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A new metal–organic framework with ultra-high surface areaGrünker, Ronny, Bon, Volodymyr, Müller, Philipp, Stoeck, Ulrich, Krause, Simon, Mueller, Uwe, Senkovska, Irena, Kaskel, Stefan 21 July 2014 (has links) (PDF)
A new mesoporous MOF, Zn4O(bpdc)(btctb)4/3 (DUT-32), containing linear ditopic (bpdc2−; 4,4′-biphenylenedicarboxylic acid) and tritopic (btctb3−; 4,4′,4′′-[benzene-1,3,5-triyltris(carbonylimino)]tris-benzoate) linkers, was synthesised. The highly porous solid has a total pore volume of 3.16 cm3 g−1 and a specific BET surface area of 6411 m2 g−1, adding this compound to the top ten porous materials with the highest BET surface area.
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A new metal–organic framework with ultra-high surface areaGrünker, Ronny, Bon, Volodymyr, Müller, Philipp, Stoeck, Ulrich, Krause, Simon, Mueller, Uwe, Senkovska, Irena, Kaskel, Stefan 21 July 2014 (has links)
A new mesoporous MOF, Zn4O(bpdc)(btctb)4/3 (DUT-32), containing linear ditopic (bpdc2−; 4,4′-biphenylenedicarboxylic acid) and tritopic (btctb3−; 4,4′,4′′-[benzene-1,3,5-triyltris(carbonylimino)]tris-benzoate) linkers, was synthesised. The highly porous solid has a total pore volume of 3.16 cm3 g−1 and a specific BET surface area of 6411 m2 g−1, adding this compound to the top ten porous materials with the highest BET surface area.
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