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La synthèse par métallurgie des poudres de nickel à grains ultrafins (UFG) a été effectuée, et l’effet de l’affinement de la microstructure sur le comportement mécanique et les propriétés physiques a été étudié. La possibilité de coupler le broyage et le frittage flash est étudiée avec des résultats prometteurs. Des échantillons de haute densité avec des tailles de grains d = 0.65 – 4 µm, caractérisés par une fraction élevée des joints de grains Σ3 et un faible niveau de contrainte ont été synthétisés. Les propriétés mécaniques des échantillons UFG montrent une bonne combinaison ductilité-résistance mécanique, avec un impact mineur des porosités présentes. L’étude de l’influence de la taille de grain dans le régime UFG sur les propriétés mécaniques montre une limite d’élasticité supérieure à celle attendue et une capacité d’écrouissage plus faible. Ces observations sont cohérentes avec la microstructure déformée à rupture, étudiée par diffraction d’électrons rétrodiffusés et microscopie électronique en transmission. Une haute diffusivité, mesurée par des expériences de traceurs radioactifs, montrent des profils de pénétration très différents liés aux structures de porosités diverses présents dans les échantillons. Ces différentes structures sont aussi responsables de la densification rétrograde observée, uniquement pour les échantillons frittés à partir de poudres broyées. / The present manuscript concerns the synthesis of ultrafine grained (UFG) Ni by powder metallurgy, and the study of the influence of UFG microstructures on the mechanical behavior and physical properties. The possibilities of coupling ball milling and Spark Plasma Sintering are presented showing promising results. Highly dense homogeneous specimens are obtained, with average grain sizes d = 0.65 - 4 µm, and microstructures highlighted by a high fraction of Σ3 grain boundaries dependent on grain size. The mechanical properties in tensile testing for UFG samples are evaluated showing a good combination of strength and ductility, with little impact from porosities, the major drawback of powder metallurgy. The influence of grain size in the UFG regime on the mechanical properties is investigated, showing strength values that deviate from the expected behavior for grain refinement. Likewise, a reduced strain hardening capacity is depicted which correlates to the microstructural observations performed on the deformed state. High diffusivity measured by means of radiotracer experiments is observed in the sintered samples, displaying different penetration profiles that relate to diverse porosity structures. Such structures are also responsible for retrograde sintering observed exclusively in samples processed from BM powders.

Embankment dams are made from soil materials of varying sizes and widely used all over the world.When constructing these, knowing the hydraulic conductivity (K) of the soil materials is a keyparameter in order to construct safe embankment dams. A knowledge gap regarding K measurementsin coarse grained soils has been identified. This thesis aims to provide a theoretical overview ofpresent day state-of-the-art methods for measuring hydraulic conductivity and the controllingcharacteristics for K. Coarse grained soils refers to a soil with the coarsest grain fraction being > 20mm and/or have a K > 10-4m/s.   It was found that the fixed wall permeameter is the most suitable laboratory method. In the field, itis possible to estimate K using tracer methods, these however show more potential for leakagepathway detection. Common for all K measurement methods are the controlling characteristics of K,grain size distribution, pore geometry, degree of compaction, particle movement and flow regime.These need to be considered when testing to produce useful measurements. If the relationshipbetween flow velocity and hydraulic head is non-linear, Darcy's law is not valid for calculating K. / Fyllnadsdammar är uppbyggda av jord och sprängsten av olika storlekar och finns över hela världen.Att känna till den hydrauliska konduktiviteten (K) av de olika lagren är viktigt för att kunna byggadessa på ett säkert och hållbart sätt. Det har identifierats en bristande kunskap angående K mätningar igrovkorniga jord- och stenmaterial. Målet med denna uppsats är att presentera en teoretisk översikt avden senaste kunskapen inom K mätningar i grovkorniga jord- och stenmaterial och vilka egenskapersom avgör ett materials K. Grovkorniga jord- och stenmaterial syftar till material där den grövstakornstorleken är > 20 mm och/eller har ett K > 10-4m/s.   För laboratorie mätningar är en permeameter med en solid vägg den mest lämpliga metoden. Förfältmätningar är det möjligt att mäta K med hjälp av spårämnen, men dessa har mer potential för attupptäcka läckage vägar i fyllnadsdammar. De faktorer som avgör ett materials K ärkornstorleksfördelningen, geometrin av porerna, graden av kompaktering, partikelrörelse ochflödestyp. För att producera mätningar som är användbara behöver dessa faktorer kontrolleras. Omsambandet mellan hydrauliskt huvud och flödeshastighet är icke linjärt kan K inte beräknas genomDarcy´s lag.

<p>A thermodynamically consistent coarsed-grained phase field model was developed to find the conditions under which a heterogeneous porous electrode can be treated as homogeneous in the description of Lithium-ions in rechargeable batteries. Four regimes of behavior under which the transport phenomena can be homogenized to describe porous LIBs were identied: regime (a), where the model is inaccurate, for physically accessible particle packings of aspect ratios smaller than c/a = 0.5 and electrode porosities between 0.34 to 0.45; regime (b), where the model is valid, for particles of aspect ratios greater than c/a = 0.7 and electrode porosities greater than 0.35; regime (c), where the model is valid, but the microstructures are physically inaccessible, and correspond to particles with aspect ratios greater than c/a = 0.7 and electrode porosities smaller than 0.34; and regime (d), where the model is invalid and the porous microstructures are physically inaccessible, and correspond to particles with aspect ratios smaller than c/a = 1 and electrode porosities smaller than 0.34.</p> <p>The developed formulation was applied to the graphite | LixNi1/3Mn1/3Co1/3O2 system to analyze the effect of microstructure and coarsed-grained long-range chemomechanical effects on the electrochemical behavior. Specically, quantiable lithium distribution populations in the cathode, as a result of long range interactions of the diffuse interface, charge effects and mechanical stresses were identified: i) diffusion limited population due to negligible composition gradients, ii) stress-induced population as a result of chemically induced stresses, and iii) lithiation-induced population, as a consequence of the electrochemical potential gradients.</p>

This work presents a basic research on the influence of electron beam technology modification on chemical, structural and phases changes of Elektron 21 magnesium alloy. The samples were systematically modified under various parameters of the electron beam and coatings on their respective surfaces were deposited via controlled plasma electrolytic oxidation (PEO) subsequently. The influence of the EB modification on the PEO coating formation was observed. Several samples with remelted fine-grained surface layer were obtained. Having a thickness of 10^1 to 10^3 µm, the average grain sizes in this layer were quantitatively evaluated. The performed EDS analysis revealed in identical chemical composition of the remelted surface layer and the original alloy material, despite the detected sample weight loss upon the EB treatment. XRD analysis revealed an increased content of Mg3(Nd,Gd) intermetallic phase in the remelted area. The PEO coatings were more compact and less porous as compared with their counterpart coatings on the original, unmodified alloy material.The results of the presented work showed, among others, a suitable microstructure and chemical composition of some of the modified samples that could potentially exhibit enhanced corrosion resistance as opposed to the unmodified material. The corrosion testing will be part of a follow-up study. More compact PEO coatings formed on some of the modified surface layers likely represent, too, a more durable variant as compared to the original material.

This thesis deals with compares the procedures carried out in the cyclical load triaxial testing device according to CSN EN 13286-7, and the procedures performed in the United States of America. In the practical part elasticity moduls of mixed recycled material are experimentally compared with mixed recycled material containing binder(connective material) and with fine-grained soil in the cyclical load triaxial testing device. Further the thesis assesses the use of mixed recycled material in the construction of a third class low-load pavement.

This thesis dealt with thermal stability of magnesium alloy AZ91 prepared by severe plastic deformation, which leeds to fine grained structure. This structure is characterised by its inherent instability and this thesis tries to find out the value of critical temperature and rate of this instability, which manifests as grain coarsening.

Sandstone bodies of the Lower and Middle Turonian well exposed in the northwestern part of the Bohemian Cretaceous Basin represent deposits of the coarse-grained deltas. Aim of this paper is to interpret the architectures, stratigraphy and depositional regime of these bodies. The main architectural elements are clinoforms which show intermediate dip 4ř to 5ř of the delta slope and the direction of the progradation of the delta to the west-southwest. Correlation of the lithological profiles with the well - log data provided the stratigraphic classification of the outcrops in the studied area mostly to the genetic sequence TUR2. Correlations in one of the two stratigraphic cross - sections revealed the existence of the second delta body prograding into the basin from Most - Teplice Palaeohigh during TUR1. Detailed study of the sedimentary structures in the outcrops show high degree of reworking of foresets by tidal generated current. Two main directions of the paleocurrents results from the analysis - dominant current to the NW and subordinate current to the SE - SSE.