Hindered-bed separators have been used in several different mineral processing fields for many years. Recent improvements in designs have led to the development of the CrossFlow separator. This new design employs a tangential feed system that has shown promise in several applications. This paper investigates the use of this relatively new technology to upgrade heavy mineral concentrates using Florida type ores. The intended use of this separatory device in this particular application is the removal of gangue quartz from other valuable heavy minerals such as ilmenite, leucoxene, rutile, zircon, and staurolite. The results of two different pilot-scale in-plant testing investigations are discussed. In general, quartz rejections in excess of 80% were achieved while maintaining TiO2 and heavy mineral recoveries above 98% and 99%, respectively. In addition to field test work, two separate unit models have been developed. The first model is an empirical investigation into understanding unit operation and functionality. The second model is a statistical prediction of unit operation based on specific field test work. These models can be used to effectively scale-up a CrossFlow unit for full-scale installation at any Florida heavy mineral sands operation. Emphasis is placed on unit capacity and other operational parameters such as elutriation flowrate and bed level. / Master of Science

The Old Hickory mine is a world class placer titanium deposit located at the boundary of the Coastal Plain and the Piedmont in Virginia, astride the Sussex-Dinwiddie county line (77°34' W Long, 36°55'N Lat., Cherry Hill Quad). The Old Hickory deposit, discovered in 1987 by C. R. Berquist, was opened as a commercial mine in 1997, and is presently operated by Iluka Resources. Heavy minerals constitute an average of 8% of the sediment, but locally reach concentrations as rich as 60%. The ore minerals, in order of decreasing concentrations, are ilmenite, rutile, and zircon, which are believed to have been derived from weathering of Piedmont and Blue Ridge sources. After fluvial transport to the coast, the ore minerals were redistributed laterally along the coast by longshore currents, and ultimately concentrated by intense wave action, probably generated by large storms. The ores occur over an area of 8 km x 3 km, with ore minerals being found from the surface to up to depths of 12 meters, and appear to occur in at least two distinct ore horizons. This study examines the general ore mineralogy and differences in the mineralogy, grain sizes, secondary textures, and geochemistry of the ore minerals in the two distinct ore zones. Distinguishable differences between the two zones include a slightly coarser grain size, more angular grains of rutile, and a higher percentage of accessory minerals (epidote, garnet, etc) in the younger zone. Approximately 40% of all the ilmenite grains contain exsolution lamellae of hematite, a residual texture from the time of original ilmenite crystallization. Weathering of these ilmenite grains has preferentially dissolved out the hematite while preserving the original texture; thus the weathering increases the titanium content of the ore by removing some of the iron. The weathering also affects the distribution of minor elements such as aluminum, manganese, and chromium. At Old Hickory, the zircon population can be divided into two main types (thin, elongate rounded pink prisms, and short, thicker white to clear prisms) that may represent either multiple source regions or multiple generations of heavy mineral deposition. The variations in grain size, angularity, and rutile content are likely to be mappable and may prove useful in continuing stratigraphic studies, and in distinguishing separate ore zones. / Master of Science

Los sedimentos de edad Cenozoico en el sur de Peru, son respuestas de una compleja interaccion de geodinamica activa y sedimentacion, de los cuales es conspicuo de la tectonica de los Andes Centrales. Mediante la combinacion de analisis multi-metodos en minerales pesados detriticos, es posible restringir la historia de levantamiento y exhumacion de los bordes de cuencas sedimentarias en el sur de Peru. Los resultados revelan que los sedimentos cenozoicos en el sur de Peru son deltas de grano grueso depositados desde hace 30 Ma, y son consecuencia de levantamientos simultaneos de la Cordillera de la Costa y la Cordillera Occidental.

Thesis (PhD (Physics))--University of Stellenbosch, 2011. / ENGLISH ABSTRACT: Radioactivity is well known and well understood, but its usefulness in industrial applications to optimise processes or increase economic viability is not yet fully utilised by many industries. This study focuses on the measurement of natural radioactivity and its application in heavy mineral separation and vineyard soil classification. The gamma radiometry set-up consisted of a high purity germanium detector, a Marinelli beaker as sample container and associated electronics. It was calibrated for laboratorybased measurements by minimising the background radiation with the use of lead castle and energy and resolution calibrations. Furthermore, detection parameters were optimised; these included the counting time, the selection of gamma rays used for analysis of a sample, the peak area calculation for the detector dead time and the detector efficiency. Given that the samples had different densities and volumes, the detector efficiency had to be corrected for volume and density effects. After implementation of the corrections and optimisations the detection system was tested and found able to accurately measure radioactivity concentrations. The systematic measurement errors for 238U were 5.1 % in the case of the heavy mineral sands and 34.3 % for the vineyard soils, 4.5 % for the 232Th concentrations and 4.7 % for 40K concentrations. Statistical errors were kept below 2 %. The application of radiometry has not been done before at any South African heavy mineral separation plant. For this reason radiometry is suggested as an easier, faster and cheaper alternative to X-ray fluorescence (XRF) for effective implementation of grade control for zircon to improve the cost benefit of the heavy mineral separation process. Zircon is an example of a heavy mineral that is worldwide in demand with a consumption of more than a million tonnes per year. It is used in a wide range of industrial applications and products that include tiles, sanitary ware and plasma displays. South Africa is the second largest producer of zircon in the world and also has the second largest reserve of available zircon, making this mineral a viable source of income for several years to come. Radioactivity, in the form of uranium and thorium, and other impurities such as iron oxide and titanium oxide are found in the crystal lattice of zircon. For it to be a sellable product, the sum of the uranium and thorium concentrations must be less than 500 parts per million for prime or first grade zircon and less than 1000 parts per million for second grade zircon. At present the concentrations of uranium and thorium in zircon concentrates are measured on a whole rock basis by XRF during and at the end of the processing cycle before the final products are ready to be shipped. This is not an ideal situation as the grab samples are taken periodically and are not necessarily representative of the stream or final assignment and has resulted in significant losses by the producer. The solution is to accurately measure the uranium and thorium concentrations fast or immediately, preferably the measurements must be made online and in real time so that processing decisions can be implemented quickly to optimise the final product. Heavy mineral sand samples were obtained from the various separation processes in a Mineral Separation Plant and their 238U and 232Th concentrations determined. The results indicated that the samples’ uranium to thorium ratios together with their total concentrations can be used to differentiate between the samples (i.e. separation processes). The measurement results were compared with those obtained with XRF. The correlations with radiometry were excellent for the uranium (r2 = 0.992), thorium (r2 = 0.998) and total concentrations (r2 = 0.998). Radiometric measurements were also conducted by decreasing the counting time from 3600 s to 1 s to investigate its effect on the accuracy of the results. Correlations between the different times and 3600 s ranged from excellent to good. The obtained results are then used to recommend that radiometry is used in a Mineral Separation Plant to verify that the zircon and zirkwa meet the specifications, to optimise the entrance feed and the other separation processes and to monitor the tailings streams. Finally the practical aspects of the implementation of radiometry are discussed. As a second application was radiometry applied in an agricultural pilot study to demonstrate the applicability of radiometry as a possible useful tool in soil classification. The creation of a vineyard is a long term and expensive investment and its yield and quality will be influenced by many factors such as the type of soil, viticultural preparations and climate. Information on the different soil types in a vineyard is therefore indispensable for the optimisation of land use with respect to vine cultivar, wine quality and production. Soil samples were obtained from Kanonkop, Simonsig and Spier vineyards and their 238U, 232Th and 40K concentrations determined, assuming that fertilisers would have no effect on the results. The difference in 40K concentrations were related to the clay fraction of the soil and demonstrated that the Kanonkop and Simonsig soils are fine-grained and clay-rich compared to the sandy coarse-grained soils of Spier. The uranium and thorium concentrations were indicators of whether the mineralogy of the soil is the same as the underlying bedrock as well as soil maturity. The measurement results were compared with those obtained with XRF. The correlation with radiometry were poor for the uranium concentrations (r2 = 0.314), as many of the samples concentrations were below the XRF detection limit. The correlations were excellent for both thorium (r2 = 0.985) and potassium (r2 = 0.999). As a positive result from the findings of the study was an in-situ measurement performed by Newman et al. for the radiometric mapping of a Simonsig vineyard for soil classification. / AFRIKAANSE OPSOMMING: Radioaktiwiteit is wel bekend en word goed verstaan, tog is die gebruik daarvan in industriele toepassings om prosesses te optimiseer of winsgrense te verhoog nog nie deur baie industrië ten volle benut nie. Hierdie studie fokus op die meting van natuurlike radioaktiwiteit en die toepassing daarvan in swaar mineraal skeiding en wingerd grond klassifikasie. Die gamma radiometrie opstelling het bestaan uit ‘n hoë suiwerheid germanium detektor, 'n Marinelli beker as monster houer en verwante elektronika. Dit was gekalibreer vir laboratorium gebaseerde metings deur die vermindering van die agtergrondstraling met die gebruik van lood kasteel en energie en resolusie kalibrasies. Verder was deteksie parameters geoptimaliseer, dit sluit in die teltyd, die keuse van gammastrale wat gebruik word vir die ontleding van 'n monster, die piek area berekening, die korreksie vir die detektor se dooie tyd en die detektor doeltreffendheid. Gegee dat die monsters van mekaar verskil het in terme van dighteid en volume was dit nodig om die detektor doeltreffendheid te korrigeer vir volume en digtheid effekte. Na die implementering van die korreksies en optimalisasie was die detektor stelsel getoets en was gevind dat radioaktiwiteit konsentrasies akkuraat gelewer kan lewer. Die sistematiese meet foute vir 238U was 5.1 % vir die mineraal sand en 34.3 % vir wingerd grond, 4.5 % vir 232Th konsentrasies en 4.7 % vir 40K konsentrasies. Statistiese foute was onder 2 % gehou. Die toepassing van radiometrie was nog nie voorheen by enige Suid-Afrikaanse swaar mineraal skeidings aanleg gedoen nie. Vir die rede is radiometrie voorgestel as ‘n makliker, vinniger en goedkoper alternatief teenoor XSF vir effektiewe implementering van graad beheer vir zirkon om die koste voordeel van die swaar mineral skeiding proses te verbeter. Zirkon is ‘n voorbeeld van ‘n swaar mineraal wat wêreldwyd in aanvraag is met ‘n verbruik van meer as ‘n miljoen ton per jaar. Dit word in ‘n wye reeks van industriele toepassings en produkte gebruik onder andere teëls, sanitêre ware en plasma skerms. Suid Afrika is die tweede grootste vervaardiger van zirkon in die wêreld en het ook die tweede grootste reserwe van besikbare zirkon. Dit veroorsaak dat die mineraal ‘n lewensvatbare brom van inkomste is vir nog etlike jare. Radioaktiwiteit, in die vorm van uraan en thorium, word tesame met ander onsuiwerhede soos ysteroksied en titaanoksied in zirkon se kristal rooster gevind. Om ‘n verkoopbare produk te wees moet die som van die uraan en thorium konsentrasies minder wees as 500 dele per miljoen vir prima en eerste graad zirkon en minder wees as 1000 dele per miljoen vir tweede graadse zirkon. Huidiglik word die uraan en thorium konsentrasies in die zirkon konsentraat gemeet op ‘n heel gesteente basis met X-straal fluoroskopie (XSF) gedurende en op die einde van die prosesering siklus net voor die finale produk reg is om versend te word. Dit is nie die ideale situasie nie, want die monsters word periodies geneem en is nie noodwendig verteenwoordigend van die stroom of die finale produk nie en het al tot beduidende verliese deur die vervaardiger gelei. Die oplossing is om die uraan en thorium konsentrasies vinnig of onmiddelik te meet, verkieslik moet die metings inlyn en intyds gedoen word om verwerkings besluite vinnig geimplementeer kan word om die finale produk te optimaliseer. Swaar mineraal sand monsters was verkry van die verskeie skeidingsprosesse in ‘n Mineraal Skeidings Aanleg en hul 238U en 232Th konsentrasies bepaal. Die resultate het aangetoon dat die monsters se uraan en thorium verhoudings saam met hul totale konsentrasies gebruik kan word om te onderskei tussen die monsters (oftewel die skeiding prosesse). Die meting resultate was vergelyk met dié verkry met XSF. Die korrelasies met radiometrie was uitstekend vir die uraan (r2 = 0.992), thorium (r2 = 0.998) en totale konsentrasies (r2 = 0.998). Radiometriese metings was ook uigevoer deur die teltyd te verminder van 3600 s tot 1 s om die uitwerking daarvan op die akkuraatheid van die resultate te ondersoek. Korrelasies tussen die verskillende tye en 3600 s het gewissel van uitstekend tot goed. Die bevindinge was dan gebruik om aan te beveel dat radiometrie in a Mineraal Skeidings Aanleg gebruik kan word om te verifeer dat daar aan die zirkon en zirkwa spesifikasies voldoen word, om die begin voer en ander skeidings prosesse te optimaliseer en ook die uitskot strome te monitor. Laastens is die praktiese aspekte van die implementering van radiometrie bespreek. Vir die tweede toepassing was radiometrie toepgepas in ‘n loods studie in die landbou om die toepaslikheid van radiometrie as ‘n moontlike nuttige instrument in grond klassifikasie te demonstreer. Die skepping van ‘n wingerd is ‘n lang termyn en duur belegging waarvan die opbrengs en kwaliteit beinvloed sal word deur vele faktore, onder andere die tipe grond, wynbou voorbereidings en die klimaat. Inligiting oor die verskillende grond tipes in ‘n wingerd is daarom onmisbaar vir die optimalisering van land gebruik in betrekking tot die wingerdstok kultivar, wyn kwaliteit en produksie. Radiometrie is toegepas om te demonstreer die toepaslikheid daaran as ‘n moontlike nuttige instrument in grond klassifikasie. Grondmonsters was verkry vanaf Kanonkop, Simonsig en Spier wingerde en hul 238U, 232Th en 40K konsentrasies bepaal met die aanname dat kunsmis nie ‘n uitwerking op die resultate sou hê nie. Die verskil in 40K konsentrasies was verwant aan die kleifraksie van die grond en het getoon dat die Kanonkop en Simonsig gronde is fyn korrelrig en kleiryk is in vergelyking met die sanderige growwe korrel grond van Spier. Die uraan en thorium konsentrasies het gedui op die samestelling van die grond en ook aangedui watter grond dieselfde is as die onderliggende rots. Die meting resultate was vergelyk met dié verkry met XSF. Die korrelasie met die radiometrie was sleg vir die uraan konsentrasies (r2 = 0.314) aangesien baie van die monster konsentrasies laer was as die XSF deteksie limiet. Die korrelasies was uitstekend vir beide thorium (r2 = 0.985) en kalium (r2 = 0.999). As ‘n positiewe resultaat van die studie se bevindinge was ‘n in-situ meting gedoen deur Newman et al. om ‘n Simonsig wingerd radiomeries te karteer vir grond klassifasie.

Master of Science / Department of Geology / Matthew W. Totten / Shales are generally regarded as organic rich source and seal rocks that are unworthy of the amount of research that has been given to their coarser-grained counterparts, even though shales comprise nearly two-thirds of Earth’s sedimentary record (Potter et al., 1980). The Woodford Shale is acknowledged as a prolific source rock across much of Oklahoma and the midcontinent (Lambert, 1990). Up to 8% world's original hydrocarbon reserves are estimated to have been sourced by the Woodford and its equivalents (Fritz et al., 1991). Study of the heavy-mineral fraction in sedimentary rocks is important because it can indicate provenance and some of the diagenetic changes that occur in sedimentary rocks. This goal of this study is to describe the heavy-mineral fraction of eight Woodford Shale samples from the Greater Anadarko Basin of Oklahoma, and determine whether or not the constituents that make up the heavy-mineral fraction have any impact on the process of thermal maturity within source rocks. This study utilizes a method designed to efficiently separate the heavy-mineral fraction of shale samples. Scanning electron microscope (SEM) and Energy Dispersive X-ray Spectroscopy (EDS) are used in this study to identify mineralogy, grain size, composition and shape. Mineral distributions in the samples have been determined from point counting. The weight percent of the heavy mineral fraction was calculated for each of the samples. This was then compared to their location within the basin, depth, vitrinite reflectance and total organic carbon (TOC). We found that as the thermal maturity increase, the weight percent of heavy minerals also increases. Pyrite (FeS₂) was the most abundant heavy mineral found in the Woodford samples used in this study. From analyzing the different forms of pyrite, it was found that as thermal maturity increases, framboidal pyrite alters to euhedral pyrite.

The Taimyr Peninsula is a key element in the circum-Arctic region and represents thenorthern margin of the Siberian Craton. The Taimyr Peninsula is a late Paleozoic fold andthrust belt and preserves late Paleozoic through Mesozoic siliciclastic sedimentarysuccessions and providing an ideal location to investigate the Paleozoic to Mesozoictectonic evolution associated with the Uralian orogeny, the Siberian Trap magmatism andopening of Amerasia Basin within a circum-Arctic framework. Multiple methods areadopted, including petrography, heavy mineral analysis and detrital zircon U-Pbgeochronology for provenance investigation, apatite fission track dating for revealingthermal history and balanced cross section for understanding the deformation style ofTaimyr.The results of this thesis indicate that the Late Carboniferous to Permian sediments ofsouthern Taimyr were deposited in a pro-foreland basin of the Uralian orogen during theUralian orogeny. In the Triassic, the siliciclastic deposits still show a strong Uraliansignature but the initiation of Siberian Trap-related input begins to be significant. Erosionof the Uralian orogen has reached a deep metamorphic level. By Late Jurassic andCretaceous time, the deposition setting of southern Taimyr is an intracratonic basin.Erosion and input from Uralian sources waned while greater input from SiberianTrap-related rocks of the Taimyr region dominated. The Taimyr Peninsula underwent atleast three cooling and uplifting episodes: 280 Ma, 250 Ma and 220 Ma, corresponding tothe Uralian orogeny, the Siberian Traps and the late Triassic transpression. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 1: Manuscript. Paper 2: In press. Paper 3: Manuscript. Paper 4: Manuscript.</p>

The objective of the treatise is to review the sample methodology and the exploration methods at a heavy mineral sands deposit. The level of confidence and the risk associated with the resource calculations will be established based on the sample methodology. Two drilling methods used at Hillendale are compared statistically and visually. It is clear from the comparison that the Wallis Aircore (WAC) method is significantly better than the Reverse Circulation (RCN) method. This is evident also when comparing results of the two methods with the recovery from the mined out areas. The WAC drilling method reduces the risk of downhole contamination due to the change in the drilling method allowing air to be forced back in an inner tube after the sample is collected compared to the air blowout of the RCN method. The WAC method reduces the variability introduced in the sample collection as compared to the RCN method. The average calculated value (for total heavy minerals (THM) and Ilmenite) of the global population for the two methods is similar. The reduced variability in the sample population of the WAC method results in a lower population being required for the confidence interval about the mean at a 95% confidence level. The lower number of required samples results in a lowering of project cost. Blockmodels created from the two drilling methods are compared statistically (mode, median, standard deviation). The global mean of the input data compares well with the global mean of the estimated blockmodel. In reconciling the resource blockmodels with actual production data, the variability as introduced by the RCN drilling method is clear. The WAC drilling information produces a blockmodel with an acceptable level of variance (deviation of the geological model from the actual values obtained during mining) as defined by Hillendale mine management of less than 10%. This is determined by reconciling the estimated geological blockmodel for a specific mined out area against the actual tonnages and plant recovery values achieved in the same area. Ultimately, because the drill spacing is standard in the mining operation under study, the required confidence in the mean might not be achieved by either of the two drilling methods in certain portions of the mine, but the results from the WAC method will be closer to the reality than the RCN method with the same number of drillholes. Three main risks are identified in the sample methodology; they have a high probability to occur or have a high cost impact. The risk inherent in sampling and analysis is the most important of the risks identified in this study. The risk can be effectively reduced by implementing a quality assurance and quality control programme (QAQC). The other high risks are introduced by the drilling method and drillhole spacing. The risk can be reduced by continuous improvement and keeping up to date with new developments in the industry such as improved drilling techniques and by improved knowledge of the ore-body. The knowledge will help in understanding the risk - It may become clear in the text how this can reduce the risk. In conclusion, the improvement and implementation of systems such as improved drilling technique and quality assurance and quality control programmes enables one to establish an acceptable confidence level in the resource calculation as well as reducing the inherent risk to an acceptable level for future decisions. Copyright / Dissertation (MSc)--University of Pretoria, 2012. / Geology / unrestricted

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