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Thesis (Ph. D.)--University of Chicago, 1942. / Lithoprinted. Includes bibliographical references.

The work reported by D. Bryce-Smith and G. F. Cox, along with several recent publications describing experimental results designed to elucidate the long disputed question of the structure of the Grignard reagent in ether stimulated the work reported here, in an effort to obtain additional evidence of the structure of the organomagnesium complex in benzene solvent. Since the primary objective of this work was to prepare organoberyllium compounds using the organomagnesium complexes in hydrocarbon solvents, it seemed an insight into the structure of these complexes would be beneficial in this work. The techniques used and experimental evidence obtained from the structure elucidation of the ethereal Grignard reagent have been most helpful in organization of the methods used to study the structure of organomagnesium halide complexes in benzene solvent. It seemed that an insight into the structure of these organomagnesium halide complexes in hydrocarbon solvents would be beneficial in accomplishing the second objective of this work. This objective was to prepare organoberyllium compounds using the organomagnesium halide complexes prepared in hydrocarbon solvents.

The starting material 3-sulfonyl-5-methoxy glutarimide was easily prepared via stepwise [3+3] annulation of N-benzyl R-sulfonylacetamide with unsaturated ester as we previously described. We wish we could build tetrahtdronaphthridine skeleton via stretching C-chain, modifying funtional group and RCM, then complete the synthesis of key intermediate of small molecule similar to RGD.

Thesis (Ph. D.)--Ohio State University, 1926. / Available online via OhioLINK's ETD Center

Thesis (M.S.)--Ohio State University, 1924. / Includes bibliographical references. Available online via OhioLINK's ETD Center

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