spiral bay coastal configuration established by Units B1 and B2 to a linear coastline orientation controlled by the trend of the pre-existing aeolianite units. This change in the morphology of the coastline is also documented by the shape of the underlying transgressive ravinement surface (reflector TRS, Sequence 4) which again was controlled by the subjacent sedimentary basin fill architecture and subsequent transgressive shoreline trajectory (Sequence 4). Sea-level rose at an average rate of 67 cm/100 years from B1 to B2 and 86 cm/100 years from B2 to B2 indicating an acceleration in the rate of sea-level rise supporting enhanced rates of sea-level rise during the MWP-1b interval which also seemed to have altered the coastal configuration and resulted in the closure of the southern outlet of the back-barrier estuarine system. Two cycles of initial aragonite followed by later HMC cement are tentatively linked to two marine flooding events related to different pulses of enhanced rates of sea-level rise during MWP-1b which are considered responsible for significant changes in the marine carbon reservoir ages. Comparisons of the U-series, C14 and optically stimulated luminescence (OSL) methods have shown OSL to be the most reliable method applied to dating submerged aeolianites and beachrocks. OSL not only provides the depositional age of the sediment but also does not suffer from open system behaviour, such as marine reservoir changes and contamination. Acoustic classification of the unconsolidated sediment samples resulted in the demarcation of 3 major acoustic facies, C to E, interpreted with sample analyses as quartzose shelf sand (C), reef-associated bioclastic-rich sand (D) and an unconsolidated lag and debris deposit (E). Grain size distribution patterns of the unconsolidated seafloor sediments indicate that the SCR system delivers fine and medium sand to the inner and middle shelf and imparts a general N-S trending pattern to the gravel and sand fractions. In addition grain size distributions support selective erosion of the seaward flank of the Sandridge with the remobilised sediment deposited in the Basin as low amplitude bedforms over the Facies E lag and debris pavement. The mud fraction is interpreted to be deposited by gravity settling from buoyant mud-rich plumes generated by river discharge. Integration of acoustic mapping, field observations and sample analyses indicate that the present distribution of the unconsolidated sediment is the result of a highly variable distribution of modern and palimpsest sediments which are continually redistributed and reworked by a complex pattern of bottom currents generated by the interaction of opposing oceanographic and swell driven circulation patterns. / Thesis (Ph.D.)-University of KwaZulu-Natal, Westville, 2012.

Geological evidence suggests large-scale continental extension during the breakup of the eastern Gondwana margin was the predominant force controlling rifting of New Caledonia from the eastern Gondwana margin and formation of the Tasman Sea in the Late Cretaceous. Tectonic models suggest slab-rollback forces elongated and thinned the crustal lithosphere detaching crustal fragments from the Gondwana margin. Current tectonic models lack detailed timing and placement of this crustal detachment with respect to New Caledonia based on lack of evidence (rocks). An isotope and paleomagnetic study was carried out on a bi-modal assemblage of volcanic rock exposed on the southwest side of New Caledonia in the Nouméa Basin. U/Pb isotope ages of zircon grains found within siliceous volcanic rock in the Nouméa Basin provide temporal evidence that volcanism persisted both before and after the breakup of the eastern Gondwana Continent (100-90 Ma) in the Late Cretaceous. Four isotope ages >97 Ma and a series (11 samples) ranging from 91-76 Ma constrain the siliceous volcanism of the Nouméa Basin to the Late Cretaceous. A paleomagnetic inquiry utilizing statistics of both McFadden/Reid and Fisher carried out on 16 Nouméa Basin siliceous and mafic in situ formations place the oldest volcanic units found within the Nouméa Basin at 650 S latitude as New Caledonia began to separate from Gondwana (~100 Ma). The data suggests a well-developed arc signature in the region, which persisted for at least 15 Ma in the Late Cretaceous. Compared to current tectonic models of the southwest Pacific Region from the Late Cretaceous to Eocene, our data suggests New Caledonia was further south on the eastern Gondwana supercontinent prior to rifting in the Late Cretaceous than current models. / Geologic background -- Tectonic setting -- Methods -- Sampling -- Results -- Discussion. / Department of Geological Sciences

Typescript (Photocopy) / Includes copies of 4 papers by the author as appendix 4 (v. 1) / Errata slip inserted / Bibliography: leaves 170-192 (v. 1) / 2 v. : ill., maps ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Thesis (Ph.D.)--Dept. of Geology and Geophysics, University of Adelaide, 1992

It is now accepted that the last British-Irish Ice Sheet (BIIS) was highly dynamic and drained by numerous fast flowing ice streams. This dynamic nature combined with its maritime location made the BIIS sensitive to the rapid climate change that characterised the Last Glacial Interglacial Transition. Gaining an understanding of the behaviour of the BIIS at this time is important to explore the nature of forcing between ice sheets and climate. This thesis presents new chronological data relating to the deglaciation of the northwest sector of the BIIS (NW-BIIS) from onshore dating of moraines using cosmogenic exposure dating. This improved chronological framework is supported by offshore data in the form of a newly constructed Ice Rafted Detritus (IRD) record from the offshore sediment core MD95-2007. These data suggest that deglaciation commenced sometime after 18 ka and that the NW-BIIS was located close to the present day shoreline by 16 ka. Further provenance analysis of the IRD using U-Pb dating of detrital minerals demonstrates that during the Last Glacial-Interglacial Transition MD95-2007 was being supplied distal IRD from a source(s) to the west. The absence of diagnostic Scottish material suggests that after retreat to the coastline at 16 ka calving margins were not re-established during Greenland Interstadial 1. By combining these results with existing data relating to the deglaciation of the NW-BIIS it is possible to summarise the deglaciation history of the NW-BIIS from the continental shelf to mountainous source regions and compare this to numerical models of BIIS behaviour during this time. With a better understanding of the chronology of NW-BIIS retreat it is possible to relate the timing of initial deglaciation to possible forcing factors and gain a better understanding of the response of a marine based sector of an ice sheet to rapid climate change.

[Truncated abstract] The realization in 1999 that the authigenic phosphate, xenotime, could be used in geochronological studies to place age constraints on burial events that affected sedimentary basins has opened numerous opportunities for establishing timeframes for sedimentary basin analysis. Since then, the mineral has been used to place new and novel age constraints on diagenesis, metamorphism, and hydrothermal alteration and mineralization events. Whilst these studies were successful, they identified many complexities in xenotime growth and were restricted to specific areas or single basins: they do not convey, demonstrate or explore the immense variety of geological applications in which xenotime may provide unique geochronological constraints. This thesis explores the nature of authigenic xenotime, utilizing studies in three different Proterozoic sedimentary basins: two in Australia, southwestern Australia and the Northern Territory, and the third in the United States of America. The thesis includes a number of discrete studies demonstrating different aspects of xenotime growth, elucidated from detailed petrography, geochronology and geochemistry of authigenic xenotime. An integrated textural, geochemical and geochronological study of authigenic xenotime from the Mt Barren Group, SW Australia, establishes an absolute timescale on some of the many processes involved during the diagenesis of siliciclastic units. ... positions and trends and broadly confirm the chemical discrimination criteria established for an Archaean basin. However, the Proterozoic data are shifted to lower Gd-Dy values and extend beyond the original field outlines, causing more overlap between fields intended to discriminate xenotimes of different origin. The plots were revised to encompass the new data. This study has significantly extended our knowledge of the nature of authigenic xenotime. It was found that xenotime may form in (meta)sediments in response to a large number of post-depositional processes, including early- and latediagenesis, (multiple) basinal hydrothermal events and low-grade metamorphism. A combination of detailed petrography and in situ geochronology provides the best avenue to decipher complex growth histories in xenotime. With further development, it is likely that xenotime geochemistry will also prove diagnostic of origin and can be incorporated into the interpretation of age data. The number of potential applications for xenotime geochronology has been expanded by this study.

The fossiliferous sediments of the Hueso and Tapiado formations exposed in the Vallecito Creek-Fish Creek section (VCFC) of the Anza-Borrego Desert (ABD) span the boundary between Blancan and Irvingtonian North American Land Mammal 'Ages.' Historically, the determination of the Blancan-Irvingtonian (B-I) boundary in the VCFC proved problematic. A new study to determine the B-I boundary in the VCFC revealed data inaccuracies in both published works and curatorial records of the mammal and other vertebrate fossils from the ABD. Most individual inaccuracies were minor, but an accumulation of over 50 years of multiple inaccuracies had significant effects on local and regional biostratigraphic and biochronologic correlations. A detailed investigation of the inaccurate data resulted in recognition of 17 types of error, with at least five sources. The two most prominent sources of error are those derived from publication and curation protocols. Examination of over 150 publications and in-house faunal lists produced over 830 taxonomic names and format variants, for 110 mammalian taxa identified from the ABD and VCFC. Approximately 50% of the taxonomic identifications were previously published without voucher catalogue numbers or fossil descriptions. A critical review of the taxonomic assignments resulted in an updated faunal list of ABD terrestrial Mammalia, including 110 taxonomic names, 66 unqualified genera, and 46 unqualified species. A supplemental list of 'retired' taxa includes 178 previously published or listed taxonomic names and format variants. The 4.5 km sequence of originally superposed sediments within VCFC is now tilted at 23 degrees and exposed in plan view. This exposure was captured in both aerial photos and satellite imagery. GIS layers of the Geomagnetic Polarity Time Scale and individual collecting localities are readily superposed onto the stratigraphic images. When united with the faunal database, GIS maps of biostratigraphic data facilitate detection and correction of data errors. Resulting corrected maps show highest and lowest stratigraphic occurrences of taxa, as well as geographic clustering of taxonomic groups, outlining possible paleohabitats. As a result of data improvement and GIS display, the local B-I boundary currently is best estimated by the presence of Ovibovini at >1.42 Ma. / text

Indiana University-Purdue University Indianapolis (IUPUI) / U/Pb and (U-Th)/He (ZHe) dating of detrital zircons from glacial till samples in the Ross Embayment, Antarctica records cooling after the Ross/Pan-African orogeny (450-625 Ma) followed by a mid-Jurassic to mid-Cretaceous heating event in the Beacon basin. Zircons were extracted from till samples from heads of major outlet glaciers in East Antarctica, one sample at the mouth of Scott Glacier, and from beneath three West Antarctic ice streams. The Ross/Pan-African U/Pb population is ubiquitous in these Antarctic tills and many Beacon Supergroup sandstones, thus 83 grains were analyzed for ZHe to subdivide this population. Two ZHe age populations are evident in East Antarctic tills, with 64% of grains 115-200 Ma and 35% between 200-650 Ma. The older population is interpreted to be associated with the Ross/Pan-African orogeny including cooling of the Granite Harbour Intrusives and/or exhumation of the older basement rocks to form the Kukri Peneplain. The lag time between zircon U/Pb, ZHe and 40Ar/39Ar ages from K-bearing minerals show cooling over 200 My. Grains in East Antarctic tills with a ZHe age of 115-200 Ma likely reflects regional heating following the breakup of Gondwana from the Ferrar dolerite intrusions, subsidence within the rift basin, and a higher geothermal gradient. Subsequent cooling and/or exhumation of the Transantarctic Mountains brought grains below the closure temperature over a span of 80 My. This population may also provide a Beacon Supergroup signature as most of the tills with this age are adjacent to nunataks mapped as Beacon Supergroup and contain an abundance of vi Beacon pebbles within the moraine. Nine zircons grains from three Beacon Supergroup sandstones collected from moraines across the Transantarctic Mountains yield ages from 125-180 Ma. West Antarctic tills contain a range of ZHe ages from 75-450 Ma reflecting the diverse provenance of basin fill from East Antarctica and Marie Byrd Land. ZHe and U/Pb ages <105 Ma appear to be distinctive of West Antarctic tills. The combination of U/Pb, ZHe and 40Ar/39Ar analyses demonstrates that these techniques can be used to better constrain the tectonic evolution and cooling of the inaccessible subglacial source terrains beneath the Antarctic Ice Sheet.